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Fast and Facile Room-Temperature Synthesis of MOF-Derived Co Nanoparticle/Nitrogen-Doped Porous Graphene in Air Atmosphere for Overall Water Splitting

  • Guang Yang
    Guang Yang
    Key Laboratory of Nanobiosensing and Nanobioanalysis at Universities of Jilin Province, Faculty of Chemistry, Northeast Normal University, Changchun 130024, Jilin, P. R. China
    More by Guang Yang
  • , 
  • Jingju Liu
    Jingju Liu
    Key Laboratory of Nanobiosensing and Nanobioanalysis at Universities of Jilin Province, Faculty of Chemistry, Northeast Normal University, Changchun 130024, Jilin, P. R. China
    More by Jingju Liu
  • , 
  • Ming Zhou*
    Ming Zhou
    Key Laboratory of Nanobiosensing and Nanobioanalysis at Universities of Jilin Province, Faculty of Chemistry, Northeast Normal University, Changchun 130024, Jilin, P. R. China
    Guangdong Provincial Key Laboratory of Energy Materials for Electric Power, Southern University of Science and Technology, Shenzhen 518055, Guangdong, P. R. China
    *E-mail: [email protected]
    More by Ming Zhou
    Orcidhttp://orcid.org/0000-0003-2239-9342
  • , 
  • Jing Bai*
    Jing Bai
    Key Laboratory of Nanobiosensing and Nanobioanalysis at Universities of Jilin Province, Faculty of Chemistry, Northeast Normal University, Changchun 130024, Jilin, P. R. China
    *E-mail: [email protected]
    More by Jing Bai
  • , and 
  • Xiangjie Bo*
    Xiangjie Bo
    Key Laboratory of Nanobiosensing and Nanobioanalysis at Universities of Jilin Province, Faculty of Chemistry, Northeast Normal University, Changchun 130024, Jilin, P. R. China
    *E-mail: [email protected]
    More by Xiangjie Bo
    Orcidhttp://orcid.org/0000-0002-0407-0976
Cite this: ACS Sustainable Chem. Eng. 2020, 8, 32, 11947–11955
Publication Date (Web):July 21, 2020
https://doi.org/10.1021/acssuschemeng.0c01008
Copyright © 2020 American Chemical Society
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    Abstract

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    Generally, metal–organic framework (MOF)-derived electrocatalysts are prepared by thermal pyrolysis at high temperatures of around 600–900 °C and in inert atmosphere. Herein we introduce a laser-induced method for preparation of MOF-derived Co nanoparticle/nitrogen-doped porous graphene (Co/PNG) at room temperature and in air atmosphere. Through a laser scribing method, the organic complex is converted into nitrogen-doped graphene (PNG) and meanwhile the decomposition of the organic linker yields a reductive chemical atmosphere. This reductive atmosphere and high energy at the local position of laser irradiation allows the reduction of Co ions into atomic Co species and in turn enables the formation of Co/PNG. In addition, the flexible polyimide (PI) film-supported Co/PNG could be directly used as an electrode for electrocatalysis without the requirement of any binder. The electrocatalytic activity of the obtained electrode could be easily controlled by adjusting the power or the loading of MOFs. The electrocatalytic result indicates that Co/PNG shows satisfying activity and stability for water electrolysis. With the porous properties and Co–Nx active sites, the flexible electrode shows overpotentials of 131, 335, and 380 mV for hydrogen, oxygen evolution reaction, and overall water splitting reaction.

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acssuschemeng.0c01008.

    • SEM image of precursors and different loading amounts, optimization of loading amount and laser power, Cdl test, optical photograph of overall water splitting, flexibility study, electrode fabrication, and table for comparing the performance and preparative method (PDF)

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