ACS Publications. Most Trusted. Most Cited. Most Read
My Activity
ADDITION / CORRECTIONThis article has been corrected. View the notice.

High-Energy-Density Hydrogen-Ion-Rocking-Chair Hybrid Supercapacitors Based on Ti3C2Tx MXene and Carbon Nanotubes Mediated by Redox Active Molecule

  • Minmin Hu
    Minmin Hu
    Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
    School of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026, China
    More by Minmin Hu
  • Cong Cui
    Cong Cui
    Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
    School of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026, China
    More by Cong Cui
  • Chao Shi
    Chao Shi
    Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
    More by Chao Shi
  • Zhong-Shuai Wu*
    Zhong-Shuai Wu
    Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian 116023, China
    *E-mail: [email protected]
  • Jinxing Yang
    Jinxing Yang
    Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
    School of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026, China
    More by Jinxing Yang
  • Renfei Cheng
    Renfei Cheng
    Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
    School of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026, China
    More by Renfei Cheng
  • Tianjia Guang
    Tianjia Guang
    Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
    School of Materials Science and Engineering, University of Science and Technology of China, Hefei 230026, China
  • Hailong Wang
    Hailong Wang
    School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China
    More by Hailong Wang
  • Hongxia Lu
    Hongxia Lu
    School of Materials Science and Engineering, Zhengzhou University, Zhengzhou 450001, China
    More by Hongxia Lu
  • , and 
  • Xiaohui Wang*
    Xiaohui Wang
    Shenyang National Laboratory for Materials Science, Institute of Metal Research, Chinese Academy of Sciences, Shenyang 110016, China
    *E-mail: [email protected]
    More by Xiaohui Wang
Cite this: ACS Nano 2019, 13, 6, 6899–6905
Publication Date (Web):May 17, 2019
Copyright © 2019 American Chemical Society

    Article Views





    Read OnlinePDF (3 MB)
    Supporting Info (1)»


    Abstract Image

    MXenes have emerged as promising high-volumetric-capacitance supercapacitor electrode materials, whereas their voltage windows are not wide. This disadvantage prevents MXenes from being made into aqueous symmetric supercapacitors with high energy density. To attain high energy density, constructing asymmetric supercapacitors is a reliable design choice. Here, we propose a strategy to achieve high energy density of hydrogen ion aqueous-based hybrid supercapacitors by integrating a negative electrode of Ti3C2Tx MXene and a positive electrode of redox-active hydroquinone (HQ)/carbon nanotubes. The two electrodes are separated by a Nafion film that is proton permeable in H2SO4 electrolyte. Upon charging/discharging, hydrogen ions shuttle back and forth between the cathode and anode for charge compensation. The proton-induced high capacitance of MXene and HQ, along with complementary working voltage windows, simultaneously enhance the electrochemical performance of the device. Specifically, the hybrid supercapacitors operate in a 1.6 V voltage window and deliver a high energy density of 62 Wh kg–1, which substantially exceeds those of the state-of-the-art aqueous asymmetric supercapacitors reported so far. Additionally, the device exhibits excellent cycling stability and the all-solid-state planar hybrid supercapacitor displays exceptional flexibility and integration for bipolar cells to boost the capacitance and voltage output. These encouraging results provide the possibility of designing high-energy-density noble-metal-free asymmetric supercapacitors for practical applications.

    Supporting Information

    Jump To

    The Supporting Information is available free of charge on the ACS Publications website at DOI: 10.1021/acsnano.9b01762.

    • SEM image, TEM image, CV curves and rate performance of Ti3C2Tx MXene; TEM images and Raman spectra of CNTs; CV curves of CNT-NaOH-MA film in H2SO4 electrolyte with different concentrations of HQ; EIS spectra of the assembled hybrid supercapacitor; photograph of the all-solid-state full cell device (PDF)

    Terms & Conditions

    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system:

    Cited By

    This article is cited by 119 publications.

    1. Rupam Sinha, Nirmal Roy, Tapas K. Mandal. N-Doped Carbon Dots and ZnO Conglomerated Electrodes for Optically Responsive Supercapacitor Applications. Langmuir 2023, 39 (12) , 4518-4529.
    2. Yuman Zhang, Xiaolin Zhu, Suya Sun, Qirui Guo, Meigui Xu, Guan Wu. Ordered Interface Engineering Enabled High-Performance Ti3C2Tx MXene Fiber-Based Supercapacitors. Energy & Fuels 2022, 36 (14) , 7898-7907.
    3. Genlong Qiu, Qiyuan Qiu, Leying Qing, Jingmin Zhou, Xiaofei Xu, Shuangliang Zhao. Effects of Polyelectrolyte Surface Coating on the Energy Storage Performance in Supercapacitors. The Journal of Physical Chemistry C 2022, 126 (19) , 8218-8226.
    4. Fei Liu, Chaohai Wang, Lei Wang, Fei Huang, Jiayao Fan, Naien Shi, Min Han, Zhihui Dai. Oxygen-Vacancy-Rich NiMnZn-Layered Double Hydroxide Nanosheets Married with Mo2CTx MXene for High-Efficiency All-Solid-State Hybrid Supercapacitors. ACS Applied Energy Materials 2022, 5 (3) , 3346-3358.
    5. Chenyang Cai, Zechang Wei, Leixin Deng, Yu Fu. Temperature-Invariant Superelastic Multifunctional MXene Aerogels for High-Performance Photoresponsive Supercapacitors and Wearable Strain Sensors. ACS Applied Materials & Interfaces 2021, 13 (45) , 54170-54184.
    6. Zhangyi Xiong, Peijing Guo, Shaoyu Yuan, Sufang Sun, Chun Wang, Yongjun Gao. Printable High-Voltage Integrated Microsupercapacitors Based on Heteroatom-Doped Porous Biomass Carbon. Energy & Fuels 2021, 35 (20) , 16903-16914.
    7. Chao Geng, Tulai Sun, Zhencui Wang, Jin-Ming Wu, Yi-Jie Gu, Hisayoshi Kobayashi, Peng Yang, Jianhang Hai, Wei Wen. Surface-Induced Desolvation of Hydronium Ion Enables Anatase TiO2 as an Efficient Anode for Proton Batteries. Nano Letters 2021, 21 (16) , 7021-7029.
    8. Zhenghui Pan, Lixing Kang, Tan Li, Moaz Waqar, Jie Yang, Qilin Gu, Ximeng Liu, Zongkui Kou, Zhao Wang, Lirong Zheng, John Wang. Black Phosphorus@Ti3C2Tx MXene Composites with Engineered Chemical Bonds for Commercial-Level Capacitive Energy Storage. ACS Nano 2021, 15 (8) , 12975-12987.
    9. Yirong Zhu, Jingying Li, Xiaoru Yun, Xianhong Chen, Junjun Yao, Zhihui Lu. Design and Fabrication of Advanced Cathode and Anode Materials for Hybrid Supercapacitors Based on Graphitic Carbon Quantum Dot-Decorated Reduced Graphene Oxide Composite Aerogels. ACS Applied Energy Materials 2021, 4 (1) , 714-729.
    10. Wei Wu, Hongfei Ge, Long Zhang, Xuejiao Lei, Yang Yang, Yan Fu, Hua Feng. Evaluating the Cytotoxicity of Ti3C2 MXene to Neural Stem Cells. Chemical Research in Toxicology 2020, 33 (12) , 2953-2962.
    11. Li Sun, Gongsheng Song, Yafei Sun, Qiang Fu, Chunxu Pan. MXene/N-Doped Carbon Foam with Three-Dimensional Hollow Neuron-like Architecture for Freestanding, Highly Compressible All Solid-State Supercapacitors. ACS Applied Materials & Interfaces 2020, 12 (40) , 44777-44788.
    12. Chunmei Wang, Renfei Cheng, Peng-Xiang Hou, Yonghui Ma, Abdul Majeed, Xiaohui Wang, Chang Liu. MXene-Carbon Nanotube Hybrid Membrane for Robust Recovery of Au from Trace-Level Solution. ACS Applied Materials & Interfaces 2020, 12 (38) , 43032-43041.
    13. Yue Li, Canping Pan, Pascal Kamdem, Xiao-Juan Jin. Binder-Free Two-Dimensional MXene/Acid Activated Carbon for High-Performance Supercapacitors and Methylene Blue Adsorption. Energy & Fuels 2020, 34 (8) , 10120-10130.
    14. Yapeng Tian, Chenhui Yang, Yangyang Luo, Hongyang Zhao, Yaping Du, Ling Bing Kong, Wenxiu Que. Understanding MXene-Based “Symmetric” Supercapacitors and Redox Electrolyte Energy Storage. ACS Applied Energy Materials 2020, 3 (5) , 5006-5014.
    15. Renfei Cheng, Zuohua Wang, Cong Cui, Tao Hu, Bingbing Fan, Hailong Wang, Yan Liang, Chao Zhang, Hongwang Zhang, Xiaohui Wang. One-Step Incorporation of Nitrogen and Vanadium between Ti3C2Tx MXene Interlayers Enhances Lithium Ion Storage Capability. The Journal of Physical Chemistry C 2020, 124 (11) , 6012-6021.
    16. Yan Wang, Song Wang, Ningning Dong, Wenyuan Kang, Kun Li, Zhou Nie. Titanium Carbide MXenes Mediated In Situ Reduction Allows Label-Free and Visualized Nanoplasmonic Sensing of Silver Ions. Analytical Chemistry 2020, 92 (6) , 4623-4629.
    17. Watinee Nunthakitgoson, Chadatip Rodaum, Peerapol Pornsetmetakul, Chularat Wattanakit, Piyarat Wattana, Anawat Thivasasith. Transformation of CO 2 to Carbon Nanotubes by Catalytic Chemical Vapor Deposition using a Metal‐Supported Hierarchical Zeolite Template. ChemPlusChem 2023, 12
    18. Chennan Zhao, Caini Liu, Wenyi Wang, Zezhou Zhang, Xiuying Yang, Jiawei Tian, Xuewen Zhang, Boyu Zhao. Interfacial polymerization layer with CNT providing fast water channels under electric field for efficient desalination of nanofiltration membranes. Desalination 2023, 565 , 116825.
    19. Wen Siong Poh, Wen Jie Yiang, Wee Jun Ong, Pau Loke Show, Chuan Yi Foo. Enhancing MXene-based supercapacitors: Role of synthesis and 3D architectures. Journal of Energy Chemistry 2023, 15
    20. Aitang Zhang, Quan Zhang, Hucheng Fu, Hanwen Zong, Hanwen Guo. Metal‐Organic Frameworks and Their Derivatives‐Based Nanostructure with Different Dimensionalities for Supercapacitors. Small 2023, 19 (48)
    21. Jian Wang, Zhenquan Wang, Zhiming Li, Naxing Liu, Yang Luo, Yuxiao Chu, Long Jiang, Fu-Gang Zhao, Kai Zhang, Xunshan Liu, Yongmiao Shen. High-energy-density flexible graphene-based supercapacitors enabled by atypical hydroquinone dimethyl ether. Journal of Colloid and Interface Science 2023, 648 , 231-241.
    22. Sithara Radhakrishnan, Chandra Sekhar Rout. Recent developments in 2D MXene-based materials for next generation room temperature NO 2 gas sensors. Nanoscale Advances 2023, 5 (18) , 4649-4669.
    23. Rui Ma, Lingyun Cao, Jingting Zhuo, Jintao Lu, Jiaxiang Chen, Jue Huang, Guowei Yang, Fang Yi. Designed Redox‐Electrolyte Strategy Boosted with Electrode Engineering for High‐Performance Ti 3 C 2 T x MXene‐Based Supercapacitors. Advanced Energy Materials 2023, 13 (34)
    24. Rongxin Xia, Yunsheng Fang, Zhuo Chen, Xinyi Zhou, Jun Cheng, Junhu Zhou, Xun Zhao, Jun Chen. Manipulating electron extraction efficiency in microbial electrochemical carbon fixation via single-atom engineering. Materials Today 2023, 68 , 51-61.
    25. Yang Li, Sowjanya Vallem, Joonho Bae. MXene-based composites for high-performance and fire-safe lithium-ion battery. Current Applied Physics 2023, 53 , 142-164.
    26. Rui Wang, Won Young Jang, Wen Zhang, Ch. Venkata Reddy, Raghava Reddy Kakarla, Changping Li, Vijai Kumar Gupta, Jaesool Shim, Tejraj M. Aminabhavi. Emerging two-dimensional (2D) MXene-based nanostructured materials: Synthesis strategies, properties, and applications as efficient pseudo-supercapacitors. Chemical Engineering Journal 2023, 472 , 144913.
    27. Yigang Jin, Sha Wu, Yong Sun, Zixin Chang, Ze Li, Yimeng Sun, Wei Xu. Nonporous, conducting bimetallic coordination polymers with an advantageous electronic structure for boosted faradaic capacitance. Materials Horizons 2023, 10 (9) , 3821-3829.
    28. Lior Carmel, Shiran Aharon, Dan Meyerstein, Yael Albo, Lonia Friedlander, Dror Shamir, Ariela Burg. WO3 dehydration and phase transition as the catalytic driver of hydrogen production by non-calcinated WO3. International Journal of Hydrogen Energy 2023, 184
    29. Yuanyuan Zhu, Jiaxin Ma, Pratteek Das, Sen Wang, Zhong‐Shuai Wu. High‐Voltage MXene‐Based Supercapacitors: Present Status and Future Perspectives. Small Methods 2023, 7 (8)
    30. Chenming Liang, Yuntong Meng, Yu Zhang, Haifeng Zhang, Weixue Wang, Min Lu, Guangsheng Wang. Insights into the impact of interlayer spacing on MXene-based electrodes for supercapacitors: A review. Journal of Energy Storage 2023, 65 , 107341.
    31. Ganji Seeta Rama Raju, Svyatoslav Kondrat, Nilesh R. Chodankar, Seung-Kyu Hwang, Jeong Han Lee, Teng Long, Eluri Pavitra, Swati J. Patil, Kugalur Shanmugam Ranjith, M. V. Basaveswara Rao, Peng Wu, Kwang Chul Roh, Yun Suk Huh, Young-Kyu Han. Electrolyte ions-matching hierarchically porous biochar electrodes with an extended potential window for next-generation supercapacitors. Journal of Materials Chemistry A 2023, 11 (28) , 15540-15552.
    32. Sedighe Hosseini, Mohammad Bagher Askari, Hadi Beitollahi. MnNi2O4-MWCNTs as a nano-electrocatalyst for methanol oxidation reaction. International Journal of Hydrogen Energy 2023, 48 (55) , 21240-21248.
    33. Chao Feng, Bingzhe Jia, Han Wang, Yan Wang, Xinming Wu. A novel strategy for high energy density supercapacitors: Formation of cyanuric acid between Ti3C2Tx (MXene) interlayer hybrid electrodes. Chemical Engineering Journal 2023, 465 , 142935.
    34. Xiaoyu Bi, Meichun Li, Guoqiang Zhou, Chaozheng Liu, Runzhou Huang, Yang Shi, Ben Bin Xu, Zhanhu Guo, Wei Fan, Hassan Algadi, Shengbo Ge. High-performance flexible all-solid-state asymmetric supercapacitors based on binder-free MXene/cellulose nanofiber anode and carbon cloth/polyaniline cathode. Nano Research 2023, 16 (5) , 7696-7709.
    35. Lijing Wang, Shan Gao, Wenting Li, Ao Zhu, Huan Li, Chunning Zhao, Haijun Zhang, Wei-Hua Wang, Weichao Wang. Machine learning assisted screening of MXenes pseudocapacitive materials. Journal of Power Sources 2023, 564 , 232834.
    36. Yaohui Lv, LeLe Zhang, Xiang Wei, Baoping Qiu, Wei Zhang, Qingqing Qin, Dedong Jia, Xiaojun He, Zailiang Liu, Feng Wei. The emerging of zinc-ion hybrid supercapacitors: Advances, challenges, and future perspectives. Sustainable Materials and Technologies 2023, 35 , e00536.
    37. Mariano M. Bruno, N. Gustavo Cotella, Cesar A. Barbero. Hierarchical Biobased Macroporous/Mesoporous Carbon: Fabrication, Characterization and Electrochemical/Ion Exchange Properties. Materials 2023, 16 (5) , 2101.
    38. Yue Sun, Jinhua Sun, Jaime S. Sanchez, Zhenyuan Xia, Linhong Xiao, Ruiqi Chen, Vincenzo Palermo. Surface chemistry and structure manipulation of graphene-related materials to address the challenges of electrochemical energy storage. Chemical Communications 2023, 59 (18) , 2571-2583.
    39. Pingwei Cai, Kai Chen, Zhiwen Lu, Ritwik Mondal, Musthafa Ottakam Thotiyl, Zhenhai Wen. Aqueous OH − /H + Dual‐Ion Zn‐Based Batteries. ChemSusChem 2023, 16 (4)
    40. Zhuo Wang, Dan Wu, Menglei Kong, Yanxin Li, Zhihui Yi. High energy storage density of conductive filler composites at low electric fields through sandwich design. Journal of Materials Science: Materials in Electronics 2023, 34 (3)
    41. Fatemeh Mohajer, Ghodsi Mohammadi Ziarani, Alireza Badiei, Siavash Iravani, Rajender S. Varma. MXene-Carbon Nanotube Composites: Properties and Applications. Nanomaterials 2023, 13 (2) , 345.
    42. Zengming Qin, Yu Song, Yaozhi Liu, Xiao-Xia Liu. Accessing the proton storage in neutral buffer electrolytes using an electrodeposited molybdenum phosphate. Energy Storage Materials 2022, 53 , 569-579.
    43. Hengtai Wang, Jianghe Liu, Sultan Ahmed, Ting Wang, Shenhua Song. Freeze-tolerant gel electrolyte membrane for flexible Zn-ion hybrid supercapacitor. Journal of Energy Storage 2022, 56 , 105923.
    44. Shicong Zhang, Xiaolin Zhao, Yifan Zhang, Yaoyao Zhao, Tao Li, Jianjun Liu, Fuqiang Huang, Tianquan Lin. Insights on the proton mechanism in carbonyl-based organic electrode of neutral aqueous battery. Journal of Power Sources 2022, 550 , 232110.
    45. Lu Wang, Jiayao Cao, Ying-Hua Zhou, Xiaoheng Liu. Design and characterization of monolayer Ti3C2 MXene/NiCo2O4 nanocones hybrid architecture for asymmetric supercapacitors. Journal of Electroanalytical Chemistry 2022, 923 , 116787.
    46. Shuaikai Xu, Zhemin Li, Guodong Wei, Yuanhao Wang, Ya Yang. Intercalation and surface modification of two-dimensional transition metal carbonitride Ti 3 CNT x for ultrafast supercapacitors. Journal of Materials Chemistry A 2022, 10 (36) , 18812-18821.
    47. Mingzhu Zhong, Miao Zhang, Xifei Li. Carbon nanomaterials and their composites for supercapacitors. Carbon Energy 2022, 4 (5) , 950-985.
    48. Alisher Abdisattar, Mukhtar Yeleuov, Chingis Daulbayev, Kydyr Askaruly, Aidos Tolynbekov, Azamat Taurbekov, Nikolay Prikhodko. Recent advances and challenges of current collectors for supercapacitors. Electrochemistry Communications 2022, 142 , 107373.
    49. Keerti Rathi, Naveen Kumar Arkoti, Kaushik Pal. Fabrication of Delaminated 2D Metal Carbide MXenes (Nb 2 CT x ) by CTAB‐based NO 2 Gas Sensor with Enhanced Stability. Advanced Materials Interfaces 2022, 9 (22)
    50. Xiao Wang, Kaixiang Zou, Weijing Wu, Yuanfu Deng, Guohua Chen. N, O co-doped porous carbon with rich pseudocapacitive groups exhibiting superior energy density in an acidic 2.4 V Li2SO4 electrolyte. Chinese Chemical Letters 2022, 33 (8) , 3883-3888.
    51. Yong Sun, Yigang Jin, Cheng Xu, Mengsu Zhu, Yang Li, Ze Li, Yimeng Sun, Wei Xu, Daoben Zhu. The Increasing Number of Electron Reservoirs in Nonporous, High‐Conducting Coordination Polymers Cu x BHT ( x   =  3, 4, and 5, BHT  =  Benzenehexathiol) for Improved Faradaic Capacitance. Small 2022, 18 (30)
    52. Jing Huang, Ying Deng, Hengshuo Zhang, Yixuan Jiang, Wei Xiao, Yanhua Zhang. Titanium dioxide nanobelts modified with manganese dioxide nanoflakes for high-performance supercapacitor applications. Journal of Nanoparticle Research 2022, 24 (7)
    53. Ting Yu, Xiping Le, Kai Fan, Haonan Chen, Jing Liu. CuS/Ti3C2Tx homostructure with enhanced hydrogel performance for supercapacitor electrode materials. European Polymer Journal 2022, 175 , 111312.
    54. Pingwei Cai, Junwei Li, Junheng Huang, Junxiang Chen, Yichun Ding, Xinxin Peng, Zhenhai Wen. Sub‐1 nm MoC Quantum Dots Decorating N‐Doped Graphene as Advanced Electrocatalysts of Flexible Hybrid Alkali–Acid Zn‐Quinone Battery. Small 2022, 18 (22)
    55. Bo Liu, Xiaobin Hao, Teng Zhai, Shuo Sun, Hongshen Zhang, Payam Ahmadian Koudakan, Cong Wei, Gongming Wang, Hui Xia. Regulating the π-π interaction with shortened electron tunneling distance for efficient charge storage. Energy Storage Materials 2022, 48 , 403-411.
    56. Xu Han, Chongchong Wu, Hao Li, Yusheng Zhang, Wenping Sun, Baohua Jia, Ian D. Gates, Zi‐Hang Huang, Tianyi Ma. Three‐In‐One Alkylamine‐Tuned MoO x for Lab‐Scale to Real‐Life Aqueous Supercapacitors. Advanced Functional Materials 2022, 32 (22)
    57. Melih Besir Arvas, Sibel Yazar, Yucel Sahin. Electrochemical synthesis and characterization of self-doped aniline 2-sulfonic acid-modified flexible electrode with high areal capacitance and rate capability for supercapacitors. Synthetic Metals 2022, 285 , 117017.
    58. Supriyo Ray, Jason Abraham, Nyiah Jordan, Mical Lindsay, Neha Chauhan. Synthetic, Photosynthetic, and Chemical Strategies to Enhance Carbon Dioxide Fixation. C 2022, 8 (1) , 18.
    59. Pragati A. Shinde, Amar M. Patil, Suchan Lee, Euigeol Jung, Seong Chan Jun. Two-dimensional MXenes for electrochemical energy storage applications. Journal of Materials Chemistry A 2022, 10 (3) , 1105-1149.
    60. Tiezhu Xu, Zhiwei Li, Di Wang, Miaoran Zhang, Liufeng Ai, Ziyang Chen, Jinhui Zhang, Xiaogang Zhang, Laifa Shen. A Fast Proton‐Induced Pseudocapacitive Supercapacitor with High Energy and Power Density. Advanced Functional Materials 2022, 32 (5)
    61. Jun Huang, Kai Yuan, Yiwang Chen. Wide Voltage Aqueous Asymmetric Supercapacitors: Advances, Strategies, and Challenges. Advanced Functional Materials 2022, 32 (4)
    62. Jensheer Shamsudeen Seenath. Energy Storage Applications of MXene. 2022, 139-169.
    63. Pengfei Tang, Bo Yang, Rui Li, Yunchuang Wang, Xiaodong Li, Guangcheng Yang. Ti3C2 MXene: A reactive combustion catalyst for efficient burning rate control of ammonium perchlorate based solid propellant. Carbon 2022, 186 , 678-687.
    64. Lijing Wang, Shan Gao, Wenting Li, Ao Zhu, Huan Li, Chunning Zhao, Haijun Zhang, Wei-Hua Wang, Weichao Wang. Machine Learning Assisted Screening of Mxenes Pseudocapacitive Materials. SSRN Electronic Journal 2022, 10
    65. Lihua Xu, De-en Jiang. Proton dynamics in water confined at the interface of the graphene–MXene heterostructure. The Journal of Chemical Physics 2021, 155 (23)
    66. Rongliang Yang, Xuchun Gui, Li Yao, Qingmei Hu, Leilei Yang, Hao Zhang, Yongtao Yao, Hui Mei, Zikang Tang. Ultrathin, Lightweight, and Flexible CNT Buckypaper Enhanced Using MXenes for Electromagnetic Interference Shielding. Nano-Micro Letters 2021, 13 (1)
    67. Xiaozhong Wu, Hua Li, Xinping Yang, Xin Wang, Zhichao Miao, Pengfei Zhou, Jinping Zhao, Jin Zhou, Shuping Zhuo. Reduced Graphene Oxide Hydrogel for High Energy Density Symmetric Supercapacitor with High Operation Potential in Aqueous Electrolyte. ChemElectroChem 2021, 8 (22) , 4353-4359.
    68. Arya Sohan, Pravallika Banoth, Mariya Aleksandrova, Andrews Nirmala Grace, Pratap Kollu. Review on MXene synthesis, properties, and recent research exploring electrode architecture for supercapacitor applications. International Journal of Energy Research 2021, 45 (14) , 19746-19771.
    69. Wancai Guo, Xutong Guo, Lei Yang, Tianyou Wang, Minghua Zhang, Gaigai Duan, Xianhu Liu, Yiwen Li. Synthetic melanin facilitates MnO supercapacitors with high specific capacitance and wide operation potential window. Polymer 2021, 235 , 124276.
    70. Yanmin Wang, Xueliang Wu, Yongqin Han, Tingxi Li. Flexible supercapacitor: Overview and outlooks. Journal of Energy Storage 2021, 42 , 103053.
    71. Chenxi Han, Xiqing Xu, Hao Mu, Qiang Tian, Qiang Li, Yitong Liu, Xuan Zhang, Zhenhuan Zhao, Xinghua Su. Construction of hierarchical sea urchin-like manganese substituted nickel cobaltite@tricobalt tetraoxide core-shell microspheres on nickel foam as binder-free electrodes for high performance supercapacitors. Journal of Colloid and Interface Science 2021, 596 , 89-99.
    72. Kunlun Liu, Chang Yu, Wei Guo, Lin Ni, Jinhe Yu, Yuanyang Xie, Zhao Wang, Yongwen Ren, Jieshan Qiu. Recent research advances of self-discharge in supercapacitors: Mechanisms and suppressing strategies. Journal of Energy Chemistry 2021, 58 , 94-109.
    73. Shilpa Kumari, Ekta Verma, Rajinder Kumar, Deepak Upreti, Bhanu Prakash, Takahiro Maruyama, Vivek Bagchi. Micropores within N,S co-doped mesoporous 3D graphene-aerogel enhance the supercapacitive performance. New Journal of Chemistry 2021, 45 (17) , 7523-7532.
    74. Xue Yang, Qian Wang, Kai Zhu, Ke Ye, Guiling Wang, Dianxue Cao, Jun Yan. 3D Porous Oxidation‐Resistant MXene/Graphene Architectures Induced by In Situ Zinc Template toward High‐Performance Supercapacitors. Advanced Functional Materials 2021, 31 (20)
    75. Shaukat Ali Mazari, Esfandyar Ali, Rashid Abro, Fahad Saleem Ahmed Khan, Israr Ahmed, Mushtaq Ahmed, Sabzoi Nizamuddin, Tahir Hussain Siddiqui, Nazia Hossain, Nabisab Mujawar Mubarak, Asif Shah. Nanomaterials: Applications, waste-handling, environmental toxicities, and future challenges – A review. Journal of Environmental Chemical Engineering 2021, 9 (2) , 105028.
    76. Jun Lv, Qinghua Huang, Tiejun Liu, Qiaoyu Pan. Energy Storage Device Application Based on MXenes Composites: a Mini Review. International Journal of Electrochemical Science 2021, 16 (4) , 210439.
    77. Haozhe Ning, Zhongying Ma, Zhihao Zhang, Dan Zhang, Yuhua Wang. A novel multifunctional flame retardant MXene/nanosilica hybrid for poly(vinyl alcohol) with simultaneously improved mechanical properties. New Journal of Chemistry 2021, 45 (9) , 4292-4302.
    78. Yang Liu, Shunjiang Huang, Jiangnan Li, Minghua Wang, Changbao Wang, Bin Hu, Nan Zhou, Zhihong Zhang. 0D/2D heteronanostructure–integrated bimetallic CoCu-ZIF nanosheets and MXene-derived carbon dots for impedimetric cytosensing of melanoma B16-F10 cells. Microchimica Acta 2021, 188 (3)
    79. Mingming Gao, Lu Wang, Baozheng Zhao, Xinglong Gu, Tong Li, Lang Huang, Qiong Wu, Shitao Yu, Shiwei Liu. Sandwich construction of chitosan/reduced graphene oxide composite as additive-free electrode material for high-performance supercapacitors. Carbohydrate Polymers 2021, 255 , 117397.
    80. Qizhen Zhu, Jiapeng Li, Patrice Simon, Bin Xu. Two-dimensional MXenes for electrochemical capacitor applications: Progress, challenges and perspectives. Energy Storage Materials 2021, 35 , 630-660.
    81. Yuanming Wang, Xue Wang, Xifei Li, Xiaolong Li, Yang Liu, Yang Bai, Huanhao Xiao, Guohui Yuan. A High‐Performance, Tailorable, Wearable, and Foldable Solid‐State Supercapacitor Enabled by Arranging Pseudocapacitive Groups and MXene Flakes on Textile Electrode Surface. Advanced Functional Materials 2021, 31 (7)
    82. Shuo Sun, Bo Liu, Hongshen Zhang, Qiubo Guo, Qiuying Xia, Teng Zhai, Hui Xia. Boosting Energy Storage via Confining Soluble Redox Species onto Solid–Liquid Interface. Advanced Energy Materials 2021, 11 (8)
    83. Yuanming Wang, Xue Wang, Xiaolong Li, Yang Bai, Huanhao Xiao, Yang Liu, Guohui Yuan. Scalable fabrication of polyaniline nanodots decorated MXene film electrodes enabled by viscous functional inks for high-energy-density asymmetric supercapacitors. Chemical Engineering Journal 2021, 405 , 126664.
    84. Dickson D. Babu, Minu Mathew, Siby Thomas. Supercapacitors based on MXenes (transition metal carbides and nitrides) and their hybrids. 2021, 217-233.
    85. Ziqian Ma, Zhiqin Sun, Fengyu Qu. High-performance battery-type Fe1-xS@CFs anode for all-solid-state battery-type asymmetric supercapacitor with high energy density and wide working temperature range. Applied Surface Science 2021, 537 , 147817.
    86. Pengfei Tang, Bo Yang, Rui Li, Yunchuang Wang, Xiaodong Li, Guangcheng Yang. Ti 3C 2 MXene: A Reactive Combustion Catalyst for Efficient Burning Rate Control of Ammonium Perchlorate Based Solid Propellant. SSRN Electronic Journal 2021, 17
    87. Tianlun Qiu, Guohui Li, Yuanlong Shao, Kun Jiang, Fangfang Zhao, Fengxia Geng. Facile synthesis of colloidal nitrogen‐doped titanium carbide sheets with enhanced electrochemical performance. Carbon Energy 2020, 2 (4) , 624-634.
    88. Yuanming Wang, Xue Wang, Xiaolong Li, Rong Liu, Yang Bai, Huanhao Xiao, Yang Liu, Guohui Yuan. Intercalating Ultrathin MoO3 Nanobelts into MXene Film with Ultrahigh Volumetric Capacitance and Excellent Deformation for High-Energy-Density Devices. Nano-Micro Letters 2020, 12 (1)
    89. Shen Tian, Guojun Cheng, Zhongfeng Tang, Feixiang Sha, Ziyue Xuan, Guoxin Ding. Fabrication of two-dimensional Ti3C2Tx MXenes by ball milling pretreatment and mild etchant and their microstructure. Ceramics International 2020, 46 (18) , 28949-28954.
    90. Jiang Xu, Xinghao Hu, Xuehang Wang, Xi Wang, Yifan Ju, Shanhai Ge, Xiaolong Lu, Jianning Ding, Ningyi Yuan, Yury Gogotsi. Low-Temperature pseudocapacitive energy storage in Ti3C2T MXene. Energy Storage Materials 2020, 33 , 382-389.
    91. Yanfeng Dong, Haodong Shi, Zhong‐Shuai Wu. Recent Advances and Promise of MXene‐Based Nanostructures for High‐Performance Metal Ion Batteries. Advanced Functional Materials 2020, 30 (47)
    92. Jing Liu, Liwei Mi, Yanan Xing, Tianfu Wang, Fu Wang. Construction of Ti3C2 supported hybrid Co3O4/NCNTs composite as an efficient oxygen reduction electrocatalyst. Renewable Energy 2020, 160 , 1168-1173.
    93. Fan Zhang, Shice Wei, Weiwei Wei, Jiang Zou, Guoying Gu, Dongqing Wu, Shuai Bi, Fan Zhang. Trimethyltriazine-derived olefin-linked covalent organic framework with ultralong nanofibers. Science Bulletin 2020, 65 (19) , 1659-1666.
    94. Minmin Hu, Hui Zhang, Tao Hu, Bingbing Fan, Xiaohui Wang, Zhenjiang Li. Emerging 2D MXenes for supercapacitors: status, challenges and prospects. Chemical Society Reviews 2020, 49 (18) , 6666-6693.
    95. Bingchao Yang, Xiangjun Li, Yong Cheng, Shuai Duan, Bo Zhao, Wencai Yi, Chao Wang, Hairui Sun, Zhixiu Wang, Dapeng Gu, Suwen Chen, Xiaobing Liu. Liquid phase exfoliation of bismuth nanosheets for flexible all-solid-state supercapacitors with high energy density. Journal of Materials Chemistry C 2020, 8 (35) , 12314-12322.
    96. Hao Wang, Jianmin Li, Xiaoxiao Kuai, Liangmin Bu, Lijun Gao, Xu Xiao, Yury Gogotsi. Enhanced Rate Capability of Ion‐Accessible Ti 3 C 2 T x ‐NbN Hybrid Electrodes. Advanced Energy Materials 2020, 10 (35)
    97. Xin Zhao, Zhe Wang, Jie Dong, Tao Huang, Qinghua Zhang, Lili Zhang. Annealing modification of MXene films with mechanically strong structures and high electrochemical performance for supercapacitor applications. Journal of Power Sources 2020, 470 , 228356.
    98. Lei Yan, Jianhang Huang, Xiaoli Dong, Zhaowei Guo, Zhuo Wang, Yonggang Wang. Energizing hybrid supercapacitors by using Mn 2+ -based active electrolyte. Journal of Materials Chemistry A 2020, 8 (30) , 15051-15057.
    99. Yue Li, Pascal Kamdem, Xiao-Juan Jin. A Freeze-and-Thaw-Assisted Approach to Fabricate MXene/ZIF-8 Composites for High-Performance Supercapacitors and Methylene Blue Adsorption. Journal of The Electrochemical Society 2020, 167 (11) , 110562.
    100. Yapeng Tian, Chenhui Yang, Yi Tang, Yangyang Luo, Xiaojie Lou, Wenxiu Que. Ti3C2T //AC dual-ions hybrid aqueous supercapacitors with high volumetric energy density. Chemical Engineering Journal 2020, 393 , 124790.
    Load all citations

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Your Mendeley pairing has expired. Please reconnect