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Understanding the Role of the Acid Sites in 5-Hydroxymethylfurfural Oxidation to 2,5-Furandicarboxylic Acid Reaction over Gold Catalysts: Surface Investigation on CexZr1–xO2 Compounds

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    Research Article

    Understanding the Role of the Acid Sites in 5-Hydroxymethylfurfural Oxidation to 2,5-Furandicarboxylic Acid Reaction over Gold Catalysts: Surface Investigation on CexZr1–xO2 Compounds
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    • Cristina Megías-Sayago*
      Cristina Megías-Sayago
      Departamento de Química Inorgánica e Instituto de Ciencia de Materiales de Sevilla, Universidad de Sevilla-CSIC, Américo Vespucio 49, 41092 Seville, Spain
      *E-mail: [email protected]
      More by Cristina Megías-Sayago
      Orcidhttp://orcid.org/0000-0002-1362-5216
    • Kristina Chakarova
      Kristina Chakarova
      Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences, Sofia 1113, Bulgaria
      More by Kristina Chakarova
    • Anna Penkova*
      Anna Penkova
      Departamento de Química Inorgánica e Instituto de Ciencia de Materiales de Sevilla, Universidad de Sevilla-CSIC, Américo Vespucio 49, 41092 Seville, Spain
      *E-mail: [email protected]
      More by Anna Penkova
      Orcidhttp://orcid.org/0000-0001-5792-2362
    • Alice Lolli
      Alice Lolli
      Dip. di Chimica Industriale “Toso Montanari”, Università di Bologna, Viale Risorgimento 4, 40136 Bologna, Italy
      More by Alice Lolli
    • Svetlana Ivanova
      Svetlana Ivanova
      Departamento de Química Inorgánica e Instituto de Ciencia de Materiales de Sevilla, Universidad de Sevilla-CSIC, Américo Vespucio 49, 41092 Seville, Spain
      More by Svetlana Ivanova
    • Stefania Albonetti
      Stefania Albonetti
      Dip. di Chimica Industriale “Toso Montanari”, Università di Bologna, Viale Risorgimento 4, 40136 Bologna, Italy
      More by Stefania Albonetti
    • Fabrizio Cavani
      Fabrizio Cavani
      Dip. di Chimica Industriale “Toso Montanari”, Università di Bologna, Viale Risorgimento 4, 40136 Bologna, Italy
      More by Fabrizio Cavani
      Orcidhttp://orcid.org/0000-0002-4282-6260
    • José Antonio Odriozola
      José Antonio Odriozola
      Departamento de Química Inorgánica e Instituto de Ciencia de Materiales de Sevilla, Universidad de Sevilla-CSIC, Américo Vespucio 49, 41092 Seville, Spain
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    ACS Catalysis

    Cite this: ACS Catal. 2018, 8, 12, 11154–11164
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    https://doi.org/10.1021/acscatal.8b02522
    Published October 22, 2018
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    Abstract

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    A series of CexZr1–xO2 supports with different Ce/Zr molar ratios were utilized for the preparation of gold catalyst used in the selective oxidation of 5-hydroxymethyl-2-furfural to 2,5-furandicarboxylic acid. The used method of gold deposition allows the preparation of gold particles with homogeneous size and shape distribution, a formulation very useful for studies dedicated to revealing the support participation in the reaction. The supports are characterized by Fourier transform infrared spectroscopy using CO as probe molecule, and the sample catalytic activity is thereafter correlated to the support acid site distribution. The possible participation of its Lewis/Brønsted acidity in the reaction mechanism is also proposed.

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acscatal.8b02522.

    • TEM images and particle size distribution of the studied samples (Figure S1) and the XPS results obtained with the AuCe25Zr sample (used for an additional verification of the obtained by IR spectroscopy oxidation states of the metal cations; Figures S3–S4) (PDF)

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    Cite this: ACS Catal. 2018, 8, 12, 11154–11164
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    https://doi.org/10.1021/acscatal.8b02522
    Published October 22, 2018
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