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Methane Hydrate Growth Promoted by Microporous Zeolitic Imidazolate Frameworks ZIF-8 and ZIF-67 for Enhanced Methane Storage

Cite this: ACS Sustainable Chem. Eng. 2021, 9, 27, 9001–9010
Publication Date (Web):June 28, 2021
https://doi.org/10.1021/acssuschemeng.1c01488
Copyright © 2021 American Chemical Society

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    Abstract

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    The demand for natural gas globally is rising due to the need for energy caused by population and economic growth. This demand calls for more effective approaches to store and transport natural gas, which consists primarily of methane. Gas hydrates, ice-like materials that encapsulate gas molecules, possess the potential for high energy density. The feasibility of this methane storage method relies upon the efficiency of hydrate formation, which must be improved before it can be developed commercially. In this study, two microporous zeolitic imidazolate frameworks, ZIF-8 (zinc based) and ZIF-67 (cobalt based), were evaluated as methane hydrate formation promoters. ZIF-8 and ZIF-67 increased the water-to-hydrate conversion in a water-and-methane system from 4.5% to 85.6% and 87.7%, respectively, thus remarkably improving the gas storage by a factor of 14.4 and 14.7, respectively. Isothermal tests revealed that ZIF-8 and ZIF-67 reduced the methane hydrate nucleation induction time by 51.6% and 92.2%, respectively. Both ZIFs maintained their structural integrity and exhibited consistent recyclability, which indicates that the materials would have a long lifecycle as promoters. These results show that ZIF-8 and ZIF-67 are effective gas hydrate growth promoters, and application of these ZIFs makes methane storage in gas hydrates industrially appealing.

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    • Table summarizing literature review of MOFs as methane hydrate growth promoters, schematic of the high pressure differential scanning calorimeter (HP-DSC), full HP-DSC cooling and warming profiles, methane adsorption isotherms, water-to-hydrate conversion for three cycles of ZIF-8 (PDF)

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    4. Abdolreza Farhadian, Ulukbek Zh. Mirzakimov, Matvei E. Semenov, Mina Maddah, Yulia F. Chirkova, Roman S. Pavelyev, Atousa Heydari, Sergei A. Nazarychev, Aleksandr M. Aimaletdinov, Mikhail A. Varfolomeev. Solidified Methane Storage Using an Efficient Class of Anionic Surfactants under Dynamic and Static Conditions: An Experimental and Computational Investigation. ACS Applied Energy Materials 2023, 6 (8) , 4119-4132. https://doi.org/10.1021/acsaem.2c03240
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    7. M. Fahed Qureshi, Vikas Dhamu, Adam Usadi, Timothy A. Barckholtz, Ashish B. Mhadeshwar, Praveen Linga. CO2 Hydrate Formation Kinetics and Morphology Observations Using High-Pressure Liquid CO2 Applicable to Sequestration. Energy & Fuels 2022, 36 (18) , 10627-10641. https://doi.org/10.1021/acs.energyfuels.1c03840
    8. Liang-Meng Wu, Xi-Yue Li, Feng-Mei Xie, Dong-Liang Zhong, Peter Englezos, Jin Yan. Minireview of Hydrate-Based CO2 Separation from a CO2/CH4 Gas Mixture: Progress and Outlook. Energy & Fuels 2022, 36 (18) , 10478-10488. https://doi.org/10.1021/acs.energyfuels.2c01533
    9. Ngoc N. Nguyen, Anh V. Nguyen. “Nanoreactors” for Boosting Gas Hydrate Formation toward Energy Storage Applications. ACS Nano 2022, 16 (8) , 11504-11515. https://doi.org/10.1021/acsnano.2c04640
    10. Yinghua Gong, Matvei E. Semenov, Dmitrii A. Emelianov, Airat G. Kiiamov, Kirill A. Cherednichenko, Andrei A. Novikov, Anton P. Semenov, Tianduo Li, Vladimir Vinokurov, Andrey S. Stoporev. Carriers for Methane Hydrate Production: Cellulose-Based Materials as a Case Study. ACS Sustainable Chemistry & Engineering 2022, 10 (31) , 10119-10131. https://doi.org/10.1021/acssuschemeng.2c00791
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    13. Shurraya Denning, Ahmad A. A. Majid, Carolyn A. Koh. Stability and Growth of Methane Hydrates in Confined Media for Carbon Sequestration. The Journal of Physical Chemistry C 2022, 126 (28) , 11800-11809. https://doi.org/10.1021/acs.jpcc.2c02936
    14. Ngoc N. Nguyen, Cuong V. Nguyen, Tuan A. H. Nguyen, Anh V. Nguyen. Surface Science in the Research and Development of Hydrate-Based Sustainable Technologies. ACS Sustainable Chemistry & Engineering 2022, 10 (13) , 4041-4058. https://doi.org/10.1021/acssuschemeng.2c00028
    15. Shurraya Denning, Ahmad AA Majid, James M. Crawford, Moises A. Carreon, Carolyn A. Koh. Promoting Methane Hydrate Formation for Natural Gas Storage over Chabazite Zeolites. ACS Applied Energy Materials 2021, 4 (12) , 13420-13424. https://doi.org/10.1021/acsaem.1c02902
    16. Ahmad A. A. Majid, Joshua Worley, Carolyn A. Koh. Thermodynamic and Kinetic Promoters for Gas Hydrate Technological Applications. Energy & Fuels 2021, 35 (23) , 19288-19301. https://doi.org/10.1021/acs.energyfuels.1c02786
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    19. Nithin B. Kummamuru, Geert Watson, Radu-George Ciocarlan, Sammy W. Verbruggen, Pegie Cool, Pascal Van Der Voort, Patrice Perreault. Accelerated methane storage in clathrate hydrates using mesoporous (Organo-) silica materials. Fuel 2023, 354 , 129403. https://doi.org/10.1016/j.fuel.2023.129403
    20. Elaheh Sadeh, Abdolreza Farhadian, Abolfazl Mohammadi, Mina Maddah, Mahdi Pourfath, Mingjun Yang. Energy-efficient storage of methane and carbon dioxide capture in the form of clathrate hydrates using a novel non-foaming surfactant: An experimental and computational investigation. Energy Conversion and Management 2023, 293 , 117475. https://doi.org/10.1016/j.enconman.2023.117475
    21. Chen Chen, FengZe Ma, XiaoMing Wang, Li Li, Ying Miao, Yang Bai, Yan He, Fei Wang. Carbon nanotubes-based porous media constructed via 3D printing for methane hydrate formation. Fuel 2023, 349 , 128645. https://doi.org/10.1016/j.fuel.2023.128645
    22. Guodong Zhang, Zhe Liu, Yaning Kong, Fei Wang. Hydrate-based adsorption-hydration hybrid approach enhances methane storage in wet MIL-101(Cr)@AC under mild condition. Chemical Engineering Journal 2023, 472 , 145068. https://doi.org/10.1016/j.cej.2023.145068
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    28. Guodong Zhang, Zhe Liu, Daming Liu, Yan Lin, Fei Wang. Hydrate-based adsorption-hydration hybrid approach enhances methane storage density in ZIF-8@AC. Chemical Engineering Journal 2023, 455 , 140503. https://doi.org/10.1016/j.cej.2022.140503
    29. Saphir Venet, Hannelore Derluyn, Fabrice Guerton, Peter Moonen, Daniel Broseta, Ross Brown. Massive growth of a fibrous gas hydrate from surface macropores of an activated carbon. Chemical Engineering Science 2023, 265 , 118190. https://doi.org/10.1016/j.ces.2022.118190
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    33. Zhixia Deng, Shuanshi Fan, Yanhong Wang, Xuemei Lang, Gang Li. Enhance hydrates formation with stainless steel fiber for high capacity methane storage. Chinese Journal of Chemical Engineering 2022, 50 , 435-443. https://doi.org/10.1016/j.cjche.2022.07.028
    34. Shurraya Denning, Ahmad A.A. Majid, James M. Crawford, Jonathan D. Wells, Moises A. Carreon, Carolyn A. Koh. Methane storage scale-up using hydrates & metal organic framework HKUST-1 in a packed column. Fuel 2022, 325 , 124920. https://doi.org/10.1016/j.fuel.2022.124920
    35. Pengfei Wang, Ying Teng, Jinlong Zhu, Wancheng Bao, Songbai Han, Yun Li, Yusheng Zhao, Heping Xie. Review on the synergistic effect between metal–organic frameworks and gas hydrates for CH4 storage and CO2 separation applications. Renewable and Sustainable Energy Reviews 2022, 167 , 112807. https://doi.org/10.1016/j.rser.2022.112807
    36. Jun Duan, Qianchuan Li, Yue Fu, Shujun Chen, Yaxue Zhang, Dandan Liu. Accelerated formation of hydrate in size-varied ZIF-8 for CH4 storage by adsorption-hydration hybrid technology. Fuel 2022, 322 , 124266. https://doi.org/10.1016/j.fuel.2022.124266
    37. Liang Yang, Chunxiao Li, Junhua Pei, Xin Wang, Ni Liu, Yingming Xie, Guomin Cui, Daoping Liu. Enhanced clathrate hydrate phase change with open-cell copper foam for efficient methane storage. Chemical Engineering Journal 2022, 440 , 135912. https://doi.org/10.1016/j.cej.2022.135912
    38. Jie Wu, Tairen Long, Haiyan Wang, Jin-Xia Liang, Chun Zhu. Oriented External Electric Fields Regurating the Reaction Mechanism of CH4 Oxidation Catalyzed by Fe(IV)-Oxo-Corrolazine: Insight from Density Functional Calculations. Frontiers in Chemistry 2022, 10 https://doi.org/10.3389/fchem.2022.896944
    39. Zeyuan Wang, Jun Duan, Shujun Chen, Yue Fu, Xiangfu Li, Di Wang, Ming Zhang, Zhiqiang Zhang, Dandan Liu, Fenghao Wang. A review on high-density methane storage in confined nanospace by adsorption-hydration hybrid technology. Journal of Energy Storage 2022, 50 , 104195. https://doi.org/10.1016/j.est.2022.104195
    40. Chong Chen, Yun Li, Jilin Cao. Methane Hydrate Formation in Hollow ZIF-8 Nanoparticles for Improved Methane Storage Capacity. Catalysts 2022, 12 (5) , 485. https://doi.org/10.3390/catal12050485
    41. Ye Zhang, Gaurav Bhattacharjee, Mohana Dharshini Vijayakumar, Praveen Linga. Rapid and energy-dense methane hydrate formation at near ambient temperature using 1,3-dioxolane as a dual-function promoter. Applied Energy 2022, 311 , 118678. https://doi.org/10.1016/j.apenergy.2022.118678
    42. Zeyuan Wang, Jun Duan, Shujun Chen, Yue Fu, Yaxue Zhang, Di Wang, Jianlin Pei, Dandan Liu. Molecular insights into hybrid CH4 physisorption-hydrate growth in hydrophobic metal–organic framework ZIF-8: Implications for CH4 storage. Chemical Engineering Journal 2022, 430 , 132901. https://doi.org/10.1016/j.cej.2021.132901
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