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Formation of Magnesium Dendrites during Electrodeposition

  • Rachel Davidson
    Rachel Davidson
    Department of Chemistry  and  Department of Materials Science & Engineering , Texas A&M University , College Station, Texas 77843, United States
  • Ankit Verma
    Ankit Verma
    School of Mechanical Engineering, Purdue University , West Lafayette, Indiana 47907, United States
    More by Ankit Verma
  • David Santos
    David Santos
    Department of Chemistry  and  Department of Materials Science & Engineering , Texas A&M University , College Station, Texas 77843, United States
    More by David Santos
  • Feng Hao
    Feng Hao
    School of Mechanical Engineering, Purdue University , West Lafayette, Indiana 47907, United States
    More by Feng Hao
  • Coleman Fincher
    Coleman Fincher
    Department of Mechanical Engineering , Texas A&M University , College Station, Texas 77843, United States
  • Sisi Xiang
    Sisi Xiang
    Department of Materials Science & Engineering , Texas A&M University , College Station, Texas 77843, United States
    More by Sisi Xiang
  • Jonathan Van Buskirk
    Jonathan Van Buskirk
    Department of Chemistry  and  Department of Materials Science & Engineering , Texas A&M University , College Station, Texas 77843, United States
  • Kelvin Xie
    Kelvin Xie
    Department of Materials Science & Engineering , Texas A&M University , College Station, Texas 77843, United States
    More by Kelvin Xie
  • Matt Pharr
    Matt Pharr
    Department of Mechanical Engineering , Texas A&M University , College Station, Texas 77843, United States
    More by Matt Pharr
  • Partha P. Mukherjee*
    Partha P. Mukherjee
    School of Mechanical Engineering, Purdue University , West Lafayette, Indiana 47907, United States
    *E-mail: [email protected]
  • , and 
  • Sarbajit Banerjee*
    Sarbajit Banerjee
    Department of Chemistry  and  Department of Materials Science & Engineering , Texas A&M University , College Station, Texas 77843, United States
    *E-mail: [email protected]
Cite this: ACS Energy Lett. 2019, 4, 2, 375–376
Publication Date (Web):December 26, 2018
https://doi.org/10.1021/acsenergylett.8b02470
Copyright © 2018 American Chemical Society
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Supporting Info (5)»

Abstract

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We demonstrate the growth of dendritic magnesium deposits with fractal morphologies exhibiting shear moduli in excess of values for polymeric separators upon the galvanostatic electrodeposition of metallic Mg from Grignard reagents in symmetric Mg–Mg cells. Dendritic growth is understood on the basis of the competing influences of reaction rate, electrolyte transport rate, and self-diffusion barrier.

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