ACS Publications. Most Trusted. Most Cited. Most Read
My Activity

Hierarchical 3D Architectured Ag Nanowires Shelled with NiMn-Layered Double Hydroxide as an Efficient Bifunctional Oxygen Electrocatalyst

  • Soressa Abera Chala
    Soressa Abera Chala
    NanoElectrochemistry Laboratory, Department of Chemical Engineering, National Taiwan University of Science and Technology, Taipei 106, Taiwan
    Sustainable Energy Development Center, National Taiwan University of Science and Technology, Taipei 106, Taiwan
  • Meng-Che Tsai*
    Meng-Che Tsai
    NanoElectrochemistry Laboratory, Graduate Institute of Applied Science and Technology, National Taiwan University of Science and Technology, Taipei 106, Taiwan
    Sustainable Energy Development Center, National Taiwan University of Science and Technology, Taipei 106, Taiwan
    *E-mail: [email protected]
  • Wei-Nien Su*
    Wei-Nien Su
    NanoElectrochemistry Laboratory, Graduate Institute of Applied Science and Technology, National Taiwan University of Science and Technology, Taipei 106, Taiwan
    Sustainable Energy Development Center, National Taiwan University of Science and Technology, Taipei 106, Taiwan
    *E-mail: [email protected]
    More by Wei-Nien Su
  • Kassa Belay Ibrahim
    Kassa Belay Ibrahim
    NanoElectrochemistry Laboratory, Graduate Institute of Applied Science and Technology, National Taiwan University of Science and Technology, Taipei 106, Taiwan
  • Balamurugan Thirumalraj
    Balamurugan Thirumalraj
    NanoElectrochemistry Laboratory, Department of Chemical Engineering, National Taiwan University of Science and Technology, Taipei 106, Taiwan
    Sustainable Energy Development Center, National Taiwan University of Science and Technology, Taipei 106, Taiwan
  • Ting-Shan Chan
    Ting-Shan Chan
    National Synchrotron Radiation Research Center, Hsin-Chu 30076, Taiwan
  • Jyh-Fu Lee
    Jyh-Fu Lee
    National Synchrotron Radiation Research Center, Hsin-Chu 30076, Taiwan
    More by Jyh-Fu Lee
  • Hongjie Dai*
    Hongjie Dai
    Department of Chemistry, Stanford University, Stanford, California 94305, United States
    *E-mail: [email protected]
    More by Hongjie Dai
  • , and 
  • Bing-Joe Hwang*
    Bing-Joe Hwang
    NanoElectrochemistry Laboratory, Department of Chemical Engineering, National Taiwan University of Science and Technology, Taipei 106, Taiwan
    NanoElectrochemistry Laboratory, Graduate Institute of Applied Science and Technology, National Taiwan University of Science and Technology, Taipei 106, Taiwan
    Sustainable Energy Development Center, National Taiwan University of Science and Technology, Taipei 106, Taiwan
    National Synchrotron Radiation Research Center, Hsin-Chu 30076, Taiwan
    *E-mail: [email protected]
Cite this: ACS Nano 2020, 14, 2, 1770–1782
Publication Date (Web):January 31, 2020
Copyright © 2020 American Chemical Society

    Article Views





    Other access options
    Supporting Info (1)»


    Abstract Image

    Herein, we report hierarchical 3D NiMn-layered double hydroxide (NiMn-LDHs) shells grown on conductive silver nanowire (Ag NWs) cores as efficient, low-cost, and durable oxygen reduction reaction (ORR)/oxygen evolution reaction (OER) bifunctional electrocatalysts for metal–air batteries. The hierarchical 3D architectured Ag NW@NiMn-LDH catalysts exhibit superb OER/ORR activities in alkaline conditions. The outstanding bifunctional activities of Ag NW@NiMn-LDHs are essentially attributed to increasing both site activity and site populations. The synergistic contributions from the hierarchical 3D open-pore structure of the LDH shells, improved electrical conductivity, and small thickness of the LDHs shells are associated with more accessible site populations. Moreover, the charge transfer between Ag cores and metals of LDH shells and the formation of defective and distorted sites (less coordinated Ni and Mn sites) strongly enhance the site activity. Thus, Ag NW@NiMn-LDH hybrids exhibit a 0.75 V overvoltage difference between ORR and OER with excellent durability for 30 h, demonstrating the distinguished bifunctional electrocatalyst reported to date. Interestingly, the homemade rechargeable Zn–air battery using the hybrid Ag NW@NiMn-LDHs (1:2) catalyst as the air electrode exhibits a charge–discharge voltage gap of ∼0.77 V at 10 mA cm–2 and shows excellent cycling stability. Thus, the concept of the hierarchical 3D architecture of Ag NW@NiMn-LDHs considerably advances the practice of LDHs toward metal–air batteries and oxygen electrocatalysts.

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.


    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. You can change your affiliated institution below.

    Supporting Information

    Jump To

    The Supporting Information is available free of charge at

    • Additional SEM images, TEM (before and after long-time stability test), HR-TEM (before and after long-time stability test), EDX, XRD, FT-IR, BET, Raman spectra, XPS (before and after long-time stability test), XANES and EXAFS analysis, electrochemical results (CV, LSV, ECSA, and durability), conductivity result measured by 4-pont probe, EIS, computational DFT calculations, and performance comparison table (PDF)

    Terms & Conditions

    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system:

    Cited By

    This article is cited by 146 publications.

    1. Yunfei Chen, Zijian Li, Haeseong Jang, Zhe Wang, Min Gyu Kim, Qing Qin, Xien Liu. Sm-Induced Symmetry-Broken Ru Centers for Boosting Acidic Water Oxidation. ACS Sustainable Chemistry & Engineering 2024, Article ASAP.
    2. Wenxue Tan, Mengyuan Qin, Guiyuan Ma, Zunhao Fan, Xing Li, Xing Xin. Efficient Overall Water Splitting Using NiFe-LDH Nanosheets Modified with CoP-Ni5P4 Heterojunction Nanoarray Electrodes. ACS Sustainable Chemistry & Engineering 2024, 12 (13) , 5139-5149.
    3. Balasubramanian Sriram, Megha Maria Stanley, Sea-Fue Wang, Yung-Fu Hsu, Mary George. Two-Dimensional CuMn-Layered Double Hydroxides: A Study of Interlayer Anion Variants on the Electrochemical Sensing of Trichlorophenol. Inorganic Chemistry 2024, 63 (5) , 2833-2843.
    4. Hoang Khoi Vu, Tahereh Mahvelati-Shamsabadi, Thanh Truong Dang, Seung Hyun Hur, Sung Gu Kang, Jin Suk Chung. Synergistic Effects of Ni and Cu in Morphology-Controlled NiCu Electrocatalysts for Ammonia Electro-oxidation. ACS Applied Nano Materials 2023, 6 (22) , 20688-20699.
    5. Ting-Ting Yin, Hou-Ming Xu, Xiao-Long Zhang, Xiaozhi Su, Lei Shi, Chao Gu, Shi-Kui Han. Mn-Incorporation-Induced Phase Transition in Bottom-Up Synthesized Colloidal Sub-1-nm Ni(OH)2 Nanosheets for Enhanced Oxygen Evolution Catalysis. Nano Letters 2023, 23 (8) , 3259-3266.
    6. Sam Sankar Selvasundarasekar, Swathi Mahendran, Rufina Raj Mohamed, Amal BaQais, Mohammed A. Amin, Subrata Kundu. Boosting the Activity of the Oxygen Evolution Reaction through an Electrospun Nickel Manganese-Based Bimetallic Zeolite Imidazolate Framework Fibrous System in Alkaline Medium. Inorganic Chemistry 2023, 62 (16) , 6411-6420.
    7. Tiantian Wang, Zijian Li, Haeseong Jang, Min Gyu Kim, Qing Qin, Xien Liu. Interface Engineering of Oxygen Vacancy-Enriched Ru/RuO2–Co3O4 Heterojunction for Efficient Oxygen Evolution Reaction in Acidic Media. ACS Sustainable Chemistry & Engineering 2023, 11 (13) , 5155-5163.
    8. Yaxin Duan, Longxiang Wang, Jiakun Zhang, Chaoyong Sun, Rou Wen, Meiling Dou. Surface Engineering Route to Non-pyrolysis MOFs with High-Density Co–Nx Sites and 3D Conductive Networks for Efficient Oxygen Reduction. ACS Applied Energy Materials 2023, 6 (6) , 3244-3250.
    9. Sakthivel Kogularasu, Balasubramanian Sriram, Sea-Fue Wang, Jinn-Kong Sheu. Superlattice Stacking by Confinement of the Layered Double Hydroxide/Vanadium Carbide Hybrid Composite. The Effect on Interlayer Anions (SO42– and CO32–) for Comparing the Electrochemical Sensing of a Food Adulterant. ACS Sustainable Chemistry & Engineering 2022, 10 (46) , 15115-15123.
    10. K. Karuppasamy, Ranjith Bose, Dinesh Babu Velusamy, Dhanasekaran Vikraman, P. Santhoshkumar, Periyasamy Sivakumar, Akram Alfantazi, Hyun-Seok Kim. Rational Design and Engineering of Metal–Organic Framework-Derived Trimetallic NiCoFe-Layered Double Hydroxides as Efficient Electrocatalysts for Water Oxidation Reaction. ACS Sustainable Chemistry & Engineering 2022, 10 (45) , 14693-14704.
    11. Teng-xiu Tu, Xiao Zhou, Peng-fang Zhang, Liang Tan, Zhi-feng Xu, Meng-qin Liu, Wen-yi Li, Xiao-min Kang, Yi-jin Wu, Jian-zhong Zheng. Co7Fe3 Nanoparticles Confined in N-Doped Carbon Nanocubes for Highly Efficient, Rechargeable Zinc–Air Batteries. ACS Sustainable Chemistry & Engineering 2022, 10 (27) , 8694-8703.
    12. Lei Wan, Ziang Xu, Qingbin Cao, Yiwen Liao, Baoguo Wang, Kai Liu. Nanoemulsion-Coated Ni–Fe Hydroxide Self-Supported Electrode as an Air-Breathing Cathode for High-Performance Zinc–Air Batteries. Nano Letters 2022, 22 (11) , 4535-4543.
    13. Jiangnan Wang, Xueying Yue, Xiuting Li, Jie Dong, Qinghua Zhang, Xin Zhao. Lightweight and Elastic Silver Nanowire/PEDOT:PSS/Polyimide Aerogels for Piezoresistive Sensors. ACS Applied Polymer Materials 2022, 4 (5) , 3205-3216.
    14. Andrew R. Akbashev. Electrocatalysis Goes Nuts. ACS Catalysis 2022, 12 (8) , 4296-4301.
    15. Danzhong Sun, Jiao Li, Tianyang Shen, Sai An, Bo Qi, Yu-Fei Song. In Situ Construction of MIL-100@NiMn-LDH Hierarchical Architectures for Highly Selective Photoreduction of CO2 to CH4. ACS Applied Materials & Interfaces 2022, 14 (14) , 16369-16378.
    16. Chenhui Zhou, Xiao Chen, Shuo Liu, Ying Han, Haibing Meng, Qinyuan Jiang, Siming Zhao, Fei Wei, Jie Sun, Ting Tan, Rufan Zhang. Superdurable Bifunctional Oxygen Electrocatalyst for High-Performance Zinc–Air Batteries. Journal of the American Chemical Society 2022, 144 (6) , 2694-2704.
    17. Dhanasekaran Thangavelu, Yuanfu Chen, Padmanaban Annamalai, Manigandan Ramadoss, Vengidusamy Narayanan. Rationally Designed Ag@polymer@2-D LDH Nanoflakes for Bifunctional Efficient Electrochemical Sensing of 4-Nitrophenol and Water Oxidation Reaction. ACS Applied Materials & Interfaces 2022, 14 (5) , 6518-6527.
    18. Wenhui Luo, Yang Wang, Liuxiong Luo, Shen Gong, Mengni Wei, Yixuan Li, Xueping Gan, Yuyuan Zhao, Zhenghong Zhu, Zhou Li. Single-Atom and Bimetallic Nanoalloy Supported on Nanotubes as a Bifunctional Electrocatalyst for Ultrahigh-Current-Density Overall Water Splitting. ACS Catalysis 2022, 12 (2) , 1167-1179.
    19. Xavier Benadict Joseph, Jeena N. Baby, Sea-Fue Wang, Balasubramanian Sriram, Mary George. Interfacial Superassembly of Mo2C@NiMn-LDH Frameworks for Electrochemical Monitoring of Carbendazim Fungicide. ACS Sustainable Chemistry & Engineering 2021, 9 (44) , 14900-14910.
    20. Satarupa Das, Subhajit Bhattacharjee, Surajit Mondal, Supriti Dutta, Neha Bothra, Swapan K. Pati, Sayan Bhattacharyya. Bimetallic Zero-Valent Alloy with Measured High-Valent Surface States to Reinforce the Bifunctional Activity in Rechargeable Zinc-Air Batteries. ACS Sustainable Chemistry & Engineering 2021, 9 (44) , 14868-14880.
    21. Longchao Wang, Dingding Kong, Fengshang Chen, Lisan Cui, Yezheng Cai, Hongqiang Wang, Xinxian Zhong, Youguo Huang, Qingyu Li, Zhaoling Ma, Sijiang Hu. Strongly Coupled MnO2 Nanosheets/Silver Nanoparticles Hierarchical Spheres for Efficient Oxygen Reduction Reaction Electrocatalysis. Energy & Fuels 2021, 35 (20) , 16829-16836.
    22. Soressa Abera Chala, Meng-Che Tsai, Bizualem Wakuma Olbasa, Keseven Lakshmanan, Wei-Hsiang Huang, Wei-Nien Su, Yen-Fa Liao, Jyh-Fu Lee, Hongjie Dai, Bing Joe Hwang. Tuning Dynamically Formed Active Phases and Catalytic Mechanisms of In Situ Electrochemically Activated Layered Double Hydroxide for Oxygen Evolution Reaction. ACS Nano 2021, 15 (9) , 14996-15006.
    23. Fei Fan, Haoran Zhou, Rui Yan, Chengdong Yang, Huang Zhu, Yun Gao, Lang Ma, Sujiao Cao, Chong Cheng, Yinghan Wang. Anchoring Fe–N–C Sites on Hierarchically Porous Carbon Sphere and CNT Interpenetrated Nanostructures as Efficient Cathodes for Zinc–Air Batteries. ACS Applied Materials & Interfaces 2021, 13 (35) , 41609-41618.
    24. Yanan Zhang, Wenlong Ye, Jinchen Fan, Volkan Cecen, Penghui Shi, Yulin Min, Qunjie Xu. Cobalt-Nanoparticle-Decorated Cobalt–Molybdenum Bimetal Oxides Embedded in Flower-like N-Doped Carbon as a Durable and Efficient Electrocatalyst for Oxygen Evolution Reaction. ACS Sustainable Chemistry & Engineering 2021, 9 (33) , 11052-11061.
    25. Di Yin, Ming-Liang Wang, Yun-Dong Cao, Xiaopeng Yang, Su-Yu Ji, Hui-Ping Hao, Guang-Gang Gao, Lin-Lin Fan, Hong Liu. Polyoxometalate@ZIF Induced CoWO4/WS2@C-N Nanoflower as a Highly Efficient Catalyst for Zn–Air Batteries. ACS Applied Energy Materials 2021, 4 (7) , 6892-6902.
    26. Yuan Rao, Shan Chen, Qin Yue, Yijin Kang. Optimizing the Spin States of Mesoporous Co3O4 Nanorods through Vanadium Doping for Long-Lasting and Flexible Rechargeable Zn–Air Batteries. ACS Catalysis 2021, 11 (13) , 8097-8103.
    27. Minghua Wang, Changbao Wang, Jiameng Liu, Feilong Rong, Linghao He, Yafei Lou, Zhihong Zhang, Miao Du. Efficient Ag/Ag2O-Doped Cobalt Metallo-Covalent Organic Framework Electrocatalysts for Rechargeable Zinc-Air Battery. ACS Sustainable Chemistry & Engineering 2021, 9 (17) , 5872-5883.
    28. Ban Fei, Chaoqi Zhang, Daoping Cai, Jingying Zheng, Qidi Chen, Yulan Xie, Longzhen Zhu, Andreu Cabot, Hongbing Zhan. Hierarchical Nanoreactor with Multiple Adsorption and Catalytic Sites for Robust Lithium–Sulfur Batteries. ACS Nano 2021, 15 (4) , 6849-6860.
    29. Po-Chun Liao, Ren-Huai Jhang, Yu-Hsiang Chiu, Joey Andrew A. Valinton, Chia-Hao Yeh, Virgilio D. Ebajo, Jr., Ching-Hsuan Wang, Chun-Hu Chen. Rock Salt Oxide Hollow Spheres Achieving Durable Performance in Bifunctional Oxygen Energy Cells. ACS Applied Energy Materials 2021, 4 (4) , 3448-3459.
    30. Yue Zheng, Rui Gao, Yunsheng Qiu, Lirong Zheng, Zhongbo Hu, Xiangfeng Liu. Tuning Co2+ Coordination in Cobalt Layered Double Hydroxide Nanosheets via Fe3+ Doping for Efficient Oxygen Evolution. Inorganic Chemistry 2021, 60 (7) , 5252-5263.
    31. Zeyu Jin, Juan Lyu, Yi-Lu Zhao, Huanglong Li, Zuhuang Chen, Xi Lin, Guoqiang Xie, Xingjun Liu, Ji-Jung Kai, Hua-Jun Qiu. Top–Down Synthesis of Noble Metal Particles on High-Entropy Oxide Supports for Electrocatalysis. Chemistry of Materials 2021, 33 (5) , 1771-1780.
    32. Chandran Balamurugan, Seungjin Song, Hyeonjeong Jo, Junhyeok Seo. GdFeO3 Perovskite Oxide Decorated by Group X Heterometal Oxides and Bifunctional Oxygen Electrocatalysis. ACS Applied Materials & Interfaces 2021, 13 (2) , 2788-2798.
    33. Chiranjita Goswami, Yusuke Yamada, Ekaterina V. Matus, Ilyas Z. Ismagilov, Mikhail Kerzhentsev, Pankaj Bharali. Elucidating the Role of Oxide–Oxide/Carbon Interfaces of CuOx–CeO2/C in Boosting Electrocatalytic Performance. Langmuir 2020, 36 (49) , 15141-15152.
    34. Balasubramanian Sriram, Jeena N. Baby, Sea-Fue Wang, Roselin Ranjitha M., Mani Govindasamy, Mary George. Eutectic Solvent-Mediated Synthesis of NiFe-LDH/Sulfur-Doped Carbon Nitride Arrays: Investigation of Electrocatalytic Activity for the Dimetridazole Sensor in Human Sustenance. ACS Sustainable Chemistry & Engineering 2020, 8 (48) , 17772-17782.
    35. Constantine Tsounis, Xunyu Lu, Nicholas M. Bedford, Bijil Subhash, Lars Thomsen, Qingran Zhang, Zhipeng Ma, Kostya (Ken) Ostrikov, Avi Bendavid, Jason A. Scott, Rose Amal, Zhaojun Han. Valence Alignment of Mixed Ni–Fe Hydroxide Electrocatalysts through Preferential Templating on Graphene Edges for Enhanced Oxygen Evolution. ACS Nano 2020, 14 (9) , 11327-11340.
    36. Shanlin Li, Ruguang Ma, Yu Pei, Baohua Mao, Hongliang Lu, Minghui Yang, Tiju Thomas, Danmin Liu, Jiacheng Wang. Geometric Structure and Electronic Polarization Synergistically Boost Hydrogen Evolution Kinetics in Alkaline Medium. The Journal of Physical Chemistry Letters 2020, 11 (9) , 3436-3442.
    37. Qi Shao, Yan Li, Xu Cui, Tianjiao Li, Heng-guo Wang, Yanhui Li, Qian Duan, Zhenjun Si. Metallophthalocyanine-Based Polymer-Derived Co2P Nanoparticles Anchoring on Doped Graphene as High-Efficient Trifunctional Electrocatalyst for Zn-Air Batteries and Water Splitting. ACS Sustainable Chemistry & Engineering 2020, 8 (16) , 6422-6432.
    38. Min Zhang, Aihui Cao, Yucui Xiang, Chaogang Ban, Guang Han, Junjie Ding, Li-Yong Gan, Xiaoyuan Zhou. Strongly Coupled Ag/Sn–SnO2 Nanosheets Toward CO2 Electroreduction to Pure HCOOH Solutions at Ampere-Level Current. Nano-Micro Letters 2024, 16 (1)
    39. Kassa Belay Ibrahim, Tofik Ahmed Shifa, Sandro Zorzi, Marshet Getaye Sendeku, Elisa Moretti, Alberto Vomiero. Emerging 2D materials beyond mxenes and TMDs: Transition metal carbo-chalcogenides. Progress in Materials Science 2024, 144 , 101287.
    40. Bohan Zhang, Jiacheng Cui, Dapeng He, Jiaming Zhang, Lieji Yang, Wei Zhu, Hualiang Lv. Transparent electromagnetic absorption film derived from the biomass derivate. Journal of Materials Science & Technology 2024, 185 , 98-106.
    41. Yu-Syuan Jheng, Shing-Jiang Jessie Lue, Kong-Wei Cheng. Nanoarchitectonics of ternary NixCo1-xSe2 electrocatalysts on Ni-foams combined with Pt-loaded carbon clothes as the air-cathodes in Zn-air energy storage systems. Journal of the Taiwan Institute of Chemical Engineers 2024, 159 , 105451.
    42. Xia Qu, Yantao Yang, Lili Dong, Zheng Li, Yuwei Feng, Tingzhou Lei, Suxia Ren. Enzymolytic lignin derived Fe–N codoped porous carbon materials as catalysts for oxygen reduction reactions. Biomass and Bioenergy 2024, 184 , 107173.
    43. Megha Maria Stanley, Balasubramanian Sriram, Sea-Fue Wang, Abhikha Sherlin, Sakthivel Kogularasu, Yen-Yi Lee, Mary George. Rational confinement of ternary layered double hydroxide within three-dimensional graphene aerogel: An electrochemical tool for propyl gallate sensing. Chemical Engineering Journal 2024, 485 , 149682.
    44. Yihua Cao, Zhi Li, Xueli Yin, Yonghao Gan, Ying Ye, Run Cai, Qi Wang, Bo Feng, Xiaoping Dai, Weiyu Song. Electronic modulation and reaction-pathway optimization on three-dimensional seaweed-like NiSe@NiMn LDH heterostructure to trigger effective oxygen evolution reaction. Journal of Colloid and Interface Science 2024, 658 , 528-539.
    45. Jiajun Li, Di Lan, Yuhang Cheng, Zirui Jia, Panbo Liu, Xuetao Shi, Hua Guo, Ailing Feng, Xing Feng, Guanglei Wu, Pengfei Yin. Constructing mixed-dimensional lightweight magnetic cobalt-based composites heterostructures: An effective strategy to achieve boosted microwave absorption and self-anticorrosion. Journal of Materials Science & Technology 2024, 171
    46. Youngsun Cha, Taewon Kim, Kyungmin Kim, Jae Wook Seo, Ho Young Jang, Wonjoon Choi. Scalable exothermic synthesis of sprout-like Ni-Co-Fe trimetallic oxide nanoparticles anchored on N-doped carbon nanotubes as bifunctional oxygen catalysts for zinc-air batteries. Carbon 2024, 220 , 118859.
    47. Mingze Gao, Chao Li, Ruiya Wang, Shiying Xiao, Ziyang Guo, Yonggang Wang. Noble metal catalysts for metal-air batteries: From nano-level to atom-level. Next Materials 2024, 2 , 100126.
    48. Ming Yang, Wanyu Ge, Zirui Liu, Qiang Yue, Jun Zhang, Yanping Lv, Hao Wu. Synthesis of defective Ni-Mn layered double hydroxides nanosheets via alkali-assisted Mo doping for urea electro-oxidation. Fuel 2024, 356 , 129626.
    49. Botao Zhu, Bo Dong, Feng Wang, Qifeng Yang, Yunpeng He, Cunjin Zhang, Peng Jin, Lai Feng. Unraveling a bifunctional mechanism for methanol-to-formate electro-oxidation on nickel-based hydroxides. Nature Communications 2023, 14 (1)
    50. Huihui Sun, Xinzhi Zang, Hui Wang, Zhen Li, Wenqiang Wang, Aijun Gu, Zhaolian Ye, Songjian Zhao. Efficient catalytic degradation of VOCs using Mn-based hydrotalcite-like compounds coupled with non-thermal plasma. Journal of Environmental Chemical Engineering 2023, 11 (6) , 111321.
    51. Chaoyang Sun, Lu Lei, Palanisamy Kannan, Palaniappan Subramanian, Shan Ji. Grain boundaries derived from layered Fe/Co di-hydroxide porous prickly-like nanosheets as potential electrocatalyst for efficient electrooxidation of hydrazine. Applied Surface Science 2023, 639 , 158265.
    52. Jie Hong, Lei Zhang, Qiliang Zhu, Ziang Du, Yingtang Zhou, Thomas Wågberg, Guangzhi Hu. A macroporous carbon nanoframe for hosting Mott–Schottky Fe–Co/Mo 2 C sites as an outstanding bi-functional oxygen electrocatalyst. Materials Horizons 2023, 10 (12) , 5969-5982.
    53. Xiaohan Wang, Junjie Xing, Xiuli Fu. Cu-doped NiFe layered double hydroxide nanosheets on nickel foam as an effective and durable electrocatalyst for oxygen evolution reaction. International Journal of Modern Physics B 2023, 37 (29)
    54. Jie Wang, Aimin Wu, Lei Xing, Shuai Ran, Wenhua Yu, Xufeng Dong, Hao Huang. Plasma preparation of highly reactive Ag-Cu NPs anchored in N-PC as catalysts for Aluminum-air battery. Journal of Energy Chemistry 2023, 86 , 217-226.
    55. E. Yu. Tyulyaeva. Noble Metal Porphyrin Complexes. Intermediates of Catalytic Processes (A Review). Russian Journal of Inorganic Chemistry 2023, 68 (11) , 1537-1561.
    56. Mao Sun, Jike Wang. Defective NiMn LDH prepared using hydrogen evolution coupled electrodeposition for highly efficient oxygen evolution reaction. Journal of Materials Chemistry A 2023, 11 (39) , 21420-21428.
    57. Kassa Belay Ibrahim, Tofik Ahmed Shifa, Matteo Bordin, Elisa Moretti, Heng‐Liang Wu, Alberto Vomiero. Confinement Accelerates Water Oxidation Catalysis: Evidence from In Situ Studies. Small Methods 2023, 7 (10)
    58. Bingbing Fan, He Wang, Qingyou Zhang, Yanmei Zhou. Fabrication PANI/NiMn/NMP composite via electrodeposition with an activated process of converse voltage for energy storage. Journal of Energy Storage 2023, 70 , 108063.
    59. Huanfeng Huang, Shunlian Ning, Yanyu Xie, Zhujie He, Jun Teng, Zhuodi Chen, Yanan Fan, Jian‐Ying Shi, Mihail Barboiu, Dawei Wang, Cheng‐Yong Su. Synergistic Modulation of Electronic Interaction to Enhance Intrinsic Activity and Conductivity of Fe–Co–Ni Hydroxide Nanotube for Highly Efficient Oxygen Evolution Electrocatalyst. Small 2023, 19 (36)
    60. Jingjing Cao, Zimou Feng, Huaxing Liang, Xinglin Lu, Wei Wang. Oriented self-assembly of anisotropic layered double hydroxides (LDHs) with 2D-on-3D hierarchical structure. Chemical Engineering Journal 2023, 472 , 144872.
    61. Xavier Benadict Joseph, Jeena N. Baby, Sea-Fue Wang, Mary George. Emerging carbonate anion intercalated- ZnCr-layered double hydroxide/vanadium carbide nanocomposite: A electrochemical sensor for diethofencarb fungicide monitoring. Chemosphere 2023, 335 , 139099.
    62. Wenjun He, Rui Zhang, Hui Liu, Qiuyan Hao, Ying Li, Xuerong Zheng, Caichi Liu, Jun Zhang, Huolin L. Xin. Atomically Dispersed Silver Atoms Embedded in NiCo Layer Double Hydroxide Boost Oxygen Evolution Reaction. Small 2023, 19 (34)
    63. Peng Long, Mengmeng Qin, Baocai Zhang, Qijing Liu, Fulai Zhao, Zijie Wu, Zhengyang Ni, Huitao Yu, Feng Li, Hao Song, Yiyu Feng, Wei Feng. Nano-flower like CoFe-layered double hydroxide@reduced graphene oxide with efficient oxygen reduction reaction for high-power air-cathode microbial fuel cells. Carbon 2023, 212 , 118088.
    64. Yuanting Wu, Qiujun Liu, Jinrong Wang, Xuhua Liu, Xinmeng Zhang. Effectively morphology-controlled NiMn layered double hydroxide microflowers by conductive silver nanowires for supercapacitor electrodes. Electrochimica Acta 2023, 460 , 142623.
    65. Lingbo Zong, Ping Li, Fenghong Lu, Chengbin Wang, Kaicai Fan, Zhenjiang Li, Lei Wang. Assembling Amorphous Metal–Organic Frameworks onto Heteroatom‐Doped Carbon Spheres for Remarkable Bifunctional Oxygen Electrocatalysis. Advanced Functional Materials 2023, 33 (30)
    66. Santanu Pal, Koji Shimizu, Sakila Khatun, Soumen Singha, Satoshi Watanabe, Poulomi Roy. Electrolyte engineering for effective seawater splitting based on manganese iron chromium layered triple hydroxides as novel bifunctional electrocatalysts. Journal of Materials Chemistry A 2023, 11 (23) , 12151-12163.
    67. Priyadarshi Roy Chowdhury, Himani Medhi, Krishna G. Bhattacharyya, Chaudhery Mustansar Hussain. Recent progress in the design and functionalization strategies of transition metal-based layered double hydroxides for enhanced oxygen evolution reaction: A critical review. Coordination Chemistry Reviews 2023, 483 , 215083.
    68. Mengxia Shen, Jiale Qi, Kun Gao, Chao Duan, Jun Liu, Qingqing Liu, Hao Yang, Yonghao Ni. Chemical vapor deposition strategy for inserting atomic FeN4 sites into 3D porous honeycomb carbon aerogels as oxygen reduction reaction catalysts in high-performance Zn-air batteries. Chemical Engineering Journal 2023, 464 , 142719.
    69. Guoqiang Shu, Yaqi Lin, Rui Zhong, Xiaofan Su, Shanhong Guo, Chao Wang, Changan Zhou, Lei Song, Li Xie, Kui Ma, Hairong Yue. Engineering triple internal electric fields in Ag NWs@BaTiO3 composites for ultrasonic-visible-light driven antibacterial activity. Chemical Engineering Journal 2023, 463 , 142310.
    70. Yi Feng, Lei Chen, Zhong-Yong Yuan. Recent advances in transition metal layered double hydroxide based materials as efficient electrocatalysts. Journal of Industrial and Engineering Chemistry 2023, 120 , 27-46.
    71. Xuekun Jin, Minghua He, Fengjuan Chen, Kezhi Li, Junyong Min, Ziyu Wang, Junhua Li, Jianjun Chen. Trace Cr(OH)3 modified α-MnO2 electrocatalyst intercalated by Ag+ with superior activity and stability for oxygen reduction reaction. Chemical Engineering Journal 2023, 34 , 142712.
    72. Qingbin Cao, Lei Wan, Ziang Xu, Wenmin Kuang, Hao Liu, Xin Zhang, Weili Zhang, Yang Lu, Yujian Yao, Baoguo Wang, Kai Liu. A Fluorinated Covalent Organic Framework with Accelerated Oxygen Transfer Nanochannels for High‐Performance Zinc–Air Batteries. Advanced Materials 2023, 35 (17)
    73. Shaohui Zhang, Hao Cui, Haikun Zhou, Xiyu Tan, Pengfei Tan, Jun Pan. Facile synthesis of PtMn@Pt core-shell nanowires for oxygen reduction reaction. Journal of Physics and Chemistry of Solids 2023, 173 , 111136.
    74. Jeena N. Baby, Megha Maria Stanley, Abhikha Sherlin V, Mary George. Eutectic solvent mediated synthesis of carbonated CoFe-LDH nanorods: The effect of interlayer anion (Cl−, SO42−, CO32−) variants for comparing the bifunctional electrochemical sensing application. Chemosphere 2023, 315 , 137716.
    75. Ziyao Li, Mengshan Chen, Lei Zhang, Rui Xing, Jinsong Hu, Xinhua Huang, Chunhui Zhou, Yingtang Zhou, Thomas Wågberg, Guangzhi Hu. Atomic-level orbital coupling in a tri-metal alloy site enables highly efficient reversible oxygen electrocatalysis. Journal of Materials Chemistry A 2023, 11 (5) , 2155-2167.
    76. Meng Yang, Jingwu Zhang, Jinming Wang, Wei Gao, Di Liu, Lanjie Li, Yimin Wang, Qiuming Peng. Spatial confinement of sliver nanoparticles in nitrogen-doped carbon framework with high catalytic activity and long-term cycling. Frontiers in Energy Research 2023, 10
    77. You Ye, Yan Shan, Hongli Zhu, Kezheng Chen, Xuegang Yu. Controllable formation of amorphous structure to improve the oxygen evolution reaction performance of a CoNi LDH. RSC Advances 2023, 13 (4) , 2467-2475.
    78. Dexin Yu, Feng Zhang, Kai Yu, Fengyu Qu. One-step construction of Co(OH)2-anchored g-C3N4 and rGO with phase junction for dopamine sensing and oxygen evolution reaction. Journal of Nanostructure in Chemistry 2023, 64
    79. Ge Gao, Kang Wang, Xitao Wang. Peony flower-like CuxS@NiMn LDH heterostructure as an efficient electrocatalyst for the oxygen evolution reaction. International Journal of Hydrogen Energy 2023, 48 (4) , 1347-1359.
    80. T.A. Kumaravelu, A. Ramakrishnan, Y.R. Lu, J.L. Chen, S.W. Chen, C.H. Du, M.Y. Chen, P.H. Yeh, A. Kandasami, C.H. Chen, C.L. Dong. Activation-induced layered structure in NiCoAl by atomic modulation for energy storage application. Materials Today Chemistry 2023, 27 , 101265.
    81. Jie Hong, Mengshan Chen, Lei Zhang, Lai Qin, Jinsong Hu, Xinhua Huang, Chunhui Zhou, Yingtang Zhou, Thomas Wågberg, Guangzhi Hu. Asymmetrically coupled Co Single-atom and Co nanoparticle in Double-shelled Carbon-based nanoreactor for enhanced reversible oxygen catalysis. Chemical Engineering Journal 2023, 455 , 140401.
    82. Kassa Belay Ibrahim, Tofik Ahmed Shifa, Paolo Moras, Elisa Moretti, Alberto Vomiero. Facile Electron Transfer in Atomically Coupled Heterointerface for Accelerated Oxygen Evolution. Small 2023, 19 (1)
    83. Xiaomin Xu, Zongping Shao. Design of Bifunctional Oxygen Catalysts in Rechargeable Zinc–Air Batteries. 2022, 69-110.
    84. Abhikha Sherlin V, Jeena N. Baby, Balasubramanian Sriram, Yung-Fu Hsu, Sea-Fue Wang, Mary George. Construction of ANbO3 (A= Na, K)/f-carbon nanofiber composite: Rapid and real-time electrochemical detection of hydroxychloroquine in environmental samples. Environmental Research 2022, 215 , 114232.
    85. Hongling Zhang, Haoqing Tang, Qiang Weng, Qingbo Wei, Mengyan Duan, Xin Bo, Feng Fu, Lingxing Zan. Engineering heterostructure of bimetallic nickel-silver sulfide as an efficient electrocatalyst for overall water splitting in alkaline media. Journal of Solid State Chemistry 2022, 316 , 123556.
    86. Yaoyao Deng, Yidong Lu, Rentong Dai, Mei Xiang, Zhenwei Zhang, Xiaoli Zhang, Quanfa Zhou, Hongwei Gu, Jirong Bai. Designing hierarchical iron doped nickel-vanadium hydroxide microsphere as an efficient electrocatalyst for oxygen evolution reaction. Journal of Colloid and Interface Science 2022, 627 , 215-223.
    87. Qing Dong, Hui Wang, Jianwei Ren, Xuyun Wang, Shan Ji, Rongfang Wang. Ultra-dispersed copper nanoparticles constructing crystalline-amorphous interface sites for alkaline water splitting. Journal of Colloid and Interface Science 2022, 627 , 650-660.
    88. Fan Gao, Chuanliang Li, Yangyang Ren, Baosong Li, Chenhao Lv, Xiaojing Yang, Xinghua Zhang, Zunming Lu, Xiaofei Yu, Lanlan Li. High‐Efficient Ultrathin PdCuMo Porous Nanosheets with Abundant Defects for Oxygen Reduction Reaction. Chemistry – A European Journal 2022, 28 (61)
    89. Chandran Balamurugan, Changhoon Lee, Kyusang Cho, Jehan Kim, Byoungwook Park, Yusin Pak, Jaemin Kong, Sooncheol Kwon. Hydrothermally Grown Dual‐Phase Heterogeneous Electrocatalysts for Highly Efficient Rechargeable Metal‐Air Batteries with Long‐Term Stability. Advanced Science 2022, 9 (32)
    90. Yu Jun Yang, Panxiang Yang, Ningya Wang, Songyang Chen, Yao Cheng, Mengxiao Liu, Chenjia Jiang. Hierarchical flower-like FeCo-LDH/GO@montmorillonite composite for efficient catalysis of oxygen reduction. Fullerenes, Nanotubes and Carbon Nanostructures 2022, 30 (10) , 1011-1018.
    91. Yuan-Yuan Yao, Yu-Syuan Jheng, Ya-Ting Su, Kong-Wei Cheng. Chemical synthesis of metallic silver-based nanopowder catalysts on the conductive carbon black particles as the active materials applied in a Zn-Ag/Zn-air hybrid energy storage system. Journal of the Taiwan Institute of Chemical Engineers 2022, 139 , 104530.
    92. Dipti Prava Sahoo, Kundan Kumar Das, Sriram Mansingh, Sabiha Sultana, Kulamani Parida. Recent progress in first row transition metal Layered double hydroxide (LDH) based electrocatalysts towards water splitting: A review with insights on synthesis. Coordination Chemistry Reviews 2022, 469 , 214666.
    93. Yang Yang, Shuya Wei, Yafei Li, Donggang Guo, Huajie Liu, Lu Liu. Effect of cobalt doping-regulated crystallinity in nickel-iron layered double hydroxide catalyzing oxygen evolution. Applied Catalysis B: Environmental 2022, 314 , 121491.
    94. Youngtae Park, Kihyun Shin, Changsoo Lee, Sang-Yeon Lee, Yong-Kul Lee, Chang-Hee Kim, Hyun-Seok Cho, Graeme Henkelman, Hyuck Mo Lee. Iterative redox activation promotes interfacial synergy in an Ag/CuxO catalyst for oxygen reduction. Chemical Engineering Journal 2022, 446 , 136966.
    95. Quan Quan, Yuxuan Zhang, Fei Wang, Xiuming Bu, Wei Wang, You Meng, Pengshan Xie, Dong Chen, Weijun Wang, Dengji Li, Chuntai Liu, SenPo Yip, Johnny C. Ho. Topochemical domain engineering to construct 2D mosaic heterostructure with internal electric field for high-performance overall water splitting. Nano Energy 2022, 101 , 107566.
    96. Jun-Jun Zhang, Meng-Yang Li, Wei-Wei Bao, Xiao-Hua Feng, Ge Liu, Chun-Ming Yang, Na Guo, Nan-Nan Zhang. Cr-doped NiZn layered double hydroxides with surface reconstruction toward the enhanced water splitting. Colloids and Surfaces A: Physicochemical and Engineering Aspects 2022, 649 , 129324.
    97. Longjun Fu, Shilong Zhou, Meng Xiang, Jingjing Yang, Wangxi Fan, Zhou Yang, Junfei Ou. Advances in anion vacancy for electrocatalytic oxygen evolution reaction. Journal of Electroanalytical Chemistry 2022, 921 , 116650.
    98. Xavier Benadict Joseph, Abhikha Sherlin V, Sea-Fue Wang, Mary George. Integration of iron–manganese layered double hydroxide/tungsten carbide composite: An electrochemical tool for diphenylamine H•+ analysis in environmental samples. Environmental Research 2022, 212 , 113291.
    99. Wenjun He, Fangqing Wang, Yaohui Gao, Qiuyan Hao, Caichi Liu. One-step synthesis of amorphous transition metal sulfides as bifunctional electrocatalysts for the hydrogen evolution reaction and oxygen evolution reaction. Sustainable Energy & Fuels 2022, 6 (16) , 3852-3857.
    100. Hongyu Zhang, Hongcheng Di, Dianxue Cao, Zhuwu Jiang, Zhipeng Hu, Xue Bai. High performance asymmetric supercapacitor assembled by Co‐Mn LDHs coating on hollow MOF structure as positive electrode and MXene‐based composite as negative electrode. International Journal of Energy Research 2022,
    Load all citations

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Your Mendeley pairing has expired. Please reconnect