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Use of Free Radicals on the Surface of Plasma Polymer for the Initiation of a Polymerization Reaction

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Institute of Research in Science and Engineering of Materials, University of Mons - UMONS, Place du Parc, 23, 7000 Mons, Belgium
Cite this: ACS Appl. Mater. Interfaces 2013, 5, 22, 11569–11577
Publication Date (Web):October 22, 2013
https://doi.org/10.1021/am402364j
Copyright © 2013 American Chemical Society
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Abstract

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A novel approach to functionalize plasma polymer films (PPFs) through the grafting polymerization initiated from free radicals trapped in the film was developed in this work. 2-Ethylhexyl acrylate (EHA) was chosen as radically polymerizable monomer given the wide use of its corresponding polymer in coating and adhesive applications. The occurrence of the grafting was first confirmed by time-of-flight secondary ion mass spectrometry (ToF-SIMS) and X-ray photoelectron spectroscopy (XPS). Then grafted chains were studied in more detail. The thickness of grafted chains was quantitatively estimated by angle-resolved XPS (ARXPS), while their morphology and interfacial behavior were qualitatively investigated by atomic force microscopy (AFM), contact angle measurements, and quartz crystal microbalance (QCM). The latter technique provided additional insights regarding the swelling behavior of the grafted layer and its stability upon exposure to challenging environments. Reported scientific findings suggest to use this approach for the covalent binding of a very thin layer on the top surface of a PPF without affecting its bulk properties.

Cited By


This article is cited by 13 publications.

  1. Farid Khelifa, Sergey Ershov, Youssef Habibi, Rony Snyders, and Philippe Dubois . Free-Radical-Induced Grafting from Plasma Polymer Surfaces. Chemical Reviews 2016, 116 (6) , 3975-4005. https://doi.org/10.1021/acs.chemrev.5b00634
  2. Rackel Reis, Ludovic F. Dumée, Li He, Fenghua She, John D. Orbell, Bjorn Winther-Jensen, and Mikel C. Duke . Amine Enrichment of Thin-Film Composite Membranes via Low Pressure Plasma Polymerization for Antimicrobial Adhesion. ACS Applied Materials & Interfaces 2015, 7 (27) , 14644-14653. https://doi.org/10.1021/acsami.5b01603
  3. Sergey Ershov, Farid Khelifa, Vincent Lemaur, Jérôme Cornil, Damien Cossement, Youssef Habibi, Philippe Dubois, and Rony Snyders . Free Radical Generation and Concentration in a Plasma Polymer: The Effect of Aromaticity. ACS Applied Materials & Interfaces 2014, 6 (15) , 12395-12405. https://doi.org/10.1021/am502255p
  4. Melanie MacGregor, Ujala Sinha, Rahul M. Visalakshan, Alex Cavallaro, Krasimir Vasilev. Preserving the reactivity of coatings plasma deposited from oxazoline precursors − An in depth study. Plasma Processes and Polymers 2019, 16 (2) , 1800130. https://doi.org/10.1002/ppap.201800130
  5. Kouhei Orihara, Atsushi Hikichi, Tomohiko Arita, Hitoshi Muguruma, Yasuo Yoshimi. Heparin molecularly imprinted polymer thin flm on gold electrode by plasma-induced graft polymerization for label-free biosensor. Journal of Pharmaceutical and Biomedical Analysis 2018, 151 , 324-330. https://doi.org/10.1016/j.jpba.2018.01.012
  6. Solmaz Saboohi, Hans J. Griesser, Bryan R. Coad, Robert D. Short, Andrew Michelmore. Promiscuous hydrogen in polymerising plasmas. Physical Chemistry Chemical Physics 2018, 20 (10) , 7033-7042. https://doi.org/10.1039/C7CP08166A
  7. Mohammad Aref Khalily, Hakan Usta, Mehmet Ozdemir, Gokhan Bakan, F. Begum Dikecoglu, Charlotte Edwards-Gayle, Jessica A. Hutchinson, Ian W. Hamley, Aykutlu Dana, Mustafa O. Guler. The design and fabrication of supramolecular semiconductor nanowires formed by benzothienobenzothiophene (BTBT)-conjugated peptides. Nanoscale 2018, 10 (21) , 9987-9995. https://doi.org/10.1039/C8NR01604F
  8. . Acrylates and Methacrylates: Radical Polymerization. 2016,,, 1-13. https://doi.org/10.1081/E-EPLT-120053955
  9. Anton Manakhov, Ekaterina Makhneva, Petr Skládal, David Nečas, Jan Čechal, Lukáš Kalina, Marek Eliáš, Lenka Zajíčková. The robust bio-immobilization based on pulsed plasma polymerization of cyclopropylamine and glutaraldehyde coupling chemistry. Applied Surface Science 2016, 360 , 28-36. https://doi.org/10.1016/j.apsusc.2015.10.178
  10. S. Ershov, F. Khelifa, M.-E. Druart, Y. Habibi, M.-G. Olivier, R. Snyders, P. Dubois. Free radical-induced grafting from plasma polymers for the synthesis of thin barrier coatings. RSC Advances 2015, 5 (19) , 14256-14265. https://doi.org/10.1039/C4RA16424E
  11. Farid Khelifa, Sergey Ershov, Marie-Eve Druart, Youssef Habibi, Didier Chicot, Marie-Georges Olivier, Rony Snyders, Philippe Dubois. A multilayer coating with optimized properties for corrosion protection of Al. Journal of Materials Chemistry A 2015, 3 (31) , 15977-15985. https://doi.org/10.1039/C5TA01920F
  12. Yoann Ladner, Fanny D'Orlyé, Camille Perréard, Bradley Da Silva, Cédric Guyon, Michael Tatoulian, Sophie Griveau, Fethi Bedioui, Anne Varenne. Surface Functionalization by Plasma Treatment and Click Chemistry of a New Family of Fluorinated Polymeric Materials for Microfluidic Chips. Plasma Processes and Polymers 2014, 11 (6) , 518-523. https://doi.org/10.1002/ppap.201300120
  13. Samuel A. Pendergraph, Gregor Klein, Mats K. G. Johansson, Anna Carlmark. Mild and rapid surface initiated ring-opening polymerisation of trimethylene carbonate from cellulose. RSC Advances 2014, 4 (40) , 20737. https://doi.org/10.1039/c4ra01788a

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