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Triboelectrification-Induced Large Electric Power Generation from a Single Moving Droplet on Graphene/Polytetrafluoroethylene
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    Triboelectrification-Induced Large Electric Power Generation from a Single Moving Droplet on Graphene/Polytetrafluoroethylene
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    † § School of Advanced Materials Science and Engineering and §SKKU Advanced Institute of Nanotechnology (SAINT), Sungkyunkwan University, Suwon 440-746, Republic of Korea
    Department of Information Science and Electronic Engineering and State Key Laboratory of Modern Optical Instrumentation, Zhejiang University, Hangzhou 310027, China
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    ACS Nano

    Cite this: ACS Nano 2016, 10, 8, 7297–7302
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    https://doi.org/10.1021/acsnano.6b03032
    Published July 14, 2016
    Copyright © 2016 American Chemical Society

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    Recently, several reports have demonstrated that a moving droplet of seawater or ionic solution over monolayer graphene produces an electric power of about 19 nW, and this has been suggested to be a result of the pseudocapacitive effect between graphene and the liquid droplet. Here, we show that the change in the triboelectrification-induced pseudocapacitance between the water droplet and monolayer graphene on polytetrafluoroethylene (PTFE) results in a large power output of about 1.9 μW, which is about 100 times larger than that presented in previous research. During the graphene transfer process, a very strong negative triboelectric potential is generated on the surface of the PTFE. Positive and negative charge accumulation, respectively, occurs on the bottom and the top surfaces of graphene due to the triboelectric potential, and the negative charges that accumulate on the top surface of graphene are driven forward by the moving droplet, charging and discharging at the front and rear of the droplet.

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    • Raman spectroscopy of monolayer graphene; detailed device structure and experimental setup for movement of the water droplet; dependence on moving speed of the water droplet using a linear motor; variation in the voltage output with different substrate materials; surface potential of each substrate material at an initial state and after immersion in DI water; surface potential of transferred graphene on a triboelectrified substrate before and after immersion of 0.6 M NaCl solution; power generation of graphene/PTFE with a single water droplet at the tilting mode and linear motion in forward and reverse electrode connection (PDF)

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    Cite this: ACS Nano 2016, 10, 8, 7297–7302
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    https://doi.org/10.1021/acsnano.6b03032
    Published July 14, 2016
    Copyright © 2016 American Chemical Society

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