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Refractive Indexes and Spectroscopic Properties to Design Er3+-Doped SiO2–Ta2O5 Films as Multifunctional Planar Waveguide Platforms for Optical Sensors and Amplifiers
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Refractive Indexes and Spectroscopic Properties to Design Er3+-Doped SiO2–Ta2O5 Films as Multifunctional Planar Waveguide Platforms for Optical Sensors and Amplifiers
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  • Jefferson L. Ferrari
    Jefferson L. Ferrari
    Laboratório de Materiais Luminescentes Micro e Nanoestruturados−Mater Lumen, Departamento de Química, FFCLRP, Universidade de São Paulo, Av. Bandeirantes, 3900−Campus da Usp, Ribeirão Preto−SP, 14040-900 São Paulo, Brazil
    Desenvolvimento de Materiais Inorgânicos com Terras Raras−DeMITeR, Laboratório de Materiais Fotoluminescentes (LAMAF), Instituto de Química−(IQ), Universidade Federal de Uberlândia−(UFU), Av. João Naves de Ávila, 2121−Bairro Santa Mônica, CEP, 38400-902 Uberlândia, Minas Gerais, Brazil
    More by Jefferson L. Ferrari
  • Karmel de O. Lima
    Karmel de O. Lima
    Laboratório de Materiais Luminescentes Micro e Nanoestruturados−Mater Lumen, Departamento de Química, FFCLRP, Universidade de São Paulo, Av. Bandeirantes, 3900−Campus da Usp, Ribeirão Preto−SP, 14040-900 São Paulo, Brazil
    More by Karmel de O. Lima
  • Rogéria R. Gonçalves*
    Rogéria R. Gonçalves
    Laboratório de Materiais Luminescentes Micro e Nanoestruturados−Mater Lumen, Departamento de Química, FFCLRP, Universidade de São Paulo, Av. Bandeirantes, 3900−Campus da Usp, Ribeirão Preto−SP, 14040-900 São Paulo, Brazil
    *Email: [email protected]. Tel: +55 16 36024851. Fax: +55 16 363288151.
    More by Rogéria R. Gonçalves
    Orcidhttp://orcid.org/0000-0001-5540-7690
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ACS Omega

Cite this: ACS Omega 2021, 6, 13, 8784–8796
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https://doi.org/10.1021/acsomega.0c05351
Published March 25, 2021

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Abstract

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This paper reports on the news about refractive index measurements and spectroscopic features of thin films, which can be applied as optical planar waveguides, focusing on their manufacturing processes, designs, and possible applications as optical amplifiers and sensors. Er3+-doped SiO2–Ta2O5 planar waveguides, with Si/Ta ratios of 90:10, 80:20, 70:30, 60:40, and 50:50, were prepared by a soft sol–gel process. Multilayer films were deposited by the dip-coating technique onto 10 μm SiO2–Si (100) p-type silicon and Si (100) silicon easily and successfully. The mechanisms of the densification process, porosity, and hydroxy group or water molecule occurrence have been accompanied by m-line and vibrational spectroscopy analyses. The thickness and refractive index values were used to understand better the influence of temperature and annealing time on the densification of the bulk films and the reduction of the pore volume as the tantalum oxide concentration increases. The refractive index shows the density of the films, and by the atomic force microscopy (AFM) technique, the films showed low surface roughness, achieving relatively high light confinement within the waveguide structure, and negligible optical loss due to surface scattering. Nanoparticle crystallization of Ta2O5 with size distribution ranging from 2.0 to 15.0 nm embedded in SiO2 was observed with size depending on annealing time and tantalum concentration. Intense and broadband emission positioned at 1550 nm, which is attributed to the 4I13/2 → 4I15/2 transition of Er3+ ions, was observed for all planar waveguides under excitation at 271, 272, and 278 nm. Depending on the porosity degree, the adsorption of H2O molecules occurs, changing the refractive index and contributing to the deactivation of excited states of Er3+ ions, making them an optical platform for use as an optical sensor for different species. Besides, the densified waveguides containing 20 or 30 mol % Ta exhibit high potential for applications as broadband optical amplifiers for wavelength division multiplexing (WDM), optical sensing, or augmented reality.

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1. Introduction

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Recent modern applications in the field of photonics have involved the use of waveguides. In the past years, new optical devices have been created enabling greater performance, more affordable prices for mass production, or even the development of new technologies. The relentless pursuit for new devices with high performance has led to a significant increase in research considering strategic areas as health, environment, and telecommunication. Planar waveguides have emerged as a target of many research groups and optoelectronic industries in the world and have been used as a platform for optical information transport in integrated optical devices. (1) For instance, their use as a platform for optical sensors is one of the great potential applications for waveguides. (2−5) Nowadays, most of the wearable augmented reality display devices operate using waveguide technology, of which some are commercial products. However, mass production has been already limited by cost and performance in many cases. (6) Among the different planar waveguide applications, the different highlights are due to the demand for information through visual means, and the augmented reality created through special glasses has been presenting a special need. (7−9) This type of application of planar waveguides regarding augmented reality manages to bring, in virtual ways, environments that in most cases would be impossible to visit in person. Thus, the contribution to the development of knowledge based on real facts becomes indispensable and possible to achieve without leaving home, for example.
Among the materials used to manufacture optical devices as planar waveguides, those based on SiO2 have been highlighted due to physical, mechanical, and chemical properties. (10) For instance, one of the most studied silica-based systems and commercial products found in the market is the Er3+-doped optical fiber amplifier (EDFA), which contains low rare-earth (RE3+) ion concentration to achieve enough gain. (11−13) However, the RE3+ concentration must be increased by at least 2 orders of magnitude than its counterpart Er3+-doped planar waveguide amplifier (EDWA). A high RE3+ ion concentration leads to the formation of clusters in the silica-based system, and consequently, competitive processes such as energy migration between them, energy transfer, and upconversion can occur, reducing drastically the near-infrared (NIR) luminescence quantum yield. The choice of the host to have great optical, structural, morphological, and luminescence properties is undoubtedly one of the most critical factors for the development of photonic devices. Regarding silicate-based planar waveguides, binary oxides, like SiO2–MO2 (M = Hf, Zr, and Ti), (14−19) have been studied and interesting optical features have been observed when doped with Er3+ ions. The addition of metal oxides such as Hf, Zr, and Ti to the silica host promotes refractive index tailoring, which is important to control optical parameters regarding waveguide applications and induce controlled-phase separation with a high distribution of RE3+ in the crystalline or amorphous metal oxide microenvironment. Luminescence at 1.5 μm has been obtained from SiO2–MO2 (M = Hf, Zr, Ti), and a full-width at half-maximum (FWHM) of up to 48 nm has been obtained for the amorphous system with a drastic reduction as the glass ceramic is produced. For instance, a FWHM of about 30 nm has been observed from the glass ceramic containing Er3+-doped HfO2 nanocrystals and 14 nm for that containing Er3+-doped ZrO2 nanocrystals. (19)
In previous works, we have reported outstanding unusual broadened emission in the silicate glass ceramic host, when Er3+-doped Ta2O5 or Nb2O5 nanocrystals are embedded into the silica-based host, similar to that observed for tellurite glasses, the most cited host in the literature displaying large inhomogeneous broadening at 1.5 μm. (20−23)
Among several techniques used for optical material preparation, the sol–gel process followed by dip-coating deposition has been used as one of the cheapest and most versatile routes for manufacturing films that exhibit high-quality optical properties. (24) Sol–gel-prepared waveguides bring interesting solutions concerning their production because of its low cost, flexibility concerning composition, and refractive index tailoring and can be applied in a wide-ranging device geometry. (25) Besides, the precursors are homogeneously mixed at the molecular level, allowing a wide range of composition, including multicomponents, wherein some of them cannot be obtained by other methodologies. For instance, binary SiO2–Ta2O5 and SiO2–Nb2O5 glasses as well as the respective glass ceramics cannot be obtained by a traditional method for producing glasses through a melt–quenching process, except using a sol–gel process. (20−23) The sol–gel process usually is applied for obtaining products at room temperature or lower temperatures in comparison with other fabrication routes. The xerogels obtained by this process can be submitted to thermal annealing for elimination of undesired species such as O–H and C–H groups and H2O molecules besides pores. Full elimination of residual species is required since they act in deactivating the excited states of RE3+ ions, reducing the emission quantum efficiency, and quenching the photoluminescence. Consequently, concerning sol–gel photonic materials, the densification of the host and total elimination of residual organic and hydroxyl groups represent one of the most important aims to be achieved for luminescence improvement and active planar waveguide fabrication. However, the presence of pores allows the adsorption of small molecules like water, ammonia, carbon dioxide, methanol, and others.
An understanding of the whole preparation process until the achievement of fully densified films passing through porous precursors is the aim of this work. In this sense, this work reports on how to design active or passive planar waveguides, as well as porous waveguides, which can be used as optical sensor platforms, using optical and spectroscopic parameters. The Er3+-doped SiO2–Ta2O5 planar waveguide samples, by changing the Si/Ta ratios as 90:10, 80:20, 70:30, 60:40, and 50:50, were prepared by the sol–gel process. Ta2O5 shows interesting properties regarding planar waveguide manufacturing and optoelectronic devices due to its transparency in from the near-UV (λ > 300 nm) to the infrared region along with its chemical and mechanical stability and high refractive index. Therefore, the addition of Ta2O5 nanocrystals to the silica matrix tailors a wide range of properties, such as refractive index, band gap energy, mechanical properties, chemical reactivity or stability, and luminescence. The latter occurs in the presence of rare-earth ions.
Here, the optical and spectroscopic properties of low loss Er3+-activated planar waveguides are discussed in terms of the composition and structural properties by changing the tantalum content and thermal annealing conditions. The luminescence from RE3+-doped orthorhombic Ta2O5-based nanocomposites opened the possibility of thin film preparation for use as active planar optical amplifiers operating not only in the C band but also in the S band and L band of telecommunication, or to be applied as optical sensors.

2. Experimental Procedure

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The Er3+-doped SiO2–Ta2O5 thin films, containing 0.3 mol % Er3+ ions, were prepared by the sol–gel route and deposited onto 10 μm SiO2–Si (100) p-type silicon and Si (100) silicon as substrates by the dip-coating technique. Solutions with a total concentration of Si + Ta = 0.445 mol L–1 were obtained with Si/Ta molar ratios of 90:10, 80:20, 70:30, 60:40, and 50:50. Tantalum ethoxide and tetraethylorthosilicate (TEOS) were used as Ta and Si precursors, respectively. The preparation of a solution was based on the experimental procedure reported by Ferrari et al.; (26−28) Er3+ ions (0.3 mol % Er3+ ions in relation to the Si + Ta ions) were added from their standardized stock ethanolic solutions, which were obtained by dissolving Er2O3 in 0.1 mol L–1 HCl aqueous solution, followed by solvent exchange with ethanol. A mixture of TEOS, anhydrous ethanol, and concentrated hydrochloric acid (solution 1) was first prepared. The TEOS/HCl molar ratio was 50:1. Tantalum ethoxide, 2-ethoxyethanol, and Er3+ ions (solution 2) were mixed in a separate container. Then, solutions 1 and 2 were mixed and kept under stirring at room temperature for 30 min. Next, an aqueous hydrochloric acid solution (0.27 mol L–1) was added to the final solution at a TEOS/HCl ratio of 1:0.007. Subsequently, the solution was filtered through a 0.2 μm filter and left to stand for 16 h for film deposition. Multiple layers were deposited by the dip-coating technique with a dipping rate of 30 mm min–1. Between each deposited layer, the film was heated to 900 °C for 60 s to ensure adhesion on the surface, organic residue elimination, and densification until 50 layers were achieved.
The planar waveguide deposited onto Si (100) silicon substrate was used to obtain information about structural properties by Fourier transform infrared (FTIR) spectra. Before further coating, each layer was annealed in an oven in air for 60 s at 900 °C. The densification process was monitored by studying the optical properties of the 50-layer films annealed at different times at the same temperature. Between each annealing time, the films deposited on the SiO2/Si substrate were characterized by an m-line apparatus (Metricon Model 2010) by the prism coupling technique. The refractive indexes of the planar waveguides were measured at room temperature for both transverse electric (TE) and magnetic (TM) polarizations. A prism with a refractive index of 1.9644 at 632.8 nm was used. The apparatus is equipped with detectors to collect visible and near-infrared radiation. He–Ne and solid lasers, operating at 632.8 and 532 nm, respectively, and one diode laser, operating at 1538 nm, were employed.
The FTIR spectra of films deposited on the Si (100) substrate were collected in the range from 4000 to 400 cm–1 using a Bomem MB102 spectrometer. Finally, after full densification, the surfaces of the films were characterized by atomic force microscopy (AFM) using a Shimadzu SPM 9600 microscope operating in the contact mode. The images were collected and analyzed using SPM version 3.03 software. The high-resolution transmission electron microscopy (HRTEM) images were collected to obtain information about crystallization and phase separation using a high-resolution TEM (JEOL 3010). The film samples for HRTEM analysis were prepared with polishing ionic attacks operating GATAN-PIPS.
Emission and excitation spectra were collected at room temperature using a Jobin Yvon Fluorolog-3-Spex. The excitation and emission slits used were adjusted to give a 3 nm bandpass. The excitation spectra were collected in the region between 240 and 550 nm, with a spectral resolution of 0.2 nm and emission fixed at 1528 nm. The emission spectra were collected in the region between 1400 and 1700 nm by fixing the excitation at 271, 274, and 278 nm for samples with Si/Ta ratios of 80:20, 70:30, and 50:50, respectively.

3. Results and Discussion

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One of the optical parameters extremely fundamental to characterize active waveguides, mainly to calculate the light confinement coefficient, the number of the guided modes, and their effective refractive index, is the refractive index value. Furthermore, this work presents its fundamental role in the design of films that can be used as active or passive planar waveguides for integrated optics, as well as porous platforms for optical sensors for certain molecules. Through the values of the refractive indexes, the porosity of the hosts as well as their entire densification process through annealing can be closely monitored, besides their influence on rare-earth luminescence properties. Variations in optical properties of films containing different concentrations of tantalum oxide were evaluated by the m-line coupling technique.
Figure 1 shows the refractive index values at 532 and 632.8 nm for all multilayered films based on Er3+-doped SiO2–Ta2O5 planar waveguides after 50 layers, which were obtained as a function of annealing time. Based on the information depicted in Figure 1A,B about the films with Si/Ta molar ratios of 90:10 and 80:20, respectively, a relatively sharp change of refractive index can be observed in the first 15 min of annealing at 900 °C, reducing it significantly. This behavior indicates clear elimination of water molecules, which were distributed into or on the surface of the pores, resulting in hosts with lower refractive indexes. Before further annealing, the films are composed basically of SiO2 and Ta2O5 inorganic hosts containing pores filled with H2O molecules. As the refractive index of H2O is around 1.333, and of air around 1.00, after H2O elimination, the refractive index of the films decreases since air occupies the place of these species in porous structures. In this way, it can be concluded that before subsequent thermal treatment, the films exhibit pore distribution, which can adsorb water molecules. Adsorption and desorption occur reversibly, with the exposure of the film to an atmosphere containing water molecules, followed by thermal treatment at 100 °C. This temperature value is only enough to remove adsorbed water molecules, while it is not sufficient to eliminate hydroxyl groups from the pore surface of the sol–gel silicate system neither does it lead to an increase in densification.

Figure 1

Figure 1. Refractive index values as a function of the annealing time at 900 °C of the Er3+-doped planar waveguides deposited onto the 10 μm SiO2–Si (100) p-type silicon substrate with Si/Ta ratios of (A) 90:10, (B) 80:20, (C) 70:30, (D) 60:40, and (E) 50:50.

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An increase of the refractive index values occurred, which can be assigned to the elimination of the pores and densification of the host by thermal annealing at 900 °C for more than 15 min. The densification process was considered complete until achievement of constant values of the refractive index, which depends fundamentally on the tantalum content.
In Figure 1C–E, different behaviors were observed. From the first minute of annealing, an increase of the refractive index values occurred, which is correlated to the host densification process. The required time to reach full densification decreased as the tantalum oxide is added, indicating that a more cross-linked structure is successfully formed by insertion of tantalum oxide into the silica host.
The porous molar ratio also was calculated based on the refractive index for each annealing time. The presence of pores in the film for application as a planar waveguide amplifier is undesirable because they can act as light scattering centers, in accordance with the Rayleigh scattering effect, in which the intensity of scattering follows the I = Kλ–4 relationship, where I is the intensity of the scattering, K is the proportionality constant, and λ is the wavelength of the light. Likewise, the distribution of the pores onto the surface can adsorb water molecules, which is an efficient NIR luminescence quencher center. Based on this effect, the percentage of pores in the films for each annealing time at 900 °C was evaluated by eq 1 proposed by Yoldas et al. (29)
(1)
where P is the pore volume fraction, n is the refractive index of the porous film at each annealing time, and nd is the refractive index of the film after full densification. Based on the percentage of pores calculated according to eq 1, it was possible to follow the evolution of the film densification process with the time of thermal treatment for each composition, as depicted in Figure 2. Figure 2 remarkably shows the influence of tantalum concentration on the densification process, where shorter heat treatment times are required with an increase in the amount of tantalum. The higher the tantalum concentration, the higher the densification, and the lower the annealing time required for complete pore elimination. Accordingly, it can be clearly attested that the tantalum concentration promotes a significant structural change in the silicate-derived host, allowing the preparation of a matrix with a more cross-linked structure, as observed before by us in powders of this system. (30) It is known that sol–gel silica bulks or films do not completely eliminate silanol groups after annealing at 900 °C, which is the temperature used in this work. (31) Besides, residual silanol groups have been observed by analyzing films containing 10 mol % Ta using vibrational spectroscopy, (20) which represents a problem to be circumvented for active planar waveguides for optical amplification in the near-infrared region and is advantageous to be explored as a crucial point for optical sensors for small molecules, like water molecules, in harsh environments. This is because tantalum oxide has high chemical stability in acidic and basic media.

Figure 2

Figure 2. Porosity as a function of the annealing time at 900 °C of the Er3+-doped planar waveguides deposited onto the 10 μm SiO2–Si (100) p-type silicon substrate with Si/Ta ratios of (A) 90:10, (B) 80:20, (C) 70:30, (D) 60:40, and (E) 50:50.

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Even containing residual porosity, full densification of the host containing 10 and 20 mol % Ta has been obtained after annealing at 900 °C for 400 and 200 min, respectively. On the other hand, thermal annealing at 900 °C for 9, 4, and 3 min are enough to eliminate the presence of pores in the films containing higher tantalum contents, with the Si/Ta molar ratios of 70:30, 60:40, and 50:50, respectively. Similar behavior was observed by Zampedri et al. (17) in films based on Er3+-doped SiO2–HfO2, where an increase of hafnium oxide amount in the binary SiO2–HfO2 system decreases the time needed for thermal annealing for elimination of water molecules from the pores and of hydroxyl groups from the pore surface to accomplish full densification of the planar waveguides.
The complete pore removal is extremely important for photonic materials, to be specially applied as low-loss active planar waveguides due to the reduction of scattering centers in the devices minimizing the contribution of volume scattering to the optical losses and removal of residual hydroxyl and water molecules inside the pores abolishing the luminescence quenching centers.
The refractive index, thickness, and number of propagation modes in the TE and TM polarization modes at 532, 632.8, and 1538 nm were acquired for films before and after full densification, which are summarized in Table 1.
Table 1. Optical Parameters Measured at 532, 632.8, and 1538 nm (TE and TM Modes) for the 0.3 mol % Er3+-doped SiO2–Ta2O5 Planar Waveguides before and after Full Densification at 900 °C after Different Annealing Times
 properties at 532 nmproperties at 632.8 nmproperties at 1538 nm 
 TETMTETMTETMthickness (μm)
Before Annealing
90Si–10Ta2 modes2 modes2 modes2 mode1 mode1 mode∼1.42
n = 1.5030 (±0.0001)n = 1.5023 (±0.0001)n = 1.4980 (±0.0001)n = 1.4968 (±0.0001)n = 1.4805 (±0.0001)n = 1.4802 (±0.0001)
80Si–20Ta3 modes3 modes3 modes3 modes1 mode1 mode∼1.33
n = 1.5883 (±0.0001)n = 1.5865 (±0.0001)n = 1.5805 (±0.0001)n = 1.5814 (±0.0001)n = 1.5609 (±0.0001)n = 1.5623 (±0.0001)
70Si–30Ta6 modes6 modes5 modes5 modes2 modes2 modes∼1.87
n = 1.6373 (±0.0001)n = 1.6368 (±0.0001)n = 1.6270 (±0.0001)n = 1.6270 (±0.0001)n = 1.6039 (±0.0001)n = 1.6029 (±0.0001)
60Si–40Ta6 modes6 modes5 modes5 modes2 modes2 modes∼1.87
n = 1.7201 (±0.0001)n = 1.7204 (±0.0001)n = 1.7077 (±0.0001)n = 1.7080 (±0.0001)n = 1.6799 (±0.0001)n = 1.6791 (±0.0001)
50Si–50Ta8 modes8 modes6 modes6 modes2 modes2 modes1.84
n = 1.8117 (±0.0001)n = 1.8124 (±0.0001)n = 1.7962 (±0.0001)n = 1.7968 (±0.0001)n = 1.7632.8 (±0.0001)n = 1.7624 (±0.0001)
After Different Annealing Times
90Si–10Ta2 modes2 modes2 modes2 modes1 mode1 mode∼1.35
n = 1.5260 (±0.0001)n = 1.5254 (±0.0001)n = 1.5202 (±0.0001)n = 1.5201 (±0.0001)n = 1.5035 (±0.0001)n = 1.5038 (±0.0001)
80Si–20Ta3 modes3 modes3 modes3 modes1 mode1 mode∼1.32
n = 1.6006 (±0.0001)n = 1.6024 (±0.0001)n = 1.5926 (±0.0001)n = 1.5939 (±0.0001)n = 1.5718 (±0.0001)n = 1.5734 (±0.0001)
70Si–30Ta6 modes6 modes5 modes5 modes2 modes2 modes∼1.95
n = 1.6461 (±0.0001)n = 1.6461 (±0.0001)n = 1.6358 (±0.0001)n = 1.6361 (±0.0001)n = 1.6122 (±0.0001)n = 1.6122 (±0.0001)
60Si–40Ta6 modes6 modes5 modes5 modes2 modes2 modes∼1.80
n = 1.7238 (±0.0001)n = 1.7244 (±0.0001)n = 1.7117 (±0.0001)n = 1.7122 (±0.0001)n = 1.6833 (±0.0001)n = 1.6833 (±0.0001)
50Si–50Ta8 modes8 modes7 modes7 modes3 modes3 modes∼2.00
n = 1.8133 (±0.0001)n = 1.8140 (±0.0001)n = 1.7980 (±0.0001)n = 1.7986 (±0.0001)n = 1.7632.8 (±0.0001)n = 1.7634 (±0.0001)
The refractive index, number of modes, and thickness of films increase as a function of the nominal tantalum content. In accordance with Gonçalves et al., (15,32) the refractive index of the SiO2 films prepared by the sol–gel method is around 1.4603, and in accordance with Chaneliere et. al., (33) the refractive index of Ta2O5 films is between 1.93 and 2.15, which is dependent on the synthesis method. Therefore, it is expected an increase of the refractive indexes as the tantalum oxide content is added to the silica host, corroborating with the measurements.
The theoretical refractive indexes of Ta2O5 and SiO2 used to calculate the refractive index of the binary composition material were 2.1852 and 1.4603 (at 532 nm), respectively. Lorentz–Lorenz and linear equations were used to calculate the theoretical value of the refractive index of each SiO2–Ta2O5 binary system. The Lorentz–Lorenz equation is represented in eq 2 and likewise reported by Rocha et al. (34) and Aquino et al. (35)
(2)
Eq 1 can be rearranged as follows
(3)
where A can be written as
(4)
The linear equation (eq 5) is represented as follows
(5)
where n is the refractive index, fSiO2 and fTa2O5 are the molar fractions of each component, and nSiO2 and nTa2O5 are the refractive indexes of each component.
The refractive index values of the fully densified films are in good agreement with the theoretical values obtained by the Lorentz–Lorenz equation, as can be seen in Figure 3. Figure 3 corroborates the discussion on the densification of materials and exhibits an important refractive index variation curve with the concentration of tantalum, which can be applied for the design of multi- or monomodal waveguides. Depending on the thickness of the planar waveguides, this curve will be the basis for projecting guides from the precursor solutions of alkoxides. As previously reported, the sol–gel methodology employed has the great advantage of obtaining a large range of composition, which may not be possible through other chemical processes. Moreover, it has been observed that the major problem of residual silanol groups can be overcome with Ta2O5 addition, or even with the appropriate heat treatment, without loss of optical quality.

Figure 3

Figure 3. Experimental refractive index values as a function of the tantalum amount in comparison to the theoretical refractive index values based on Lorentz–Lorenz and linear equations.

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Similarities were observed in sol–gel-prepared SiO2–Nb2O5 nanocomposite films, (21) which have also been described to exhibit refractive indexes in accordance with this model after achievement of full densification. In the literature, it has been also found a linear dependence of the refractive index on the molar fraction of the components of SiO2–Ta2O5 films prepared by rf sputtering. (36,37) The linear dependence of the refractive index values on the calculated Ta2O5 molar fraction is also plotted in Figure 3 for comparison; however, the experimental data are closer to those calculated by the Lorentz–Lorenz equation, as described before.
An increase in the concentration of tantalum also influences the thickness of the films, as observed from Table 1. Layer thickness increased with increasing tantalum content from 10 to 50 mol %, namely, from 1.3 up to 2.0 μm (Table 1). A similar effect was also observed by Aquino et al. (35) in sol–gel-prepared SiO2–Nb2O5 nanocomposite films. Gonçalves et al. (15,17) have also observed in the 70SiO2–30HfO2 films doped with 0.3, 0.5, and 1 mol % of Er3+ ions that the viscosity of the initial solution was influenced by Er3+ concentration and consequently affected the thickness of each layer during preparation of the films, resulting in different final thicknesses. The metal ions (as Er3+ or Nb5+ and Ta5+) added to the host exhibited a higher coordination number in comparison to Si2+. Adding to this fact, the high reactivity of tantalum alkoxide promotes the formation of cross-linking, with Si–O–M bonds, involving the monomers and polymers of the silicon oxide precursor in an acidic medium. Consequently, an increase of viscosity directly influences the thickness of films deposited on SiO2–Si substrates.
Furthermore, it is observed an increase of refractive index values for all films after full densification compared with the films without any further annealing at 900 °C, attesting the removal of pores and structural defects. Measurements of the refractive index profile in TE and TM modes at 532 and 632.8 nm indicated that birefringence is practically negligible, even for higher tantalum contents. Low optical losses of around 0.8–1.0 dB/cm (±0.3) at 532 and 632.8 nm in the TE mode were measured for densified films containing up to 30 mol % Ta, demonstrating the high optical and structural quality of the films, which corroborates to the elimination of pores, any cracks, smooth surfaces, and host transparency. As reported before, the pores or phase separation can act as scattering centers, increasing the optical losses. A large number of scattering centers were observed in the case of films containing 60 and 50 mol % Ta, which can be explained by the phase separation increase, which will be discussed further using high-resolution transmission electron microscopy (HRTEM). The propagation loss values observed in the films containing up to 30 mol % Ta were low enough to consider these materials suitable for optical planar waveguides in photonic applications.
Figure 4 shows the n(k) dispersion curves for the (100 – x)SiO2 – xTa2O5 planar waveguides in the TE mode. The refractive index (n) values obtained by the prism coupling technique, exhibited in Table 1, were used to construct the dispersion curves using the Cauchy equation. (35,38) Cauchy dispersion fitted properly shows a decrease in the refractive index values as a function of the wavelength in the visible and near-infrared spectral regions.

Figure 4

Figure 4. Dispersion curves of the planar waveguides based on Er3+-doped SiO2–Ta2O5 deposited onto the 10 μm SiO2–Si (100) p-type silicon substrate with Si/Ta ratios of 90:10, 80:20, 70:30, 60:40, and 50:50.

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Figure 5 depicts the squared electric field (E2) profiles for the TE0 modes of the waveguides, which were calculated at 532, 632.8, and 1538 nm using the thickness and refractive index of the film, propagation angle, and effective refractive index for the Er3+-doped SiO2–Ta2O5 films deposited onto the 10 μm SiO2–Si (100) p-type silicon substrate with Si/Ta ratios of (A) 90:10, (B) 80:20, (C) 70:30, (D) 60:40, and (E) 50:50. The confinement coefficients were calculated by the integrated intensity ratio, i.e., the ratio between the field intensity in the guiding film and the total intensity, which also includes the squared evanescent field based on the works reported by Aquino et al. (35) and Tosello et al. (39)Table 2 summarizes the confinement coefficients at 532, 632.8, and 1538 nm for TE0 (transversal electric) mode. Confinement coefficients higher than 97% were observed for most planar waveguides, except for the films containing 10 and 20 mol %, which exhibited confinement coefficients of 66 and 72% at 1538 nm, respectively. The confinement coefficient of light for the planar waveguides demonstrated efficient light injection at 1538 nm, attesting that a well-confined mode at 1538 nm was obtained for application in the C-telecom band.

Figure 5

Figure 5. Squared electric field profiles in the TE0 mode at 532, 632.8, and 1538 nm of the planar waveguides based on the Er3+-doped SiO2–Ta2O5 deposited onto 10 μm SiO2–Si (100) p-type silicon substrate with Si/Ta ratios of (A) 90:10, (B) 80:20, (C) 70:30, (D) 60:40, and (E) 50:50.

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Table 2. Percentage of the Confinement Coefficient of Light in Different Wavelengths for Planar Waveguides with Different Si/Ta Ratios
 wavelengths
planar waveguide composition (Si/Ta)532 nm632.8 nm1538 nm
90:1097.9696.7265.98
80:1099.4298.9472.06
70:3099.7799.6896.81
60:4099.8699.7797.04
50:5097.4197.1194.51
Figure 6 illustrates the FTIR spectra of the films with Si/Ta molar ratios from 10 to 50 mol % Ta deposited on Si (100) substrates. It is important to highlight here the use of films deposited directly on the silicon substrates, avoiding the thick layer of silica that would prevent the analysis of films up to 2 μm. Vibrational spectroscopy is an important technique for elucidating structural information relevant to the design of planar waveguides. As reported before by us, (20) the multilayer deposition process combined with the thermal treatment to eliminate organic and hydroxyl groups can be accompanied by the FTIR technique, which provides relevant structural information for design optical films. Thinner films were used in a previous study to monitor the film densification change with the annealing time. (20) FTIR was used as a fundamental complementary technique for refractive index measurements aiming to detect the elimination of water molecules and hydroxyl groups as the pores were closed densifying the film. Herein, thicker films of around 1.3–2.0 μm were analyzed. The thickness of the films is high enough to promote the appearance of interference fringes, which were clearly observed as a low-intensity interference fringe pattern from 4000 to near 1450 cm–1. Due to the high thickness of the films, a cutoff in the 1245–1019 cm–1 range occurred, attributed to the most intense bands assigned to silica materials, indicating SiO2 network formation. Usually, silica shows a band localized at around 1100 cm–1, assigned to asymmetric stretching of Si–O–Si, and a shoulder located in the vicinity of 1200 cm–1, which is more intense in porous materials. (35) The main focus of this work is to analyze the region below 1000 cm–1, attributing the presence of Si–O–Si, Si–OH, and Si–Ta–Si vibrational modes, as well as phase separation through vibrational modes corresponding to Ta2O5 nanocrystals.

Figure 6

Figure 6. FTIR transmission spectra of Er3+-doped SiO2–Ta2O5 deposited onto the 10 μm SiO2–Si (100) p-type silicon substrate with Si and Ta ratios of (A) 90:10, (B) 80:20, (C) 70:30, (D) 60:40, and (E) 50:50.

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In addition to the Si–O–Si vibrational modes at 460 and 800 cm–1, a band positioned at around 950 cm–1 is clearly observed, which is assigned to the Si–O–Ta or Si–OH stretching bond. As reported before, in accordance with Ferrari et al., (20) after 15 min of annealing at 900 °C, H2O was removed from the films with the lowest Ta concentrations. Here, longer annealing times were used to achieve constant values of the refractive index. Besides, the relative intensity of the absorption band at 950 cm–1 increased with the tantalum concentration, and consequently, it could be concluded that the band localized at around 950 cm–1 is assigned only to Si–O–Ta. This is evidence of the cross-linked structure with formation of a covalent bond between SiO2 and Ta2O5.
The bands localized between 855 and 588 cm–1 are assigned to the Ta2O5 phonons, in agreement with the data reported by Huang and Chu. (40) A broadband emission in this spectral region appears, which is characteristic of Ta2O5 in the orthorhombic phase. A higher Ta content and the augmented relative intensity bands at around 855–588 cm–1 indicate the presence of phase separation, which is more evident for higher tantalum oxide concentrations.
The surface morphology of films was determined by AFM analysis, and the surface morphology and roughness in the 3 × 3 μm area are shown in Figure 7. Surface roughness is considered as one of the sources of losses, involving light interaction at the air–film interface. Depending on the roughness, diffuse scattering and consequently high propagation losses can be observed. However, considering a planar waveguide with high surface quality and low roughness, the respective losses are negligible. Homogeneous and crack-free films were obtained for all the compositions. Films do not exhibit any texture under AFM inspection. The AFM images display low surface roughness, with values of about 0.4 nm (±0.1). The losses are not correlated to the tantalum content, as already seen in similar waveguides based on silica–titania, (41) silica–hafnia, (16,17,42) and silica–zirconia. (19,43) Huong et al. (44) reported that planar waveguide based on silica–zirconia–alumina-doped Er3+ shows propagation loss <2.5 dB/cm with a surface roughness of 2 nm. Here, lower values of the surface roughness were obtained, attesting the high optical quality of the films.

Figure 7

Figure 7. Two-dimensional (2D), three-dimensional (3D), and roughness profile of the Er3+- doped SiO2–Ta2O5 film after full densification at 900 °C.

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Figure 8 shows the high-resolution transmission electron microscopy (HRTEM) images of the films after full densification. The ordered regions of dark contrast, which correspond to the nucleation and crystallization of Ta2O5 nanocrystals, have size distributions, in general, below 15 nm embedded into a SiO2-based host. Nanocrystals embedded in an amorphous phase, with average sizes of around 2, 5, 7, and 8 nm for Er3+-doped planar waveguide fully densified with Si/Ta ratios of (A) 90:10, (B) 80:20, (C) 70:30, and (D) 60:40, respectively, can be observed. The dependence of Ta2O5 nanoparticle size distribution on annealing temperature is remarkable. Planar waveguides require hosts with homogeneously dispersed nanoparticles and sizes on the order of λ–4 to avoid Rayleigh scattering. Electron scattering patterns (insets of Figure 8C and D) show that the nanoparticles are crystalline. In accordance with Stephenson and Roth in 1971, (45) Ta2O5 with an orthorhombic structure and with a = 6.19800 Å, b = 40.29000 Å, c = 3.88800 Å, α = β = δ = 90°, belonging to space group P21212 in accordance with JCPDS 25-0922, can be represented by a chain of 8 edge-sharing pentagons, where each unit cell contains 22 Ta atoms and 55 O atoms, resulting at least in 12 different symmetry sites of Ta5+ ions. Consequently, this type of structure promotes the formation of numerous interstices with a volume able to accommodate several ions into its structure. Ferrari et al. (30) have reported the formation of nanocomposites based on Er3+-doped SiO2–Ta2O5 prepared by the sol–gel method, in which orthorhombic Ta2O5 nanocrystals were grown in accordance with the same crystalline structure reported by Stephenson and Roth in 1971. (45)

Figure 8

Figure 8. HRTEM micrographs of the Er3+-doped planar waveguides fully densified at 900 °C with Si/Ta ratios of (A) 90:10, (B) 80:20, (C) 70:30, and (D) 60:40.

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Figure 9 shows the excitation spectra of the Er3+-doped SiO2–Ta2O5 planar waveguides with fixed emission at 1528 nm. The excitation spectra show bands that are assigned to the intraconfigurational f–f transition of Er3+ ions. There are observed bands localized at around 378 and 521 nm assigned to 4I15/2 → 4G11/2 and 4I15/2 → 2H11/2, respectively, and a band below 325 nm with a maximum between 278 and 271 nm, in which the maximum of the band varies according to the amount Ta, can be attributed to the charge transfer between oxygen and the rare-earth metal. It is clearly seen that the intensity of the bands assigned to the f–f transitions increases as a function of the amount of Ta present in the system. It was discussed previously that the increase of nanoparticle size is dependent on the higher Ta amount, and it can be assumed the preferential distribution of Er3+ ions in a Ta2O5 crystalline environment, as reported before. (30)

Figure 9

Figure 9. Excitation spectra of the Er3+-doped SiO2–Ta2O5 planar waveguides with fixed emission at 1528 nm.

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Figure 10 shows the emission spectra of the planar waveguides in the region between 1400 and 1700 nm, when excited at 271, 274, and 278 nm for samples with Si/Ta ratio of 80:20, 70:30, and 50:50. This emission band is attributed to the 4I13/2 → 4I15/2 f–f intraconfigurational transition of the Er3+ ion. This band has an intense photoluminescence emission in the third telecommunication window region, with a FWHM between 50 and 62 nm, whose spectral bandwidth changes slightly with the content of tantalum oxide. In this work, a temperature of 900 °C was used to maintain the average size of nanoparticles, with a narrow size distribution, lower than 10 nm. Table 3 shows the FWHM values obtained in this work in comparison with other planar waveguides reported in the literature. It can be observed similar or even higher FWHM values in comparison with other waveguides reported in the literature, indicating interesting results for applications in devices that require broadband emission at 1550 nm.

Figure 10

Figure 10. Photoluminescence spectra assigned to the 4I13/2 → 4I15/2 transition of the Er3+ ions for the planar waveguides based on Er3+-doped SiO2–Ta2O5 deposited onto the 10 μm SiO2–Si (100) p-type silicon substrate with Si/Ta ratios of (A) 90:10, (B) 70:30, and (C) 50:50.

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Table 3. FWHM Values of 4I13/2 → 4I15/2 Emission around 1550 nm Assigned to the Er3+-Doped Planar Waveguides from Different Compositions
planar waveguides compositionFWHM (nm)references
SiO2–Ta2O5between 50 and 62results of this work
SiO2–Nb2O5between 48 and 52 (35)
SiO2–HfO248 (42)
SiO2–TiO2between 45 and 51 (18)
Similar compounds (powders) exhibited a broader bandwidth, which increased from 74 up to 93 nm as the tantalum oxide content increased for samples annealed at 1100 °C for 2 h. This inhomogeneous broadening is related to the presence of Er3+ ions preferentially in many different sites in the orthorhombic Ta2O5 structure. As mentioned before, orthorhombic Ta2O5 has a huge unit cell with 12 sites occupied by Ta5+ ions, so if the Er3+ ions substitute the Ta5+ ions, the observed inhomogeneous broadening in the emission spectra can be explained. The significant meaning of broad bandwidth values is related to the presence of a more flat-gain region in Er3+-doped materials for amplifiers to be combined to wavelength division multiplexing (WDM). The large optical bandwidth of the Er3+-doped SiO2–Ta2O5 waveguides prepared by the sol–gel method makes them a suitable candidate for WDM applications.

4. Conclusions

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Er3+-doped planar waveguides based on SiO2–Ta2O5 deposited onto SiO2–Si and Si (100) substrates were prepared successfully by the sol–gel process followed by the dip-coating technique. This set of techniques for preparation allowed obtaining planar waveguides with suitable optical properties for applications in optical devices. The annealing temperature, 900 °C, at different times, has been shown to be enough to promote the densification, pore elimination, and increase and control the refractive index values. The refractive index also has been shown to be dependent on the Ta concentration and annealing time. The surface of the planar waveguides displays low roughness, of around 0.245 and 0.436 nm, and contributes to low loss in waveguides by means of scattering. An average attenuation coefficient of 1 dB/cm at 514.5 and 612.8 nm was verified. Confinement of light in three wavelengths (532, 632.8, and 1538 nm) of above 65% in the planar waveguides also contributes to the reduction of optical loss of light propagation. The efficiency of confinement of light inside the planar waveguides appeared to be dependent on the amount of Ta present in the system. The excitation spectra showed characteristic bands assigned to the intraconfigurational f–f transition of Er3+ ions and a band below 300 nm assigned to the charge transfer between Er3+ and O2– ions when fixing the emission at 1538 nm. The planar waveguides showed intense emission in the region between 1440 and 1700 nm (C-telecom band) with an intensity maximum at approximately 1538 nm and a FWHM of the emission band between 50 and 60 nm. Based on the information obtained in this work, the synergism between optical, structural, surface, and photoluminescent properties brings together important characteristics that make this system a potential device for application in integrated circuits and for use in optical amplification at 1550 nm, photodectors, and devices for augmented reality.

Author Information

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  • Corresponding Author
    • Rogéria R. Gonçalves - Laboratório de Materiais Luminescentes Micro e Nanoestruturados−Mater Lumen, Departamento de Química, FFCLRP, Universidade de São Paulo, Av. Bandeirantes, 3900−Campus da Usp, Ribeirão Preto−SP, 14040-900 São Paulo, Brazil;  Orcidhttp://orcid.org/0000-0001-5540-7690;  Email: [email protected]
  • Authors
    • Jefferson L. Ferrari - Laboratório de Materiais Luminescentes Micro e Nanoestruturados−Mater Lumen, Departamento de Química, FFCLRP, Universidade de São Paulo, Av. Bandeirantes, 3900−Campus da Usp, Ribeirão Preto−SP, 14040-900 São Paulo, Brazil;  Desenvolvimento de Materiais Inorgânicos com Terras Raras−DeMITeR, Laboratório de Materiais Fotoluminescentes (LAMAF), Instituto de Química−(IQ), Universidade Federal de Uberlândia−(UFU), Av. João Naves de Ávila, 2121−Bairro Santa Mônica, CEP, 38400-902 Uberlândia, Minas Gerais, Brazil
    • Karmel de O. Lima - Laboratório de Materiais Luminescentes Micro e Nanoestruturados−Mater Lumen, Departamento de Química, FFCLRP, Universidade de São Paulo, Av. Bandeirantes, 3900−Campus da Usp, Ribeirão Preto−SP, 14040-900 São Paulo, Brazil
  • Notes
    The authors declare no competing financial interest.

Acknowledgments

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The authors thank FAPESP (2020/05319-9, 2018/18213-4), CNPq, and CAPES. This work has been supported by the Brazilian Synchrotron Light Laboratory (LNLS) under proposal TEM-HR 7952. This study was financed in part by the Coordenação de Aperfeiçoamento de Pessoal de Nível Superior—Brasil (CAPES)—Finance Code 001.

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    Laming, R. I.; Farries, M. C.; Morkel, P. R.; Reekie, L.; Payne, D. N.; Scrivener, P. L.; Fontana, F.; Righetti, A. Efficient Pump Wavelengths of Erbium-Doped Fibre Optical Amplifier. Electron. Lett. 1989, 25, 12– 14,  DOI: 10.1049/el:19890009
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    Righini, G. C.; Berneschi, S.; Nunzi Conti, G.; Pelli, S.; Moser, E.; Retoux, R.; Féron, P.; Gonçalves, R. R.; Speranza, G.; Jestin, Y.; Ferrari, M.; Chiasera, A.; Chiappini, A.; Armellini, C. Er3+-Doped Silica-Hafnia Films for Optical Waveguides and Spherical Resonators. J. Non-Cryst. Solids 2009, 355, 1853– 1860,  DOI: 10.1016/j.jnoncrysol.2008.12.022
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    Er3+-doped silica-hafnia films for optical waveguides and spherical resonators
    Righini, G. C.; Berneschi, S.; Nunzi Conti, G.; Pelli, S.; Moser, E.; Retoux, R.; Feron, P.; Goncalves, R. R.; Speranza, G.; Jestin, Y.; Ferrari, M.; Chiasera, A.; Chiappini, A.; Armellini, C.
    Journal of Non-Crystalline Solids (2009), 355 (37-42), 1853-1860CODEN: JNCSBJ; ISSN:0022-3093. (Elsevier B.V.)
    The authors present some result on sol-gel derived SiO2-hafnia systems. In particular the authors focus on fabrication, morphol. and spectroscopic assessment of Er3+-activated thin films. Two examples of SiO2-hafnia-derived waveguiding glass ceramics, prepd. by top-down and bottom-up techniques are reported, and the main optical properties are discussed. Finally, some properties of activated microspherical resonators, having a SiO2 core, obtained by melting the end of a telecom fiber, coated with an Er3+-doped 70SiO2-30HfO2 film, are presented.
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  15. 15
    Gonçalves, R. R.; Carturan, G.; Zampedri, L.; Ferrari, M.; Montagna, M.; Chiasera, A.; Righini, G. C.; Pelli, S.; Ribeiro, S. J. L.; Messaddeq, Y. Sol-Gel Er-Doped SiO2-HfO2 Planar Waveguides: A Viable System for 1.5 Mm Application. Appl. Phys. Lett. 2002, 81, 28– 30,  DOI: 10.1063/1.1489477
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    15
    Sol-gel Er-doped SiO2-HfO2 planar waveguides: A viable system for 1.5 μm application
    Goncalves, R. R.; Carturan, G.; Zampedri, L.; Ferrari, M.; Montagna, M.; Chiasera, A.; Righini, G. C.; Pelli, S.; Ribeiro, S. J. L.; Messaddeq, Y.
    Applied Physics Letters (2002), 81 (1), 28-30CODEN: APPLAB; ISSN:0003-6951. (American Institute of Physics)
    70SiO2-30HfO2 planar waveguides, doped with Er3+ concns. ranging from 0.3 to 1 mol.%, were prepd. by sol-gel route, using dip-coating deposition on silica glass substrates. The waveguides show high densification degree, effective intermingling of the two components of the film, and uniform surface morphol. Propagation losses of about 1 dB/cm were measured at 632.8 nm. When pumped with 987 or 514.5 nm continuous-wave laser light, the waveguides show the 4I13/2 4I15/2 emission band with a bandwidth of 48 nm. The spectral features are found independent both on erbium content and excitation wavelength. The 4I13/2 level decay curves presented a single-exponential profile, with a lifetime between 2.9 and 5.0 ms, depending on the erbium concn.
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  16. 16
    Gonçalves, R. R.; Carturan, G.; Zampedri, L.; Ferrari, M.; Chiasera, A.; Montagna, M.; Righini, G. C.; Pelli, S.; Ribeiro, S. J. L.; Messaddeq, Y. Infrared-to-Visible CW Frequency Upconversion in Erbium Activated Silica-Hafnia Waveguides Prepared by Sol-Gel Route. J. Non-Cryst. Solids 2003, 322, 306– 310,  DOI: 10.1016/S0022-3093(03)00220-5
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    16
    Infrared-to-visible CW frequency upconversion in erbium activated silica-hafnia waveguides prepared by sol-gel route
    Goncalves, Rogeria R.; Carturan, Giovanni; Zampedri, Luca; Ferrari, Maurizio; Chiasera, Alessandro; Montagna, Maurizio; Righini, Giancarlo C.; Pelli, Stefano; Ribeiro, Sidney J. L.; Messaddeq, Younes
    Journal of Non-Crystalline Solids (2003), 322 (1-3), 306-310CODEN: JNCSBJ; ISSN:0022-3093. (Elsevier Science B.V.)
    70SiO2-30HfO2 mol% planar waveguides, doped with Er3+ with concns. ranging from 0.3 to 2 mol% were prepd. by sol-gel route, using dip-coating deposition on vitreous-SiO2 substrates. IR-to-visible upconversion emission, upon excitation at 980 nm, was obsd. for all the samples. The upconversion results in green, red and blue emissions. The study of the upconversion dynamic as a function of the Er3+ concn. and excitation power, show that processes such as excited state absorption and energy transfer upconversion are effective.
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  17. 17
    Gonçalves, R. R.; Carturan, G.; Montagna, M.; Ferrari, M.; Zampedri, L.; Pelli, S.; Righini, G. C.; Ribeiro, S. J. L.; Messaddeq, Y. Erbium-Activated HfO2-Based Waveguides for Photonics. Opt. Mater. 2004, 25, 131– 139,  DOI: 10.1016/S0925-3467(03)00261-1
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    Erbium-activated HfO2-based waveguides for photonics
    Goncalves, Rogeria R.; Carturan, Giovanni; Montagna, Maurizio; Ferrari, Maurizio; Zampedri, Luca; Pelli, Stefano; Righini, Giancarlo C.; Ribeiro, Sidney J. L.; Messaddeq, Younes
    Optical Materials (Amsterdam, Netherlands) (2004), 25 (2), 131-139CODEN: OMATET; ISSN:0925-3467. (Elsevier Science B.V.)
    SiO2-based sol-gel waveguides activated by Er3+ ions are attractive materials for integrated optic devices. 70SiO2-30HfO2 planar waveguides, doped with Er3+ concns. ranging from 0.01 to 4 mol%, were prepd. by sol-gel route. The films were deposited on v-SiO2 and SiO2-on-Si substrates, using dip-coating technique. The waveguides show a homogeneous surface morphol., high densification degree and uniform refractive index across the thickness. Emission in the C-telecommunication band was obsd. at room temp. for all the samples upon excitation at 980 nm. The shape is almost independent on Er content, with a FWHM between 44 and 48 nm. The 4I13/2 level decay curves presented a single-exponential profile, with a lifetime ranging between 1.1 and 6.7 ms, depending on the Er concn. The waveguide deposited on SiO2-on-Si substrate supports one single propagation mode at 1.5 μm with a confinement coeff. of 0.85, and a losses of ∼0.8 dB/cm at 632.8 nm.
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  18. 18
    Zampedri, L.; Ferrari, M.; Armellini, C.; Visintainer, F.; Tosello, C.; Ronchin, S.; Rolli, R.; Montagna, M.; Chiasera, A.; Pelli, S.; Righini, G. C.; Monteil, A.; Duverger, C.; Gonçalves, R. R. Erbium-Activated Silica-Titania Planar Waveguides. J. Sol-Gel Sci. Technol. 2003, 26, 1033– 1036,  DOI: 10.1023/A:1020734018629
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    Erbium-Activated Silica-Titania Planar Waveguides
    Zampedri, L.; Ferrari, M.; Armellini, C.; Visintainer, F.; Tosello, C.; Ronchin, S.; Rolli, R.; Montagna, M.; Chiasera, A.; Pelli, S.; Righini, G. C.; Monteil, A.; Duverger, C.; Goncalves, R. R.
    Journal of Sol-Gel Science and Technology (2003), 26 (1/2/3), 1033-1036CODEN: JSGTEC; ISSN:0928-0707. (Kluwer Academic Publishers)
    (100 - X)SiO2-(x)TiO2-ErO3/2 planar waveguides, with 7 ≤ x ≤ 20 were prepd. by sol-gel route using the dip-coating technique. The thickness of the films was optimized to support a single propagating mode at 1550 nm, with a confinement coeff. >0.75. The process of densification of the gel and the devitrification with the growth of TiO2 nanocrystals were studied by Raman scattering. Devitrification is important only for x ≥ 15, but it was not possible to obtain full densification of the samples, even at the lowest TiO2 content, without the appearance of nanocrystals. Emission in the C telecom band was obsd.; the spectral width of the 4I13/2 4I15/2 transition of Er3+ slightly increases with the TiO2 content. For x ≤ 12 most of Er3+ ions (∼65%) decay exponentially with a lifetime of ∼8 ms.
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  19. 19
    Gonçalves, R. R.; Guimarães, J. J.; Ferrari, J. L.; Maia, L. J. Q.; Ribeiro, S. J. L. Active Planar Waveguides Based on Sol-Gel Er3+-Doped SiO2-ZrO2 for Photonic Applications: Morphological, Structural and Optical Properties. J. Non-Cryst. Solids 2008, 354, 4846– 4851,  DOI: 10.1016/j.jnoncrysol.2008.05.055
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    Active planar waveguides based on sol-gel Er3+-doped SiO2-ZrO2 for photonic applications: Morphological, structural and optical properties
    Goncalves, R. R.; Guimaraes, J. J.; Ferrari, J. L.; Maia, L. J. Q.; Ribeiro, S. J. L.
    Journal of Non-Crystalline Solids (2008), 354 (42-44), 4846-4851CODEN: JNCSBJ; ISSN:0022-3093. (Elsevier B.V.)
    Er3+-doped glass-ceramic SiO2-ZrO2 optical planar waveguides were prepd. by the sol-gel route using different SiO2:ZrO2 molar ratios (90:10, 85:15, 80:20, and 75:25). Multilayered films were deposited onto Si(1 0 0) substrates by the dip-coating technique. Structural characterization was performed using vibrational spectroscopy and x-ray diffraction. Some optical properties, densification and surface morphol. of these films were studied as a function of the SiO2:ZrO2 ratio, annealing temp. and time. Optical properties such as refractive index, no. of propagating modes and attenuation coeff. were measured at 632.8, 543.5, and 1550 nm, by the prism coupling technique. Uniform surface morphol. with roughness <0.5 nm. Low losses, <0.9 dB/cm at 612.8 nm in the TE0 mode, were measured for the planar waveguides contg. up to 25 mol.% Zr oxide. Luminescence of Er3+ in the near IR was obsd. for the active nanocomposite.
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  20. 20
    Ferrari, J. L.; Lima, K. O.; Maia, L. J. Q.; Gonçalves, R. R. Sol-Gel Preparation of near-Infrared Broadband Emitting Er 3+-Doped SiO2-Ta2O5 Nanocomposite Films. Thin Solid Films 2010, 519, 1319– 1324,  DOI: 10.1016/j.tsf.2010.09.035
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    Aquino, F. T.; Caixeta, F. J.; de Oliveira Lima, K.; Kochanowicz, M.; Dorosz, D.; Gonçalves, R. R. Broadband NIR Emission from Rare Earth Doped-SiO2-Nb2O5 and SiO2-Ta2O5 Nanocomposites. J. Lumin. 2018, 199, 138– 142,  DOI: 10.1016/j.jlumin.2018.03.018
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    Broadband NIR emission from rare earth doped-SiO2-Nb2O5 and SiO2-Ta2O5 nanocomposites
    Aquino, Felipe Thomaz; Caixeta, Fabio Jose; Lima, Karmel de Oliveira; Kochanowicz, Marcin; Dorosz, Dominik; Goncalves, Rogeria Rocha
    Journal of Luminescence (2018), 199 (), 138-142CODEN: JLUMA8; ISSN:0022-2313. (Elsevier B.V.)
    The rising demand for more efficient telecommunication networks that can carry larger data vol. is currently one of the most pressing technol. challenges. In this sense, developing new materials to obtain NIR broadband emission is an urgent matter. We have successfully prepd. Tm3+/Yb3+ co-doped 70SiO2-30Nb2O5 and 70SiO2-30Ta2O5 (mol%) nanocomposites by the sol-gel method. The Tm3+/Yb3+ co-doped 70SiO2-30Nb2O5 and 70SiO2-30Ta2O5 nanocomposites displayed intense broad emission that extends from 1.6 to 2.1μm, with max. at 1.8μm. The bandwidth values lied around 230 or 260nm depending on the cryst. phase. Increasing rare earth content elicited discrete quenching, which attests to good rare earth soly. and distribution within the hosts. The luminescence results are outstanding in terms of silicate hosts and point to the potential application of these materials in optical amplifiers, remote sensing, and LIDAR systems.
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  22. 22
    Aquino, F. T.; Pereira, R. R.; Ferrari, J. L.; Ribeiro, S. J. L.; Ferrier, A.; Goldner, P.; Gonçalves, R. R. Unusual Broadening of the NIR Luminescence of Er3+-Doped Nb 2O5 Nanocrystals Embedded in Silica Host: Preparation and Their Structural and Spectroscopic Study for Photonics Applications. Mater. Chem. Phys. 2014, 147, 751– 760,  DOI: 10.1016/j.matchemphys.2014.06.016
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    22
    Unusual broadening of the NIR luminescence of Er3+-doped Nb2O5 nanocrystals embedded in silica host: Preparation and their structural and spectroscopic study for photonics applications
    Aquino, Felipe Thomaz; Pereira, Rafael R.; Ferrari, Jefferson Luis; Ribeiro, Sidney Jose Lima; Ferrier, Alban; Goldner, Philippe; Goncalves, Rogeria Rocha
    Materials Chemistry and Physics (2014), 147 (3), 751-760CODEN: MCHPDR; ISSN:0254-0584. (Elsevier B.V.)
    This paper reports on the prepn. of novel sol-gel Er-doped SiO2-based nanocomposites embedded with Nb2O5 nanocrystals fabricated using a bottom-up method and describes their structural, morphol., and luminescence characterization. To prep. the glass ceramics, the authors synthesized xerogels contg. Si/Nb molar ratios of 90:10 up to 50:50 at room temp., followed by annealing at 900, 1000, or 1100° for 10 h. The authors identified crystn. accompanying host densification in all the nanocomposites with orthorhombic (T-phase) or monoclinic (M-phase) Nb2O5 nanocrystals dispersed in the amorphous SiO2 phase, depending on the Nb content and annealing temp. A high-intensity broadband emission in the near-IR region assigned to the 4I13/2 → 4I15/2 transition of the Er3+ ions was registered for all the nanocomposites. The shape and the bandwidth changed with the Nb2O5 cryst. phase, with values achieving up to 81 nm. Er3+ ions were located mainly in Nb2O5-rich regions, and the complex structure of the different Nb2O5 polymorphs accounted for the broadening in the emission spectra. The materials contg. the T-phase, displayed higher luminescence intensity, longer 4I13/2 lifetime and broader bandwidth. In conclusion, these nanostructured materials are potential candidates for photonic applications like optical amplifiers and WDM devices operating in the S, C, and L telecommunication bands.
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    Ferrari, J. L.; Lima, K. O.; Maia, L. J. Q.; Ribeiro, S. J. L.; Gomes, A. S. L.; Gonçalves, R. R. Broadband NIR Emission in Sol-Gel Er 3-Activated SiO 2-Ta 2O 5 Glass Ceramic Planar and Channel Waveguides for Optical Application. J. Nanosci. Nanotechnol. 2011, 11, 2540– 2544,  DOI: 10.1166/jnn.2011.3565
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    23
    Broadband NIR emission in sol-gel Er3+-activated SiO2-Ta2O5 glass ceramic planar and channel waveguides for optical application
    Ferrari, J. L.; Lima, K. O.; Maia, L. J. Q.; Ribeiro, S. J. L.; Gomes, A. S. L.; Goncalves, R. R.
    Journal of Nanoscience and Nanotechnology (2011), 11 (3), 2540-2544CODEN: JNNOAR; ISSN:1533-4880. (American Scientific Publishers)
    An Er3+-doped SiO2:Ta2O5 optical channel waveguide and nanocomposite were prepd. by the sol-gel route at a Si:Ta 50:50 molar ratio. Channels with an excellent surface profile were easily and quickly fabricated by focusing a femtosecond laser onto the surface of multilayered films deposited on SiO2/Si substrates. In parallel, the same sol used to prep. the film was annealed at 900, 1000, and 1100 °C for 2 h, to get the nanocomposite materials. A broadband NIR emission around 1538 nm, assigned to the 4I13/2 → 4I15/2 transition of the Er3+ ions was obsd. in the nanocomposites of amorphous SiO2 contg. dispersed Ta2O5 nanocrystals. The 4I13/2 lifetime and emission bandwidth depend on the annealing temp. In conclusion, Er3+-doped SiO2:Ta2O5 channel waveguides and nanocomposites are promising materials for photonic applications.
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    Zha, J.; Roggendorf, H. Sol-Gel Science, the Physics and Chemistry of Sol-Gel Processing, Ed. by C. J. Brinker and G. W. Scherer, Academic Press, Boston 1990, Xiv, 908 Pp., Bound?ISBN 0-12-134970-5. Adv. Mater. 1991, 3, 522,  DOI: 10.1002/adma.19910031025
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    Jung-Chieh Su, H.-C.; Chien-Kang Kao, H.-T. I.-N.; Lin, H.-C. C.-H. T.; Chi, H.-C. C.-C.; Hsin-Chu; ; Yung-Sheng Liu, H.-C. Manufacturing Process for Preparing Sol-Gel Optical Waveguides. U.S. Patent US6.391,515B12002.
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    Ferrari, J. L.; Lima, K. O.; Maia, L. J. Q.; Gonçalves, R. R. Sol-Gel Preparation of near-Infrared Broadband Emitting Er3+-Doped SiO2-Ta2O5 Nanocomposite Films. Thin Solid Films 2010, 519, 1319– 1324,  DOI: 10.1016/j.tsf.2010.09.035
    Google Scholar
    There is no corresponding record for this reference.
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    Ferrari, J. L.; Lima, K. O.; Maia, L. J. Q.; Ribeiro, S. J. L.; Gonaçalves, R. R. Structural and Spectroscopic Properties of Luminescent Er 3+-Doped SiO2-Ta2O5 Nanocomposites. J. Am. Ceram. Soc. 2011, 94, 1230– 1237,  DOI: 10.1111/j.1551-2916.2010.04191.x
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    27
    Structural and spectroscopic properties of luminescent Er3+-doped SiO2-Ta2O5 nanocomposites
    Ferrari, Jefferson L.; Lima, Karmel O.; Maia, Lauro J. Q.; Ribeiro, Sidney J. L.; Goncalves, Rogeria R.
    Journal of the American Ceramic Society (2011), 94 (4), 1230-1237CODEN: JACTAW; ISSN:0002-7820. (Wiley-Blackwell)
    This paper reports on the prepn. and structural, morphol., and luminescence properties of Er3+-doped nanocomposites based on SiO2-Ta2O5 prepd. by the sol-gel method. The influence of the tantalum oxide content on the structural and spectroscopic properties was analyzed for Si/Ta molar ratios of 90:10, 80:20, 70:30, 60:40, and 50:50. The sols were kept at 60°C for formation of the xerogel, followed by annealing at 900°, 1000°, and 1100°C for 2 h for prodn. of the nanocomposites. The densification, phase sepn., and crystn. processes were monitored through vibrational spectroscopy (FTIR), X-ray diffraction, and high-resoln. TEM. Er3+ emission in the IR region, assigned to the 4I13/2→4I15/2 transition, was obsd. for all the nanocomposites. Evolution from a vitreous-like environment to a cryst. one was identified upon increasing the annealing temp. and tantalum content. According to the results obtained, the Er3+ ions are preferentially localized close to the region rich in Ta2O5 nanoparticles. The localization of Er3+ ions was shown to be dependent on the amt. of tantalum. Moreover, the fact that the Er3+ ions are located close to Ta2O5 nanoparticles promotes a broadband emission with full-width at half-max. of 90 nm at ∼1550 nm.
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  28. 28
    Ferrari, J. L.; Lima, K. O.; Maia, L. J. Q.; Ribeiro, S. J. L.; Gomes, A. S. L.; Gonçalves, R. R. Broadband NIR Emission in Sol-Gel Er3+-Activated SiO2-Ta2O5 Glass Ceramic Planar and Channel Waveguides for Optical Application. J. Nanosci. Nanotechnol. 2011, 11, 2540– 2544,  DOI: 10.1166/jnn.2011.3565
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    28
    Broadband NIR emission in sol-gel Er3+-activated SiO2-Ta2O5 glass ceramic planar and channel waveguides for optical application
    Ferrari, J. L.; Lima, K. O.; Maia, L. J. Q.; Ribeiro, S. J. L.; Gomes, A. S. L.; Goncalves, R. R.
    Journal of Nanoscience and Nanotechnology (2011), 11 (3), 2540-2544CODEN: JNNOAR; ISSN:1533-4880. (American Scientific Publishers)
    An Er3+-doped SiO2:Ta2O5 optical channel waveguide and nanocomposite were prepd. by the sol-gel route at a Si:Ta 50:50 molar ratio. Channels with an excellent surface profile were easily and quickly fabricated by focusing a femtosecond laser onto the surface of multilayered films deposited on SiO2/Si substrates. In parallel, the same sol used to prep. the film was annealed at 900, 1000, and 1100 °C for 2 h, to get the nanocomposite materials. A broadband NIR emission around 1538 nm, assigned to the 4I13/2 → 4I15/2 transition of the Er3+ ions was obsd. in the nanocomposites of amorphous SiO2 contg. dispersed Ta2O5 nanocrystals. The 4I13/2 lifetime and emission bandwidth depend on the annealing temp. In conclusion, Er3+-doped SiO2:Ta2O5 channel waveguides and nanocomposites are promising materials for photonic applications.
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    Yoldas, B. E. Investigations of Porous Oxides as an Antireflective Coating for Glass Surfaces. Appl. Opt. 1980, 19, 1425,  DOI: 10.1364/AO.19.001425
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    Investigations of porous oxides as an antireflective coating for glass surfaces
    Yoldas, Bulent E.
    Applied Optics (1980), 19 (9), 1425-9CODEN: APOPAI; ISSN:0003-6935.
    Possible applications of porous oxide films as an antireflective coating were investigated. A porous aluminum oxide film is deposited on glass surfaces from a clear organometallic derived sol. The index of the oxide coating is reduced by the presence of pores whose size is <100 Å; this constitutes up to 64% porosity. These pores, being considerably smaller than the wavelength of light, do not interfere with the optical transparency of the material but reduce the index of refraction; thus they make it possible to obtain transparent oxide materials and coatings with very low index.
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    Ferrari, J. L.; Lima, K. O.; Maia, L. J. Q.; Ribeiro, S. J. L.; Goncalves, R. R. Structural and Spectroscopic Properties of Luminescent Er3+-Doped SiO2-Ta2O5 Nanocomposites. J. Am. Ceram. Soc. 2011, 94, 1230– 1237,  DOI: 10.1111/j.1551-2916.2010.04191.x
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    30
    Structural and spectroscopic properties of luminescent Er3+-doped SiO2-Ta2O5 nanocomposites
    Ferrari, Jefferson L.; Lima, Karmel O.; Maia, Lauro J. Q.; Ribeiro, Sidney J. L.; Goncalves, Rogeria R.
    Journal of the American Ceramic Society (2011), 94 (4), 1230-1237CODEN: JACTAW; ISSN:0002-7820. (Wiley-Blackwell)
    This paper reports on the prepn. and structural, morphol., and luminescence properties of Er3+-doped nanocomposites based on SiO2-Ta2O5 prepd. by the sol-gel method. The influence of the tantalum oxide content on the structural and spectroscopic properties was analyzed for Si/Ta molar ratios of 90:10, 80:20, 70:30, 60:40, and 50:50. The sols were kept at 60°C for formation of the xerogel, followed by annealing at 900°, 1000°, and 1100°C for 2 h for prodn. of the nanocomposites. The densification, phase sepn., and crystn. processes were monitored through vibrational spectroscopy (FTIR), X-ray diffraction, and high-resoln. TEM. Er3+ emission in the IR region, assigned to the 4I13/2→4I15/2 transition, was obsd. for all the nanocomposites. Evolution from a vitreous-like environment to a cryst. one was identified upon increasing the annealing temp. and tantalum content. According to the results obtained, the Er3+ ions are preferentially localized close to the region rich in Ta2O5 nanoparticles. The localization of Er3+ ions was shown to be dependent on the amt. of tantalum. Moreover, the fact that the Er3+ ions are located close to Ta2O5 nanoparticles promotes a broadband emission with full-width at half-max. of 90 nm at ∼1550 nm.
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  31. 31
    Montagna, M.; Chiasera, A.; Moser, E.; Visintainer, F.; Ferrari, M.; Zampedri, L.; Gonçalves, R. R.; Ribeiro, S. J. L.; Martucci, A.; Guglielmi, M.; Ivanda, M.; Almeida, R. M. Nucleation and Crystallization of Titania Nanoparticles in Silica Titania Planar Waveguides: A Study by Low Frequency Raman Scattering. Mater. Sci. Forum 2004, 455–456, 520– 526,  DOI: 10.4028/www.scientific.net/msf.455-456.520
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    Nucleation and crystallization of titania nanoparticles in silica titania planar waveguides: a study by low frequency Raman scattering
    Montagna, M.; Chiasera, A.; Moser, E.; Visintainer, F.; Ferrari, M.; Zampedri, L.; Goncalves, R. R.; Ribeiro, S. J. L.; Martucci, A.; Guglielmi, M.; Ivanda, M.; Almeida, R. M.
    Materials Science Forum (2004), 455-456 (), 520-526CODEN: MSFOEP; ISSN:0255-5476. (Trans Tech Publications Ltd.)
    SiO2(1-x)-TiO2(x) waveguides, with the mole fraction x in the range 0.07-0.20 and thickness of about 0.4 μm, were deposited on silica substrates by a dip-coating technique. The thermal treatments at 700-900°C, used to fully densify the xerogels, produce nucleation of TiO2 nanocrystals even for the lowest TiO2 content. The nucleation of TiO2 nanocrystals and their growth by thermal annealing up to 1300°C were studied by waveguide Raman spectroscopy, for the SiO2(0.8)-TiO2(0.2) compn. By increasing the annealing temp., the Raman spectrum evolves from that typical of the silica-titania glass to that of anatase, but brookite phase is dominant at intermediate temps. In the low-frequency region (5-50 cm-1) of the Raman spectra, acoustic vibrations of the nanocrystals are obsd. From the measured line shapes, we can deduce the size distribution of the particles. The results are compared with those obtained from the line widths in the X-ray diffraction patterns. Nanocrystals with a mean size in the range 4-20 nm are obtained by thermal annealing in a corresponding range of 800-1300°C.
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    Zampedri, L.; Mattarelli, M.; Montagna, M.; Gonçalves, R. R. Evaluation of Local Field Effect on the I 13 2 4 Lifetimes in Er-Doped Silica-Hafnia Planar Waveguides. Phys. Rev. B 2007, 75, 073105  DOI: 10.1103/PhysRevB.75.073105
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    Evaluation of local field effect on the 4I13/2 lifetimes in Er-doped silica-hafnia planar waveguides
    Zampedri, L.; Mattarelli, M.; Montagna, M.; Goncalves, R. R.
    Physical Review B: Condensed Matter and Materials Physics (2007), 75 (7), 073105/1-073105/4CODEN: PRBMDO; ISSN:1098-0121. (American Physical Society)
    (100-X) SiO2-xHfO2 planar waveguides (10<x<45) doped with 0.01 mol % Er3+ were prepd. by a sol-gel route. The lifetime of the 4I13/2 level and the refractive index of the waveguides were measured. The magnetic dipole and elec. dipole rates of the 4I13/2→ 4I15/2 transition were estd. as a function of the refractive index. The elec. dipole transition rates were well reproduced by the real cavity model.
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    Chaneliere, C.; Autran, J. L.; Devine, R. A. B.; Balland, B. Tantalum Pentoxide (Ta2O5) Thin Films for Advanced Dielectric Applications. Mater. Sci. Eng., R 1998, 22, 269– 322,  DOI: 10.1016/S0927-796X(97)00023-5
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    Tantalum pentoxide (Ta2O5) thin films for advanced dielectric applications
    Chaneliere, C.; Autran, J. L.; Devine, R. A. B.; Balland, B.
    Materials Science & Engineering, R: Reports (1998), R22 (6), 269-322 pp.CODEN: MIGIEA; ISSN:0927-796X. (Elsevier Science S.A.)
    A review with 324 refs. on the present knowledge on Ta2O5 thin films and their applications in the field of microelectronics and integrated microtechnologies. Different methods used to produce Ta2O5 layers are described, emphasizing elaboration mechanisms and key parameters for each technique. We also review recent advances in the deposition of Ta2O5 in the particular field of microelectronics where high quality layers are required from the structural and elec. points of view. The phys., structural, optical, chem. and elec. properties of Ta2O5 thin films on semiconductors are then presented and essential film parameters, such as optical index, film d. or dielec. permittivity, are discussed. After a reminder of the basic mechanisms that control the bulk elec. conduction in insulating films, we carefully examine the origin of leakage currents in Ta2O5 and present the state-of-the-art concerning the insulating behavior of Ta2O5 layers. Finally, applications of Ta2O5 thin films are presented in the last part of this paper. We show how Ta2O5 was employed as an antireflection coating, insulating layer, gate oxide, corrosion-resistant material, and sensitive layer in a wide variety of components, circuits, and sensors.
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    Rocha, L. A.; Schiavon, M. A.; Ribeiro, S. J. L.; Gonçalves, R. R.; Ferrari, J. L. Eu3+-Doped SiO2–Gd2O3 Prepared by the Sol–Gel Process: Structural and Optical Properties. J. Sol-Gel Sci. Technol. 2015, 76, 260– 270,  DOI: 10.1007/s10971-015-3773-6
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    Eu3+-doped SiO2-Gd2O3 prepared by the sol-gel process: structural and optical properties
    Rocha, Leonardo Alves; Schiavon, Marco Antonio; Ribeiro, Sidney Jose L.; Goncalves, Rogeria Rocha; Ferrari, Jefferson Luis
    Journal of Sol-Gel Science and Technology (2015), 76 (2), 260-270CODEN: JSGTEC; ISSN:0928-0707. (Springer)
    Abstr.: Eu3+-doped SiO2-Gd2O3 materials were prepd. by the sol-gel process changing the Si4+:Gd3+ molar ratio of 100:0, 70:30, 50:50, 30:70 and 0:100 mol%. The amt. of Eu3+ was fixed at 0.2 mol% in relation to the total no. of moles of [Si4+ + Gd3+] in the systems. The xerogels obtained from sols were heat-treated at 900, 1000 and 1100 °C for 8 h. By TGA/DTA, XRD and Raman spectroscopy anal., the formation of Gd2O3 cryst. was detected. The microstrains and crystallite size were calcd. by the Williamson-Hall and Scherrer's equation, resp. The results showed the direct dependence of microstrain and crystallite size as a function of the heat-treatment temp. By the FTIR anal. was obsd. the elimination of species like H2O, O-H and C-H groups, which can act as photoluminescence quenchers. All materials obtained in this work showed intense photoluminescence emission in the red region due to the 5D0 → 7F2 transition of Eu3+. The emission can be obsd. through the naked eye. The excited state lifetime shows to be dependent on values of refractive index and heat-treatment temps. The microstrain values affected the lifetime values and consequently the photoluminescence properties. In summary, the materials obtained in this work showed great absorption in the UV region promoting intense emission in the visible region, making them potential candidates for future applications in devices such as solar cells, image generator, biomarkers, among others. Graphical Abstr.: [Figure not available: see fulltext.].
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    Aquino, F. T.; Ferrari, J. L.; Ribeiro, S. J. L.; Ferrier, A.; Goldner, P.; Gonçalves, R. R. Broadband NIR Emission in Novel Sol-Gel Er3+-Doped SiO 2-Nb2O5 Glass Ceramic Planar Waveguides for Photonic Applications. Opt. Mater. 2013, 35, 387– 396,  DOI: 10.1016/j.optmat.2012.09.029
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    Broadband NIR emission in novel sol-gel Er3+-doped SiO2-Nb2O5 glass ceramic planar waveguides for photonic applications
    Aquino, Felipe Thomaz; Ferrari, Jefferson Luis; Ribeiro, Sidney Jose Lima; Ferrier, Alban; Goldner, Philippe; Goncalves, Rogeria Rocha
    Optical Materials (Amsterdam, Netherlands) (2013), 35 (3), 387-396CODEN: OMATET; ISSN:0925-3467. (Elsevier B.V.)
    This paper reports on the sol-gel prepn. and structural and optical characterization of new Er3+-doped SiO2-Nb2O5 nanocomposite planar waveguides. Erbium-doped (100-x)SiO2-xNb2O5 waveguides were deposited on silica-on-silicon substrates and Si(1 0 0) by the dip-coating technique. The waveguides exhibited uniform refractive index distribution across the thickness, efficient light injection at 1538 nm, and low losses at 632 and 1538 nm. The band-gap values lied between 4.12 eV and 3.55 eV for W1-W5, resp., showing an excellent transparency in the visible and near IR region for the waveguides. Fourier Transform IR (FTIR) Spectroscopy anal. evidenced SiO2-Nb2O5 nanocomposite formation with controlled phase sepn. in the films. The HRTEM and XRD analyses revealed Nb2O5 orthorhombic T-phase nanocrystals dispersed in a silica-based host. Photoluminescence (PL) anal. showed a broad band emission at 1531 nm, assigned to the 4I13/2 → 4I15/2 transition of the Er3+ ions present in the nanocomposite, with a full-width at half medium of 48-68 nm, depending on the niobium content and annealing. Hence, these waveguides are excellent candidates for application in integrated optics, esp. in EDWA and WDM devices.
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    Cevro, M. Ion-Beam Sputtering of (Ta2O5)x- (SiO2)1-x Composite Thin Films. Thin Solid Films 1995, 258, 91– 103,  DOI: 10.1016/0040-6090(94)06356-7
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    Ion-beam sputtering of (Ta2O5)x-(SiO2)1-x composite thin films
    Cevro, M.
    Thin Solid Films (1995), 258 (1-2), 91-103CODEN: THSFAP; ISSN:0040-6090. (Elsevier)
    Composite (Ta2O5)x-(SiO2)1-x thin films were deposited by ion-beam sputtering using a single ion-beam gun. The compn. of the composite films was adjusted by simple movement of the superposed tantalum and silicon targets. Optical properties of the films - refractive index n, extinction coeff. k and optical energy bandgap Eg - were detd. as a function of compn. of the films. Optical properties of the individual oxide films were also detd. (for λ = 550 nm) for Ta2O5 (n = 2.12, k≤2×10-4, Eg = 4.3 eV) and for SiO2 (n = 1.485, k<2×10-4, Eg = 9 eV).Composite films of (Ta2O5)x-(SiO2)1-x with uniform thickness exhibited a continuous change in their optical properties as a function of compn. ratio x/(1-x). The refractive index of the composite film was found to follow an exactly linear relationship as a function of compn. ratio of the film. Spectrophotometry and ellipsometry were used to measure refractive index (and other optical properties), while Rutherford backscattering spectroscopy was used to det. the compn. of the films. Argon incorporation was detected in the films, originating from the Ar neutrals reflected from the sputtering targets. Its value (0.1-2.5%) changed with the compn. of the composite films, being higher for tantalum-oxide-rich films. The optical bandgap position (4.3-9 eV) changed non-linearly with the linear change in the compn. ratio of the film. X-Ray spectroscopy peaks of composite films (Si 2p for SiO2 and Ta 4d, Ta 4f for Ta2O5) revealed that all oxygen was bonded, confirming that films were fully mixed. All films were amorphous as detected by X-ray diffraction. Films with linear and V-shape compn. variations with thickness were produced and are discussed. A single-layer anti-reflection coating was produced with n = 1.88 for silicon substrate, achieving zero reflection at λ = 1060 nm.Stress in the films was measured. All films were under compressive stress, in the range (3.2-5.5)×108 Pa, depending upon compn. of the films.
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    Kobayashi, M.; Terui, H. Refractive Index and Attenuation Characteristics of SiO_2–Ta_2O_5 Optical Waveguide Film. Appl. Opt. 1983, 22, 3121,  DOI: 10.1364/AO.22.003121
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    Refractive index and attenuation characteristics of silica-tantalum oxide optical waveguide film
    Kobayashi, Mario; Terui, Hiroshi
    Applied Optics (1983), 22 (19), 3121-7CODEN: APOPAI; ISSN:0003-6935.
    The n and optical attenuation of sputtered SiO2-Ta2O5 waveguide film were measured in the 0.633-1.32-μm wavelength region.,. The waveguide film had a large n range of 1.46-2.08, which can be adjusted by suitable selection of the compn. ratio of the SiO2-Ta2O5 target. Substrate heating, up to 270° during the sputtering process was effective for obtaining low attenuation. The waveguide films showed low attenuations, <0.41 decibel/cm for the TE0 mode. The best fits of the form λγ to the measured attenuation have γ between 0 and -1, where λ is the wavelength. This wavelength dependence of the attenuation can be interpreted based on mode conversions due to the film surface roughness.
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    Barbosa, A. J.; Dias Filho, F. A.; Messaddeq, Y.; Ribeiro, S. J. L.; Gonçalves, R. R.; Lüthi, S. R.; Gomes, A. S. L. 1.5μm Emission and Infrared-to-Visible Frequency Upconversion in Er+3/Yb+3-Doped Phosphoniobate Glasses. J. Non-Cryst. Solids 2006, 352, 3636– 3641,  DOI: 10.1016/j.jnoncrysol.2006.03.095
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    1.5 μm Emission and infrared-to-visible frequency upconversion in Er+3/Yb+3-doped phosphoniobate glasses
    Barbosa, A. J.; Dias Filho, F. A.; Messaddeq, Y.; Ribeiro, S. J. L.; Goncalves, R. R.; Luethi, S. R.; Gomes, A. S. L.
    Journal of Non-Crystalline Solids (2006), 352 (32-35), 3636-3641CODEN: JNCSBJ; ISSN:0022-3093. (Elsevier B.V.)
    Na phosphoniobate glasses (mol%) 75NaPO3-25Nb2O5 and contg. 2 mol% Yb3+ and x mol% Er3+ (0.01 ≤ x ≤ 2) were prepd. using the conventional melting/casting process. Er3+ emission at 1.5 μm and IR-to-visible upconversion emission, upon excitation at 976 nm, are evaluated as a function of the Er3+ concn. For the lowest Er3+ content, 1.5 μm emission quantum efficiency was 90%. Increasing the Er3+ concn. up to 2 mol%, the emission quantum efficiency decreases to 37% due to concn. quenching. The green and red upconversion emission intensity ratio was studied as a function of Yb3+ co-doping and the Er3+-Er3+ energy transfer processes.
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    Tosello, C.; Rossi, F.; Ronchin, S.; Rolli, R.; Righini, G.; Pozzi, F.; Pelli, S.; Fossi, M.; Moser, E.; Montagna, M.; Ferrari, M.; Duverger, C.; Chiappini, A.; De Bernardi, C. Erbium-Activated Silica–Titania Planar Waveguides on Silica-on-Silicon Substrates Prepared by Rf Sputtering. J. Non-Cryst. Solids Solids 2001, 284, 230– 236,  DOI: 10.1016/S0022-3093(01)00407-0
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    Erbium-activated silica-titania planar waveguides on silica-on-silicon substrates prepared by rf sputtering
    Tosello, C.; Rossi, F.; Ronchin, S.; Rolli, R.; Righini, G. C.; Pozzi, F.; Pelli, S.; Fossi, M.; Moser, E.; Montagna, M.; Ferrari, M.; Duverger, C.; Chiappini, A.; De Bernardi, C.
    Journal of Non-Crystalline Solids (2001), 284 (1-3), 230-236CODEN: JNCSBJ; ISSN:0022-3093. (Elsevier Science B.V.)
    Er-activated SiO2-TiO2 planar waveguides were prepd. by radiofrequency (rf) sputtering technique. SiO2-on-Si substrates obtained by plasma-enhanced CVD (PECVD) and radiofrequency sputtering (RFS) were employed. The refractive indexes, the thickness and the propagation losses of the waveguides were measured. The refractive index and the roughness of the SiO2 substrates produced by RFS appear to be dependent on the thickness. Thermal annealing, which is a necessary condition to obtain light propagation, induces a decrease of the refractive index in the SiO2 substrates. The waveguide deposited on PECVD substrate exhibits several propagating modes with an attenuation coeff. 1.7 dB/cm compared with 12.2 dB/cm measured for the waveguide deposited on SiO2 substrate produced by RFS technique. Emission of the 4I13/2 - 4I15/2 transition with a 53 nm bandwidth was obsd.
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    Huang, A. P.; Chu, P. K. Crystallization Improvement of Ta2O5 Thin Films by the Addition of Water Vapor. J. Cryst. Growth 2005, 274, 73– 77,  DOI: 10.1016/j.jcrysgro.2004.10.004
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    Crystallization improvement of Ta2O5 thin films by the addition of water vapor
    Huang, A. P.; Chu, Paul K.
    Journal of Crystal Growth (2005), 274 (1-2), 73-77CODEN: JCRGAE; ISSN:0022-0248. (Elsevier B.V.)
    By the addn. of water vapor into the working gas, cryst. Ta2O5 thin films can be fabricated at low substrate temps. At 500°, by the addn. of water vapor, the crystallinity of the thin films was obviously improved. The grains with tetragonal structure were clearly obsd. by AFM. Total transmission greater than 85% was achieved between wavelengths of 400 and 800 nm and the optical absorption edge of the thin films also shifted to smaller wavelength. The crystallinity of the thin films can be improved and the crystd. temp. can be decreased with the introduction of water vapor in the fabrication process. The effects of water vapor on the crystn. of Ta2O5 thin films are discussed in details.
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    Chiasera, A.; Tosello, C.; Moser, E.; Montagna, M.; Belli, R.; Gonçalves, R. R.; Righini, G. C.; Pelli, S.; Chiappini, A.; Zampedri, L.; Ferrari, M. Er3+/Yb3+-Activated Silica–Titania Planar Waveguides for EDPWAs Fabricated by Rf-Sputtering. J. Non-Cryst. Solids 2003, 322, 289– 294,  DOI: 10.1016/S0022-3093(03)00217-5
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    Er3+/Yb3+-activated silica-titania planar waveguides for EDPWAs fabricated by rf-sputtering
    Chiasera, A.; Tosello, C.; Moser, E.; Montagna, M.; Belli, R.; Goncalves, R. R.; Righini, G. C.; Pelli, S.; Chiappini, A.; Zampedri, L.; Ferrari, M.
    Journal of Non-Crystalline Solids (2003), 322 (1-3), 289-294CODEN: JNCSBJ; ISSN:0022-3093. (Elsevier Science B.V.)
    Two Er3+/Yb3+-codoped 92SiO2-8TiO2 planar waveguides, with 1.2 mol% Er and molar ratio Er/Yb of 2, were fabricated by radiofrequency-sputtering technique. The active films were deposited on SiO2-on-Si and SiO2 glass substrates. The thickness of the waveguides and the refractive index at 632.8 and 543.5 nm were measured by an m-line app. The losses, for the TE0 mode, were evaluated at 632.8 and 1300 nm. The structural properties were studied by energy dispersive spectroscopy and Raman spectroscopy. All waveguides were single-mode at 1550 nm. An attenuation coeff. of 0.5 dB/cm at 632.8 nm and 0.1 dB/cm at 1300 nm were measured. The emission at 1530 nm of the 4I13/2 4I15/2 transition of Er3+ ion was obsd. at room temp. upon continuous wave excitation at 981 and 514.5 nm. Back energy transfer from Er3+ to Yb3+ was demonstrated by measurement of Yb3+ emission upon Er3+ excitation at 514.5 nm. Effective excitation efficiency of Er3+ ions by co-doping with Yb3+ ions was shown by photoluminescence excitation spectroscopy.
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    Gonçalves, R. R.; Carturan, G.; Zampedri, L.; Ferrari, M.; Montagna, M.; Chiasera, A.; Righini, G. C.; Pelli, S.; Ribeiro, S. J. L.; Messaddeq, Y. Sol-Gel Er-Doped SiO2–HfO2 Planar Waveguides: A Viable System for 1.5 Mm Application. Appl. Phys. Lett. 2002, 81, 28– 30,  DOI: 10.1063/1.1489477
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    Sol-gel Er-doped SiO2-HfO2 planar waveguides: A viable system for 1.5 μm application
    Goncalves, R. R.; Carturan, G.; Zampedri, L.; Ferrari, M.; Montagna, M.; Chiasera, A.; Righini, G. C.; Pelli, S.; Ribeiro, S. J. L.; Messaddeq, Y.
    Applied Physics Letters (2002), 81 (1), 28-30CODEN: APPLAB; ISSN:0003-6951. (American Institute of Physics)
    70SiO2-30HfO2 planar waveguides, doped with Er3+ concns. ranging from 0.3 to 1 mol.%, were prepd. by sol-gel route, using dip-coating deposition on silica glass substrates. The waveguides show high densification degree, effective intermingling of the two components of the film, and uniform surface morphol. Propagation losses of about 1 dB/cm were measured at 632.8 nm. When pumped with 987 or 514.5 nm continuous-wave laser light, the waveguides show the 4I13/2 4I15/2 emission band with a bandwidth of 48 nm. The spectral features are found independent both on erbium content and excitation wavelength. The 4I13/2 level decay curves presented a single-exponential profile, with a lifetime between 2.9 and 5.0 ms, depending on the erbium concn.
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    Cunha, C. D. S.; Ferrari, J. L.; De Oliveira, D. C.; Maia, L. J. Q.; Gomes, A. S. L.; Ribeiro, S. J. L.; Gonçalves, R. R. NIR Luminescent Er3+/Yb3+Co-Doped SiO<inf>2</Inf>-ZrO<inf>2</Inf>nanostructured Planar and Channel Waveguides: Optical and Structural Properties. Mater. Chem. Phys. 2012, 136, 120– 129,  DOI: 10.1016/j.matchemphys.2012.06.040
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    NIR luminescent Er3+/Yb3+ co-doped SiO2-ZrO2 nanostructured planar and channel waveguides: Optical and structural properties
    Cunha, Cesar dos Santos; Ferrari, Jefferson Luis; de Oliveira, Drielly Cristina; Maia, Lauro June Queiroz; Gomes, Anderson Stevens Leonidas; Ribeiro, Sidney Jose Lima; Goncalves, Rogeria Rocha
    Materials Chemistry and Physics (2012), 136 (1), 120-129CODEN: MCHPDR; ISSN:0254-0584. (Elsevier B.V.)
    Optical and structural properties of planar and channel waveguides based on sol-gel Er3+ and Yb3+ co-doped SiO2-ZrO2 are reported. Microstructured channels with high homogeneous surface profile were written onto the surface of multilayered densified films deposited on SiO2/Si substrates by a femtosecond laser etching technique. The densification of the planar waveguides was evaluated from changes in the refractive index and thickness, with full densification being achieved at 900° after annealing from 23 up to 500 min, depending on the ZrO2 content. Crystal nucleation and growth took place together with densification, thereby producing transparent glass ceramic planar waveguides contg. rare earth-doped ZrO2 nanocrystals dispersed in a SiO2-based glassy host. Low roughness and crack-free surface as well as high confinement coeff. were achieved for all the compns. Enhanced NIR luminescence of the Er3+ ions was obsd. for the Yb3+-codoped planar waveguides, denoting an efficient energy transfer from the Yb3+ to the Er3+ ion.
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  • Abstract

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    Figure 1

    Figure 1. Refractive index values as a function of the annealing time at 900 °C of the Er3+-doped planar waveguides deposited onto the 10 μm SiO2–Si (100) p-type silicon substrate with Si/Ta ratios of (A) 90:10, (B) 80:20, (C) 70:30, (D) 60:40, and (E) 50:50.

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    Figure 2

    Figure 2. Porosity as a function of the annealing time at 900 °C of the Er3+-doped planar waveguides deposited onto the 10 μm SiO2–Si (100) p-type silicon substrate with Si/Ta ratios of (A) 90:10, (B) 80:20, (C) 70:30, (D) 60:40, and (E) 50:50.

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    Figure 3

    Figure 3. Experimental refractive index values as a function of the tantalum amount in comparison to the theoretical refractive index values based on Lorentz–Lorenz and linear equations.

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    Figure 4

    Figure 4. Dispersion curves of the planar waveguides based on Er3+-doped SiO2–Ta2O5 deposited onto the 10 μm SiO2–Si (100) p-type silicon substrate with Si/Ta ratios of 90:10, 80:20, 70:30, 60:40, and 50:50.

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    Figure 5

    Figure 5. Squared electric field profiles in the TE0 mode at 532, 632.8, and 1538 nm of the planar waveguides based on the Er3+-doped SiO2–Ta2O5 deposited onto 10 μm SiO2–Si (100) p-type silicon substrate with Si/Ta ratios of (A) 90:10, (B) 80:20, (C) 70:30, (D) 60:40, and (E) 50:50.

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    Figure 6

    Figure 6. FTIR transmission spectra of Er3+-doped SiO2–Ta2O5 deposited onto the 10 μm SiO2–Si (100) p-type silicon substrate with Si and Ta ratios of (A) 90:10, (B) 80:20, (C) 70:30, (D) 60:40, and (E) 50:50.

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    Figure 7

    Figure 7. Two-dimensional (2D), three-dimensional (3D), and roughness profile of the Er3+- doped SiO2–Ta2O5 film after full densification at 900 °C.

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    Figure 8

    Figure 8. HRTEM micrographs of the Er3+-doped planar waveguides fully densified at 900 °C with Si/Ta ratios of (A) 90:10, (B) 80:20, (C) 70:30, and (D) 60:40.

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    Figure 9

    Figure 9. Excitation spectra of the Er3+-doped SiO2–Ta2O5 planar waveguides with fixed emission at 1528 nm.

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    Figure 10

    Figure 10. Photoluminescence spectra assigned to the 4I13/2 → 4I15/2 transition of the Er3+ ions for the planar waveguides based on Er3+-doped SiO2–Ta2O5 deposited onto the 10 μm SiO2–Si (100) p-type silicon substrate with Si/Ta ratios of (A) 90:10, (B) 70:30, and (C) 50:50.

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      https://chemport.cas.org/services/resolver?origin=ACS&resolution=options&coi=1%3ACAS%3A528%3ADC%252BD1MXhtVKisLfM&md5=3a61870dcb9fd7bfc0a618f0226de369
    15. 15
      Gonçalves, R. R.; Carturan, G.; Zampedri, L.; Ferrari, M.; Montagna, M.; Chiasera, A.; Righini, G. C.; Pelli, S.; Ribeiro, S. J. L.; Messaddeq, Y. Sol-Gel Er-Doped SiO2-HfO2 Planar Waveguides: A Viable System for 1.5 Mm Application. Appl. Phys. Lett. 2002, 81, 28– 30,  DOI: 10.1063/1.1489477
      15
      Sol-gel Er-doped SiO2-HfO2 planar waveguides: A viable system for 1.5 μm application
      Goncalves, R. R.; Carturan, G.; Zampedri, L.; Ferrari, M.; Montagna, M.; Chiasera, A.; Righini, G. C.; Pelli, S.; Ribeiro, S. J. L.; Messaddeq, Y.
      Applied Physics Letters (2002), 81 (1), 28-30CODEN: APPLAB; ISSN:0003-6951. (American Institute of Physics)
      70SiO2-30HfO2 planar waveguides, doped with Er3+ concns. ranging from 0.3 to 1 mol.%, were prepd. by sol-gel route, using dip-coating deposition on silica glass substrates. The waveguides show high densification degree, effective intermingling of the two components of the film, and uniform surface morphol. Propagation losses of about 1 dB/cm were measured at 632.8 nm. When pumped with 987 or 514.5 nm continuous-wave laser light, the waveguides show the 4I13/2 4I15/2 emission band with a bandwidth of 48 nm. The spectral features are found independent both on erbium content and excitation wavelength. The 4I13/2 level decay curves presented a single-exponential profile, with a lifetime between 2.9 and 5.0 ms, depending on the erbium concn.
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    16. 16
      Gonçalves, R. R.; Carturan, G.; Zampedri, L.; Ferrari, M.; Chiasera, A.; Montagna, M.; Righini, G. C.; Pelli, S.; Ribeiro, S. J. L.; Messaddeq, Y. Infrared-to-Visible CW Frequency Upconversion in Erbium Activated Silica-Hafnia Waveguides Prepared by Sol-Gel Route. J. Non-Cryst. Solids 2003, 322, 306– 310,  DOI: 10.1016/S0022-3093(03)00220-5
      16
      Infrared-to-visible CW frequency upconversion in erbium activated silica-hafnia waveguides prepared by sol-gel route
      Goncalves, Rogeria R.; Carturan, Giovanni; Zampedri, Luca; Ferrari, Maurizio; Chiasera, Alessandro; Montagna, Maurizio; Righini, Giancarlo C.; Pelli, Stefano; Ribeiro, Sidney J. L.; Messaddeq, Younes
      Journal of Non-Crystalline Solids (2003), 322 (1-3), 306-310CODEN: JNCSBJ; ISSN:0022-3093. (Elsevier Science B.V.)
      70SiO2-30HfO2 mol% planar waveguides, doped with Er3+ with concns. ranging from 0.3 to 2 mol% were prepd. by sol-gel route, using dip-coating deposition on vitreous-SiO2 substrates. IR-to-visible upconversion emission, upon excitation at 980 nm, was obsd. for all the samples. The upconversion results in green, red and blue emissions. The study of the upconversion dynamic as a function of the Er3+ concn. and excitation power, show that processes such as excited state absorption and energy transfer upconversion are effective.
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    17. 17
      Gonçalves, R. R.; Carturan, G.; Montagna, M.; Ferrari, M.; Zampedri, L.; Pelli, S.; Righini, G. C.; Ribeiro, S. J. L.; Messaddeq, Y. Erbium-Activated HfO2-Based Waveguides for Photonics. Opt. Mater. 2004, 25, 131– 139,  DOI: 10.1016/S0925-3467(03)00261-1
      17
      Erbium-activated HfO2-based waveguides for photonics
      Goncalves, Rogeria R.; Carturan, Giovanni; Montagna, Maurizio; Ferrari, Maurizio; Zampedri, Luca; Pelli, Stefano; Righini, Giancarlo C.; Ribeiro, Sidney J. L.; Messaddeq, Younes
      Optical Materials (Amsterdam, Netherlands) (2004), 25 (2), 131-139CODEN: OMATET; ISSN:0925-3467. (Elsevier Science B.V.)
      SiO2-based sol-gel waveguides activated by Er3+ ions are attractive materials for integrated optic devices. 70SiO2-30HfO2 planar waveguides, doped with Er3+ concns. ranging from 0.01 to 4 mol%, were prepd. by sol-gel route. The films were deposited on v-SiO2 and SiO2-on-Si substrates, using dip-coating technique. The waveguides show a homogeneous surface morphol., high densification degree and uniform refractive index across the thickness. Emission in the C-telecommunication band was obsd. at room temp. for all the samples upon excitation at 980 nm. The shape is almost independent on Er content, with a FWHM between 44 and 48 nm. The 4I13/2 level decay curves presented a single-exponential profile, with a lifetime ranging between 1.1 and 6.7 ms, depending on the Er concn. The waveguide deposited on SiO2-on-Si substrate supports one single propagation mode at 1.5 μm with a confinement coeff. of 0.85, and a losses of ∼0.8 dB/cm at 632.8 nm.
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    18. 18
      Zampedri, L.; Ferrari, M.; Armellini, C.; Visintainer, F.; Tosello, C.; Ronchin, S.; Rolli, R.; Montagna, M.; Chiasera, A.; Pelli, S.; Righini, G. C.; Monteil, A.; Duverger, C.; Gonçalves, R. R. Erbium-Activated Silica-Titania Planar Waveguides. J. Sol-Gel Sci. Technol. 2003, 26, 1033– 1036,  DOI: 10.1023/A:1020734018629
      18
      Erbium-Activated Silica-Titania Planar Waveguides
      Zampedri, L.; Ferrari, M.; Armellini, C.; Visintainer, F.; Tosello, C.; Ronchin, S.; Rolli, R.; Montagna, M.; Chiasera, A.; Pelli, S.; Righini, G. C.; Monteil, A.; Duverger, C.; Goncalves, R. R.
      Journal of Sol-Gel Science and Technology (2003), 26 (1/2/3), 1033-1036CODEN: JSGTEC; ISSN:0928-0707. (Kluwer Academic Publishers)
      (100 - X)SiO2-(x)TiO2-ErO3/2 planar waveguides, with 7 ≤ x ≤ 20 were prepd. by sol-gel route using the dip-coating technique. The thickness of the films was optimized to support a single propagating mode at 1550 nm, with a confinement coeff. >0.75. The process of densification of the gel and the devitrification with the growth of TiO2 nanocrystals were studied by Raman scattering. Devitrification is important only for x ≥ 15, but it was not possible to obtain full densification of the samples, even at the lowest TiO2 content, without the appearance of nanocrystals. Emission in the C telecom band was obsd.; the spectral width of the 4I13/2 4I15/2 transition of Er3+ slightly increases with the TiO2 content. For x ≤ 12 most of Er3+ ions (∼65%) decay exponentially with a lifetime of ∼8 ms.
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    19. 19
      Gonçalves, R. R.; Guimarães, J. J.; Ferrari, J. L.; Maia, L. J. Q.; Ribeiro, S. J. L. Active Planar Waveguides Based on Sol-Gel Er3+-Doped SiO2-ZrO2 for Photonic Applications: Morphological, Structural and Optical Properties. J. Non-Cryst. Solids 2008, 354, 4846– 4851,  DOI: 10.1016/j.jnoncrysol.2008.05.055
      19
      Active planar waveguides based on sol-gel Er3+-doped SiO2-ZrO2 for photonic applications: Morphological, structural and optical properties
      Goncalves, R. R.; Guimaraes, J. J.; Ferrari, J. L.; Maia, L. J. Q.; Ribeiro, S. J. L.
      Journal of Non-Crystalline Solids (2008), 354 (42-44), 4846-4851CODEN: JNCSBJ; ISSN:0022-3093. (Elsevier B.V.)
      Er3+-doped glass-ceramic SiO2-ZrO2 optical planar waveguides were prepd. by the sol-gel route using different SiO2:ZrO2 molar ratios (90:10, 85:15, 80:20, and 75:25). Multilayered films were deposited onto Si(1 0 0) substrates by the dip-coating technique. Structural characterization was performed using vibrational spectroscopy and x-ray diffraction. Some optical properties, densification and surface morphol. of these films were studied as a function of the SiO2:ZrO2 ratio, annealing temp. and time. Optical properties such as refractive index, no. of propagating modes and attenuation coeff. were measured at 632.8, 543.5, and 1550 nm, by the prism coupling technique. Uniform surface morphol. with roughness <0.5 nm. Low losses, <0.9 dB/cm at 612.8 nm in the TE0 mode, were measured for the planar waveguides contg. up to 25 mol.% Zr oxide. Luminescence of Er3+ in the near IR was obsd. for the active nanocomposite.
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    20. 20
      Ferrari, J. L.; Lima, K. O.; Maia, L. J. Q.; Gonçalves, R. R. Sol-Gel Preparation of near-Infrared Broadband Emitting Er 3+-Doped SiO2-Ta2O5 Nanocomposite Films. Thin Solid Films 2010, 519, 1319– 1324,  DOI: 10.1016/j.tsf.2010.09.035
      There is no corresponding record for this reference.
    21. 21
      Aquino, F. T.; Caixeta, F. J.; de Oliveira Lima, K.; Kochanowicz, M.; Dorosz, D.; Gonçalves, R. R. Broadband NIR Emission from Rare Earth Doped-SiO2-Nb2O5 and SiO2-Ta2O5 Nanocomposites. J. Lumin. 2018, 199, 138– 142,  DOI: 10.1016/j.jlumin.2018.03.018
      21
      Broadband NIR emission from rare earth doped-SiO2-Nb2O5 and SiO2-Ta2O5 nanocomposites
      Aquino, Felipe Thomaz; Caixeta, Fabio Jose; Lima, Karmel de Oliveira; Kochanowicz, Marcin; Dorosz, Dominik; Goncalves, Rogeria Rocha
      Journal of Luminescence (2018), 199 (), 138-142CODEN: JLUMA8; ISSN:0022-2313. (Elsevier B.V.)
      The rising demand for more efficient telecommunication networks that can carry larger data vol. is currently one of the most pressing technol. challenges. In this sense, developing new materials to obtain NIR broadband emission is an urgent matter. We have successfully prepd. Tm3+/Yb3+ co-doped 70SiO2-30Nb2O5 and 70SiO2-30Ta2O5 (mol%) nanocomposites by the sol-gel method. The Tm3+/Yb3+ co-doped 70SiO2-30Nb2O5 and 70SiO2-30Ta2O5 nanocomposites displayed intense broad emission that extends from 1.6 to 2.1μm, with max. at 1.8μm. The bandwidth values lied around 230 or 260nm depending on the cryst. phase. Increasing rare earth content elicited discrete quenching, which attests to good rare earth soly. and distribution within the hosts. The luminescence results are outstanding in terms of silicate hosts and point to the potential application of these materials in optical amplifiers, remote sensing, and LIDAR systems.
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    22. 22
      Aquino, F. T.; Pereira, R. R.; Ferrari, J. L.; Ribeiro, S. J. L.; Ferrier, A.; Goldner, P.; Gonçalves, R. R. Unusual Broadening of the NIR Luminescence of Er3+-Doped Nb 2O5 Nanocrystals Embedded in Silica Host: Preparation and Their Structural and Spectroscopic Study for Photonics Applications. Mater. Chem. Phys. 2014, 147, 751– 760,  DOI: 10.1016/j.matchemphys.2014.06.016
      22
      Unusual broadening of the NIR luminescence of Er3+-doped Nb2O5 nanocrystals embedded in silica host: Preparation and their structural and spectroscopic study for photonics applications
      Aquino, Felipe Thomaz; Pereira, Rafael R.; Ferrari, Jefferson Luis; Ribeiro, Sidney Jose Lima; Ferrier, Alban; Goldner, Philippe; Goncalves, Rogeria Rocha
      Materials Chemistry and Physics (2014), 147 (3), 751-760CODEN: MCHPDR; ISSN:0254-0584. (Elsevier B.V.)
      This paper reports on the prepn. of novel sol-gel Er-doped SiO2-based nanocomposites embedded with Nb2O5 nanocrystals fabricated using a bottom-up method and describes their structural, morphol., and luminescence characterization. To prep. the glass ceramics, the authors synthesized xerogels contg. Si/Nb molar ratios of 90:10 up to 50:50 at room temp., followed by annealing at 900, 1000, or 1100° for 10 h. The authors identified crystn. accompanying host densification in all the nanocomposites with orthorhombic (T-phase) or monoclinic (M-phase) Nb2O5 nanocrystals dispersed in the amorphous SiO2 phase, depending on the Nb content and annealing temp. A high-intensity broadband emission in the near-IR region assigned to the 4I13/2 → 4I15/2 transition of the Er3+ ions was registered for all the nanocomposites. The shape and the bandwidth changed with the Nb2O5 cryst. phase, with values achieving up to 81 nm. Er3+ ions were located mainly in Nb2O5-rich regions, and the complex structure of the different Nb2O5 polymorphs accounted for the broadening in the emission spectra. The materials contg. the T-phase, displayed higher luminescence intensity, longer 4I13/2 lifetime and broader bandwidth. In conclusion, these nanostructured materials are potential candidates for photonic applications like optical amplifiers and WDM devices operating in the S, C, and L telecommunication bands.
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    23. 23
      Ferrari, J. L.; Lima, K. O.; Maia, L. J. Q.; Ribeiro, S. J. L.; Gomes, A. S. L.; Gonçalves, R. R. Broadband NIR Emission in Sol-Gel Er 3-Activated SiO 2-Ta 2O 5 Glass Ceramic Planar and Channel Waveguides for Optical Application. J. Nanosci. Nanotechnol. 2011, 11, 2540– 2544,  DOI: 10.1166/jnn.2011.3565
      23
      Broadband NIR emission in sol-gel Er3+-activated SiO2-Ta2O5 glass ceramic planar and channel waveguides for optical application
      Ferrari, J. L.; Lima, K. O.; Maia, L. J. Q.; Ribeiro, S. J. L.; Gomes, A. S. L.; Goncalves, R. R.
      Journal of Nanoscience and Nanotechnology (2011), 11 (3), 2540-2544CODEN: JNNOAR; ISSN:1533-4880. (American Scientific Publishers)
      An Er3+-doped SiO2:Ta2O5 optical channel waveguide and nanocomposite were prepd. by the sol-gel route at a Si:Ta 50:50 molar ratio. Channels with an excellent surface profile were easily and quickly fabricated by focusing a femtosecond laser onto the surface of multilayered films deposited on SiO2/Si substrates. In parallel, the same sol used to prep. the film was annealed at 900, 1000, and 1100 °C for 2 h, to get the nanocomposite materials. A broadband NIR emission around 1538 nm, assigned to the 4I13/2 → 4I15/2 transition of the Er3+ ions was obsd. in the nanocomposites of amorphous SiO2 contg. dispersed Ta2O5 nanocrystals. The 4I13/2 lifetime and emission bandwidth depend on the annealing temp. In conclusion, Er3+-doped SiO2:Ta2O5 channel waveguides and nanocomposites are promising materials for photonic applications.
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      https://chemport.cas.org/services/resolver?origin=ACS&resolution=options&coi=1%3ACAS%3A528%3ADC%252BC3MXivFektro%253D&md5=37ff5aea9524d3a261b842950d4528c4
    24. 24
      Zha, J.; Roggendorf, H. Sol-Gel Science, the Physics and Chemistry of Sol-Gel Processing, Ed. by C. J. Brinker and G. W. Scherer, Academic Press, Boston 1990, Xiv, 908 Pp., Bound?ISBN 0-12-134970-5. Adv. Mater. 1991, 3, 522,  DOI: 10.1002/adma.19910031025
      There is no corresponding record for this reference.
    25. 25
      Jung-Chieh Su, H.-C.; Chien-Kang Kao, H.-T. I.-N.; Lin, H.-C. C.-H. T.; Chi, H.-C. C.-C.; Hsin-Chu; ; Yung-Sheng Liu, H.-C. Manufacturing Process for Preparing Sol-Gel Optical Waveguides. U.S. Patent US6.391,515B12002.
      There is no corresponding record for this reference.
    26. 26
      Ferrari, J. L.; Lima, K. O.; Maia, L. J. Q.; Gonçalves, R. R. Sol-Gel Preparation of near-Infrared Broadband Emitting Er3+-Doped SiO2-Ta2O5 Nanocomposite Films. Thin Solid Films 2010, 519, 1319– 1324,  DOI: 10.1016/j.tsf.2010.09.035
      There is no corresponding record for this reference.
    27. 27
      Ferrari, J. L.; Lima, K. O.; Maia, L. J. Q.; Ribeiro, S. J. L.; Gonaçalves, R. R. Structural and Spectroscopic Properties of Luminescent Er 3+-Doped SiO2-Ta2O5 Nanocomposites. J. Am. Ceram. Soc. 2011, 94, 1230– 1237,  DOI: 10.1111/j.1551-2916.2010.04191.x
      27
      Structural and spectroscopic properties of luminescent Er3+-doped SiO2-Ta2O5 nanocomposites
      Ferrari, Jefferson L.; Lima, Karmel O.; Maia, Lauro J. Q.; Ribeiro, Sidney J. L.; Goncalves, Rogeria R.
      Journal of the American Ceramic Society (2011), 94 (4), 1230-1237CODEN: JACTAW; ISSN:0002-7820. (Wiley-Blackwell)
      This paper reports on the prepn. and structural, morphol., and luminescence properties of Er3+-doped nanocomposites based on SiO2-Ta2O5 prepd. by the sol-gel method. The influence of the tantalum oxide content on the structural and spectroscopic properties was analyzed for Si/Ta molar ratios of 90:10, 80:20, 70:30, 60:40, and 50:50. The sols were kept at 60°C for formation of the xerogel, followed by annealing at 900°, 1000°, and 1100°C for 2 h for prodn. of the nanocomposites. The densification, phase sepn., and crystn. processes were monitored through vibrational spectroscopy (FTIR), X-ray diffraction, and high-resoln. TEM. Er3+ emission in the IR region, assigned to the 4I13/2→4I15/2 transition, was obsd. for all the nanocomposites. Evolution from a vitreous-like environment to a cryst. one was identified upon increasing the annealing temp. and tantalum content. According to the results obtained, the Er3+ ions are preferentially localized close to the region rich in Ta2O5 nanoparticles. The localization of Er3+ ions was shown to be dependent on the amt. of tantalum. Moreover, the fact that the Er3+ ions are located close to Ta2O5 nanoparticles promotes a broadband emission with full-width at half-max. of 90 nm at ∼1550 nm.
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      https://chemport.cas.org/services/resolver?origin=ACS&resolution=options&coi=1%3ACAS%3A528%3ADC%252BC3MXnsVelsr4%253D&md5=a9b3b3791bfd97a7b59f835800034e3c
    28. 28
      Ferrari, J. L.; Lima, K. O.; Maia, L. J. Q.; Ribeiro, S. J. L.; Gomes, A. S. L.; Gonçalves, R. R. Broadband NIR Emission in Sol-Gel Er3+-Activated SiO2-Ta2O5 Glass Ceramic Planar and Channel Waveguides for Optical Application. J. Nanosci. Nanotechnol. 2011, 11, 2540– 2544,  DOI: 10.1166/jnn.2011.3565
      28
      Broadband NIR emission in sol-gel Er3+-activated SiO2-Ta2O5 glass ceramic planar and channel waveguides for optical application
      Ferrari, J. L.; Lima, K. O.; Maia, L. J. Q.; Ribeiro, S. J. L.; Gomes, A. S. L.; Goncalves, R. R.
      Journal of Nanoscience and Nanotechnology (2011), 11 (3), 2540-2544CODEN: JNNOAR; ISSN:1533-4880. (American Scientific Publishers)
      An Er3+-doped SiO2:Ta2O5 optical channel waveguide and nanocomposite were prepd. by the sol-gel route at a Si:Ta 50:50 molar ratio. Channels with an excellent surface profile were easily and quickly fabricated by focusing a femtosecond laser onto the surface of multilayered films deposited on SiO2/Si substrates. In parallel, the same sol used to prep. the film was annealed at 900, 1000, and 1100 °C for 2 h, to get the nanocomposite materials. A broadband NIR emission around 1538 nm, assigned to the 4I13/2 → 4I15/2 transition of the Er3+ ions was obsd. in the nanocomposites of amorphous SiO2 contg. dispersed Ta2O5 nanocrystals. The 4I13/2 lifetime and emission bandwidth depend on the annealing temp. In conclusion, Er3+-doped SiO2:Ta2O5 channel waveguides and nanocomposites are promising materials for photonic applications.
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      https://chemport.cas.org/services/resolver?origin=ACS&resolution=options&coi=1%3ACAS%3A528%3ADC%252BC3MXivFektro%253D&md5=37ff5aea9524d3a261b842950d4528c4
    29. 29
      Yoldas, B. E. Investigations of Porous Oxides as an Antireflective Coating for Glass Surfaces. Appl. Opt. 1980, 19, 1425,  DOI: 10.1364/AO.19.001425
      29
      Investigations of porous oxides as an antireflective coating for glass surfaces
      Yoldas, Bulent E.
      Applied Optics (1980), 19 (9), 1425-9CODEN: APOPAI; ISSN:0003-6935.
      Possible applications of porous oxide films as an antireflective coating were investigated. A porous aluminum oxide film is deposited on glass surfaces from a clear organometallic derived sol. The index of the oxide coating is reduced by the presence of pores whose size is <100 Å; this constitutes up to 64% porosity. These pores, being considerably smaller than the wavelength of light, do not interfere with the optical transparency of the material but reduce the index of refraction; thus they make it possible to obtain transparent oxide materials and coatings with very low index.
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      https://chemport.cas.org/services/resolver?origin=ACS&resolution=options&coi=1%3ACAS%3A528%3ADyaL3cXit1Cisrw%253D&md5=f82df953307604e53d8286aea8c78b10
    30. 30
      Ferrari, J. L.; Lima, K. O.; Maia, L. J. Q.; Ribeiro, S. J. L.; Goncalves, R. R. Structural and Spectroscopic Properties of Luminescent Er3+-Doped SiO2-Ta2O5 Nanocomposites. J. Am. Ceram. Soc. 2011, 94, 1230– 1237,  DOI: 10.1111/j.1551-2916.2010.04191.x
      30
      Structural and spectroscopic properties of luminescent Er3+-doped SiO2-Ta2O5 nanocomposites
      Ferrari, Jefferson L.; Lima, Karmel O.; Maia, Lauro J. Q.; Ribeiro, Sidney J. L.; Goncalves, Rogeria R.
      Journal of the American Ceramic Society (2011), 94 (4), 1230-1237CODEN: JACTAW; ISSN:0002-7820. (Wiley-Blackwell)
      This paper reports on the prepn. and structural, morphol., and luminescence properties of Er3+-doped nanocomposites based on SiO2-Ta2O5 prepd. by the sol-gel method. The influence of the tantalum oxide content on the structural and spectroscopic properties was analyzed for Si/Ta molar ratios of 90:10, 80:20, 70:30, 60:40, and 50:50. The sols were kept at 60°C for formation of the xerogel, followed by annealing at 900°, 1000°, and 1100°C for 2 h for prodn. of the nanocomposites. The densification, phase sepn., and crystn. processes were monitored through vibrational spectroscopy (FTIR), X-ray diffraction, and high-resoln. TEM. Er3+ emission in the IR region, assigned to the 4I13/2→4I15/2 transition, was obsd. for all the nanocomposites. Evolution from a vitreous-like environment to a cryst. one was identified upon increasing the annealing temp. and tantalum content. According to the results obtained, the Er3+ ions are preferentially localized close to the region rich in Ta2O5 nanoparticles. The localization of Er3+ ions was shown to be dependent on the amt. of tantalum. Moreover, the fact that the Er3+ ions are located close to Ta2O5 nanoparticles promotes a broadband emission with full-width at half-max. of 90 nm at ∼1550 nm.
      >> More from SciFinder ®
      https://chemport.cas.org/services/resolver?origin=ACS&resolution=options&coi=1%3ACAS%3A528%3ADC%252BC3MXnsVelsr4%253D&md5=a9b3b3791bfd97a7b59f835800034e3c
    31. 31
      Montagna, M.; Chiasera, A.; Moser, E.; Visintainer, F.; Ferrari, M.; Zampedri, L.; Gonçalves, R. R.; Ribeiro, S. J. L.; Martucci, A.; Guglielmi, M.; Ivanda, M.; Almeida, R. M. Nucleation and Crystallization of Titania Nanoparticles in Silica Titania Planar Waveguides: A Study by Low Frequency Raman Scattering. Mater. Sci. Forum 2004, 455–456, 520– 526,  DOI: 10.4028/www.scientific.net/msf.455-456.520
      31
      Nucleation and crystallization of titania nanoparticles in silica titania planar waveguides: a study by low frequency Raman scattering
      Montagna, M.; Chiasera, A.; Moser, E.; Visintainer, F.; Ferrari, M.; Zampedri, L.; Goncalves, R. R.; Ribeiro, S. J. L.; Martucci, A.; Guglielmi, M.; Ivanda, M.; Almeida, R. M.
      Materials Science Forum (2004), 455-456 (), 520-526CODEN: MSFOEP; ISSN:0255-5476. (Trans Tech Publications Ltd.)
      SiO2(1-x)-TiO2(x) waveguides, with the mole fraction x in the range 0.07-0.20 and thickness of about 0.4 μm, were deposited on silica substrates by a dip-coating technique. The thermal treatments at 700-900°C, used to fully densify the xerogels, produce nucleation of TiO2 nanocrystals even for the lowest TiO2 content. The nucleation of TiO2 nanocrystals and their growth by thermal annealing up to 1300°C were studied by waveguide Raman spectroscopy, for the SiO2(0.8)-TiO2(0.2) compn. By increasing the annealing temp., the Raman spectrum evolves from that typical of the silica-titania glass to that of anatase, but brookite phase is dominant at intermediate temps. In the low-frequency region (5-50 cm-1) of the Raman spectra, acoustic vibrations of the nanocrystals are obsd. From the measured line shapes, we can deduce the size distribution of the particles. The results are compared with those obtained from the line widths in the X-ray diffraction patterns. Nanocrystals with a mean size in the range 4-20 nm are obtained by thermal annealing in a corresponding range of 800-1300°C.
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    32. 32
      Zampedri, L.; Mattarelli, M.; Montagna, M.; Gonçalves, R. R. Evaluation of Local Field Effect on the I 13 2 4 Lifetimes in Er-Doped Silica-Hafnia Planar Waveguides. Phys. Rev. B 2007, 75, 073105  DOI: 10.1103/PhysRevB.75.073105
      32
      Evaluation of local field effect on the 4I13/2 lifetimes in Er-doped silica-hafnia planar waveguides
      Zampedri, L.; Mattarelli, M.; Montagna, M.; Goncalves, R. R.
      Physical Review B: Condensed Matter and Materials Physics (2007), 75 (7), 073105/1-073105/4CODEN: PRBMDO; ISSN:1098-0121. (American Physical Society)
      (100-X) SiO2-xHfO2 planar waveguides (10<x<45) doped with 0.01 mol % Er3+ were prepd. by a sol-gel route. The lifetime of the 4I13/2 level and the refractive index of the waveguides were measured. The magnetic dipole and elec. dipole rates of the 4I13/2→ 4I15/2 transition were estd. as a function of the refractive index. The elec. dipole transition rates were well reproduced by the real cavity model.
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    33. 33
      Chaneliere, C.; Autran, J. L.; Devine, R. A. B.; Balland, B. Tantalum Pentoxide (Ta2O5) Thin Films for Advanced Dielectric Applications. Mater. Sci. Eng., R 1998, 22, 269– 322,  DOI: 10.1016/S0927-796X(97)00023-5
      33
      Tantalum pentoxide (Ta2O5) thin films for advanced dielectric applications
      Chaneliere, C.; Autran, J. L.; Devine, R. A. B.; Balland, B.
      Materials Science & Engineering, R: Reports (1998), R22 (6), 269-322 pp.CODEN: MIGIEA; ISSN:0927-796X. (Elsevier Science S.A.)
      A review with 324 refs. on the present knowledge on Ta2O5 thin films and their applications in the field of microelectronics and integrated microtechnologies. Different methods used to produce Ta2O5 layers are described, emphasizing elaboration mechanisms and key parameters for each technique. We also review recent advances in the deposition of Ta2O5 in the particular field of microelectronics where high quality layers are required from the structural and elec. points of view. The phys., structural, optical, chem. and elec. properties of Ta2O5 thin films on semiconductors are then presented and essential film parameters, such as optical index, film d. or dielec. permittivity, are discussed. After a reminder of the basic mechanisms that control the bulk elec. conduction in insulating films, we carefully examine the origin of leakage currents in Ta2O5 and present the state-of-the-art concerning the insulating behavior of Ta2O5 layers. Finally, applications of Ta2O5 thin films are presented in the last part of this paper. We show how Ta2O5 was employed as an antireflection coating, insulating layer, gate oxide, corrosion-resistant material, and sensitive layer in a wide variety of components, circuits, and sensors.
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    34. 34
      Rocha, L. A.; Schiavon, M. A.; Ribeiro, S. J. L.; Gonçalves, R. R.; Ferrari, J. L. Eu3+-Doped SiO2–Gd2O3 Prepared by the Sol–Gel Process: Structural and Optical Properties. J. Sol-Gel Sci. Technol. 2015, 76, 260– 270,  DOI: 10.1007/s10971-015-3773-6
      34
      Eu3+-doped SiO2-Gd2O3 prepared by the sol-gel process: structural and optical properties
      Rocha, Leonardo Alves; Schiavon, Marco Antonio; Ribeiro, Sidney Jose L.; Goncalves, Rogeria Rocha; Ferrari, Jefferson Luis
      Journal of Sol-Gel Science and Technology (2015), 76 (2), 260-270CODEN: JSGTEC; ISSN:0928-0707. (Springer)
      Abstr.: Eu3+-doped SiO2-Gd2O3 materials were prepd. by the sol-gel process changing the Si4+:Gd3+ molar ratio of 100:0, 70:30, 50:50, 30:70 and 0:100 mol%. The amt. of Eu3+ was fixed at 0.2 mol% in relation to the total no. of moles of [Si4+ + Gd3+] in the systems. The xerogels obtained from sols were heat-treated at 900, 1000 and 1100 °C for 8 h. By TGA/DTA, XRD and Raman spectroscopy anal., the formation of Gd2O3 cryst. was detected. The microstrains and crystallite size were calcd. by the Williamson-Hall and Scherrer's equation, resp. The results showed the direct dependence of microstrain and crystallite size as a function of the heat-treatment temp. By the FTIR anal. was obsd. the elimination of species like H2O, O-H and C-H groups, which can act as photoluminescence quenchers. All materials obtained in this work showed intense photoluminescence emission in the red region due to the 5D0 → 7F2 transition of Eu3+. The emission can be obsd. through the naked eye. The excited state lifetime shows to be dependent on values of refractive index and heat-treatment temps. The microstrain values affected the lifetime values and consequently the photoluminescence properties. In summary, the materials obtained in this work showed great absorption in the UV region promoting intense emission in the visible region, making them potential candidates for future applications in devices such as solar cells, image generator, biomarkers, among others. Graphical Abstr.: [Figure not available: see fulltext.].
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    35. 35
      Aquino, F. T.; Ferrari, J. L.; Ribeiro, S. J. L.; Ferrier, A.; Goldner, P.; Gonçalves, R. R. Broadband NIR Emission in Novel Sol-Gel Er3+-Doped SiO 2-Nb2O5 Glass Ceramic Planar Waveguides for Photonic Applications. Opt. Mater. 2013, 35, 387– 396,  DOI: 10.1016/j.optmat.2012.09.029
      35
      Broadband NIR emission in novel sol-gel Er3+-doped SiO2-Nb2O5 glass ceramic planar waveguides for photonic applications
      Aquino, Felipe Thomaz; Ferrari, Jefferson Luis; Ribeiro, Sidney Jose Lima; Ferrier, Alban; Goldner, Philippe; Goncalves, Rogeria Rocha
      Optical Materials (Amsterdam, Netherlands) (2013), 35 (3), 387-396CODEN: OMATET; ISSN:0925-3467. (Elsevier B.V.)
      This paper reports on the sol-gel prepn. and structural and optical characterization of new Er3+-doped SiO2-Nb2O5 nanocomposite planar waveguides. Erbium-doped (100-x)SiO2-xNb2O5 waveguides were deposited on silica-on-silicon substrates and Si(1 0 0) by the dip-coating technique. The waveguides exhibited uniform refractive index distribution across the thickness, efficient light injection at 1538 nm, and low losses at 632 and 1538 nm. The band-gap values lied between 4.12 eV and 3.55 eV for W1-W5, resp., showing an excellent transparency in the visible and near IR region for the waveguides. Fourier Transform IR (FTIR) Spectroscopy anal. evidenced SiO2-Nb2O5 nanocomposite formation with controlled phase sepn. in the films. The HRTEM and XRD analyses revealed Nb2O5 orthorhombic T-phase nanocrystals dispersed in a silica-based host. Photoluminescence (PL) anal. showed a broad band emission at 1531 nm, assigned to the 4I13/2 → 4I15/2 transition of the Er3+ ions present in the nanocomposite, with a full-width at half medium of 48-68 nm, depending on the niobium content and annealing. Hence, these waveguides are excellent candidates for application in integrated optics, esp. in EDWA and WDM devices.
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    36. 36
      Cevro, M. Ion-Beam Sputtering of (Ta2O5)x- (SiO2)1-x Composite Thin Films. Thin Solid Films 1995, 258, 91– 103,  DOI: 10.1016/0040-6090(94)06356-7
      36
      Ion-beam sputtering of (Ta2O5)x-(SiO2)1-x composite thin films
      Cevro, M.
      Thin Solid Films (1995), 258 (1-2), 91-103CODEN: THSFAP; ISSN:0040-6090. (Elsevier)
      Composite (Ta2O5)x-(SiO2)1-x thin films were deposited by ion-beam sputtering using a single ion-beam gun. The compn. of the composite films was adjusted by simple movement of the superposed tantalum and silicon targets. Optical properties of the films - refractive index n, extinction coeff. k and optical energy bandgap Eg - were detd. as a function of compn. of the films. Optical properties of the individual oxide films were also detd. (for λ = 550 nm) for Ta2O5 (n = 2.12, k≤2×10-4, Eg = 4.3 eV) and for SiO2 (n = 1.485, k<2×10-4, Eg = 9 eV).Composite films of (Ta2O5)x-(SiO2)1-x with uniform thickness exhibited a continuous change in their optical properties as a function of compn. ratio x/(1-x). The refractive index of the composite film was found to follow an exactly linear relationship as a function of compn. ratio of the film. Spectrophotometry and ellipsometry were used to measure refractive index (and other optical properties), while Rutherford backscattering spectroscopy was used to det. the compn. of the films. Argon incorporation was detected in the films, originating from the Ar neutrals reflected from the sputtering targets. Its value (0.1-2.5%) changed with the compn. of the composite films, being higher for tantalum-oxide-rich films. The optical bandgap position (4.3-9 eV) changed non-linearly with the linear change in the compn. ratio of the film. X-Ray spectroscopy peaks of composite films (Si 2p for SiO2 and Ta 4d, Ta 4f for Ta2O5) revealed that all oxygen was bonded, confirming that films were fully mixed. All films were amorphous as detected by X-ray diffraction. Films with linear and V-shape compn. variations with thickness were produced and are discussed. A single-layer anti-reflection coating was produced with n = 1.88 for silicon substrate, achieving zero reflection at λ = 1060 nm.Stress in the films was measured. All films were under compressive stress, in the range (3.2-5.5)×108 Pa, depending upon compn. of the films.
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    37. 37
      Kobayashi, M.; Terui, H. Refractive Index and Attenuation Characteristics of SiO_2–Ta_2O_5 Optical Waveguide Film. Appl. Opt. 1983, 22, 3121,  DOI: 10.1364/AO.22.003121
      37
      Refractive index and attenuation characteristics of silica-tantalum oxide optical waveguide film
      Kobayashi, Mario; Terui, Hiroshi
      Applied Optics (1983), 22 (19), 3121-7CODEN: APOPAI; ISSN:0003-6935.
      The n and optical attenuation of sputtered SiO2-Ta2O5 waveguide film were measured in the 0.633-1.32-μm wavelength region.,. The waveguide film had a large n range of 1.46-2.08, which can be adjusted by suitable selection of the compn. ratio of the SiO2-Ta2O5 target. Substrate heating, up to 270° during the sputtering process was effective for obtaining low attenuation. The waveguide films showed low attenuations, <0.41 decibel/cm for the TE0 mode. The best fits of the form λγ to the measured attenuation have γ between 0 and -1, where λ is the wavelength. This wavelength dependence of the attenuation can be interpreted based on mode conversions due to the film surface roughness.
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    38. 38
      Barbosa, A. J.; Dias Filho, F. A.; Messaddeq, Y.; Ribeiro, S. J. L.; Gonçalves, R. R.; Lüthi, S. R.; Gomes, A. S. L. 1.5μm Emission and Infrared-to-Visible Frequency Upconversion in Er+3/Yb+3-Doped Phosphoniobate Glasses. J. Non-Cryst. Solids 2006, 352, 3636– 3641,  DOI: 10.1016/j.jnoncrysol.2006.03.095
      38
      1.5 μm Emission and infrared-to-visible frequency upconversion in Er+3/Yb+3-doped phosphoniobate glasses
      Barbosa, A. J.; Dias Filho, F. A.; Messaddeq, Y.; Ribeiro, S. J. L.; Goncalves, R. R.; Luethi, S. R.; Gomes, A. S. L.
      Journal of Non-Crystalline Solids (2006), 352 (32-35), 3636-3641CODEN: JNCSBJ; ISSN:0022-3093. (Elsevier B.V.)
      Na phosphoniobate glasses (mol%) 75NaPO3-25Nb2O5 and contg. 2 mol% Yb3+ and x mol% Er3+ (0.01 ≤ x ≤ 2) were prepd. using the conventional melting/casting process. Er3+ emission at 1.5 μm and IR-to-visible upconversion emission, upon excitation at 976 nm, are evaluated as a function of the Er3+ concn. For the lowest Er3+ content, 1.5 μm emission quantum efficiency was 90%. Increasing the Er3+ concn. up to 2 mol%, the emission quantum efficiency decreases to 37% due to concn. quenching. The green and red upconversion emission intensity ratio was studied as a function of Yb3+ co-doping and the Er3+-Er3+ energy transfer processes.
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    39. 39
      Tosello, C.; Rossi, F.; Ronchin, S.; Rolli, R.; Righini, G.; Pozzi, F.; Pelli, S.; Fossi, M.; Moser, E.; Montagna, M.; Ferrari, M.; Duverger, C.; Chiappini, A.; De Bernardi, C. Erbium-Activated Silica–Titania Planar Waveguides on Silica-on-Silicon Substrates Prepared by Rf Sputtering. J. Non-Cryst. Solids Solids 2001, 284, 230– 236,  DOI: 10.1016/S0022-3093(01)00407-0
      39
      Erbium-activated silica-titania planar waveguides on silica-on-silicon substrates prepared by rf sputtering
      Tosello, C.; Rossi, F.; Ronchin, S.; Rolli, R.; Righini, G. C.; Pozzi, F.; Pelli, S.; Fossi, M.; Moser, E.; Montagna, M.; Ferrari, M.; Duverger, C.; Chiappini, A.; De Bernardi, C.
      Journal of Non-Crystalline Solids (2001), 284 (1-3), 230-236CODEN: JNCSBJ; ISSN:0022-3093. (Elsevier Science B.V.)
      Er-activated SiO2-TiO2 planar waveguides were prepd. by radiofrequency (rf) sputtering technique. SiO2-on-Si substrates obtained by plasma-enhanced CVD (PECVD) and radiofrequency sputtering (RFS) were employed. The refractive indexes, the thickness and the propagation losses of the waveguides were measured. The refractive index and the roughness of the SiO2 substrates produced by RFS appear to be dependent on the thickness. Thermal annealing, which is a necessary condition to obtain light propagation, induces a decrease of the refractive index in the SiO2 substrates. The waveguide deposited on PECVD substrate exhibits several propagating modes with an attenuation coeff. 1.7 dB/cm compared with 12.2 dB/cm measured for the waveguide deposited on SiO2 substrate produced by RFS technique. Emission of the 4I13/2 - 4I15/2 transition with a 53 nm bandwidth was obsd.
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    40. 40
      Huang, A. P.; Chu, P. K. Crystallization Improvement of Ta2O5 Thin Films by the Addition of Water Vapor. J. Cryst. Growth 2005, 274, 73– 77,  DOI: 10.1016/j.jcrysgro.2004.10.004
      40
      Crystallization improvement of Ta2O5 thin films by the addition of water vapor
      Huang, A. P.; Chu, Paul K.
      Journal of Crystal Growth (2005), 274 (1-2), 73-77CODEN: JCRGAE; ISSN:0022-0248. (Elsevier B.V.)
      By the addn. of water vapor into the working gas, cryst. Ta2O5 thin films can be fabricated at low substrate temps. At 500°, by the addn. of water vapor, the crystallinity of the thin films was obviously improved. The grains with tetragonal structure were clearly obsd. by AFM. Total transmission greater than 85% was achieved between wavelengths of 400 and 800 nm and the optical absorption edge of the thin films also shifted to smaller wavelength. The crystallinity of the thin films can be improved and the crystd. temp. can be decreased with the introduction of water vapor in the fabrication process. The effects of water vapor on the crystn. of Ta2O5 thin films are discussed in details.
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    41. 41
      Chiasera, A.; Tosello, C.; Moser, E.; Montagna, M.; Belli, R.; Gonçalves, R. R.; Righini, G. C.; Pelli, S.; Chiappini, A.; Zampedri, L.; Ferrari, M. Er3+/Yb3+-Activated Silica–Titania Planar Waveguides for EDPWAs Fabricated by Rf-Sputtering. J. Non-Cryst. Solids 2003, 322, 289– 294,  DOI: 10.1016/S0022-3093(03)00217-5
      41
      Er3+/Yb3+-activated silica-titania planar waveguides for EDPWAs fabricated by rf-sputtering
      Chiasera, A.; Tosello, C.; Moser, E.; Montagna, M.; Belli, R.; Goncalves, R. R.; Righini, G. C.; Pelli, S.; Chiappini, A.; Zampedri, L.; Ferrari, M.
      Journal of Non-Crystalline Solids (2003), 322 (1-3), 289-294CODEN: JNCSBJ; ISSN:0022-3093. (Elsevier Science B.V.)
      Two Er3+/Yb3+-codoped 92SiO2-8TiO2 planar waveguides, with 1.2 mol% Er and molar ratio Er/Yb of 2, were fabricated by radiofrequency-sputtering technique. The active films were deposited on SiO2-on-Si and SiO2 glass substrates. The thickness of the waveguides and the refractive index at 632.8 and 543.5 nm were measured by an m-line app. The losses, for the TE0 mode, were evaluated at 632.8 and 1300 nm. The structural properties were studied by energy dispersive spectroscopy and Raman spectroscopy. All waveguides were single-mode at 1550 nm. An attenuation coeff. of 0.5 dB/cm at 632.8 nm and 0.1 dB/cm at 1300 nm were measured. The emission at 1530 nm of the 4I13/2 4I15/2 transition of Er3+ ion was obsd. at room temp. upon continuous wave excitation at 981 and 514.5 nm. Back energy transfer from Er3+ to Yb3+ was demonstrated by measurement of Yb3+ emission upon Er3+ excitation at 514.5 nm. Effective excitation efficiency of Er3+ ions by co-doping with Yb3+ ions was shown by photoluminescence excitation spectroscopy.
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    42. 42
      Gonçalves, R. R.; Carturan, G.; Zampedri, L.; Ferrari, M.; Montagna, M.; Chiasera, A.; Righini, G. C.; Pelli, S.; Ribeiro, S. J. L.; Messaddeq, Y. Sol-Gel Er-Doped SiO2–HfO2 Planar Waveguides: A Viable System for 1.5 Mm Application. Appl. Phys. Lett. 2002, 81, 28– 30,  DOI: 10.1063/1.1489477
      42
      Sol-gel Er-doped SiO2-HfO2 planar waveguides: A viable system for 1.5 μm application
      Goncalves, R. R.; Carturan, G.; Zampedri, L.; Ferrari, M.; Montagna, M.; Chiasera, A.; Righini, G. C.; Pelli, S.; Ribeiro, S. J. L.; Messaddeq, Y.
      Applied Physics Letters (2002), 81 (1), 28-30CODEN: APPLAB; ISSN:0003-6951. (American Institute of Physics)
      70SiO2-30HfO2 planar waveguides, doped with Er3+ concns. ranging from 0.3 to 1 mol.%, were prepd. by sol-gel route, using dip-coating deposition on silica glass substrates. The waveguides show high densification degree, effective intermingling of the two components of the film, and uniform surface morphol. Propagation losses of about 1 dB/cm were measured at 632.8 nm. When pumped with 987 or 514.5 nm continuous-wave laser light, the waveguides show the 4I13/2 4I15/2 emission band with a bandwidth of 48 nm. The spectral features are found independent both on erbium content and excitation wavelength. The 4I13/2 level decay curves presented a single-exponential profile, with a lifetime between 2.9 and 5.0 ms, depending on the erbium concn.
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    43. 43
      Cunha, C. D. S.; Ferrari, J. L.; De Oliveira, D. C.; Maia, L. J. Q.; Gomes, A. S. L.; Ribeiro, S. J. L.; Gonçalves, R. R. NIR Luminescent Er3+/Yb3+Co-Doped SiO<inf>2</Inf>-ZrO<inf>2</Inf>nanostructured Planar and Channel Waveguides: Optical and Structural Properties. Mater. Chem. Phys. 2012, 136, 120– 129,  DOI: 10.1016/j.matchemphys.2012.06.040
      43
      NIR luminescent Er3+/Yb3+ co-doped SiO2-ZrO2 nanostructured planar and channel waveguides: Optical and structural properties
      Cunha, Cesar dos Santos; Ferrari, Jefferson Luis; de Oliveira, Drielly Cristina; Maia, Lauro June Queiroz; Gomes, Anderson Stevens Leonidas; Ribeiro, Sidney Jose Lima; Goncalves, Rogeria Rocha
      Materials Chemistry and Physics (2012), 136 (1), 120-129CODEN: MCHPDR; ISSN:0254-0584. (Elsevier B.V.)
      Optical and structural properties of planar and channel waveguides based on sol-gel Er3+ and Yb3+ co-doped SiO2-ZrO2 are reported. Microstructured channels with high homogeneous surface profile were written onto the surface of multilayered densified films deposited on SiO2/Si substrates by a femtosecond laser etching technique. The densification of the planar waveguides was evaluated from changes in the refractive index and thickness, with full densification being achieved at 900° after annealing from 23 up to 500 min, depending on the ZrO2 content. Crystal nucleation and growth took place together with densification, thereby producing transparent glass ceramic planar waveguides contg. rare earth-doped ZrO2 nanocrystals dispersed in a SiO2-based glassy host. Low roughness and crack-free surface as well as high confinement coeff. were achieved for all the compns. Enhanced NIR luminescence of the Er3+ ions was obsd. for the Yb3+-codoped planar waveguides, denoting an efficient energy transfer from the Yb3+ to the Er3+ ion.
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    44. 44
      Thu Huong, T.; Kim Anh, T.; Hoai Nam, M.; Barthou, C.; Strek, W.; Quoc Minh, L. Preparation and Infrared Emission of Silica–Zirconia–Alumina Doped with Erbium for Planar Waveguide. J. Lumin. 2007, 122–123, 911– 913,  DOI: 10.1016/j.jlumin.2006.01.324
      There is no corresponding record for this reference.
    45. 45
      Stephenson, N. C.; Roth, R. S. The Crystal Structure of the High Temperature Form of Ta2O5. J. Solid State Chem. 1971, 3, 145– 153,  DOI: 10.1016/0022-4596(71)90018-1
      45
      Crystal structure of the high temperature form of tantalum pentoxide
      Stephenson, N. C.; Roth, R. S.
      Journal of Solid State Chemistry (1971), 3 (2), 145-53CODEN: JSSCBI; ISSN:0022-4596.
      The structure of the high-temp. form of Ta2O5 can be stabilized by doping with 2 mole % Sc2O3, and single crystals have been prepd. from a Ta2O5-Sc2O3 (98:2) compn. by the Czochralski technique. The crystal system which at first appeared to be body-centered tetragonal has been detd. to be face-centered monoclinic, space group C2 with a = 35.966, b = 3.810, c = 3.810 Å, β = 96°7'. Least-squares refinement cycles reduced the reliability index R to 0.089. The structure consists of α-UO3-type blocks in which each Ta atom is surrounded by a pentagonal bipyramid of O atoms. These blocks are infinite in 2 directions and are sepd. from similar blocks along a 3rd direction by shear planes. In the vicinity of these shear planes, the Ta atoms are surrounded by distorted octahedral coordination polyhedra. The stabilizing effect of the Sc2O3 impurity is probably due to an increase in the concn. of shear planes. Random shear planes (Wadsley defects) are introduced at ∼300 Å intervals along the large axis by doping with a substance (Sc2O3) that has cations (Sc) large enough to substitute for the host (Ta) but a lower O:metal ratio than the host compd. (Ta2O5).
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