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Multipurpose Solar-Thermal Hydrogel Platform for Desalination of Seawater and Subsequent Collection of Atmospheric Water

  • Xiang Li
    Xiang Li
    Engineering Research Center of Advanced Wooden Materials and Key Laboratory of Bio-based Material Science and Technology of Ministry of Education, Northeast Forestry University, Harbin 150040, P. R. China
    More by Xiang Li
  • Chenhui Yang*
    Chenhui Yang
    Engineering Research Center of Advanced Wooden Materials and Key Laboratory of Bio-based Material Science and Technology of Ministry of Education, Northeast Forestry University, Harbin 150040, P. R. China
    *Email: [email protected]
    More by Chenhui Yang
  • Zhijun Chen*
    Zhijun Chen
    Engineering Research Center of Advanced Wooden Materials and Key Laboratory of Bio-based Material Science and Technology of Ministry of Education, Northeast Forestry University, Harbin 150040, P. R. China
    *Email: [email protected]
    More by Zhijun Chen
  • Shouxin Liu
    Shouxin Liu
    Engineering Research Center of Advanced Wooden Materials and Key Laboratory of Bio-based Material Science and Technology of Ministry of Education, Northeast Forestry University, Harbin 150040, P. R. China
    More by Shouxin Liu
  • Jian Li
    Jian Li
    Engineering Research Center of Advanced Wooden Materials and Key Laboratory of Bio-based Material Science and Technology of Ministry of Education, Northeast Forestry University, Harbin 150040, P. R. China
    More by Jian Li
  • , and 
  • Shujun Li*
    Shujun Li
    Engineering Research Center of Advanced Wooden Materials and Key Laboratory of Bio-based Material Science and Technology of Ministry of Education, Northeast Forestry University, Harbin 150040, P. R. China
    *Email: [email protected]
    More by Shujun Li
Cite this: ACS EST Water 2023, 3, 7, 1740–1746
Publication Date (Web):May 3, 2022
https://doi.org/10.1021/acsestwater.2c00067
Copyright © 2022 American Chemical Society

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    Abstract

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    Clean water collection is the most challenging global issue. Hydrogel platform for producing fresh water from both seawater and the atmosphere holds great promise, but it has been difficult to achieve multifunction and integration with it. Here, we have developed a multipurpose solar-thermal hydrogel (TA-Fe@PAM) that can be used for desalination of seawater and subsequent water collection from the atmosphere by impregnating a polyacrylamide network with an iron-tannin photothermal complex. Rapid solar desalination (∼1.93 kg m–2 h–1) was achieved by TA-Fe@PAM under 1 sun irradiation. During this process, large amounts of deliquescent salts, including CaCl2, MgCl2, KCl, and NaCl, entered the TA-Fe@PAM, forming DS-TA-Fe@PAM, which can then be used to collect water from the atmosphere. DS-TA-Fe@PAM captured ∼1.26%, ∼5.56%, ∼17.32%, and ∼31.02% (w/w) water from the atmosphere within 450 min when the relative humidity was 10%, 30%, 50%, and 70%, respectively. More interestingly, almost 100% captured atmospheric water was collected from the inbuilt solar-thermal DS-TA-Fe@PAM under normal intensity sunlight.

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acsestwater.2c00067.

    • Protocol of TA-Fe@PAM preparation, photothermal performance including surface temperature change and evaporation rate of TA-Fe@PAM with different doses of TA and Fe2(SO4)3, water absorption capacity, photothermal and structure stability tests, corresponding digital photograph, effect of solar irradiation intensity to photothermal performance, water evaporation data of polyacrylamide hydrogel and pure water evaporation data, calculation details of heat loss, water vapor sorption data, and corresponding salts content (PDF)

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    Cited By

    This article is cited by 3 publications.

    1. Bibek Chaw pattnayak, Sasmita Mohapatra. Photothermal–Photocatalytic CSG@ZFG Evaporator for Synergistic Salt Rejection and VOC Removal during Solar-Driven Water Distillation. Langmuir 2023, 39 (13) , 4651-4661. https://doi.org/10.1021/acs.langmuir.2c03438
    2. William Schmid, Aleida Machorro-Ortiz, Bryant Jerome, Alberto Naldoni, Naomi J. Halas, Pratiksha D. Dongare, Alessandro Alabastri. Decentralized Solar-Driven Photothermal Desalination: An Interdisciplinary Challenge to Transition Lab-Scale Research to Off-Grid Applications. ACS Photonics 2022, 9 (12) , 3764-3776. https://doi.org/10.1021/acsphotonics.2c01251
    3. Hao‐Yu Zhao, Chao Shu, Xin Wang, Peng Min, Changjun Li, Fu‐Lin Gao, Xiaofeng Li, Zhong‐Zhen Yu. Bioinspired Intelligent Solar‐Responsive Thermally Conductive Pyramidal Phase Change Composites with Radially Oriented Layered Structures toward Efficient Solar–Thermal–Electric Energy Conversion. Advanced Functional Materials 2023, 6 https://doi.org/10.1002/adfm.202302527

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