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Unravelling the Behavior of Dion–Jacobson Layered Hybrid Perovskites in Humid Environments

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    Unravelling the Behavior of Dion–Jacobson Layered Hybrid Perovskites in Humid Environments
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    ACS Energy Letters

    Cite this: ACS Energy Lett. 2021, 6, 2, 337–344
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    https://doi.org/10.1021/acsenergylett.0c02344
    Published December 31, 2020
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    Abstract

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    Layered hybrid halide perovskites are known to be more environmentally stable than their 3D analogues. The enhanced stability is particularly relevant for Dion–Jacobson-type layered perovskites due to their promising photovoltaic performances. However, in contrast to the expected resilience to moisture, we reveal that the structure of Dion–Jacobson perovskite phases based on a 1,4-phenylenedimethanammonium spacer is disrupted in humid conditions using X-ray diffraction, UV–vis spectroscopy, thermogravimetric analysis, and solid-state NMR spectroscopy. The process takes place at ≥65 ± 5% relative humidity, with a time scale on the order of minutes. The original layered structure can be restored upon annealing and the hydration can be suppressed by postsynthetic annealing in air, which is attributed to the generation of a self-protective layer of PbI2. This study thereby reveals a unique behavior of layered perovskites in humid environments, which is critical to their stabilizing role in perovskite devices.

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    • Materials and methods, X-ray crystal structure analysis, TGA data for (PDMA)PbI4 and (PDMA)I2 powders, solid-state NMR spectroscopy data, and supplementary spectral data (PDF)

    • Crystal structure of the (PDMA)I2 (CIF)

    • Crystal structure of the (PDMA)PbI4 (CIF)

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    Cite this: ACS Energy Lett. 2021, 6, 2, 337–344
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acsenergylett.0c02344
    Published December 31, 2020
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