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Waveguide-Integrated MoTe2 pin Homojunction Photodetector
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    Waveguide-Integrated MoTe2pin Homojunction Photodetector
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    • Chen Li
      Chen Li
      Key Laboratory of Light Field Manipulation and Information Acquisition, Ministry of Industry and Information Technology, and Shaanxi Key Laboratory of Optical Information Technology, School of Physical Science and Technology, Northwestern Polytechnical University, Xi’an710129, China
      More by Chen Li
    • Ruijuan Tian
      Ruijuan Tian
      Key Laboratory of Light Field Manipulation and Information Acquisition, Ministry of Industry and Information Technology, and Shaanxi Key Laboratory of Optical Information Technology, School of Physical Science and Technology, Northwestern Polytechnical University, Xi’an710129, China
      More by Ruijuan Tian
    • Xiaoqing Chen
      Xiaoqing Chen
      Key Laboratory of Light Field Manipulation and Information Acquisition, Ministry of Industry and Information Technology, and Shaanxi Key Laboratory of Optical Information Technology, School of Physical Science and Technology, Northwestern Polytechnical University, Xi’an710129, China
    • Linpeng Gu
      Linpeng Gu
      Key Laboratory of Light Field Manipulation and Information Acquisition, Ministry of Industry and Information Technology, and Shaanxi Key Laboratory of Optical Information Technology, School of Physical Science and Technology, Northwestern Polytechnical University, Xi’an710129, China
      More by Linpeng Gu
    • Zhengdong Luo
      Zhengdong Luo
      Wide Bandgap Semiconductor Technology Disciplines State Key Laboratory, School of Microelectronics, Xidian University, Xi’an710071, China
    • Qiao Zhang
      Qiao Zhang
      Key Laboratory of Light Field Manipulation and Information Acquisition, Ministry of Industry and Information Technology, and Shaanxi Key Laboratory of Optical Information Technology, School of Physical Science and Technology, Northwestern Polytechnical University, Xi’an710129, China
      More by Qiao Zhang
    • Ruixuan Yi
      Ruixuan Yi
      Key Laboratory of Light Field Manipulation and Information Acquisition, Ministry of Industry and Information Technology, and Shaanxi Key Laboratory of Optical Information Technology, School of Physical Science and Technology, Northwestern Polytechnical University, Xi’an710129, China
      More by Ruixuan Yi
    • Zhiwen Li
      Zhiwen Li
      Key Laboratory of Light Field Manipulation and Information Acquisition, Ministry of Industry and Information Technology, and Shaanxi Key Laboratory of Optical Information Technology, School of Physical Science and Technology, Northwestern Polytechnical University, Xi’an710129, China
      More by Zhiwen Li
    • Biqiang Jiang
      Biqiang Jiang
      Key Laboratory of Light Field Manipulation and Information Acquisition, Ministry of Industry and Information Technology, and Shaanxi Key Laboratory of Optical Information Technology, School of Physical Science and Technology, Northwestern Polytechnical University, Xi’an710129, China
    • Yan Liu
      Yan Liu
      Wide Bandgap Semiconductor Technology Disciplines State Key Laboratory, School of Microelectronics, Xidian University, Xi’an710071, China
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    • Andres Castellanos-Gomez
      Andres Castellanos-Gomez
      Materials Science Factory, Instituto de Ciencia de Materiales de Madrid (ICMM-CSIC), MadridE-28049, Spain
    • Soo-Jin Chua
      Soo-Jin Chua
      Department of Electrical and Computer Engineering, National University of Singapore, 4 Engineering Drive 3, 117583, Singapore
      LEES Program, Singapore-MIT Alliance for Research & Technology (SMART), 1 CREATE Way, #10-01 CREATE Tower, 138602, Singapore
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    • Xiaomu Wang
      Xiaomu Wang
      School of Electronic Science and Engineering, Nanjing University, Nanjing210093, China
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    • Zhipei Sun
      Zhipei Sun
      Department of Electronics and Nanoengineering and QTF Centre of Excellence, Aalto University, AaltoFI-00076, Finland
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    • Jianlin Zhao
      Jianlin Zhao
      Key Laboratory of Light Field Manipulation and Information Acquisition, Ministry of Industry and Information Technology, and Shaanxi Key Laboratory of Optical Information Technology, School of Physical Science and Technology, Northwestern Polytechnical University, Xi’an710129, China
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    • Xuetao Gan*
      Xuetao Gan
      Key Laboratory of Light Field Manipulation and Information Acquisition, Ministry of Industry and Information Technology, and Shaanxi Key Laboratory of Optical Information Technology, School of Physical Science and Technology, Northwestern Polytechnical University, Xi’an710129, China
      *Email: [email protected]
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    Other Access OptionsSupporting Information (1)

    ACS Nano

    Cite this: ACS Nano 2022, 16, 12, 20946–20955
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    https://doi.org/10.1021/acsnano.2c08549
    Published November 22, 2022
    Copyright © 2022 American Chemical Society

    Abstract

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    Two-dimensional (2D) materials, featuring distinctive electronic and optical properties and dangling-bond-free surfaces, are promising for developing high-performance on-chip photodetectors in photonic integrated circuits. However, most of the previously reported devices operating in the photoconductive mode suffer from a high dark current or a low responsivity. Here, we demonstrate a MoTe2pin homojunction fabricated directly on a silicon photonic crystal (PC) waveguide, which enables on-chip photodetection with ultralow dark current, high responsivity, and fast response speed. The adopted silicon PC waveguide is electrically split into two individual back gates to selectively dope the top regions of the MoTe2 channel in p- or n-types. High-quality reconfigurable MoTe2 (pin, nip, nin, pip) homojunctions are realized successfully, presenting rectification behaviors with ideality factors approaching 1.0 and ultralow dark currents less than 90 pA. Waveguide-assisted MoTe2 absorption promises a sensitive photodetection in the telecommunication O-band from 1260 to 1340 nm, though it is close to MoTe2’s absorption band-edge. A competitive photoresponsivity of 0.4 A/W is realized with a light on/off current ratio exceeding 104 and a record-high normalized photocurrent-to-dark-current ratio of 106 mW–1. The ultrasmall capacitance of pin homojunction and high carrier mobility of MoTe2 promise a high dynamic response bandwidth close to 34.0 GHz. The proposed device geometry has the advantages of employing a silicon PC waveguide as the back gates to build a 2D material pin homojunction directly and simultaneously to enhance light–2D material interaction. It provides a potential pathway to develop 2D material-based photodetectors, laser diodes, and electro-optic modulators on silicon photonic chips.

    Copyright © 2022 American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acsnano.2c08549.

    • Raman and AFM characterizations of the 2D materials; structure design and mode simulation of the PC waveguide; analysis of electrical characteristics of the fabricated device; calculations of the absorption power; results of responsivity and quantum efficiency of the device demonstrated in the main text; estimation of the response speed of the waveguide-integrated MoTe2pin homojunction photodetector; performance comparisons with other waveguide-integrated and vertical illuminated photodetectors; stability of the device; and another waveguide-integrated MoTe2pin homojunction photodetector (PDF)

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    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

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    This article is cited by 6 publications.

    1. Dong Wu, Wei He, Peng Yu, Guowei Yang. Van der Waals Gate-Induced Ultrafast Photoresponse in a 2D PdPSe-Based Photodetector. ACS Photonics 2024, 11 (4) , 1743-1752. https://doi.org/10.1021/acsphotonics.4c00069
    2. Muhammad Rabeel, Honggyun Kim, Muhammad Asghar Khan, Muhammad Abubakr, Ibtisam Ahmad, Muneeb Ahmad, Shania Rehman, Myoung-Jae Lee, Muhammad Farooq Khan, Deok-kee Kim. Broadband and Flexible Photodiode of a Bromine-Doped Lateral MoTe2 Homojunction. ACS Photonics 2023, 10 (12) , 4425-4436. https://doi.org/10.1021/acsphotonics.3c01281
    3. Jiayang Jiang, Weiting Xu, Fuqiang Guo, Shengxue Yang, Weikun Ge, Bo Shen, Ning Tang. Polarization-Resolved Near-Infrared PdSe2 p-i-n Homojunction Photodetector. Nano Letters 2023, 23 (20) , 9522-9528. https://doi.org/10.1021/acs.nanolett.3c03086
    4. Chenglin Wang, Qianqian Wu, Yang Ding, Xiumei Zhang, Wenhui Wang, Xitao Guo, Zhenhua Ni, Liangliang Lin, Zhengyang Cai, Xiaofeng Gu, Shaoqing Xiao, Haiyan Nan. High-Responsivity and Broadband MoS2 Photodetector Using Interfacial Engineering. ACS Applied Materials & Interfaces 2023, 15 (39) , 46236-46246. https://doi.org/10.1021/acsami.3c09322
    5. Guo Yi Huang, Yabin Hao, Shi Qi Li, Yi Ding Jia, Jin Chuan Guo, Han Zhang, Bing Wang. Recent progress in waveguide-integrated photodetectors based on 2D materials for infrared detection. Journal of Physics D: Applied Physics 2023, 56 (11) , 113001. https://doi.org/10.1088/1361-6463/acb6a3
    6. Huaxin Yi, Yuhang Ma, Qiaojue Ye, Jianting Lu, Wan Wang, Zhaoqiang Zheng, Churong Ma, Jiandong Yao, Guowei Yang. Promoting 2D Material Photodetectors by Optical Antennas beyond Noble Metals. Advanced Sensor Research 2023, 36 , 2200079. https://doi.org/10.1002/adsr.202200079

    ACS Nano

    Cite this: ACS Nano 2022, 16, 12, 20946–20955
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acsnano.2c08549
    Published November 22, 2022
    Copyright © 2022 American Chemical Society

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