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Structural and Nanomechanical Properties of Paperboard Coatings Studied by Peak Force Tapping Atomic Force Microscopy

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KTH Royal Institute of Technology, School of Chemical Science and Engineering, Department of Chemistry, Surface and Corrosion Science, Drottning Kristinas väg 51, SE-100 44 Stockholm, Sweden
VTT Technical Research Centre of Finland, Functional Fibre Products, Biologinkuja 7, Espoo, PL 1000, FI-02044 VTT, Finland
§ YKI Institute of Surface Chemistry, P.O. Box 5707, SE-114 86 Stockholm, Sweden
*Fax: +46(0)8208284. Tel: +46(0)87909920. E-mail: [email protected]
Cite this: ACS Appl. Mater. Interfaces 2012, 4, 10, 5534–5541
Publication Date (Web):September 13, 2012
https://doi.org/10.1021/am301439k
Copyright © 2012 American Chemical Society
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Abstract

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Paper coating formulations containing starch, latex, and clay were applied to paperboard and have been investigated by scanning electron microscopy and Peak Force tapping atomic force microscopy. A special focus has been on the measurement of the variation of the surface topography and surface material properties with a nanometer scaled spatial resolution. The effects of coating composition and drying conditions were investigated. It is concluded that the air-coating interface of the coating is dominated by close-packed latex particles embedded in a starch matrix and that the spatial distribution of the different components in the coating can be identified due to their variation in material properties. Drying the coating at an elevated temperature compared to room temperature changes the surface morphology and the surface material properties due to partial film formation of latex. However, it is evident that the chosen elevated drying temperature and exposure time is insufficient to ensure complete film formation of the latex which in an end application will be needed.

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