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Increase of Ceria Redox Ability by Lanthanum Addition on Ni Based Catalysts for Hydrogen Production

  • Cristina Pizzolitto
    Cristina Pizzolitto
    CATMAT Lab, Department of Molecular Sciences and Nanosystems, Ca’ Foscari University Venice and INSTM RU of Venice, via Torino 155, I-30172 Venezia, Mestre, Italy
  • Federica Menegazzo
    Federica Menegazzo
    CATMAT Lab, Department of Molecular Sciences and Nanosystems, Ca’ Foscari University Venice and INSTM RU of Venice, via Torino 155, I-30172 Venezia, Mestre, Italy
  • Elena Ghedini
    Elena Ghedini
    CATMAT Lab, Department of Molecular Sciences and Nanosystems, Ca’ Foscari University Venice and INSTM RU of Venice, via Torino 155, I-30172 Venezia, Mestre, Italy
  • Giada Innocenti
    Giada Innocenti
    Department of Industrial Chemistry “Toso Montanari”, University of Bologna, viale Risorgimento 4, I-40136 Bologna, Italy
    Consorzio INSTM, UdR di Bologna, Firenze, Italy
  • Alessandro Di Michele
    Alessandro Di Michele
    Department of Physics and Geology, University of Perugia, Via Pascoli 1, I-06123, Perugia, Italy
  • Giuseppe Cruciani
    Giuseppe Cruciani
    Department of Physics and Earth Sciences, University of Ferrara, Via Saragat 1, I-44122 Ferrara, Italy
  • Fabrizio Cavani
    Fabrizio Cavani
    Department of Industrial Chemistry “Toso Montanari”, University of Bologna, viale Risorgimento 4, I-40136 Bologna, Italy
    Consorzio INSTM, UdR di Bologna, Firenze, Italy
  • , and 
  • Michela Signoretto*
    Michela Signoretto
    CATMAT Lab, Department of Molecular Sciences and Nanosystems, Ca’ Foscari University Venice and INSTM RU of Venice, via Torino 155, I-30172 Venezia, Mestre, Italy
    *E-mail: [email protected]
Cite this: ACS Sustainable Chem. Eng. 2018, 6, 11, 13867–13876
Publication Date (Web):October 4, 2018
https://doi.org/10.1021/acssuschemeng.8b02103
Copyright © 2018 American Chemical Society

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    Abstract

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    The effects of lanthanum addition in Ni/CeO2 catalysts were investigated. The influence of synthetic procedures, namely, impregnation or coprecipitation of lanthanum and cerium oxide, were evaluated. Materials were analyzed by BET, AAS, DRIFT-MS, TPR, OSC, XRD, and SEM-EDX. Samples were tested in ethanol steam reforming (ESR). Both lanthanum-promoted samples exhibited a higher stability in time than nonpromoted catalyst. Nonetheless, catalytic behavior is strongly affected by the preparation method. TPR, OSC, and XRD analyses showed that the coprecipitation method allowed the best interaction between ceria and lanthana, leading to an increased redox ability and best catalytic performances as a result. A catalyst with a support prepared via the coprecipitation method showed ethanol conversion of 90% and hydrogen selectivity higher than 70% even after 60 h of reaction.

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    • Mass analyses of both support and catalysts feeding ethanol and the hypothesized surface (PDF)

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