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Cascade Reaction-Based Chemiresistive Array for Ethylene Sensing

Cite this: ACS Sens. 2020, 5, 5, 1405–1410
Publication Date (Web):May 11, 2020
https://doi.org/10.1021/acssensors.0c00194
Copyright © 2020 American Chemical Society
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    Abstract

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    Chemiresistive sensors, which are based on semiconducting materials, offer real-time monitoring of environment. However, detection of nonpolar chemical substances is often challenging because of the weakness of the doping effect. Herein, we report a concept of combining a cascade reaction (CR) and a chemiresistive sensor array for sensitive and selective detection of a target analyte (herein, ethylene in air). Ethylene was converted to acetaldehyde through a Pd-catalyzed heterogeneous Wacker reaction at 40 °C, followed by condensation with hydroxylamine hydrochloride to emit HCl vapor. HCl works as a strong dopant for single-walled carbon nanotubes (SWCNTs), enabling the main sensor to detect ethylene with excellent sensitivity (10.9% ppm–1) and limit of detection (0.2 ppm) in 5 min. False responses that occur in the main sensor are easily discriminated by reference sensors that partially employ CR. Moreover, though the sensor monitors the variation of normalized electric resistance (ΔR/R0) in the SWCNT network, temporary deactivation of CR yields a sensor system that does not require analyte-free air for a baseline correction (i.e., estimation of R0) and recovery of response. The concept presented here is generally applicable and offers a solution for several issues that are inherently present in chemiresistive sensing systems.

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    Cited By

    This article is cited by 13 publications.

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    9. Masaki Yumoto, Yasushi Kawata, Tetsuya Abe, Tomoki Matsuyama, Satoshi Wada. Non-destructive mid-IR spectroscopy with quantum cascade laser can detect ethylene gas dynamics of apple cultivar ‘Fuji’ in real time. Scientific Reports 2021, 11 (1) https://doi.org/10.1038/s41598-021-00254-1
    10. Xin Li, Yanli Lu, Qingjun Liu. Electrochemical and optical biosensors based on multifunctional MXene nanoplatforms: Progress and prospects. Talanta 2021, 235 , 122726. https://doi.org/10.1016/j.talanta.2021.122726
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