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    Superconducting Ferromagnetic Nanodiamond
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    † †INPAC-Insititute for Nanoscale Physics and Chemistry and ∥Laboratory of Solid State Physics and Magnetism, KU Leuven, Celestijnenlaan 200D, B-3001 Heverlee, Belgium
    ‡ Centre of Low Temperature Physics, Institute of Experimental Physics, Slovak Academy of Sciences and Faculty of Science, P. J. Safarik University, 04001 Kosice, Slovakia
    § School of Electrical and Computer Engineering, University of California, Davis, California 95616, United States
    ⊥ Institute of Ion Beam Physics and Materials Research, Helmholtz-Zentrum Dresden-Rossendorf, Bautzner Landstr. 400, 01328 Dresden, Germany
    ∇ School of Chemistry, University of Bristol, Bristol BS8 1TS, United Kingdom
    #Centre for Surface Chemistry and Catalysis and Department of Chemistry, KU Leuven, Celestijnenlaan 200F, B-3001 Heverlee, Belgium
    ○ Research Institute of Superconductor Electronics, Nanjing University, 210093 Nanjing, China
    ∞ Nuclear Physics Institute, Academy of Sciences of the Czech Republic, 25068 Husinec-Rez, Czech Republic
    *E-mail: [email protected]
    *E-mail: [email protected]
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    ACS Nano

    Cite this: ACS Nano 2017, 11, 6, 5358–5366
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    https://doi.org/10.1021/acsnano.7b01688
    Published May 16, 2017
    Copyright © 2017 American Chemical Society
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    Abstract

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    Superconductivity and ferromagnetism are two mutually antagonistic states in condensed matter. Research on the interplay between these two competing orderings sheds light not only on the cause of various quantum phenomena in strongly correlated systems but also on the general mechanism of superconductivity. Here we report on the observation of the electronic entanglement between superconducting and ferromagnetic states in hydrogenated boron-doped nanodiamond films, which have a superconducting transition temperature Tc ∼ 3 K and a Curie temperature TCurie > 400 K. In spite of the high TCurie, our nanodiamond films demonstrate a decrease in the temperature dependence of magnetization below 100 K, in correspondence to an increase in the temperature dependence of resistivity. These anomalous magnetic and electrical transport properties reveal the presence of an intriguing precursor phase, in which spin fluctuations intervene as a result of the interplay between the two antagonistic states. Furthermore, the observations of high-temperature ferromagnetism, giant positive magnetoresistance, and anomalous Hall effect bring attention to the potential applications of our superconducting ferromagnetic nanodiamond films in magnetoelectronics, spintronics, and magnetic field sensing.

    Copyright © 2017 American Chemical Society

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    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acsnano.7b01688.

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    ACS Nano

    Cite this: ACS Nano 2017, 11, 6, 5358–5366
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acsnano.7b01688
    Published May 16, 2017
    Copyright © 2017 American Chemical Society
    Request reuse permissions

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