ACS Publications. Most Trusted. Most Cited. Most Read
My Activity

Anatase TiO2 Activated by Gold Nanoparticles for Selective Hydrodeoxygenation of Guaiacol to Phenolics

View Author Information
State Key Laboratory of Catalysis, Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, P. R. China
State Key Laboratory of Fine Chemicals, PSU-DUT Joint Center for Energy Research, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, P. R. China
§ College of Environmental and Chemical Engineering, Dalian University, Dalian 116622, China
Cite this: ACS Catal. 2017, 7, 1, 695–705
Publication Date (Web):December 5, 2016
Copyright © 2016 American Chemical Society

    Article Views





    Other access options
    Supporting Info (1)»


    Abstract Image

    Gold nanoparticles on a number of supporting materials, including anatase TiO2 (TiO2-A, in 40 nm and 45 μm), rutile TiO2 (TiO2-R), ZrO2, Al2O3, SiO2 , and activated carbon, were evaluated for hydrodeoxygenation of guaiacol in 6.5 MPa initial H2 pressure at 300 °C. The presence of gold nanoparticles on the supports did not show distinguishable performance compared to that of the supports alone in the conversion level and in the product distribution, except for that on a TiO2-A-40 nm. The lack of marked catalytic activity on supports other than TiO2-A-40 nm suggests that Au nanoparticles are not catalytically active on these supports. Most strikingly, the gold nanoparticles on the least-active TiO2-A-40 nm support stood out as the best catalyst exhibiting high activity with excellent stability and remarkable selectivity to phenolics from guaiacol hydrodeoxygenation. The conversion of guaiacol (∼43.1%) over gold on the TiO2-A-40 nm was about 33 times that (1.3%) over the TiO2-A-40 nm alone. The selectivity of phenolics was 87.1%. The products are mainly phenolic compounds with no aromatics and saturated hydrocarbons such as cyclohexane. The gold particle size ranging from 2.7 to 41 nm and water content were found to significantly affect the Au/TiO2-A-40 nm catalyst activity but not the product selectivity. The reaction rates of 0.26 and 0.91 (min–1 g-cat–1 cm3) were determined for guaiacol hydrogenation and catechol hydrogenation, respectively. Bimolecular methylation was established as the dominant mechanism for methyl group transfer among the phenolics. Two major pathways of guaiacol hydrogenation to phenolics over the 0.4Au-19 nm/TiO2-A-40 nm are proposed: (1) direct hydrogenation of guaiacol to form phenol and methanol, (2) hydrodehydroxylation of catechol intermediate from the transmethylation between guaiacol and phenol.

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.


    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. You can change your affiliated institution below.

    Supporting Information

    Jump To

    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acscatal.6b02368.

    • X-ray diffraction (XRD) of samples and supports; preparation method of 0.4Au-3 nm/TiO2-A-40 nm; XPS spectra of 0.4Au-19 nm/TiO2-A-40 nm (Au 4f); TEM of 0.4Au-3 nm/TiO2-A-40 nm; average particle size of 0.4Au-3 nm/TiO2-A-40 nm; effect of gold particle size on guaiacol hydrogenation; gold surface atoms of Au NPs (PDF)

    Terms & Conditions

    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system:

    Cited By

    This article is cited by 81 publications.

    1. Xiaohong Ren, Qian Qiang, Zhuohua Sun, Ting Wei, Xiaoqiang Yu, Zeming Rong, Changzhi Li. Water Splitting Integrated with Self-Transfer Hydrogenolysis for Efficient Demethoxylation of Guaiacols to Phenols over the Ni/MgO Catalyst. ACS Catalysis 2024, 14 (7) , 5247-5259.
    2. Qi Fang, Hong Du, Xiaoqiang Zhang, Yunjie Ding, Z. Conrad Zhang. Alteration of Hydrodeoxygenation Pathways of Ni/TiO2-A Catalyst through Controlled Regulation of Strong Metal–Support Interactions and Surface Acidity. ACS Catalysis 2024, 14 (7) , 5047-5063.
    3. Zhong-Qiu Liu, Yuan-Yuan Yu, Yu-Jing Liu, An-Guo Ying, Xiao-Long Zhang, Ye Wang. Unlocking Birch Lignin Hydrocracking through Tandem Catalysis: Unraveling the Role of Moderate Hydrogen Spillover. ACS Catalysis 2024, 14 (3) , 2115-2126.
    4. Hao Zhou, Kepeng Song, Yong Guo, Xiaohui Liu, Yanqin Wang. Selective Production of 4-Propylphenol from Lignin Oil without Exogenous Hydrogen over a RuNi/NiAl2O4 Catalyst. ACS Sustainable Chemistry & Engineering 2023, 11 (41) , 15052-15059.
    5. Jie Xia, Lin Dong, Xiaohui Liu, Roman Chernikov, Mohsen Shakouri, Yongfeng Hu, Yong Guo, Jianjian Wang, Kepeng Song, Peijun Hu, Yanqin Wang, Haifeng Wang. Identifying the Activity Origin of a Single-Atom Au1/Nb2O5 Catalyst for Hydrodeoxygenation of Methylcatechol: A Stable Substitutional Au+ Site. ACS Catalysis 2023, 13 (9) , 6093-6103.
    6. Man Lang, Hao Li. Toward Value-Added Arenes from Lignin-Derived Phenolic Compounds via Catalytic Hydrodeoxygenation. ACS Sustainable Chemistry & Engineering 2022, 10 (40) , 13208-13243.
    7. Liang Xiang, Mengran Liu, Guoli Fan, Lan Yang, Feng Li. MoOx-Decorated ZrO2 Nanostructures Supporting Ru Nanoclusters for Selective Hydrodeoxygenation of Anisole to Benzene. ACS Applied Nano Materials 2021, 4 (11) , 12588-12599.
    8. Lingxiao Li, Tingting Zhang, Zhiruo Guo, Xiaohui Liu, Yong Guo, Yongmin Huang, Yanqin Wang. Unraveling the Role of Metal in M/NiAl2O4 (M = Pt, Pd, Ru) Catalyst for the Self-Reforming-Driven Hydrogenolysis of Lignin. Industrial & Engineering Chemistry Research 2021, 60 (31) , 11699-11706.
    9. Xiaowa Nie, Wenjia Wan, Zeshi Zhang, Yonggang Chen, Michael J. Janik, Chunshan Song, Xinwen Guo. Mechanistic Insight into the Hydrodeoxygenation of Hydroquinone over Au/a-TiO2 Catalyst. The Journal of Physical Chemistry C 2021, 125 (12) , 6660-6672.
    10. Xinchao Wang, Peixuan Wu, Zhuangqing Wang, Leilei Zhou, Yanchun Liu, Haiyang Cheng, Masahiko Arai, Chao Zhang, Fengyu Zhao. Chlorine-Modified Ru/TiO2 Catalyst for Selective Guaiacol Hydrodeoxygenation. ACS Sustainable Chemistry & Engineering 2021, 9 (8) , 3083-3094.
    11. Lingxiao Li, Lin Dong, Didi Li, Yong Guo, Xiaohui Liu, Yanqin Wang. Hydrogen-Free Production of 4-Alkylphenols from Lignin via Self-Reforming-Driven Depolymerization and Hydrogenolysis. ACS Catalysis 2020, 10 (24) , 15197-15206.
    12. Na Ji, Xinyong Diao, Xinxin Li, Zhichao Jia, Yujun Zhao, Xuebin Lu, Chunfeng Song, Qingling Liu, Changzhi Li. Toward Alkylphenols Production: Lignin Depolymerization Coupling with Methoxy Removal over Supported MoS2 Catalyst. Industrial & Engineering Chemistry Research 2020, 59 (39) , 17287-17299.
    13. Ahmed Halilu Ahmad Abulfathi Umar Yahaya Umar Balarabe Mhd Abd Cader Mhd Haniffa Khadija Munawar Kiran Sunku Putla Sudarsanam . Advances in Single-Atom Catalysts for Lignin Conversion. 2020, 93-125.
    14. Jingbo Mao, Bin Zhao, Jinxia Zhou, Li Zhang, Fan Yang, Xinwen Guo, Z. Conrad Zhang. Identification and Characteristics of Catalytic Quad-Functions on Au/Anatase TiO2. ACS Catalysis 2019, 9 (9) , 7900-7911.
    15. Xiaoqiang Zhang, Peifang Yan, Bin Zhao, Kairui Liu, Mayfair C. Kung, Harold H. Kung, Shanyong Chen, Z. Conrad Zhang. Selective Hydrodeoxygenation of Guaiacol to Phenolics by Ni/Anatase TiO2 Catalyst Formed by Cross-Surface Migration of Ni and TiO2. ACS Catalysis 2019, 9 (4) , 3551-3563.
    16. Xiaoming Huang, Jasper M. Ludenhoff, Mike Dirks, Xianhong Ouyang, Michael D. Boot, Emiel J. M. Hensen. Selective Production of Biobased Phenol from Lignocellulose-Derived Alkylmethoxyphenols. ACS Catalysis 2018, 8 (12) , 11184-11190.
    17. Wenjia Wan, Xiaowa Nie, Michael J. Janik, Chunshan Song, Xinwen Guo. Adsorption, Dissociation, and Spillover of Hydrogen over Au/TiO2 Catalysts: The Effects of Cluster Size and Metal–Support Interaction from DFT. The Journal of Physical Chemistry C 2018, 122 (31) , 17895-17916.
    18. Zhuohua Sun, Bálint Fridrich, Alessandra de Santi, Saravanakumar Elangovan, and Katalin Barta . Bright Side of Lignin Depolymerization: Toward New Platform Chemicals. Chemical Reviews 2018, 118 (2) , 614-678.
    19. Xinru Wu, Hongwei Zhang, Cejun Hu, Xiaojun Bao, Pei Yuan. Advances in enhancing hydrodeoxygenation selectivity of lignin-derived oxygenates: From synthetic strategies to fundamental techniques. Green Energy & Environment 2024, 8
    20. Xian Wu, Ewoud Smet, Francesco Brandi, Deepak Raikwar, Zhenlei Zhang, Bert U. W. Maes, Bert F. Sels. Advancements and Perspectives toward Lignin Valorization via O ‐Demethylation. Angewandte Chemie 2024, 136 (10)
    21. Xian Wu, Ewoud Smet, Francesco Brandi, Deepak Raikwar, Zhenlei Zhang, Bert U. W. Maes, Bert F. Sels. Advancements and Perspectives toward Lignin Valorization via O ‐Demethylation. Angewandte Chemie International Edition 2024, 63 (10)
    22. Gilles De Smet, Xingfeng Bai, Bert U. W. Maes. Selective C(aryl)–O bond cleavage in biorenewable phenolics. Chemical Society Reviews 2024, 19
    23. Xinze Du, Hongjun Fan, Shenglin Liu, Z. Conrad Zhang. Selective nucleophilic α-C alkylation of phenols with alcohols via Ti=Cα intermediate on anatase TiO2 surface. Nature Communications 2023, 14 (1)
    24. Shangjian Li, Kui Wu, Dan Wang, Hongyun Yang, Zhigang Shen, Weiyan Wang. Single-atom Au atomically trapped in WO3− catalyst for selective demethoxylation of lignin-derived guaiacols. Applied Surface Science 2023, 638 , 158128.
    25. Surachet Hongkailers, Adisak Pattiya, Napida Hinchiranan. Hydrodeoxygenation of Oxygenates Derived from Biomass Pyrolysis Using Titanium Dioxide-Supported Cobalt Catalysts. Molecules 2023, 28 (22) , 7468.
    26. Jack Jarvis, Hao Xu, Yimeng Li, Zhaofei Li, Wenping Li, Shijun Meng, Lo-Yueh Chang, Lijia Liu, Hua Song. Methane-assisted selective bio-oil deoxygenation for high-quality renewable fuel production: A rational catalyst design and mechanistic study. Chemical Engineering Journal 2023, 475 , 146052.
    27. Jinliang Yan, Zhiyu Li, Yuchun Zhang, Rundong Liu, Ling Zhou, Peng Fu. Hydrodeoxygenation of lignin phenolic derivatives to aromatics: A review of catalyst functionalization for targeted deoxygenation and active site modification strategies. Fuel Processing Technology 2023, 250 , 107914.
    28. Zhuojie Zhong, Bowen Luo, Chengyin Lin, Tao Yin, Zhipeng Tian, Chao Wang, Ying Chen, Yanxue Wu, Riyang Shu. Ultrafast microfluidic preparation of highly dispersed Ru/TiO2 catalyst for the hydrodeoxygenation of lignin-derived phenolic compounds. Fuel 2023, 340 , 127567.
    29. Bin Zhao, Xiaoqiang Zhang, Jingbo Mao, Yanli Wang, Guanghui Zhang, Zongchao Conrad Zhang, Xinwen Guo. Crystal-Plane-Dependent Guaiacol Hydrodeoxygenation Performance of Au on Anatase TiO2. Catalysts 2023, 13 (4) , 699.
    30. Xiaohong Ren, Zhuohua Sun, Jiqing Lu, Jinling Cheng, Panwang Zhou, Xiaoqiang Yu, Zeming Rong, Changzhi Li. Hydrodeoxygenation of guaiacol to phenol using endogenous hydrogen induced by chemo-splitting of water over a versatile nano-porous Ni catalyst. Green Chemistry 2023, 25 (5) , 1955-1969.
    31. Huaizhou Yang, Xiaotian Zhu, Helda Wika Amini, Boy Fachri, Majid Ahmadi, Gert H. ten Brink, Peter J. Deuss, Hero J. Heeres. Efficient Cu-based catalysts for the selective demethoxylation of guaiacols. Applied Catalysis A: General 2023, 654 , 119062.
    32. Weiping Deng, Yunchao Feng, Jie Fu, Haiwei Guo, Yong Guo, Buxing Han, Zhicheng Jiang, Lingzhao Kong, Changzhi Li, Haichao Liu, Phuc T.T. Nguyen, Puning Ren, Feng Wang, Shuai Wang, Yanqin Wang, Ye Wang, Sie Shing Wong, Kai Yan, Ning Yan, Xiaofei Yang, Yuanbao Zhang, Zhanrong Zhang, Xianhai Zeng, Hui Zhou. Catalytic conversion of lignocellulosic biomass into chemicals and fuels. Green Energy & Environment 2023, 8 (1) , 10-114.
    33. Fan Wang, Chenglong Wen, Mohong Lu, Peng Zhang, Jie Zhu, Mingshi Li, Yuhua Shan, Chunshan Song. SBA-15-supported ultrastable Mo2N@CN catalysts for hydrodeoxygenation of guaiacol. Biomass and Bioenergy 2023, 168 , 106680.
    34. Kairui Liu, Guangjin Hou, Pan Gao, Xuezhong Nie, Shi Bai, Michael J. Janik, Z. Conrad Zhang. Evolution of multiple spillover hydrogen species on anatase titanium dioxide. Cell Reports Physical Science 2022, 3 (12) , 101190.
    35. . Direct Lignin C – OAr , ArO – Ar or C – Ar Bonds Cleavage without First Activation of the Adjacent Chemical Bonds. 2022, 147-187.
    36. Beilei Cui, Hua Wang, Jinyu Han, Qingfeng Ge, Xinli Zhu. Crystal-phase-depended strong metal-support interactions enhancing hydrodeoxygenation of m-cresol on Ni/TiO2 catalysts. Journal of Catalysis 2022, 413 , 880-890.
    37. Kyungho Lee, Yaxuan Jing, Yanqin Wang, Ning Yan. A unified view on catalytic conversion of biomass and waste plastics. Nature Reviews Chemistry 2022, 6 (9) , 635-652.
    38. Beilei Cui, Hua Wang, Qingfeng Ge, Xinli Zhu. Size-Dependent Strong Metal–Support Interactions of Rutile TiO2-Supported Ni Catalysts for Hydrodeoxygenation of m-Cresol. Catalysts 2022, 12 (9) , 955.
    39. Huaizhou Yang, Wang Yin, Xiaotian Zhu, Peter J. Deuss, Hero J. Heeres. Selective Demethoxylation of Guaiacols to Phenols using Supported MoO 3 Catalysts. ChemCatChem 2022, 14 (16)
    40. Yanlin Xu, Zhuoyi Liu, Bin Liu, Bin Dong, Yichuan Li, Yanpeng Li, Hailing Guo, Yongming Chai, Chenguang Liu. Hydrodeoxygenation of guaiacol to bio-hydrocarbons over Ni catalyst supported on activated coconut carbon in alkaline condition. Biomass and Bioenergy 2022, 163 , 106506.
    41. Zihang Wang, An Wang, Lan Yang, Guoli Fan, Feng Li. Supported Ru nanocatalyst over phosphotungstate intercalated Zn-Al layered double hydroxide derived mixed metal oxides for efficient hydrodeoxygenation of guaiacol. Molecular Catalysis 2022, 528 , 112503.
    42. Xinchao Wang, Zhuangqing Wang, Leilei Zhou, Yanchun Liu, Yinze Yang, Liyan Zhang, Zongling Shang, Hui Li, Tingting Xiao, Chao Zhang, Fengyu Zhao. Efficient hydrodeoxygenation of guaiacol to phenol over Ru/Ti–SiO 2 catalysts: the significance of defect-rich TiO x species. Green Chemistry 2022, 24 (15) , 5822-5834.
    43. Yong Guo, Yanqin Wang. Lignin Upgrading. 2022, 507-558.
    44. Zhiquan Yu, Yao Wang, Guoqiang Zhang, Zhichao Sun, Ying-Ya Liu, Chuan Shi, Wei Wang, Anjie Wang. A highly dispersed Ni3P/HZSM-5 catalyst for hydrodeoxygenation of phenolic compounds to cycloalkanes. Journal of Catalysis 2022, 410 , 294-306.
    45. Qi Liu, Liangyu Zou, Yangqiang Huang, Zhiwu Liang. Kinetics of the in−situ hydrogenation of phenol with formic acid as a hydrogen source. International Journal of Hydrogen Energy 2022, 47 (18) , 10239-10249.
    46. Fabian Morteo‐Flores, Alberto Roldan. The Effect of Pristine and Hydroxylated Oxide Surfaces on the Guaiacol HDO Process: A DFT Study. ChemPhysChem 2022, 23 (1)
    47. 钰 王. Research Progress of Niobium-Based Catalysts in the Depolymerization of Lignin. Advances in Material Chemistry 2022, 10 (01) , 6-12.
    48. Surachet Hongkailers, Yaxuan Jing, Yanqin Wang, Napida Hinchiranan, Ning Yan. Recovery of Arenes from Polyethylene Terephthalate (PET) over a Co/TiO 2 Catalyst. ChemSusChem 2021, 14 (19) , 4330-4339.
    49. Dongfei Xu, Jiaan Ren, Shengnan Yue, Xiujing Zou, Xingfu Shang, Xueguang Wang. One-Pot Synthesis of Al-P-O Catalysts and Their Catalytic Properties for O-Methylation of Catechol and Methanol. Materials 2021, 14 (20) , 5942.
    50. Bin Zhao, Guanghui Zhang, Jingbo Mao, Yanli Wang, Hong Yang, Xinwen Guo. The Effect of Gold Nanoparticles on the Catalytic Activity of NiTiO3 for Hydrodeoxygenation of Guaiacol. Catalysts 2021, 11 (8) , 994.
    51. Xinfeng Ren, Dongfei Xu, Yuchen Yin, Xiujing Zou, Yankai Wang, Xingfu Shang, Xueguang Wang. High Catalytic Performance and Sustainability of Zr Modified Aluminophosphate for Vapor-Phase Selective O-Methylation of Catechol with Methanol. Catalysts 2021, 11 (6) , 740.
    52. Xiaoxia Wu, Qingfeng Ge, Xinli Zhu. Vapor phase hydrodeoxygenation of phenolic compounds on group 10 metal-based catalysts: Reaction mechanism and product selectivity control. Catalysis Today 2021, 365 , 143-161.
    53. Xiaoqiang Zhang, Peifang Yan, Bin Zhao, Z. Conrad Zhang. Identification of electron-rich mononuclear Ni atoms on TiO 2 -A distinguished from Ni particles on TiO 2 -R in guaiacol hydrodeoxygenation pathways. Catalysis Science & Technology 2021, 11 (1) , 297-311.
    54. Xinchao Wang, Masahiko Arai, Qifan Wu, Chao Zhang, Fengyu Zhao. Hydrodeoxygenation of lignin-derived phenolics – a review on the active sites of supported metal catalysts. Green Chemistry 2020, 22 (23) , 8140-8168.
    55. Zhuohua Sun, Jinling Cheng, Dingsheng Wang, Tong‐Qi Yuan, Guoyong Song, Katalin Barta. Downstream Processing Strategies for Lignin‐First Biorefinery. ChemSusChem 2020, 13 (19) , 5199-5212.
    56. Qiuyue Wang, Yufang Chen, Guanheng Yang, Ping Deng, Xinqing Lu, Rui Ma, Yanghe Fu, Weidong Zhu. Low‐Temperature Catalytic Hydrogenolysis of Guaiacol to Phenol over Al‐Doped SBA‐15 Supported Ni Catalysts. ChemCatChem 2020, 12 (19) , 4930-4938.
    57. Yaxuan Jing, Yanqin Wang. Catalytic Hydrodeoxygenation of Lignin-Derived Feedstock Into Arenes and Phenolics. Frontiers in Chemical Engineering 2020, 2
    58. Yaxuan Jing, Lin Dong, Yong Guo, Xiaohui Liu, Yanqin Wang. Chemicals from Lignin: A Review of Catalytic Conversion Involving Hydrogen. ChemSusChem 2020, 13 (17) , 4181-4198.
    59. Xiaojun Shen, Yu Xin, Huizhen Liu, Buxing Han. Product‐oriented Direct Cleavage of Chemical Linkages in Lignin. ChemSusChem 2020, 13 (17) , 4367-4381.
    60. Zeming Rong, Jiqing Lu, Guanqun Yu, Jingjing Li, Mei Wang, Shufen Zhang. Promoting selective hydrodeoxygenation of guaiacol over amorphous nanoporous NiMnO2. Catalysis Communications 2020, 140 , 105987.
    61. Xiaojun Shen, Qinglei Meng, Qingqing Mei, Junfeng Xiang, Huizhen Liu, Buxing Han. The production of 4-ethyltoluene via directional valorization of lignin. Green Chemistry 2020, 22 (7) , 2191-2196.
    62. Thomas Cuypers, Thomas Morias, Simon Windels, Carlos Marquez, Cédric Van Goethem, Ivo Vankelecom, Dirk E. De Vos. Ni-Catalyzed reductive amination of phenols with ammonia or amines into cyclohexylamines. Green Chemistry 2020, 22 (6) , 1884-1893.
    63. Jiqing Lu, Xing Liu, Guanqun Yu, Jinkun Lv, Zeming Rong, Mei Wang, Yue Wang. Selective Hydrodeoxygenation of Guaiacol to Cyclohexanol Catalyzed by Nanoporous Nickel. Catalysis Letters 2020, 150 (3) , 837-848.
    64. Adarsh Kumar, Anushree, Jitendra Kumar, Thallada Bhaskar. Utilization of lignin: A sustainable and eco-friendly approach. Journal of the Energy Institute 2020, 93 (1) , 235-271.
    65. Abdul Rahman Mohamed, Maedeh Mohammadi. Upgrading pyrolysis-derived bio-oils via catalytic hydrodeoxygenation: an overview of advanced nanocatalysts. 2020, 241-272.
    66. Yaxuan Jing, Yong Guo, Qineng Xia, Xiaohui Liu, Yanqin Wang. Catalytic Production of Value-Added Chemicals and Liquid Fuels from Lignocellulosic Biomass. Chem 2019, 5 (10) , 2520-2546.
    67. Jiping Ma, Song Shi, Xiuquan Jia, Fei Xia, Hong Ma, Jin Gao, Jie Xu. Advances in catalytic conversion of lignocellulose to chemicals and liquid fuels. Journal of Energy Chemistry 2019, 36 , 74-86.
    68. Xi Chen, Ning Yan. Nanoparticle Design for the Catalytic Valorization of Lignocellulosic Biomass. 2019, 184-206.
    69. Lin Dong, Yu Xin, Xiaohui Liu, Yong Guo, Chih-Wen Pao, Jeng-Lung Chen, Yanqin Wang. Selective hydrodeoxygenation of lignin oil to valuable phenolics over Au/Nb 2 O 5 in water. Green Chemistry 2019, 21 (11) , 3081-3090.
    70. Francesca Broglia, Luca Rimoldi, Daniela Meroni, Sebastiano De Vecchi, Massimo Morbidelli, Silvia Ardizzone. Guaiacol hydrodeoxygenation as a model for lignin upgrading. Role of the support surface features on Ni-based alumina-silica catalysts. Fuel 2019, 243 , 501-508.
    71. Putla Sudarsanam, Elise Peeters, Ekaterina V. Makshina, Vasile I. Parvulescu, Bert F. Sels. Advances in porous and nanoscale catalysts for viable biomass conversion. Chemical Society Reviews 2019, 48 (8) , 2366-2421.
    72. Virendra Ranaware, Deepak Verma, Rizki Insyani, Asim Riaz, Seung Min Kim, Jaehoon Kim. Highly-efficient and magnetically-separable ZnO/Co@N-CNTs catalyst for hydrodeoxygenation of lignin and its derived species under mild conditions. Green Chemistry 2019, 21 (5) , 1021-1042.
    73. Wei Chen, Yanhong Wang, Wenfeng Shangguan. Au as a cocatalyst loaded on solid solution Bi0.5Y0.5VO4 for enhancing photocatalytic CO2 reduction activity. Materials Letters 2019, 238 , 74-76.
    74. Mei Xiang, Dongfang Wu. Highly selective catalytic conversion of lignin-derived phenolic compounds to cycloalkanes over a hierarchically structured zeolite catalyst. Journal of Materials Science 2019, 54 (4) , 2940-2959.
    75. Lifang Chen, Wenyu Yang, Zhenyou Gui, Shunmugavel Saravanamurugan, Anders Riisager, Wenrong Cao, Zhiwen Qi. MnOx/P25 with tuned surface structures of anatase-rutile phase for aerobic oxidation of 5-hydroxymethylfurfural into 2,5-diformylfuran. Catalysis Today 2019, 319 , 105-112.
    76. Dongdong Ye, Ronghui Huang, Haiyan Zhu, Liang-Hua Zou, Dawei Wang. Thienylbenzotriazole promoted highly active gold nanoparticles supported on N-doped graphene as efficient catalysts in water and a mechanism exploration. Organic Chemistry Frontiers 2019, 6 (1) , 62-69.
    77. Xun Wang, Shanhui Zhu, Sen Wang, Jianguo Wang, Weibin Fan, Yongkang Lv. Ni nanoparticles entrapped in nickel phyllosilicate for selective hydrogenation of guaiacol to 2-methoxycyclohexanol. Applied Catalysis A: General 2018, 568 , 231-241.
    78. Xiangyu Zhao, Xiaoxia Wu, Hua Wang, Jinyu Han, Qingfeng Ge, Xinli Zhu. Effect of Strong Metal‐Support Interaction of Pt/TiO 2 on Hydrodeoxygenation of m‐Cresol. ChemistrySelect 2018, 3 (37) , 10364-10370.
    79. Xiaoyang Liu, Wei An, Yixing Wang, C. Heath Turner, Daniel E. Resasco. Hydrodeoxygenation of guaiacol over bimetallic Fe-alloyed (Ni, Pt) surfaces: reaction mechanism, transition-state scaling relations and descriptor for predicting C–O bond scission reactivity. Catalysis Science & Technology 2018, 8 (8) , 2146-2158.
    80. Zhe Cai, Fumin Wang, Xubin Zhang, Rosine Ahishakiye, Yi Xie, Yu Shen. Selective hydrodeoxygenation of guaiacol to phenolics over activated carbon supported molybdenum catalysts. Molecular Catalysis 2017, 441 , 28-34.
    81. Tuan Ngoc Phan, Young-Kwon Park, In-Gu Lee, Chang Hyun Ko. Enhancement of C O bond cleavage to afford aromatics in the hydrodeoxygenation of anisole over ruthenium-supporting mesoporous metal oxides. Applied Catalysis A: General 2017, 544 , 84-93.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Your Mendeley pairing has expired. Please reconnect