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Iron Disilyl Complex as an Effective Catalyst for Hydrogenation of Unfunctionalized Multisubstituted Alkenes

  • Yoshinao Kobayashi
    Yoshinao Kobayashi
    Department of Applied Chemistry, School of Engineering Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8505, Japan
  •  and 
  • Yusuke Sunada*
    Yusuke Sunada
    Department of Applied Chemistry, School of Engineering Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8505, Japan
    Institute of Industrial Science, The University of Tokyo, 4-6-1 Komaba, Meguro-ku, Tokyo 153-8505, Japan
    *Email: [email protected]
Cite this: ACS Sustainable Chem. Eng. 2022, 10, 3, 1078–1082
Publication Date (Web):January 11, 2022
https://doi.org/10.1021/acssuschemeng.1c07822
Copyright © 2022 American Chemical Society

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    Abstract

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    The catalytic hydrogenation of various unfunctionalized alkenes by the iron disilyl complex Fe[Si(SiMe3)3]2(THF)2 was investigated. The catalytically active species can be generated in situ by simply mixing the commercially available precursors FeBr2, Si(SiMe3)4, and KOtBu to prepare a practical iron catalyst system in the absence of any pyrophoric reactive reagents.

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    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acssuschemeng.1c07822.

    • Additional experimental procedure details, additional experimental results, and 1H and 13C NMR data of the product (PDF)

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    Cited By

    This article is cited by 1 publications.

    1. Bradley A. Davis, Jeffrey A. Bennett, Jan Genzer, Kirill Efimenko, Milad Abolhasani. Intensified Hydrogenation in Flow Using a Poly(β-cyclodextrin) Network-Supported Catalyst. ACS Sustainable Chemistry & Engineering 2022, 10 (48) , 15987-15998. https://doi.org/10.1021/acssuschemeng.2c05467

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