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Designing Carbon-Foam Composites via Molten-State Reduction for Multifunctional Electromagnetic Interference Shielding
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    Designing Carbon-Foam Composites via Molten-State Reduction for Multifunctional Electromagnetic Interference Shielding
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    • Heguang Liu*
      Heguang Liu
      School of Materials Science and Engineering, Xi’an University of Technology, Xi’an 710048, China
      *Email: [email protected]
      More by Heguang Liu
    • Fengyu Lei
      Fengyu Lei
      School of Materials Science and Engineering, Xi’an University of Technology, Xi’an 710048, China
      More by Fengyu Lei
    • Wanyin Xu
      Wanyin Xu
      Materials Genome Institute, Shanghai University, Shanghai 200444, China
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    • Qianqian Li
      Qianqian Li
      Materials Genome Institute, Shanghai University, Shanghai 200444, China
      More by Qianqian Li
    • Chao Lei
      Chao Lei
      School of Materials Science and Engineering, Xi’an University of Technology, Xi’an 710048, China
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    • Chuanyin Xiong
      Chuanyin Xiong
      College of Bioresources Chemical and Materials Engineering, Shaanxi University of Science and Technology, Xi’an 710021, China
    • Na Tian
      Na Tian
      School of Materials Science and Engineering, Xi’an University of Technology, Xi’an 710048, China
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    • Caiyin You*
      Caiyin You
      School of Materials Science and Engineering, Xi’an University of Technology, Xi’an 710048, China
      *Email: [email protected]
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    • Yang Yang*
      Yang Yang
      NanoScience Technology Center, Department of Materials Science and Engineering, Department of Chemistry, Renewable Energy and Chemical Transformation Cluster, The Stephen W. Hawking Center for Microgravity Research and Education, University of Central Florida, Orlando, Florida 32826, United States
      *Email: [email protected]
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    ACS Nano

    Cite this: ACS Nano 2025, 19, 1, 1198–1210
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    https://doi.org/10.1021/acsnano.4c13329
    Published January 2, 2025
    Copyright © 2025 American Chemical Society

    Abstract

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    Advanced electromagnetic interference (EMI) shielding materials are in great demand because of the severe electromagnetic population problem caused by the explosive growth of advanced electronics. Besides superior EMI shielding properties, the mechanical strength of the shielding materials is also critical for some specific application scenarios (e.g., shielding cases and shielding frames). Although most reported EMI shielding materials possess good shielding properties and lightweight characteristics, they usually exhibit a poor mechanical strength. Concurrently, multifunctionality is also essential for the application of the EMI shielding material. This study develops a molten-state-based in situ reduction strategy to fabricate an efficient EMI shielding composite, enabling the uniform dispersion of Co-nanoparticles on the carbon form matrix while featuring a high density of defects. This ensures the high mechanical strength of the composite due to the presence of a huge interface and significantly enhances the EMI shielding performance. The composite achieves an optimal shielding effectiveness of 32.6 dB and compressive strength of 38.31 MPa, respectively, improved by 65.4 and 123.4% compared to the pristine carbon foam. Simultaneously, the composite also exhibits desirable electrochemical and photothermal conversion properties. This research offers insights into the design of composites that excel in electromagnetic interference shielding, mechanical robustness, and multifunctionality.

    Copyright © 2025 American Chemical Society

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    Supporting Information

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acsnano.4c13329.

    • XRD, SEM, XPS, and TEM data of mesophase pitch, needle-like Co3O4 materials, Co-nanoparticles, and carbon foam composites; viscosity of the mesophase pitches with different amounts of Co3O4 materials; Young’s modulus, simulated compressive strain–stress curves, transmission coefficient, and infrared thermal images of carbon foam composites; table of the porosity of the carbon foam composites and performance comparison of the carbon foam composites with the reported materials (PDF)

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    This article is cited by 2 publications.

    1. Haitao Li, Qingchun Yan, Jihao Li, Jieshan Qiu, Haijiao Zhang. Porous Carbon Materials: from Traditional Synthesis, Machine Learning‐Assisted Design, to Their Applications in Advanced Energy Storage and Conversion. Advanced Functional Materials 2025, 120 https://doi.org/10.1002/adfm.202504272
    2. Danyu Liu, Pan Xue, Jingli Zhang, Yingjia Tong, Yixuan Zhang, Yajing Yu, Qingda Zhang, Mengfei Huang, Yiheng Gao, Jie Li, Qufu Wei, Pengfei Lv. Robust integration of p-MXene ink with a bacterial cellulose-reinforced polymer enables dynamic interaction of superior electromagnetic shielding and sensing. Journal of Materials Chemistry A 2025, 145 https://doi.org/10.1039/D5TA01796C

    ACS Nano

    Cite this: ACS Nano 2025, 19, 1, 1198–1210
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acsnano.4c13329
    Published January 2, 2025
    Copyright © 2025 American Chemical Society

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