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Color-Tunable Resonant Photoluminescence and Cavity-Mediated Multistep Energy Transfer Cascade

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† Division of Materials Science, Faculty of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8573, Japan
‡ Division of Chemistry, Faculty of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8571, Japan
§ Faculty of Physics and CENIDE, University of Duisburg—Essen, Lotharstrasse 1, Duisburg D-47048, Germany
|| International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS), 1-1 Namiki, Tsukuba, Ibaraki 305-0044, Japan
⊥ CREST, Japan Science and Technology Agency (JST), 4-1-8 Honcho, Kawaguchi, Saitama 332-0012, Japan
Tsukuba Research Center for Interdisciplinary Materials Science (TIMS), Faculty of Pure and Applied Sciences, University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8571, Japan
# Center for Integrated Research in Fundamental Science and Technology (CiRfSE), University of Tsukuba, 1-1-1 Tennodai, Tsukuba, Ibaraki 305-8571, Japan
*E-mail: [email protected]
Cite this: ACS Nano 2016, 10, 7, 7058–7063
Publication Date (Web):June 27, 2016
https://doi.org/10.1021/acsnano.6b03188
Copyright © 2016 American Chemical Society
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Abstract

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Color-tunable resonant photoluminescence (PL) was attained from polystyrene microspheres doped with a single polymorphic fluorescent dye, boron-dipyrrin (BODIPY) 1. The color of the resonant PL depends on the assembling morphology of 1 in the microspheres, which can be selectively controlled from green to red by the initial concentration of 1 in the preparation process of the microspheres. Studies on intersphere PL propagation with multicoupled microspheres, prepared by micromanipulation technique, revealed that multistep photon transfer takes place through the microspheres, accompanying energy transfer cascade with stepwise PL color change. The intersphere energy transfer cascade is direction selective, where energy donor-to-acceptor down conversion direction is only allowed. Such cavity-mediated long-distance and multistep energy transfer will be advantageous for polymer photonics device application.

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The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acsnano.6b03188.

  • Materials and measurements, sample preparation, UV–vis and PL spectra, XRD, WGM PL, and simulation. (PDF)

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  11. Yusuke Chiba, Takashi Nakamura, Ryota Matsuoka, Tatsuya Nabeshima. Synthesis and Functions of Oligomeric and Multidentate Dipyrrin Derivatives and their Complexes. Synlett 2020, 31 (17) , 1663-1680. https://doi.org/10.1055/s-0040-1707155
  12. Mikhail Popov, Evgeniy Mamonov, Nikolai Mitetelo, Karina Zhdanova, Jada Ravi, Rajadurai Chandrasekar, Tatiana Murizina. Laser intensity-dependent nonlinear-optical effects in organic whispering gallery mode cavity microstructures. Optics Letters 2020, 45 (16) , 4622. https://doi.org/10.1364/OL.400620
  13. Hui Pan, Zhengji Wen, Zhihong Tang, Gangyi Xu, Xiaohang Pan, Qianqian Xu, Yue Lu, Hao Xu, Yan Sun, Ning Dai, Jiaming Hao. Wide gamut, angle-insensitive structural colors based on deep-subwavelength bilayer media. Nanophotonics 2020, 9 (10) , 3385-3392. https://doi.org/10.1515/nanoph-2020-0106
  14. Daichi Okada, Zhan-Hong Lin, Jer-Shing Huang, Osamu Oki, Masakazu Morimoto, Xuying Liu, Takeo Minari, Satoshi Ishii, Tadaaki Nagao, Masahiro Irie, Yohei Yamamoto. Optical microresonator arrays of fluorescence-switchable diarylethenes with unreplicable spectral fingerprints. Materials Horizons 2020, 7 (7) , 1801-1808. https://doi.org/10.1039/D0MH00566E
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  31. Xiaochuan Li, Yujie Han, Kyeongsu Min, Young-A Son. Configuration of white light emission by courmarin and naphthalimide. Molecular Crystals and Liquid Crystals 2018, 660 (1) , 10-16. https://doi.org/10.1080/15421406.2018.1452861
  32. Yu Dong, Alessandro Iagatti, Paolo Foggi, Jianzhang Zhao, Gloria Mazzone, Kejing Xu, Wei Ji, Mariangela Di Donato, Nino Russo. Bodipy-squaraine triads: Preparation and study of the intramolecular energy transfer, charge separation and intersystem crossing. Dyes and Pigments 2017, 147 , 560-572. https://doi.org/10.1016/j.dyepig.2017.08.028
  33. Goudappagouda Goudappagouda, Vivek Chandrakant Wakchaure, Kayaramkodath Chandran Ranjeesh, Chalona Antony Ralph Abhai, Sukumaran Santhosh Babu. Cascade energy transfer and tunable emission from nanosheet hybrids: locating acceptor molecules through chiral doping. Chemical Communications 2017, 53 (52) , 7072-7075. https://doi.org/10.1039/C7CC02994B
  34. Soh Kushida, Daichi Okada, Fumio Sasaki, Zhan-Hong Lin, Jer-Shing Huang, Yohei Yamamoto. Low-Threshold Whispering Gallery Mode Lasing from Self-Assembled Microspheres of Single-Sort Conjugated Polymers. Advanced Optical Materials 2017, 5 (10) , 1700123. https://doi.org/10.1002/adom.201700123
  35. Hyeonuk Yeo, Kazuo Tanaka, Yoshiki Chujo. Construction and properties of a light-harvesting antenna system for phosphorescent materials based on oligofluorene-tethered Pt–porphyrins. RSC Advances 2017, 7 (18) , 10869-10874. https://doi.org/10.1039/C6RA28735B
  36. Sandeep Cherumukkil, Samrat Ghosh, Vakayil K. Praveen, Ayyappanpillai Ajayaghosh. An unprecedented amplification of near-infrared emission in a Bodipy derived π-system by stress or gelation. Chemical Science 2017, 8 (8) , 5644-5649. https://doi.org/10.1039/C7SC01696D
  37. A. J. Musser, S. K. Rajendran, K. Georgiou, L. Gai, R. T. Grant, Z. Shen, M. Cavazzini, A. Ruseckas, G. A. Turnbull, I. D. W. Samuel, J. Clark, D. G. Lidzey. Intermolecular states in organic dye dispersions: excimers vs. aggregates. Journal of Materials Chemistry C 2017, 5 (33) , 8380-8389. https://doi.org/10.1039/C7TC02655B
  38. Yohei Yamamoto. Spherical resonators from π-conjugated polymers. Polymer Journal 2016, 48 (11) , 1045-1050. https://doi.org/10.1038/pj.2016.81

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