ACS Publications. Most Trusted. Most Cited. Most Read
Monolayer CoMoS Anchored on Hydrophobic Reduced Graphene Nanoribbons for Efficient Hydrodeoxygenation

OR SEARCH CITATIONS

My Activity
Publications

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:ACS Sustainable Chem. Eng. 2024, 12, 47, 17135-17146
    Research Article

    Monolayer CoMoS Anchored on Hydrophobic Reduced Graphene Nanoribbons for Efficient Hydrodeoxygenation
    Click to copy article linkArticle link copied!

    • Cen Zhang
      Cen Zhang
      Department of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang, Hunan 414006, China
      More by Cen Zhang
      Orcidhttps://orcid.org/0000-0001-9833-6327
    • Tianyi Liu
      Tianyi Liu
      Department of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang, Hunan 414006, China
      More by Tianyi Liu
    • Siyan Zou
      Siyan Zou
      Department of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang, Hunan 414006, China
      More by Siyan Zou
    • Xinyi Liu
      Xinyi Liu
      Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, Liaoning 116023, China
      More by Xinyi Liu
    • Binbin Zhou*
      Binbin Zhou
      Department of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang, Hunan 414006, China
      *Email: [email protected]. Phone: + 86 730 8640122. Fax: +86 730 8640122.
      More by Binbin Zhou
      Orcidhttps://orcid.org/0000-0002-1754-7710
    • Jiali Mu*
      Jiali Mu
      Dalian National Laboratory for Clean Energy, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, Liaoning 116023, China
      *Email: [email protected]
      More by Jiali Mu
    • Jing Cao*
      Jing Cao
      Department of Chemistry and Chemical Engineering, Hunan Institute of Science and Technology, Yueyang, Hunan 414006, China
      *Email: [email protected]
      More by Jing Cao
      Orcidhttps://orcid.org/0000-0002-4961-0577
    Other Access OptionsSupporting Information (1)

    ACS Sustainable Chemistry & Engineering

    Cite this: ACS Sustainable Chem. Eng. 2024, 12, 47, 17135–17146
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acssuschemeng.4c05233
    Published November 14, 2024
    Copyright © 2024 American Chemical Society
    Request reuse permissions

    Abstract

    Click to copy section linkSection link copied!
    Abstract Image

    Improving both the activity and stability is of great importance for MoS2-based catalysts in the hydrodeoxygenation (HDO) reaction. Herein, we report the construction of monolayer CoMoS anchored on hydrophobic-reduced graphene nanoribbons (ML-CoMoS/rGNRs) which exhibited excellent activity and stability in the HDO of 4-methylphenol. The superior HDO activity was attributed to the single layer structure of MoS2, which allows the good exposure of abundant edge sites for accommodating Co promoters to form the Co–Mo–S active phase. Besides, the hydrophobicity of rGNRs enables the fast removal of H2O during the HDO reaction, which alleviates the sulfur loss and endows the excellent stability of supported CoMoS monolayers. Consequently, ML-CoMoS/rGNRs afforded 97.3% conversion and 98.4% toluene selectivity at 220 °C for at least five reaction cycles. This work provides novel insights for designing highly active and stable metal sulfide catalysts for the application in the HDO reaction.

    Copyright © 2024 American Chemical Society

    Subjects

    what are subjects

    Keywords

    what are keywords

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. Add or change your institution or let them know you’d like them to include access.

    Supporting Information

    Click to copy section linkSection link copied!

    The Supporting Information is available free of charge at https://pubs.acs.org/doi/10.1021/acssuschemeng.4c05233.

    • Equations for calculating the Mo dispersion (fMo), average slab length (Lav), and average layer number (Nav) of MoS2 particles; XAFS characterization details; contact angle of B-CoMoS; TEM images and EPR spectra of B-CoMoS, FL-CoMoS/rGNRs, and ML-CoMoS/rGNRs; EXAFS fitting parameters; reaction routes in the HDO of 4-methylphenol; stability test of B-CoMoS; and HDO performance of other lignin-derived phenolic compounds on ML-CoMoS/rGNRs (PDF)

    Terms & Conditions

    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    Click to copy section linkSection link copied!

    This article has not yet been cited by other publications.

    Download PDF
    Go to ACS Sustainable Chemistry & Engineering
    Get e-Alerts
    Get e-Alerts

    ACS Sustainable Chemistry & Engineering

    Cite this: ACS Sustainable Chem. Eng. 2024, 12, 47, 17135–17146
    Click to copy citationCitation copied!
    https://doi.org/10.1021/acssuschemeng.4c05233
    Published November 14, 2024
    Copyright © 2024 American Chemical Society
    Request reuse permissions

    Article Views

    177

    Altmetric

    -

    Citations

    -
    Learn about these metrics

    Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.

    Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.

    The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.