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Anisotropy Reversal of Thermal Conductivity in Silicon Nanowire Networks Driven by Quasi-Ballistic Phonon Transport
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    Anisotropy Reversal of Thermal Conductivity in Silicon Nanowire Networks Driven by Quasi-Ballistic Phonon Transport
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    • Byunggi Kim*
      Byunggi Kim
      Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro, Tokyo 153-8505, Japan
      *Email: [email protected]
      More by Byunggi Kim
    • Félix Barbier-Chebbah
      Félix Barbier-Chebbah
      Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro, Tokyo 153-8505, Japan
      Physics Department, Ecole Normale Supérieure, Université PSL, Paris 75005, France
    • Yohei Ogawara
      Yohei Ogawara
      Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro, Tokyo 153-8505, Japan
    • Laurent Jalabert
      Laurent Jalabert
      Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro, Tokyo 153-8505, Japan
      LIMMS, CNRS-IIS IRL 2820, The University of Tokyo, 4-6-1 Komaga, Meguro, Tokyo 153-8505, Japan
    • Ryoto Yanagisawa
      Ryoto Yanagisawa
      Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro, Tokyo 153-8505, Japan
    • Roman Anufriev
      Roman Anufriev
      Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro, Tokyo 153-8505, Japan
      LIMMS, CNRS-IIS IRL 2820, The University of Tokyo, 4-6-1 Komaga, Meguro, Tokyo 153-8505, Japan
    • Masahiro Nomura*
      Masahiro Nomura
      Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro, Tokyo 153-8505, Japan
      *Email: [email protected]
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    ACS Nano

    Cite this: ACS Nano 2024, 18, 15, 10557–10565
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    https://doi.org/10.1021/acsnano.3c12767
    Published April 4, 2024
    Copyright © 2024 American Chemical Society

    Abstract

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    Nanostructured semiconductors promise functional thermal management for microelectronics and thermoelectrics through a rich design capability. However, experimental studies on anisotropic in-plane thermal conduction remain limited, despite the demand for directional heat dissipation. Here, inspired by an oriental wave pattern, a periodic network of bent wires, we investigate anisotropic in-plane thermal conduction in nanoscale silicon phononic crystals with the thermally dead volume. We observed the anisotropy reversal of the material thermal conductivity from 1.2 at 300 K to 0.8 at 4 K, with the reversal temperature of 80 K mediated by the transition from a diffusive to a quasi-ballistic regime. Our Monte Carlo simulations revealed that the backflow of the directional phonons induces the anisotropy reversal, showing that the quasi-ballistic phonon transport introduces preferential thermal conduction channels with anomalous temperature dependence. Accordingly, the anisotropy of the effective thermal conductivity varied from 2.7 to 5.0 in the range of 4–300 K, indicating an anisotropic heat manipulation capability. Our findings demonstrate that the design of nanowire networks enables the directional thermal management of electronic devices.

    Copyright © 2024 American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acsnano.3c12767.

    • Details of the design of the oriental wave PnC, the thermally dead volume formation at the bridge boundary, and convergence of the MC simulations (PDF)

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    This article is cited by 4 publications.

    1. Anri Nakajima, Taisei Hanawa, Masafumi Mishima, Toshiki Mukae. Bis-PCBM-Containing Electrically Conducting Electron-Beam Resist for Nanometer-Scale Organic Devices. ACS Applied Electronic Materials 2025, 7 (8) , 3297-3307. https://doi.org/10.1021/acsaelm.4c02325
    2. Yao Chen, Zizhen Zhou, Bin Zhang, Guang Han, Tian Xie, Sikang Zheng, Xu Lu, Guoyu Wang, Xiaoyuan Zhou. Lattice Overdamping Induced Anisotropy Decoupling of Phonon and Carrier Transports in Quasi‐1D KCu 7 S 4 Textured Materials. Advanced Functional Materials 2025, 12 https://doi.org/10.1002/adfm.202503765
    3. Byunggi Kim, Younggeun Lee, Dongwook Yang, Kazuyoshi Fushinobu, Young‐Jin Kim, Masahiro Nomura. Rapid Electro‐Thermal Micro‐Actuation of Flat Optics Enabled by Laser‐Induced Graphene on Colorless Polyimide Substrates. Advanced Optical Materials 2025, 11 https://doi.org/10.1002/adom.202500498
    4. Byunggi Kim, Masahiro Nomura. Heat Flow Control in Semiconductors using Japanese Traditional Patterns. Journal of the Society of Powder Technology, Japan 2025, 62 (4) , 224-229. https://doi.org/10.4164/sptj.62.224

    ACS Nano

    Cite this: ACS Nano 2024, 18, 15, 10557–10565
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acsnano.3c12767
    Published April 4, 2024
    Copyright © 2024 American Chemical Society

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