ACS Publications. Most Trusted. Most Cited. Most Read
Interfacial Polymerization of Cellulose Nanocrystal Polyamide Janus Nanocomposites with Controlled Architectures

OR SEARCH CITATIONS

My Activity
Publications

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:ACS Macro Lett. 2019, 8, 10, 1334-1340
    Letter

    Interfacial Polymerization of Cellulose Nanocrystal Polyamide Janus Nanocomposites with Controlled Architectures
    Click to copy article linkArticle link copied!

    Other Access OptionsSupporting Information (1)

    ACS Macro Letters

    Cite this: ACS Macro Lett. 2019, 8, 10, 1334–1340
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acsmacrolett.9b00692
    Published September 27, 2019
    Copyright © 2019 American Chemical Society
    Request reuse permissions

    Abstract

    Click to copy section linkSection link copied!
    Abstract Image

    The widespread use of renewable nanomaterials has been limited due to poor integration with conventional polymer matrices. Often, chemical and physical surface modifications are implemented to improve compatibility, however, this comes with environmental and economic cost. This work demonstrates that renewable nanomaterials, specifically cellulose nanocrystals (CNCs), can be utilized in their unmodified state and presents a simple and versatile, one-step method to produce polyamide/CNC nanocomposites with unique Janus-like properties. Nanocomposites in the form of films, fibers, and capsules are prepared by dispersing as-prepared CNCs in the aqueous phase prior to the interfacial polymerization of aromatic diamines and acyl chlorides. The diamines in the aqueous phase not only serve as a monomer for polymerization, but additionally, adsorb to and promote the incorporation of CNCs into the nanocomposite. Regardless of the architecture, CNCs are only present along the surface facing the aqueous phase, resulting in materials with unique, Janus-like wetting behavior and potential applications in filtration, separations, drug delivery, and advanced fibers.

    Copyright © 2019 American Chemical Society

    Subjects

    what are subjects

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. Add or change your institution or let them know you’d like them to include access.

    Supporting Information

    Click to copy section linkSection link copied!

    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acsmacrolett.9b00692.

    • Materials and Methods, AFM and SEM images showing composite morphology, ITC data and fitting, interfacial tension data, TGA, and FTIR characterization and contact angles (PDF)

    Terms & Conditions

    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    Click to copy section linkSection link copied!
    Citation Statements
    Explore this article's citation statements on scite.ai
    powered by  Scite

    This article is cited by 19 publications.

    1. Qianqian Wang, Rui Zhou, Jianzhong Sun, Jun Liu, Qianqian Zhu. Naturally Derived Janus Cellulose Nanomaterials: Anisotropic Cellulose Nanomaterial Building Blocks and Their Assembly into Asymmetric Structures. ACS Nano 2022, 16 (9) , 13468-13491. https://doi.org/10.1021/acsnano.2c04883
    2. Mehran Ghasemlou, Fugen Daver, Elena P. Ivanova, Billy J. Murdoch, Benu Adhikari. Use of Synergistic Interactions to Fabricate Transparent and Mechanically Robust Nanohybrids Based on Starch, Non-Isocyanate Polyurethanes, and Cellulose Nanocrystals. ACS Applied Materials & Interfaces 2020, 12 (42) , 47865-47878. https://doi.org/10.1021/acsami.0c14525
    3. Emily G. Facchine, Soo-Ah Jin, Richard J. Spontak, Saad A. Khan, Orlando J. Rojas. Quantitative Calorimetric Studies of the Chiral Nematic Mesophase in Aqueous Cellulose Nanocrystal Suspensions. Langmuir 2020, 36 (36) , 10830-10837. https://doi.org/10.1021/acs.langmuir.0c01871
    4. Chang Liu, Cheng-Ye Zhu, Chao Zhang, Hao-Cheng Yang, Zhi-Kang Xu. Thermodynamic and kinetic understanding for managing the controllability of interfacial polymerization. Progress in Polymer Science 2024, 152 , 101815. https://doi.org/10.1016/j.progpolymsci.2024.101815
    5. Na Xu, Guodong Wang, Yanan Tao. Construction of unsaturated systems on the surface of polyamide fibers. Textile Research Journal 2023, 93 (23-24) , 5336-5344. https://doi.org/10.1177/00405175231193778
    6. Afrinal Firmanda, Farah Fahma, Khaswar Syamsu, Suprihatin Suprihatin, Rini Purnawati, Melbi Mahardika, Lisman Suryanegara, Yukie Saito, Kathleen Wood, Rafles Sinaga. Cellulose and its composite for sustainable oils/water (O/W) separation: From cellulose sponge to 3D printed nanocellulose. Journal of Environmental Chemical Engineering 2023, 11 (5) , 110359. https://doi.org/10.1016/j.jece.2023.110359
    7. Sikai Chen, Dong Li, Fei Song, Xiu-Li Wang, Yu-Zhong Wang. Thermoformable and transparent one-component nanocomposites based on surface grafted cellulose nanofiber. International Journal of Biological Macromolecules 2022, 223 , 213-222. https://doi.org/10.1016/j.ijbiomac.2022.11.010
    8. Langming Bai, Aiming Ding, Guibai Li, Heng Liang. Application of cellulose nanocrystals in water treatment membranes: A review. Chemosphere 2022, 308 , 136426. https://doi.org/10.1016/j.chemosphere.2022.136426
    9. J.L. Fajardo-Diaz, A. Morelos-Gomez, R. Cruz-Silva, K. Ishii, T. Yasuike, T. Kawakatsu, A. Yamanaka, S. Tejima, K. Izu, S. Saito, J. Maeda, K. Takeuchi, M. Endo. Low-pressure reverse osmosis membrane made of cellulose nanofiber and carbon nanotube polyamide nano-nanocomposite for high purity water production. Chemical Engineering Journal 2022, 448 , 137359. https://doi.org/10.1016/j.cej.2022.137359
    10. Khairatun Najwa Mohd Amin, Alireza Hosseinmardi, Darren J. Martin, Pratheep K. Annamalai. A mixed acid methodology to produce thermally stable cellulose nanocrystal at high yield using phosphoric acid. Journal of Bioresources and Bioproducts 2022, 7 (2) , 99-108. https://doi.org/10.1016/j.jobab.2021.12.002
    11. Zhaleh Atoufi, Michael S. Reid, Per A. Larsson, Lars Wågberg. Surface tailoring of cellulose aerogel-like structures with ultrathin coatings using molecular layer-by-layer assembly. Carbohydrate Polymers 2022, 282 , 119098. https://doi.org/10.1016/j.carbpol.2022.119098
    12. Lauren Geurds, Jan Lauko, Alan E. Rowan, Nasim Amiralian. Tailored nanocellulose-grafted polymer brush applications. Journal of Materials Chemistry A 2021, 9 (32) , 17173-17188. https://doi.org/10.1039/D1TA03264J
    13. Kevin De France, Zhihui Zeng, Tingting Wu, Gustav Nyström. Functional Materials from Nanocellulose: Utilizing Structure–Property Relationships in Bottom‐Up Fabrication. Advanced Materials 2021, 33 (28) https://doi.org/10.1002/adma.202000657
    14. Caitlyn M. Clarkson, Sami M. El Awad Azrak, Endrina S. Forti, Gregory T. Schueneman, Robert J. Moon, Jeffrey P. Youngblood. Recent Developments in Cellulose Nanomaterial Composites. Advanced Materials 2021, 33 (28) https://doi.org/10.1002/adma.202000718
    15. Sharayu Govardhane, Pravin Shende. Polymeric-Ceramic Nanocomposites Toxicity. 2021, 723-742. https://doi.org/10.1007/978-3-030-40513-7_55
    16. Rodolfo Cruz-Silva, Kazuo Izu, Jun Maeda, Shigeru Saito, Aaron Morelos-Gomez, Celia Aguilar, Yoshihiro Takizawa, Ayaka Yamanaka, Syogo Tejiima, Kazunori Fujisawa, Kenji Takeuchi, Takuya Hayashi, Toru Noguchi, Akira Isogai, Morinobu Endo. Nanocomposite desalination membranes made of aromatic polyamide with cellulose nanofibers: synthesis, performance, and water diffusion study. Nanoscale 2020, 12 (38) , 19628-19637. https://doi.org/10.1039/D0NR02915G
    17. Djalal Trache, Ahmed Fouzi Tarchoun, Mehdi Derradji, Tuan Sherwyn Hamidon, Nanang Masruchin, Nicolas Brosse, M. Hazwan Hussin. Nanocellulose: From Fundamentals to Advanced Applications. Frontiers in Chemistry 2020, 8 https://doi.org/10.3389/fchem.2020.00392
    18. Pascal Bertsch, Peter Fischer. Adsorption and interfacial structure of nanocelluloses at fluid interfaces. Advances in Colloid and Interface Science 2020, 276 , 102089. https://doi.org/10.1016/j.cis.2019.102089
    19. Sharayu Govardhane, Pravin Shende. Polymeric-Ceramic Nanocomposites Toxicity. 2020, 1-20. https://doi.org/10.1007/978-3-030-10614-0_55-1
    Download PDF
    Go to ACS Macro Letters
    Get e-Alerts
    Get e-Alerts

    ACS Macro Letters

    Cite this: ACS Macro Lett. 2019, 8, 10, 1334–1340
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acsmacrolett.9b00692
    Published September 27, 2019
    Copyright © 2019 American Chemical Society
    Request reuse permissions

    Article Views

    1653

    Altmetric

    -

    Citations

    19
    Learn about these metrics

    Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.

    Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.

    The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.