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    Colossal Ultraviolet Photoresponsivity of Few-Layer Black Phosphorus
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    † ‡ †Department of Physics, ‡Centre for Advanced 2D Materials and Graphene Research Centre, and ∥Department of Chemistry, National University of Singapore, 117542, Singapore
    § NanoCore, National University of Singapore, 117576, Singapore
    ⊥ National University of Singapore (Suzhou) Research Institute, 377 Lin Quan Street, Suzhou Industrial Park, Jiang Su 215123, China
    *Address correspondence to [email protected]
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    ACS Nano

    Cite this: ACS Nano 2015, 9, 8, 8070–8077
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    https://doi.org/10.1021/acsnano.5b01922
    Published July 24, 2015
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    Black phosphorus has an orthorhombic layered structure with a layer-dependent direct band gap from monolayer to bulk, making this material an emerging material for photodetection. Inspired by this and the recent excitement over this material, we studied the optoelectronics characteristics of high-quality, few-layer black phosphorus-based photodetectors over a wide spectrum ranging from near-ultraviolet (UV) to near-infrared (NIR). It is demonstrated for the first time that black phosphorus can be configured as an excellent UV photodetector with a specific detectivity ∼3 × 1013 Jones. More critically, we found that the UV photoresponsivity can be significantly enhanced to ∼9 × 104 A W–1 by applying a source-drain bias (VSD) of 3 V, which is the highest ever measured in any 2D material and 107 times higher than the previously reported value for black phosphorus. We attribute such a colossal UV photoresponsivity to the resonant-interband transition between two specially nested valence and conduction bands. These nested bands provide an unusually high density of states for highly efficient UV absorption due to the singularity of their nature.

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    2. Tiancai Jiang, Xianke Wu, Zhixue He, Zhen Li, Ying Qiu, Jin Tao, Rui Xiong, Xi Xiao. Two-Dimensional SnSe Films on Paper Substrates for Flexible Broadband Photodetectors. ACS Applied Nano Materials 2024, 7 (3) , 2992-3000. https://doi.org/10.1021/acsanm.3c05369
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    5. Kaixiang Du, Quanjiang Lv, Zhiping Liang, Guiwu Liu, Shahid Hussain, Junlin Liu, Guanjun Qiao. Trends in the Preparation and Passivation Techniques of Black Phosphorus Nanostructures for Optoelectronics Applications: A Review. ACS Applied Nano Materials 2023, 6 (5) , 3159-3183. https://doi.org/10.1021/acsanm.2c05549
    6. Xiaozhi Bao, Linqing Zhuo, Weikang Dong, Junpo Guo, Gang Wang, Bingzhe Wang, Qi Wei, Zongyu Huang, Jianding Li, Jingjun Shen, Jianhui Yu, Zhaogang Nie, Wencai Ren, Guanyu Liu, Guichuan Xing, Huaiyu Shao. Black Arsenic–Phosphorus Nanosheets for Highly Responsive Photodetection and Dual-Wavelength Ultrafast Pulse Generation at Telecommunication Bands. ACS Applied Materials & Interfaces 2022, 14 (46) , 52270-52278. https://doi.org/10.1021/acsami.2c10857
    7. Shiyi Han, Yan Zhao, Nguyen Tuan Hung, Bo Xu, Riichiro Saito, Jin Zhang, Lianming Tong. Complex Raman Tensor in Helicity-Changing Raman Spectra of Black Phosphorus under Circularly Polarized Light. The Journal of Physical Chemistry Letters 2022, 13 (5) , 1241-1248. https://doi.org/10.1021/acs.jpclett.1c03826
    8. Meirong Li, Chengliang Mao, Lan Ling. In Situ Visualization on Surface Oxidative Corrosion with Free Radicals: Black Phosphorus Nanoflake as an Example. Environmental Science & Technology 2022, 56 (1) , 361-367. https://doi.org/10.1021/acs.est.1c06567
    9. Ziming Wang, Peng Luo, Bing Han, Xiang Zhang, Shuqi Zhao, Shilei Wang, Xiaohua Chen, Limei Wei, Sijie Yang, Xing Zhou, Shanpeng Wang, Xutang Tao, Tianyou Zhai. Strong In-Plane Anisotropic SiP2 as a IV–V 2D Semiconductor for Polarized Photodetection. ACS Nano 2021, 15 (12) , 20442-20452. https://doi.org/10.1021/acsnano.1c08892
    10. Guozhen He, Tao Dong, Zhaochu Yang, Per Ohlckers. Tuning 2D Black Phosphorus: Defect Tailoring and Surface Functionalization. Chemistry of Materials 2019, 31 (24) , 9917-9938. https://doi.org/10.1021/acs.chemmater.9b03639
    11. Junjia Wang, Adrien Rousseau, Elad Eizner, Anne-Laurence Phaneuf-L’Heureux, Léonard Schue, Sébastien Francoeur, Stéphane Kéna-Cohen. Spectral Responsivity and Photoconductive Gain in Thin Film Black Phosphorus Photodetectors. ACS Photonics 2019, 6 (12) , 3092-3099. https://doi.org/10.1021/acsphotonics.9b00951
    12. Do-Hyun Kwak, Parthiban Ramasamy, Yang-Soo Lee, Min-Hye Jeong, Jong-Soo Lee. High-Performance Hybrid InP QDs/Black Phosphorus Photodetector. ACS Applied Materials & Interfaces 2019, 11 (32) , 29041-29046. https://doi.org/10.1021/acsami.9b07910
    13. Parikshit Sahatiya, S. Solomon Jones, Venkat Mattela, Sushmee Badhulika. Direct Growth of Black Phosphorus (p-Type) on a Flexible Substrate with Dual Role of Two-Dimensional ZnO (n-Type) as Effective Passivation and Enabling Highly Stable Broadband Photodetection. ACS Applied Electronic Materials 2019, 1 (7) , 1076-1083. https://doi.org/10.1021/acsaelm.9b00026
    14. Youngsu Lee, Doo-Seung Um, Seongdong Lim, Hochan Lee, Minsoo P. Kim, Tzu-Yi Yang, Yu-Lun Chueh, Hyung-jun Kim, Hyunhyub Ko. Gate-Tunable and Programmable n-InGaAs/Black Phosphorus Heterojunction Diodes. ACS Applied Materials & Interfaces 2019, 11 (26) , 23382-23391. https://doi.org/10.1021/acsami.9b07701
    15. Seyed Ali Hosseini, Ali Esfandiar, Azam Iraji Zad, Seyed Hossein Hosseini-Shokouh, Seyed Mohammad Mahdavi. High-Photoresponsive Backward Diode by Two-Dimensional SnS2/Silicon Heterostructure. ACS Photonics 2019, 6 (3) , 728-734. https://doi.org/10.1021/acsphotonics.8b01626
    16. Li Huang, Bowei Dong, Xin Guo, Yuhua Chang, Nan Chen, Xin Huang, Wugang Liao, Chunxiang Zhu, Hong Wang, Chengkuo Lee, Kah-Wee Ang. Waveguide-Integrated Black Phosphorus Photodetector for Mid-Infrared Applications. ACS Nano 2019, 13 (1) , 913-921. https://doi.org/10.1021/acsnano.8b08758
    17. Bowei Dong Li Huang Chengkuo Lee Kah-Wee Ang . Black Phosphorus Based Photodetectors. 2019, 135-153. https://doi.org/10.1021/bk-2019-1333.ch007
    18. Arnob Islam, Wei Du, Vida Pashaei, Hao Jia, Zenghui Wang, Jaesung Lee, Guo Jun Ye, Xian Hui Chen, Philip X.-L. Feng. Discerning Black Phosphorus Crystal Orientation and Anisotropy by Polarized Reflectance Measurement. ACS Applied Materials & Interfaces 2018, 10 (30) , 25629-25637. https://doi.org/10.1021/acsami.8b05408
    19. Sangik Lee, Chansoo Yoon, Ji Hye Lee, Yeon Soo Kim, Mi Jung Lee, Wondong Kim, Jaeyoon Baik, Quanxi Jia, Bae Ho Park. Enhanced Performance of Field-Effect Transistors Based on Black Phosphorus Channels Reduced by Galvanic Corrosion of Al Overlayers. ACS Applied Materials & Interfaces 2018, 10 (22) , 18895-18901. https://doi.org/10.1021/acsami.8b04700
    20. Shaofan Yuan, Chenfei Shen, Bingchen Deng, Xiaolong Chen, Qiushi Guo, Yuqiang Ma, Ahmad Abbas, Bilu Liu, Ralf Haiges, Claudia Ott, Tom Nilges, Kenji Watanabe, Takashi Taniguchi, Ofer Sinai, Doron Naveh, Chongwu Zhou, Fengnian Xia. Air-Stable Room-Temperature Mid-Infrared Photodetectors Based on hBN/Black Arsenic Phosphorus/hBN Heterostructures. Nano Letters 2018, 18 (5) , 3172-3179. https://doi.org/10.1021/acs.nanolett.8b00835
    21. A-Young Lee, Hyun-Soo Ra, Do-Hyun Kwak, Min-Hye Jeong, Jeong-Hyun Park, Yeon-Su Kang, Weon-Sik Chae, Jong-Soo Lee. Hybrid Black Phosphorus/Zero-Dimensional Quantum Dot Phototransistors: Tunable Photodoping and Enhanced Photoresponsivity. ACS Applied Materials & Interfaces 2018, 10 (18) , 16033-16040. https://doi.org/10.1021/acsami.8b03285
    22. Jianbo Gao, Apparao M. Rao, Hongbo Li, Jianbing Zhang, Ou Chen. Carrier Transport Dynamics in High Speed Black Phosphorus Photodetectors. ACS Photonics 2018, 5 (4) , 1412-1417. https://doi.org/10.1021/acsphotonics.7b01431
    23. Bingchao Yang, Chunxue Hao, Fusheng Wen, Bochong Wang, Congpu Mu, Jianyong Xiang, Lei Li, Bo Xu, Zhisheng Zhao, Zhongyuan Liu, and Yongjun Tian . Flexible Black-Phosphorus Nanoflake/Carbon Nanotube Composite Paper for High-Performance All-Solid-State Supercapacitors. ACS Applied Materials & Interfaces 2017, 9 (51) , 44478-44484. https://doi.org/10.1021/acsami.7b13572
    24. Qixing Wang, Jun Guo, Zijing Ding, Dianyu Qi, Jizhou Jiang, Zhuo Wang, Wei Chen, Yuanjiang Xiang, Wenjing Zhang, and Andrew T. S. Wee . Fabry–Perot Cavity-Enhanced Optical Absorption in Ultrasensitive Tunable Photodiodes Based on Hybrid 2D Materials. Nano Letters 2017, 17 (12) , 7593-7598. https://doi.org/10.1021/acs.nanolett.7b03579
    25. Li Huang, Wee Chong Tan, Lin Wang, Bowei Dong, Chengkuo Lee, and Kah-Wee Ang . Infrared Black Phosphorus Phototransistor with Tunable Responsivity and Low Noise Equivalent Power. ACS Applied Materials & Interfaces 2017, 9 (41) , 36130-36136. https://doi.org/10.1021/acsami.7b09713
    26. Cheng Han, Zehua Hu, Lidia C. Gomes, Yang Bao, Alexandra Carvalho, Sherman J. R. Tan, Bo Lei, Du Xiang, Jing Wu, Dianyu Qi, Li Wang, Fengwei Huo, Wei Huang, Kian Ping Loh, and Wei Chen . Surface Functionalization of Black Phosphorus via Potassium toward High-Performance Complementary Devices. Nano Letters 2017, 17 (7) , 4122-4129. https://doi.org/10.1021/acs.nanolett.7b00903
    27. Dibyendu Ghosh, Sutanu Kapri, and Sayan Bhattacharyya . Phenomenal Ultraviolet Photoresponsivity and Detectivity of Graphene Dots Immobilized on Zinc Oxide Nanorods. ACS Applied Materials & Interfaces 2016, 8 (51) , 35496-35504. https://doi.org/10.1021/acsami.6b13037
    28. Dominik Kufer and Gerasimos Konstantatos . Photo-FETs: Phototransistors Enabled by 2D and 0D Nanomaterials. ACS Photonics 2016, 3 (12) , 2197-2210. https://doi.org/10.1021/acsphotonics.6b00391
    29. Hyuksang Kwon, Sung Won Seo, Tae Gun Kim, Eun Seong Lee, Phung Thi Lanh, Sena Yang, Sunmin Ryu, and Jeong Won Kim . Ultrathin and Flat Layer Black Phosphorus Fabricated by Reactive Oxygen and Water Rinse. ACS Nano 2016, 10 (9) , 8723-8731. https://doi.org/10.1021/acsnano.6b04194
    30. Junpeng Lu, Jiong Yang, Alexandra Carvalho, Hongwei Liu, Yuerui Lu, and Chorng Haur Sow . Light–Matter Interactions in Phosphorene. Accounts of Chemical Research 2016, 49 (9) , 1806-1815. https://doi.org/10.1021/acs.accounts.6b00266
    31. Zenghui Wang, Hao Jia, Xu-Qian Zheng, Rui Yang, G. J. Ye, X. H. Chen, and Philip X.-L. Feng . Resolving and Tuning Mechanical Anisotropy in Black Phosphorus via Nanomechanical Multimode Resonance Spectromicroscopy. Nano Letters 2016, 16 (9) , 5394-5400. https://doi.org/10.1021/acs.nanolett.6b01598
    32. Enze Zhang, Peng Wang, Zhe Li, Haifeng Wang, Chaoyu Song, Ce Huang, Zhi-Gang Chen, Lei Yang, Kaitai Zhang, Shiheng Lu, Weiyi Wang, Shanshan Liu, Hehai Fang, Xiaohao Zhou, Hugen Yan, Jin Zou, Xiangang Wan, Peng Zhou, Weida Hu, and Faxian Xiu . Tunable Ambipolar Polarization-Sensitive Photodetectors Based on High-Anisotropy ReSe2 Nanosheets. ACS Nano 2016, 10 (8) , 8067-8077. https://doi.org/10.1021/acsnano.6b04165
    33. Prashant Bhaskar, Alexander W. Achtstein, Martien J. W. Vermeulen, and Laurens D. A. Siebbeles . Radiatively Dominated Charge Carrier Recombination in Black Phosphorus. The Journal of Physical Chemistry C 2016, 120 (25) , 13836-13842. https://doi.org/10.1021/acs.jpcc.6b04741
    34. Guangzhen Shen, Xirui Tian, Limin Cao, Hongli Guo, Xintong Li, Yishu Tian, Xuefeng Cui, Min Feng, Jin Zhao, Bing Wang, Hrvoje Petek, Shijing Tan. Ultrafast energizing the parity-forbidden dark exciton in black phosphorus. Nature Communications 2025, 16 (1) https://doi.org/10.1038/s41467-025-58930-z
    35. Zhengwang Chen, Jiajun Linghu, Qiang Zhang, Junwei Che, Xuezhi Wang, Songrui Wei. A highly polarization-sensitive near-infrared photodetector based on two-dimensional germanane/α-CdS heterostructure. 2D Materials 2025, 12 (2) , 025012. https://doi.org/10.1088/2053-1583/adac70
    36. Beiyun Liu, Chengjie Zhi, Guanxia Dai, Boxing An, Feihong Chu, Jicheng Mo, Xiuyan Zhang. Ultra-wide range infrared photodetector based on BP/MoSe2 heterojunction. Micro and Nanostructures 2025, 199 , 208081. https://doi.org/10.1016/j.micrna.2025.208081
    37. Arshiya Ansari, Shahzad Ahmed, Mohsenah H. J. Mashniwi, Sangram M. Shinde, Afzal Khan, Pranay Ranjan, Devendra Singh Negi. Review: recent advancements in photodetection utilizing inorganic, organic low-dimensional materials and their hybrids. Journal of Materials Science 2025, 60 (6) , 2711-2743. https://doi.org/10.1007/s10853-024-10572-0
    38. Yangjun Gao, Chenhao Zhang, Liangjie Zhao, Xuanli Zheng, Yiyan Cao, Feiya Xu, Chunmiao Zhang, Zhiming Wu, Yaping Wu, Xu Li, Junyong Kang. Van der Waals GeSe with Strain‐ and Gate‐Tunable Linear Dichroism for Wearable Electronics. Small 2025, 21 (1) https://doi.org/10.1002/smll.202406217
    39. Nagaraj Nandihalli. Performance analysis of photodetectors based on 2D materials and heterostructures. Critical Reviews in Solid State and Materials Sciences 2024, 49 (6) , 999-1085. https://doi.org/10.1080/10408436.2023.2289928
    40. Zhi-Hao Huang, Liu-Xing Peng, Xiao-Lei Liu, Kun Sun, Jie-Feng Liu, Fu-Mei Yang, Qing Wu. Advancing sensing frontiers: elevating performance metrics and extending applications through two-dimensional materials. Rare Metals 2024, 463 https://doi.org/10.1007/s12598-024-03012-0
    41. Fengkai Ruan, Changqian Liu, Jie Zeng, Fucong Zhang, Yu Jiang, Zhenghong Zuo, Chengyong He. Multi-omics integration identifies ferroptosis involved in black phosphorus quantum dots-induced renal injury. Science of The Total Environment 2024, 947 , 174532. https://doi.org/10.1016/j.scitotenv.2024.174532
    42. Rajwali Khan, Naveed Ur Rahman, Muhammad Faisal Hayat, Djamel Ghernaout, Alsamani A. M. Salih, Ghulam Abbas Ashraf, Abdus Samad, Muhammad Adil Mahmood, Nasir Rahman, Mohammad Sohail, Shahid Iqbal, Sherzod Abdullaev, Alamzeb Khan. Unveiling cutting-edge developments: architectures and nanostructured materials for application in optoelectronic artificial synapses. Nanoscale 2024, 16 (31) , 14589-14620. https://doi.org/10.1039/D4NR00904E
    43. Muna M. Shalaan, Mohammed K. Khalaf, Bilal K. Al-Rawi. Impact of gold nanoparticles doping on the characterization of vacuum ultraviolet MSM detector utilizing tungsten trioxide thin film. Journal of Optics 2024, 15 https://doi.org/10.1007/s12596-024-02047-x
    44. Shan Yan, Jia Yang, Yuchen Cai, Yanrong Wang, Shuhui Li, Xueying Zhan, Feng Wang, Jun He, Zhenxing Wang. Filter‐Free UV Photodetectors Based on Unipolar Barrier Van der Waals α‐In 2 Se 3 /h‐BN Heterostructures. Small 2024, 32 https://doi.org/10.1002/smll.202401996
    45. Xiuxiu Wang, Suofu Wang, Yanwei Wu, Wenhui Wang, Zhangyu Cao, Binbin Wei, Tao Han, Feng Li, Shaoliang Wang, Lei Shan, Mingsheng Long. A Self‐Powered Photodetector Based on Graphene Enhanced WSe 2 /PtSe 2 Heterodiode with Fast Speed and Broadband Response. Advanced Optical Materials 2024, 12 (18) https://doi.org/10.1002/adom.202400052
    46. Chensheng Li, Ruhao Pan, Changzhi Gu, Haiming Guo, Junjie Li. Reconfigurable Micro/Nano‐Optical Devices Based on Phase Transitions: From Materials, Mechanisms to Applications. Advanced Science 2024, 11 (20) https://doi.org/10.1002/advs.202306344
    47. Jingying Luo, Gurpreet Singh Selopal, Xin Tong, Zhiming Wang. Colloidal quantum dots and two‐dimensional material heterostructures for photodetector applications. Electron 2024, 2 (2) https://doi.org/10.1002/elt2.30
    48. Weichun HUANG, You ZI, Mengke WANG, Lanping HU, Yunzheng WANG, Zhongjian XIE, Meng QIU, Han ZHANG. Advancements in photophysics research and applications of phosphorene semiconductors. Journal of Shenzhen University Science and Engineering 2024, 41 (3) , 323-347. https://doi.org/10.3724/SP.J.1249.2024.03323
    49. Rajesh Jana, Sagnik Ghosh, Ritamay Bhunia, Avijit Chowdhury. Recent developments in the state-of-the-art optoelectronic synaptic devices based on 2D materials: a review. Journal of Materials Chemistry C 2024, 12 (15) , 5299-5338. https://doi.org/10.1039/D4TC00371C
    50. Xiangzhe Zhang, Chuyun Deng, Tongcheng Yu, Xingheng Yan, Wei Luo, Bowen Lv, Jinxin Liu, Junhao Cai, Haitao Wei, Junsheng Li, Gang Peng, Yaping Yang, Shiqiao Qin. Ultraclean surface restoration and giant photoresponse enhancement of violet phosphorus. Applied Surface Science 2024, 651 , 159232. https://doi.org/10.1016/j.apsusc.2023.159232
    51. Fengkai Ruan, Jie Zeng, Changqian Liu, Jianrong Han, Naying Zheng, Kun Li, Hanying Yin, Mingtao Wu, Xiaoyan Ding, Changshun Han, Lingtao Yang, Chunyan Yang, Dai Wang, Nengming Xiao, Zhenghong Zuo, Chengyong He. Gut microbiota dysbiosis mediates mouse kidney fibrosis induced by black phosphorus quantum dots. Nano Today 2024, 55 , 102203. https://doi.org/10.1016/j.nantod.2024.102203
    52. Yuan Li, Xinyu Cheng, Ying Ding, Longfei Guo, Tianchen Wang, Gaofeng Xu, Wu-Ming Liu. Vacancy-induced giant photogalvanic effect in TiSe 2 heterojunctions. Physical Review B 2024, 109 (16) https://doi.org/10.1103/PhysRevB.109.165438
    53. Xiangzhe Zhang, Bowen Lv, Haitao Wei, Xingheng Yan, Gang Peng, Shiqiao Qin. Photodegradation and van der Waals Passivation of Violet Phosphorus. Nanomaterials 2024, 14 (5) , 422. https://doi.org/10.3390/nano14050422
    54. Mengting Liu, Xiangyu Fan, Jie rui Fu, Yang Li, Tai Yao, Yi Wang, Yumin Zhang, Xianjie Wang, Yonghua Sheng, Bo Song. Ionic liquid gated black phosphorus/SiC-based 2D/3D mixed-dimensional photodetector. Applied Physics Letters 2024, 124 (6) https://doi.org/10.1063/5.0188811
    55. Shuang Meng, Jia Zhou. Armchair zinc chalcogenide nanoribbons for high-performance photodetectors: A computational study. Applied Physics Letters 2024, 124 (3) https://doi.org/10.1063/5.0171954
    56. Degao Xu, Jindou Ru, Biao Cai, Jianing Tan, Kaike Yang, Guowei Yang, Gang Ouyang. Theoretical Design of a Multifunctional Two-Dimensional Hf Ge Te 4 -Based Optoelectronic Device Utilizing the Anisotropic Photogalvanic Effect. Physical Review Applied 2023, 20 (5) https://doi.org/10.1103/PhysRevApplied.20.054025
    57. H. Rezania, M. Abdi, E. Nourian, B. Astinchap. Effects of spin–orbit coupling on transmission and absorption of electromagnetic waves in strained armchair phosphorene nanoribbons. RSC Advances 2023, 13 (32) , 22287-22301. https://doi.org/10.1039/D3RA03686C
    58. Yaoyun Zhu, Shuang Meng, Jia Zhou. Nonequilibrium quantum transport properties of tetragonal zinc chalcogenide monolayers. Materials Today Electronics 2023, 4 , 100041. https://doi.org/10.1016/j.mtelec.2023.100041
    59. Yaoyun Zhu, Shuang Meng, Jia Zhou. Electronic transport properties of two-dimensional tetragonal zinc chalcogenides. Physical Chemistry Chemical Physics 2023, 25 (20) , 14635-14641. https://doi.org/10.1039/D3CP00864A
    60. Tingting Guo, Zixu Sa, Pengfei Wei, Yuxuan Jian, Xiang Chen, Zhesheng Chen, Jose Avila, Pavel Dudin, Zai-xing Yang, Xiufeng Song, Fengjing Liu, Shengli Zhang. High-performance flexible broadband photodetectors enabled by 2D Ta 2 NiSe 5 nanosheets. 2D Materials 2023, 10 (2) , 025004. https://doi.org/10.1088/2053-1583/acb1c3
    61. Xiaoling Ye, Yining Du, Mingyang Wang, Benqing Liu, Jiangwei Liu, Syed Hassan Mujtaba Jafri, Wencheng Liu, Raffaello Papadakis, Xiaoxiao Zheng, Hu Li. Advances in the Field of Two-Dimensional Crystal-Based Photodetectors. Nanomaterials 2023, 13 (8) , 1379. https://doi.org/10.3390/nano13081379
    62. Ze Song, Binbin Wei, Qilong Wang, Wenhui Wang, Zhangyu Cao, Li Zhang, Qingge Mu, Tao Han, Feng Li, Xiangde Zhu, Lei Shan, Mingsheng Long. High-performance metal electrode-enhanced double parallel p–n heterojunctions photodetector. Journal of Applied Physics 2023, 133 (12) https://doi.org/10.1063/5.0141523
    63. Arun Kumar, Loredana Viscardi, Enver Faella, Filippo Giubileo, Kimberly Intonti, Aniello Pelella, Stephan Sleziona, Osamah Kharsah, Marika Schleberger, Antonio Di Bartolomeo. Black phosphorus unipolar transistor, memory, and photodetector. Journal of Materials Science 2023, 58 (6) , 2689-2699. https://doi.org/10.1007/s10853-023-08169-0
    64. Ming Yang, Hongxi Zhou, Jun Wang. Topological insulators photodetectors: Preparation, advances and application challenges. Materials Today Communications 2022, 33 , 104190. https://doi.org/10.1016/j.mtcomm.2022.104190
    65. Feng Zhang, Jiajie Pei, Alexander Baev, Marek Samoc, Yanqi Ge, Paras N. Prasad, Han Zhang. Photo-dynamics in 2D materials: Processes, tunability and device applications. Physics Reports 2022, 993 , 1-70. https://doi.org/10.1016/j.physrep.2022.09.005
    66. Xiao-Xi Li, Guang Zeng, Yu-Chun Li, Hao Zhang, Zhi-Gang Ji, Ying-Guo Yang, Man Luo, Wei-Da Hu, David Wei Zhang, Hong-Liang Lu. High responsivity and flexible deep-UV phototransistor based on Ta-doped β-Ga2O3. npj Flexible Electronics 2022, 6 (1) https://doi.org/10.1038/s41528-022-00179-3
    67. Jose Mario Galicia Hernandez, H. N. Fernandez-Escamilla, J. Guerrero Sanchez, Noboru Takeuchi. Electronic and optical properties of the buckled and puckered phases of phosphorene and arsenene. Scientific Reports 2022, 12 (1) https://doi.org/10.1038/s41598-022-24425-w
    68. Shiqi Li, Guoyi Huang, Yiding Jia, Bing Wang, Hongcheng Wang, Han Zhang. Photoelectronic properties and devices of 2D Xenes. Journal of Materials Science & Technology 2022, 126 , 44-59. https://doi.org/10.1016/j.jmst.2022.02.038
    69. Taimur Ahmed, Sumeet Walia. Defect Engineering in Layered Black Phosphorus for Multi-Functional Optoelectronics. 2022, 33-52. https://doi.org/10.1039/9781839162909-00033
    70. Xingyun Li, Bin Han, Xin Chen, Xiaofeng Li, Jian Weng, Qingchi Xu, Jun Xu. It takes two: advances in employing the interactions between black phosphorous and metals in various applications. Journal of Materials Chemistry A 2022, 10 (36) , 18490-18508. https://doi.org/10.1039/D2TA05490F
    71. Vivek Chaudhary, P Neugebauer, O Mounkachi, S Lahbabi, A El Fatimy. Phosphorene—an emerging two-dimensional material: recent advances in synthesis, functionalization, and applications. 2D Materials 2022, 9 (3) , 032001. https://doi.org/10.1088/2053-1583/ac6dc2
    72. Yang Gao, Yueqiu Hu, Guanghao Rui, Jun He, Yiping Cui, Bing Gu. Tunable absorptive nonlinearities of silver-modified few-layer black phosphorous nanocomposites. Optik 2022, 259 , 168969. https://doi.org/10.1016/j.ijleo.2022.168969
    73. Rong Qiao, Xiao Dong, Yangfan Li. Regulation of electronic and optical properties of monolayer black phosphorus by co-doping B and Si. AIP Advances 2022, 12 (6) https://doi.org/10.1063/5.0096441
    74. Maria Malik, Muhammad Aamir Iqbal, Jeong Ryeol Choi, Phuong V. Pham. 2D Materials for Efficient Photodetection: Overview, Mechanisms, Performance and UV-IR Range Applications. Frontiers in Chemistry 2022, 10 https://doi.org/10.3389/fchem.2022.905404
    75. Nasir Ilyas, Jinyong Wang, Chunmei Li, Dongyang Li, Hao Fu, Deen Gu, Xiangdong Jiang, Fucai Liu, Yadong Jiang, Wei Li. Nanostructured Materials and Architectures for Advanced Optoelectronic Synaptic Devices. Advanced Functional Materials 2022, 32 (15) https://doi.org/10.1002/adfm.202110976
    76. Ashok Kumar, Mustaque A Khan, Mahesh Kumar. Recent advances in UV photodetectors based on 2D materials: a review. Journal of Physics D: Applied Physics 2022, 55 (13) , 133002. https://doi.org/10.1088/1361-6463/ac33d7
    77. Shun Jiang, Jinzhao Li, Junyu Li, Jianjun Lai, Fei Yi. Metamaterial microbolometers for multi-spectral infrared polarization imaging. Optics Express 2022, 30 (6) , 9065. https://doi.org/10.1364/OE.452981
    78. Ayesha Khan Tareen, Karim Khan, Sarish Rehman, Muhammad Iqbal, Jian Yu, Nasir mahmood, Zewen Zhou, Jinde Yin, Chuan li, Han Zhang. Recent development in emerging phosphorene based novel materials: Progress, challenges, prospects and their fascinating sensing applications. Progress in Solid State Chemistry 2022, 65 , 100336. https://doi.org/10.1016/j.progsolidstchem.2021.100336
    79. Xiaoyang Cui, Yu Li Huang, Andrew Thye Shen Wee. Functionalized 2D materials. 2022, 127-155. https://doi.org/10.1016/B978-0-323-85457-3.00001-3
    80. Xu Li, Haiyang Liu, Congming Ke, Weiqing Tang, Mengyu Liu, Feihong Huang, Yaping Wu, Zhiming Wu, Junyong Kang. Review of Anisotropic 2D Materials: Controlled Growth, Optical Anisotropy Modulation, and Photonic Applications. Laser & Photonics Reviews 2021, 15 (12) https://doi.org/10.1002/lpor.202100322
    81. Shun Feng, Chi Liu, Qianbing Zhu, Xin Su, Wangwang Qian, Yun Sun, Chengxu Wang, Bo Li, Maolin Chen, Long Chen, Wei Chen, Lili Zhang, Chao Zhen, Feijiu Wang, Wencai Ren, Lichang Yin, Xiaomu Wang, Hui-Ming Cheng, Dong-Ming Sun. An ultrasensitive molybdenum-based double-heterojunction phototransistor. Nature Communications 2021, 12 (1) https://doi.org/10.1038/s41467-021-24397-x
    82. Mei Xian Low, Sruthi Kuriakose, Qian Liu, Patrick D. Taylor, Dashen Dong, Terry Chien-Jen Yang, Taimur Ahmed, Gregory Wilson, Michelle J. S. Spencer, Sherif Abdulkader Tawfik, Sharath Sriram, Madhu Bhaskaran, Prashant Sonar, Sumeet Walia. Black Phosphorus—Diketopyrrolopyrrole Polymer Semiconductor Hybrid for Enhanced Charge Transfer and Photodetection. Advanced Photonics Research 2021, 2 (11) https://doi.org/10.1002/adpr.202100150
    83. Hui Qiao, Huating Liu, Zongyu Huang, Rong Hu, Qian Ma, Jianxin Zhong, Xiang Qi. Tunable Electronic and Optical Properties of 2D Monoelemental Materials Beyond Graphene for Promising Applications. ENERGY & ENVIRONMENTAL MATERIALS 2021, 4 (4) , 522-543. https://doi.org/10.1002/eem2.12154
    84. Gustavo A. Saenz, Ravindra K. Mehta, Dalal Fadil, Anupama B. Kaul. Photocurrent Generation Mechanisms in Molybdenum‐Contacted Semiconducting Black Phosphorus and Contributions from the Photobolometric Effect. physica status solidi (a) 2021, 218 (20) https://doi.org/10.1002/pssa.202100196
    85. Cheng Yang, Guangcan Wang, Maomao Liu, Fei Yao, Huamin Li. Mechanism, Material, Design, and Implementation Principle of Two-Dimensional Material Photodetectors. Nanomaterials 2021, 11 (10) , 2688. https://doi.org/10.3390/nano11102688
    86. Seung Gi Seo, Seung Yeob Kim, Jinheon Jeong, Sung Hun Jin. Progress in light-to-frequency conversion circuits based on low dimensional semiconductors. Nano Research 2021, 14 (9) , 2938-2964. https://doi.org/10.1007/s12274-021-3586-6
    87. Mansoor Farbod, Rasoul Taheri, Abdolnabi Kosarian. High performance photoresponsivity and high frequency of phosphorene/metal heterojunction as Schottky photodiode rectifier. Applied Materials Today 2021, 24 , 101092. https://doi.org/10.1016/j.apmt.2021.101092
    88. Ying-Ying Li, Bo Gao, Ying Han, Bing-Kun Chen, Jia-Yu Huo. Optoelectronic characteristics and application of black phosphorus and its analogs. Frontiers of Physics 2021, 16 (4) https://doi.org/10.1007/s11467-021-1052-2
    89. Duc Anh Nguyen, Dae Young Park, Juchan Lee, Ngoc Thanh Duong, Chulho Park, Duc Hieu Nguyen, Thi Suong Le, Dongseok Suh, Heejun Yang, Mun Seok Jeong. Patterning of type-II Dirac semimetal PtTe2 for optimized interface of tellurene optoelectronic device. Nano Energy 2021, 86 , 106049. https://doi.org/10.1016/j.nanoen.2021.106049
    90. Tiantian Wang, Feng Chi, Mingyan Chen, Jia Liu. Giant Photogalvanic effect in Janus monolayer In2SSe. Optics Communications 2021, 492 , 126945. https://doi.org/10.1016/j.optcom.2021.126945
    91. Ningqin Deng, He Tian, Jian Zhang, Jinming Jian, Fan Wu, Yang Shen, Yi Yang, Tian-Ling Ren. Black phosphorus junctions and their electrical and optoelectronic applications. Journal of Semiconductors 2021, 42 (8) , 081001. https://doi.org/10.1088/1674-4926/42/8/081001
    92. Wenhui Wang, Junpeng Lu, Zhenhua Ni. Position-sensitive detectors based on two-dimensional materials. Nano Research 2021, 14 (6) , 1889-1900. https://doi.org/10.1007/s12274-020-2917-3
    93. Xinyue Niu, Ying Yu, Jiadong Yao, Mengge Li, Jian Sha, Yewu Wang. Preparation of black phosphorus quantum dots and the surface decoration effect on the monolayer MoS2 photodetectors. Chemical Physics Letters 2021, 772 , 138571. https://doi.org/10.1016/j.cplett.2021.138571
    94. Qianqian Hu, Yang Cao, Yu Liu, Yingxin Wang, Chenfeng Wang, Jia-Lin Zhu, Ning Yang, Weidong Chu, Wanyun Ma, Jia-Lin Sun. Ultra-wideband self-powered photodetector based on suspended reduced graphene oxide with asymmetric metal contacts. RSC Advances 2021, 11 (32) , 19482-19491. https://doi.org/10.1039/D1RA03438C
    95. Bhuvaneshwari Ezhilmaran, Abhinandan Patra, Stenny Benny, Sreelakshmi M. R., Akshay V. V., S. Venkataprasad Bhat, Chandra Sekhar Rout. Recent developments in the photodetector applications of Schottky diodes based on 2D materials. Journal of Materials Chemistry C 2021, 9 (19) , 6122-6150. https://doi.org/10.1039/D1TC00949D
    96. Vyacheslav D. Neverov, Alexander E. Lukyanov, Yaroslav V. Zhumagulov, Andrey V. Krasavin, Vasili Perebeinos. Polaronic signatures in pristine phosphorene. Physical Review Materials 2021, 5 (5) https://doi.org/10.1103/PhysRevMaterials.5.054008
    97. Ruyue Han, Shun Feng, Dong-Ming Sun, Hui-Ming Cheng. Properties and photodetector applications of two-dimensional black arsenic phosphorus and black phosphorus. Science China Information Sciences 2021, 64 (4) https://doi.org/10.1007/s11432-020-3172-1
    98. Taimur Ahmed, Muhammad Tahir, Mei Xian Low, Yanyun Ren, Sherif Abdulkader Tawfik, Edwin L. H. Mayes, Sruthi Kuriakose, Shahid Nawaz, Michelle J. S. Spencer, Hua Chen, Madhu Bhaskaran, Sharath Sriram, Sumeet Walia. Fully Light‐Controlled Memory and Neuromorphic Computation in Layered Black Phosphorus. Advanced Materials 2021, 33 (10) https://doi.org/10.1002/adma.202004207
    99. Shuchi Kaushik, Sahin Sorifi, Rajendra Singh. Study of temperature dependent behavior of h-BN nanoflakes based deep UV photodetector. Photonics and Nanostructures - Fundamentals and Applications 2021, 43 , 100887. https://doi.org/10.1016/j.photonics.2020.100887
    100. Shiu-Ming Huang, Jai-Lung Hung, Mitch Chou, Chi-Yang Chen, Fang-Chen Liu, Ruei-San Chen. The Highly Uniform Photoresponsivity from Visible to Near IR Light in Sb2Te3 Flakes. Sensors 2021, 21 (4) , 1535. https://doi.org/10.3390/s21041535
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