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A Commercial Conducting Polymer as Both Binder and Conductive Additive for Silicon Nanoparticle-Based Lithium-Ion Battery Negative Electrodes

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† Centre for Research on Adaptive Nanostructures and Nanodevices (CRANN) & Advanced Materials Bio-Engineering Research Centre (AMBER), Trinity College Dublin, Dublin 2, Ireland
‡ School of Physics, Trinity College Dublin, Dublin 2, Ireland
§ School of Chemistry, Trinity College Dublin, Dublin 2, Ireland
∥ Efficient Energy Transfer Deptmartment, Bell Labs Research, Nokia, Blanchardstown Business & Technology Park, Snugborough Road, Dublin 15, Ireland
*E-mail: [email protected]
*E-mail: [email protected]
Cite this: ACS Nano 2016, 10, 3, 3702–3713
Publication Date (Web):March 3, 2016
https://doi.org/10.1021/acsnano.6b00218
Copyright © 2016 American Chemical Society
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    This work describes silicon nanoparticle-based lithium-ion battery negative electrodes where multiple nonactive electrode additives (usually carbon black and an inert polymer binder) are replaced with a single conductive binder, in this case, the conducting polymer PEDOT:PSS. While enabling the production of well-mixed slurry-cast electrodes with high silicon content (up to 95 wt %), this combination eliminates the well-known occurrence of capacity losses due to physical separation of the silicon and traditional inorganic conductive additives during repeated lithiation/delithiation processes. Using an in situ secondary doping treatment of the PEDOT:PSS with small quantities of formic acid, electrodes containing 80 wt % SiNPs can be prepared with electrical conductivity as high as 4.2 S/cm. Even at the relatively high areal loading of 1 mg/cm2, this system demonstrated a first cycle lithiation capacity of 3685 mA·h/g (based on the SiNP mass) and a first cycle efficiency of ∼78%. After 100 repeated cycles at 1 A/g this electrode was still able to store an impressive 1950 mA·h/g normalized to Si mass (∼75% capacity retention), corresponding to 1542 mA·h/g when the capacity is normalized by the total electrode mass. At the maximum electrode thickness studied (∼1.5 mg/cm2), a high areal capacity of 3 mA·h/cm2 was achieved. Importantly, these electrodes are based on commercially available components and are produced by the standard slurry coating methods required for large-scale electrode production. Hence, the results presented here are highly relevant for the realization of commercial LiB negative electrodes that surpass the performance of current graphite-based negative electrode systems.

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    70. Deepa Elizabeth Mathew, R. Baby Dhanalakshmi, S. Sathya, M. Kathiresan, Sabu Thomas, Mohamed H. Alkordi, A. Manuel Stephan. Comparative study of different lithium salts as electrolyte additives of Li/SiOx–Si–C half-cells for lithium sulfur batteries. SN Applied Sciences 2023, 5 (8) https://doi.org/10.1007/s42452-023-05410-y
    71. Xiao Zhan, Miao Li, Sha Li, Xikun Pang, Fangqin Mao, Huiqun Wang, Zhefei Sun, Xiang Han, Bing Jiang, Yan-Bing He, Meicheng Li, Qiaobao Zhang, Li Zhang. Challenges and opportunities towards silicon-based all-solid-state batteries. Energy Storage Materials 2023, 61 , 102875. https://doi.org/10.1016/j.ensm.2023.102875
    72. Linfeng Chen, Jun Wang, Lihong Liang. Size dependent thermal cracking of silicon anodes. Engineering Fracture Mechanics 2023, 288 , 109378. https://doi.org/10.1016/j.engfracmech.2023.109378
    73. Huilin Shen, Qilin Wang, Zheng Chen, Changru Rong, Danming Chao. Application and Development of Silicon Anode Binders for Lithium-Ion Batteries. Materials 2023, 16 (12) , 4266. https://doi.org/10.3390/ma16124266
    74. Y. Tzeng, C.-Y. Jhan, K.-M. Chiu, Y.-C. Wu, G.-Y. Chen, P.-S. Wang. Si–Ni-alloy-assisted very high-areal-capacity silicon-based anode on Ni foam for lithium ion battery. Materials Today Chemistry 2023, 30 , 101570. https://doi.org/10.1016/j.mtchem.2023.101570
    75. Masytha Nuzula Ramdhiny, Ju‐Won Jeon. Design of multifunctional polymeric binders in silicon anodes for lithium‐ion batteries. Carbon Energy 2023, https://doi.org/10.1002/cey2.356
    76. Hao Chen, Shanqing Zhang, Gao Liu, Cheng Yan. Polymeric Binders in Modern Metal‐ion Batteries. 2023, 61-117. https://doi.org/10.1002/9783527838615.ch2
    77. Megha Goyal, Satya Narayan Agarwal, Kulwant Singh, Nitu Bhatnagar. Synthesis and characterization of poly [(3,4‐ethylenedioxy) thiophene]:polystyrene sulfonate ( PEDOT : PSS ) for energy storage device application. Journal of Applied Polymer Science 2023, 140 (19) https://doi.org/10.1002/app.53830
    78. Yanxiu Liu, Rong Shao, Ruiyu Jiang, Xinyu Song, Zhong Jin, Lin Sun. A review of existing and emerging binders for silicon anodic Li-ion batteries. Nano Research 2023, 16 (5) , 6736-6752. https://doi.org/10.1007/s12274-022-5281-7
    79. Anukriti Pokhriyal, Rosa M. González-Gil, Leandro N. Bengoa, Pedro Gómez-Romero. Nanostructured Thick Electrode Strategies toward Enhanced Electrode–Electrolyte Interfaces. Materials 2023, 16 (9) , 3439. https://doi.org/10.3390/ma16093439
    80. Chuanfang (John) Zhang, Wengao Zhao, Sang‐Hoon Park, Tiezhu Guo, Shungui Deng, Andrés Seral‐Ascaso, Mayan Si, Rabeb Grissa, Sebastian Barwich, Valeria Nicolosi. Interconnected Metallic Membrane Enabled by MXene Inks Toward High‐Rate Anode and High‐Voltage Cathode for Li‐Ion Batteries. Advanced Functional Materials 2023, 33 (14) https://doi.org/10.1002/adfm.202213860
    81. Trevor R. Martin, Leah Rynearson, Mackenzie Kuller, Joseph Quinn, Chongmin Wang, Brett Lucht, Nathan R. Neale. Conjugated Imine Polymer Synthesized via Step‐Growth Metathesis for Highly Stable Silicon Nanoparticle Anodes in Lithium‐Ion Batteries. Advanced Energy Materials 2023, 13 (13) https://doi.org/10.1002/aenm.202203921
    82. R. Maji, M.A. Salvador, A. Ruini, R. Magri, E. Degoli. A first-principles study of self-healing binders for next-generation Si-based lithium-ion batteries. Materials Today Chemistry 2023, 29 , 101474. https://doi.org/10.1016/j.mtchem.2023.101474
    83. Jaegeon Ryu, Soojin Park, Dongki Hong, Sunghee Shin. Intertwining porous silicon with conducting polymer for high-efficiency stable Li-ion battery anodes. Korean Journal of Chemical Engineering 2023, 40 (3) , 497-503. https://doi.org/10.1007/s11814-022-1227-8
    84. Zhong Xu, Xiang Chu, Keli Wang, Haitao Zhang, Zhongqian He, Yanting Xie, Weiqing Yang. Stress-dissipated conductive polymer binders for high-stability silicon anode in lithium-ion batteries. Journal of Materiomics 2023, 9 (2) , 378-386. https://doi.org/10.1016/j.jmat.2022.09.013
    85. Dmitrii Yu. Semerukhin, Aleksei V. Kubarkov, Evgeny V. Antipov, Vladimir G. Sergeyev. Carbon nanotubes and carbon-coated current collector significantly improve the performance of lithium-ion battery with PEDOT:PSS binder. Mendeleev Communications 2023, 33 (2) , 206-208. https://doi.org/10.1016/j.mencom.2023.02.018
    86. Anja Marinow, Zviadi Katcharava, Wolfgang H. Binder. Self-Healing Polymer Electrolytes for Next-Generation Lithium Batteries. Polymers 2023, 15 (5) , 1145. https://doi.org/10.3390/polym15051145
    87. Wenlei Wang, Yu Wang, Lixuan Yuan, Chaolin You, Junwei Wu, Lili Liu, Jilei Ye, Yunling Wu, Lijun Fu. Recent advances in modification strategies of silicon-based lithium-ion batteries. Nano Research 2023, 16 (3) , 3781-3803. https://doi.org/10.1007/s12274-022-5147-z
    88. Yifeng Cai, Caixia Liu, Zhiao Yu, Wencan Ma, Qi Jin, Ruichun Du, Bingyun Qian, Xinxin Jin, Haomin Wu, Qiuhong Zhang, Xudong Jia. Slidable and Highly Ionic Conductive Polymer Binder for High‐Performance Si Anodes in Lithium‐Ion Batteries. Advanced Science 2023, 10 (6) https://doi.org/10.1002/advs.202205590
    89. Weihua Wang, Juan Ding, Zhenjie Liu, Yanbin Wei, Wenhua Cheng, Qingcui Liu, Weilu Zhang, XingChao Wang, Wenjun Zhang, Bao Wang, Jiulin Wang, Yudai Huang. Novel-designed cobweb-like binder by “four-in-one” strategy for high performance SiO anode. Chemical Engineering Journal 2023, 458 , 141387. https://doi.org/10.1016/j.cej.2023.141387
    90. C. Yang, K. S. Ravi Chandran. A critical review of silicon nanowire electrodes and their energy storage capacities in Li-ion cells. RSC Advances 2023, 13 (6) , 3947-3957. https://doi.org/10.1039/D2RA07326A
    91. Jieun Kang, Dong‐Yeob Han, Sungho Kim, Jaegeon Ryu, Soojin Park. Multiscale Polymeric Materials for Advanced Lithium Battery Applications. Advanced Materials 2023, 35 (4) https://doi.org/10.1002/adma.202203194
    92. Qitao Shi, Yuanhao Cheng, Jiaqi Wang, Junhua Zhou, Huy Quang Ta, Xueyu Lian, Klaudia Kurtyka, Barbara Trzebicka, Thomas Gemming, Mark H. Rümmeli. Strain Regulating and Kinetics Accelerating of Micro‐Sized Silicon Anodes via Dual‐Size Hollow Graphitic Carbons Conductive Additives. Small 2023, 19 (4) https://doi.org/10.1002/smll.202205284
    93. Ana López-Cudero, Nuria García, Víctor Gregorio, Francisco J. González, Aránzazu Martínez-Gómez, Pilar Tiemblo. The Role of Polymer-Based Materials in Sustainable, Safe, and Efficient Metal Batteries. 2023, 415-441. https://doi.org/10.1007/978-3-031-18428-4_20
    94. Fozia Maqsood, Faisal Jamil, Umar Sohail Shoukat, Muhammad Adnan Iqbal. Recent Advancements in MXene-Based Lithium-Ion Batteries. 2023, 97-125. https://doi.org/10.1007/978-981-99-2038-9_7
    95. Hongbin Liu, Qing Sun, Hongqiang Zhang, Jun Cheng, Yuanyuan Li, Zhen Zeng, Shuai Zhang, Xiao Xu, Fengjun Ji, Deping Li, Jingyu Lu, Lijie Ci. The application road of silicon-based anode in lithium-ion batteries: From liquid electrolyte to solid-state electrolyte. Energy Storage Materials 2023, 55 , 244-263. https://doi.org/10.1016/j.ensm.2022.11.054
    96. Daniel A. Gribble, Evan McCulfor, Zheng Li, Mihit Parekh, Vilas G. Pol. Enhanced capacity and thermal safety of lithium-ion battery graphite anodes with conductive binder. Journal of Power Sources 2023, 553 , 232204. https://doi.org/10.1016/j.jpowsour.2022.232204
    97. Anita Li, Jacob L. Hempel, Michael P. Balogh, Yang-Tse Cheng, Alan I. Taub. Effect of Binder Content on Silicon Microparticle Anodes for Lithium-Ion Batteries. Journal of The Electrochemical Society 2023, 170 (1) , 010533. https://doi.org/10.1149/1945-7111/acb388
    98. Md. Wali Ullah, Naoki Haraguchi, Md. Azgar Ali, Md. Rabiul Alam, Samiul Islam Chowdhury. Synthesis of homo- and copolymer containing sulfonic acid via atom transfer radical polymerization. Designed Monomers and Polymers 2022, 25 (1) , 261-270. https://doi.org/10.1080/15685551.2022.2126092
    99. Heather Au, Maria Crespo‐Ribadeneyra. Polymers in Sodium‐Ion Batteries. 2022, 429-499. https://doi.org/10.1002/9783527825769.ch14
    100. Kunxiang Yu, Junhao Liu, Xuzhong Gong, Xianren Zhang, Zhi Wang. Rationally designed high‐conductivity Hydrangea macrophylla ‐like Si@NiO@Ni/C composites as a high‐performance anode material for lithium‐ion batteries. Electrochemical Science Advances 2022, 2 (6) https://doi.org/10.1002/elsa.202100169
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