Nickel Metal–Organic Framework Derived Hierarchically Mesoporous Nickel Phosphate toward Smoke Suppression and Mechanical Enhancement of Intumescent Flame Retardant Wood Fiber/Poly(lactic acid) CompositesClick to copy article linkArticle link copied!
- Lu ZhangLu ZhangIMDEA Materials Institute, Calle Eric Kandel, 2, 28906 Getafe, Madrid, SpainMore by Lu Zhang
- Siqi ChenSiqi ChenIMDEA Materials Institute, Calle Eric Kandel, 2, 28906 Getafe, Madrid, SpainSchool of Material Science and Engineering, Tongji University, Cao’an Road 4800, Jiading District, 201804 Shanghai, People’s Republic of ChinaMore by Siqi Chen
- Ye-Tang PanYe-Tang PanIMDEA Materials Institute, Calle Eric Kandel, 2, 28906 Getafe, Madrid, SpainMore by Ye-Tang Pan
- Shuidong ZhangShuidong ZhangSchool of Mechanical and Automotive Engineering, South China University of Technology, Wushan Road 381, Tianhe District, 510640 Guangzhou, People’s Republic of ChinaMore by Shuidong Zhang
- Shibin NieShibin NieSchool of Mining and Safety Engineering, Anhui University of Science and Technology, Taifeng Road 168, 232001 Huainan, People’s Republic of ChinaMore by Shibin Nie
- Ping Wei
- Xiuqin ZhangXiuqin ZhangSchool of Materials Science and Technology, Beijing Institute of Fashion Technology, Yinghuayuan East Street A 2, Chaoyang District, 100096 Beijing, People’s Republic of ChinaMore by Xiuqin Zhang
- Rui WangRui WangSchool of Materials Science and Technology, Beijing Institute of Fashion Technology, Yinghuayuan East Street A 2, Chaoyang District, 100096 Beijing, People’s Republic of ChinaMore by Rui Wang
- De-Yi Wang*De-Yi Wang*Tel.: 0034-917871888. E-mail: [email protected]IMDEA Materials Institute, Calle Eric Kandel, 2, 28906 Getafe, Madrid, SpainMore by De-Yi Wang
Abstract

Over the past decade, the use of metal–organic framework derived materials has emerged as a novel direction to prepare high performance polymer composites. In this work, nickel based metal–organic framework (Ni-MOF) was synthesized via a cost-effective and environmentally acceptable approach. Ni-MOF derived hierarchically mesoporous nickel phosphate was prepared via a facile hydrothermal method. Morphological evolution from Ni-MOF to nickel phosphate during the synthesis was clearly revealed. The microsized rod-like nickel phosphate was evaluated in both smoke suppression and mechanical enhancement of intumescent flame retardant wood fiber/poly(lactic acid) system. The cone calorimeter test showed a 43% reduction in total smoke production when 5 wt % ammonium polyphosphate was substituted by nickel phosphate. More importantly, both tensile and impact strength of the composites were improved with the addition of nickel phosphate. The as-synthesized nickel phosphate proved to be a promising substitution for ammonium polyphosphate in wood fiber/poly(lactic acid) composites.
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