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Novel Composite Material [email protected](Cr): A Highly Efficient Electrocatalyst for Ascorbic Acid Oxidation

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† REQUIMTE, Departamento de Química e Bioquímica, Faculdade de Ciências, Universidade do Porto, 4169-007 Porto, Portugal
‡ Departamento de Química e Bioquímica, CQB, Faculdade de Ciências, Universidade de Lisboa, Campo Grande C8, 1749-016 Lisboa, Portugal
*E-mail: [email protected]
*E-mail: [email protected]
Cite this: ACS Appl. Mater. Interfaces 2013, 5, 24, 13382–13390
Publication Date (Web):December 5, 2013
https://doi.org/10.1021/am4042564
Copyright © 2013 American Chemical Society
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Abstract

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A novel hybrid composite material, PMo10V2@MIL-101 was prepared by the encapsulation of the tetra-butylammonium (TBA) salt of the vanadium-substituted phosphomolybdate [PMo10V2O40]5– (PMo10V2) into the porous metal-organic framework (MOF) MIL-101(Cr). The materials characterization by powder X-ray diffraction, Fourier transform infrared spectra and scanning electron microscopy confirmed the preparation of the composite material without disruption of the MOF porous structure. Pyrolytic graphite electrodes modified with the original components (MIL-101(Cr), PMo10V2), and the composite material PMo10V2@MIL-101 were prepared and their electrochemical responses were studied by cyclic voltammetry. Surface confined redox processes were observed for all the immobilized materials. MIL-101(Cr) showed one-electron reduction process due to chromium centers (CrIII→CrII), while PMo10V2 presented five reduction processes: the peak at more positive potentials is attributed to two superimposed 1-electron vanadium reduction processes (VV→VIV) and the other four peaks to Mo-centred two-electron reduction processes (MoVI→MoV). The electrochemical behavior of the composite material PMo10V2@MIL-101 showed both MIL-101(Cr) and PMo10V2 redox features, although with the splitting of the two vanadium processes and the shift of the Mo- and Cr- centered processes to more negative potentials. Finally, PMo10V2@MIL-101 modified electrode showed outstanding enhanced vanadium-based electrocatalytic properties towards ascorbic acid oxidation, in comparison with the free PMo10V2, as a result of its immobilization into the porous structure of the MOF. Furthermore, PMo10V2@MIL-101 modified electrode showed successful simultaneous detection of ascorbic acid and dopamine.

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(1) UV–vis spectra of the reaction solution during the preparation of the composite material PMo10V2@MIL-101; (2) SEM images of MIL-101 (Cr) and PMo10V2@MIL-101; and (3) Mesopore size distribution for MIL-101(Cr), PMo10V2, and PMo10V2@MIL-101. This material is available free of charge via the Internet at http://pubs.acs.org.

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  7. Matthew Genovese and Keryn Lian . Ionic Liquid-Derived Imidazolium Cation Linkers for the Layer-by-Layer Assembly of Polyoxometalate-MWCNT Composite Electrodes with High Power Capability. ACS Applied Materials & Interfaces 2016, 8 (29) , 19100-19109. https://doi.org/10.1021/acsami.6b03261
  8. Yang Wang, Lu Wang, Huanhuan Chen, Xiaoya Hu, and Shengqian Ma . Fabrication of Highly Sensitive and Stable Hydroxylamine Electrochemical Sensor Based on Gold Nanoparticles and Metal–Metalloporphyrin Framework Modified Electrode. ACS Applied Materials & Interfaces 2016, 8 (28) , 18173-18181. https://doi.org/10.1021/acsami.6b04819
  9. Yizhen Yang, Qingxiang Wang, Weiwei Qiu, Hongxu Guo, and Feng Gao . Covalent Immobilization of Cu3(btc)2 at Chitosan–Electroreduced Graphene Oxide Hybrid Film and Its Application for Simultaneous Detection of Dihydroxybenzene Isomers. The Journal of Physical Chemistry C 2016, 120 (18) , 9794-9803. https://doi.org/10.1021/acs.jpcc.6b01574
  10. Diana M. Fernandes, Alexandra Teixeira, and Cristina Freire . Multielectrocatalysis by Layer-by-Layer Films Based on Pararosaniline and Vanadium-Substituted Phosphomolybdate. Langmuir 2015, 31 (5) , 1855-1865. https://doi.org/10.1021/la5043266
  11. Jiuxiao Dong, Peiying Li, Hongyu Guan, Chunhua Ge, Yufeng Bai, Yuhui Zhao, Xiangdong Zhang. The synthesis of HKUST-1/SiO2 composite material based on 3D printing. Inorganic Chemistry Communications 2020, 117 , 107975. https://doi.org/10.1016/j.inoche.2020.107975
  12. Bo Huang, Degang Ke, Zhelun Xiong, Yu Wang, Kanghong Hu, Peng Jiang, Minghui Liang, Zicheng Xiao, Pingfan Wu. Covalent hybrid materials between polyoxometalates and organic molecules for enhanced electrochemical properties. Journal of Materials Science 2020, 55 (13) , 5554-5570. https://doi.org/10.1007/s10853-020-04404-0
  13. Jiamin Sun, Sara Abednatanzi, Pascal Van Der Voort, Ying-Ya Liu, Karen Leus. [email protected] Hybrids: Synthesis and Applications. Catalysts 2020, 10 (5) , 578. https://doi.org/10.3390/catal10050578
  14. Di Zhu, Zhenyuan Bai, Huiyuan Ma, Lichao Tan, Haijun Pang, Xinming Wang. High performance simultaneous detection of β-nicotinamide adenine dinucleotide and l-tryptophan in human serum based on a novel nanocomposite of ferroferric oxide-functionalized polyoxometalates. Sensors and Actuators B: Chemical 2020, 309 , 127787. https://doi.org/10.1016/j.snb.2020.127787
  15. Dan Wang, Lulu Liu, Jun Jiang, Lijuan Chen, Junwei Zhao. Polyoxometalate-based composite materials in electrochemistry: state-of-the-art progress and future outlook. Nanoscale 2020, 12 (10) , 5705-5718. https://doi.org/10.1039/C9NR10573E
  16. Xue-Ting Liu, Tian Lin, Chen-Xi Zhang, Qing-Lun Wang. A phosphonate coordination polymer with highly sensitive detection of ascorbic acid and the proton conductivity of its polymer composites. Polyhedron 2020, 178 , 114347. https://doi.org/10.1016/j.poly.2020.114347
  17. Fuli Wang, Cuiyuan Liang, Jiyu Tang, Feng Zhang, Fengyu Qu. The promotion of proton conductivity by immobilizing molybdovanadophosphoric acids in metal–organic frameworks. New Journal of Chemistry 2020, 44 (5) , 1912-1920. https://doi.org/10.1039/C9NJ05572J
  18. S. Gheytani, S. K. Hassaninejad‐Darzi, M. Taherimehr. Formaldehyde Electro‐catalytic Oxidation onto Carbon Paste Electrode Modified by MIL‐101(Cr) Nanoparticles. Fuel Cells 2020, 20 (1) , 3-16. https://doi.org/10.1002/fuce.201800161
  19. Xuerong Peng, Yue Wan, Yanying Wang, Tao Liu, Ping Zou, Xianxiang Wang, Qingbiao Zhao, Fang Ding, Hanbing Rao. Flower‐like Ni(II)‐based Metal‐organic Framework‐decorated Ag Nanoparticles: Fabrication, Characterization and Electrochemical Detection of Glucose. Electroanalysis 2019, 31 (11) , 2179-2186. https://doi.org/10.1002/elan.201900259
  20. Borong Lu, Shaobin Li, Xiaozhou Zhang, Deqing Zhang, Linlin Fan, Eryun Yan, Yongjuan Zhang, Liang Yu. A novel polyoxometalate-based metal–organic nanotube framework templated by twin-Dawson clusters: synthesis, structure and bifunctional electrocatalytic properties. New Journal of Chemistry 2019, 43 (39) , 15804-15810. https://doi.org/10.1039/C9NJ02004G
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  22. Hamed Valizadeh, Javad Tashkhourian, Abdolkarim Abbaspour. A carbon paste electrode modified with a metal-organic framework of type MIL-101(Fe) for voltammetric determination of citric acid. Microchimica Acta 2019, 186 (7) https://doi.org/10.1007/s00604-019-3585-4
  23. Mariana L. Díaz-Ramírez, Elí Sánchez-González, J. Raziel Álvarez, Gerardo A. González-Martínez, Satoshi Horike, Kentaro Kadota, Kenji Sumida, Eduardo González-Zamora, Marie-Anne Springuel-Huet, Aída Gutiérrez-Alejandre, Vojtech Jancik, Shuhei Furukawa, Susumu Kitagawa, Ilich A. Ibarra, Enrique Lima. Partially fluorinated MIL-101(Cr): from a miniscule structure modification to a huge chemical environment transformation inspected by 129 Xe NMR. Journal of Materials Chemistry A 2019, 7 (25) , 15101-15112. https://doi.org/10.1039/C9TA02237F
  24. Lihui Zhang, Qiwen Wang, Yu Qi, Ling Li, Shengtian Wang, Xiaohong Wang. An ultrasensitive sensor based on polyoxometalate and zirconium dioxide nanocomposites hybrids material for simultaneous detection of toxic clenbuterol and ractopamine. Sensors and Actuators B: Chemical 2019, 288 , 347-355. https://doi.org/10.1016/j.snb.2019.03.033
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  26. Dadong Liang, Chen Liang, Lingkun Meng, Yue Lou, Chunguang Li, Zhan Shi. [email protected]/MoS 2 : a composite material based on the MIL-101 platform with enhanced performances. New Journal of Chemistry 2019, 43 (8) , 3432-3438. https://doi.org/10.1039/C8NJ05179H
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  30. Lihui Zhang, Jessie Khungwa, Yue Liu, Ling Li, Xiaohong Wang, Shengtian Wang. Fabrication of Electro-Active Pt/IMo 6 O 24 /Graphene Oxide Nanohybrid Modified Electrode for the Simultaneous Determination of Ascorbic Acid, Dopamine and Uric Acid. Journal of The Electrochemical Society 2019, 166 (8) , H351-H358. https://doi.org/10.1149/2.1141908jes
  31. Yuxia Xu, Qing Li, Huaiguo Xue, Huan Pang. Metal-organic frameworks for direct electrochemical applications. Coordination Chemistry Reviews 2018, 376 , 292-318. https://doi.org/10.1016/j.ccr.2018.08.010
  32. Jinxiao Guo, Huaijuan Zhou, Jiaxing Wang, Wei Liu, Mengqi Cheng, Xiaochun Peng, Hui Qin, Jianfeng Wei, Ping Jin, Jinhua Li, Xianlong Zhang. Nano vanadium dioxide films deposited on biomedical titanium: a novel approach for simultaneously enhanced osteogenic and antibacterial effects. Artificial Cells, Nanomedicine, and Biotechnology 2018, 46 (sup2) , 58-74. https://doi.org/10.1080/21691401.2018.1452020
  33. Wanqing Zhang, Dawei Duan, Shanqin Liu, Yongsheng Zhang, Leipeng Leng, Xinli Li, Na Chen, Yuping Zhang. Metal-organic framework-based molecularly imprinted polymer as a high sensitive and selective hybrid for the determination of dopamine in injections and human serum samples. Biosensors and Bioelectronics 2018, 118 , 129-136. https://doi.org/10.1016/j.bios.2018.07.047
  34. Qiwen Wang, Jessie Khungwa, Ling Li, Yue Liu, Xiaohong Wang, Shengtian Wang. Fabrication of polyoxometalate/GO/PDDA hybrid nanocomposite modified electrode and electrocatalysis for nitrite ion, ascorbic acid and dopamine. Journal of Electroanalytical Chemistry 2018, 824 , 91-98. https://doi.org/10.1016/j.jelechem.2018.07.043
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  36. Xue‐jun Zhou, Yue‐Xia Ji, Jia‐Feng Cao, Zhi‐Feng Xin. Polyoxometalate encapsulated in metal‐organic gel as an efficient catalyst for visible‐light‐driven dye degradation applications. Applied Organometallic Chemistry 2018, 32 (3) , e4206. https://doi.org/10.1002/aoc.4206
  37. Sureshkumar Kempahanumakkagari, Kowsalya Vellingiri, Akash Deep, Eilhann E. Kwon, Nanthi Bolan, Ki-Hyun Kim. Metal–organic framework composites as electrocatalysts for electrochemical sensing applications. Coordination Chemistry Reviews 2018, 357 , 105-129. https://doi.org/10.1016/j.ccr.2017.11.028
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  40. Haolin Zhu, Dingxin Liu, Dianting Zou, Jianyong Zhang. The photo-, electro- and photoelectro-catalytic properties and application prospects of porous coordinate polymers. Journal of Materials Chemistry A 2018, 6 (15) , 6130-6154. https://doi.org/10.1039/C8TA00494C
  41. Hengbin Xu, Zhenyuan Bai, Guangning Wang, Kevin P. O’Halloran, Lichao Tan, Haijun Pang, Huiyuan Ma. Voltammetric determination of folic acid at physiological pH values by using a glassy carbon electrode modified with a multilayer composite consisting of polyoxometalate (H8P2Mo16V2O62) and reduced graphene oxide and prepared via layer-by-layer self-assembly and in-situ photoreduction. Microchimica Acta 2017, 184 (11) , 4295-4303. https://doi.org/10.1007/s00604-017-2447-1
  42. Wanqing Zhang, Zhongyin Zhang, Yuanchao Li, Jun Chen, Xiaobo Li, Yadong Zhang, Yuping Zhang. Novel nanostructured MIL-101(Cr)/XC-72 modified electrode sensor: A highly sensitive and selective determination of chloramphenicol. Sensors and Actuators B: Chemical 2017, 247 , 756-764. https://doi.org/10.1016/j.snb.2017.03.104
  43. , , , , , . Preparation of Cationic MOFs with Mobile Anions by Anion Stripping to Remove 2,4-D from Water. Materials 2017, 10 (8) , 879. https://doi.org/10.3390/ma10080879
  44. Si-Wen Li, Jia-Rong Li, Yan Gao, Ling-Ling Liang, Rong-Lan Zhang, Jian-she Zhao. Metal modified heteropolyacid incorporated into porous materials for a highly oxidative desulfurization of DBT under molecular oxygen. Fuel 2017, 197 , 551-561. https://doi.org/10.1016/j.fuel.2017.02.064
  45. André D.S. Barbosa, Diana Julião, Diana M. Fernandes, Andreia F. Peixoto, Cristina Freire, Baltazar de Castro, Carlos M. Granadeiro, Salete S. Balula, Luís Cunha-Silva. Catalytic performance and electrochemical behaviour of Metal–organic frameworks: MIL-101(Fe) versus NH2-MIL-101(Fe). Polyhedron 2017, 127 , 464-470. https://doi.org/10.1016/j.poly.2016.10.032
  46. Diana M. Fernandes, Marta Nunes, Belén Bachiller-Baeza, Inmaculada Rodríguez-Ramos, Antonio Guerrero-Ruiz, Cristina Delerue-Matos, Cristina Freire. [email protected] electrochemical properties and its application as electrochemical sensor for determination of acetaminophen. Journal of Solid State Electrochemistry 2017, 21 (4) , 1059-1068. https://doi.org/10.1007/s10008-016-3463-5
  47. Tao Wei, Mi Zhang, Ping Wu, Yu-Jia Tang, Shun-Li Li, Feng-Cui Shen, Xiao-Li Wang, Xin-Ping Zhou, Ya-Qian Lan. POM-based metal-organic framework/reduced graphene oxide nanocomposites with hybrid behavior of battery-supercapacitor for superior lithium storage. Nano Energy 2017, 34 , 205-214. https://doi.org/10.1016/j.nanoen.2017.02.028
  48. Sara Abednatanzi, Karen Leus, Parviz Gohari Derakhshandeh, Fady Nahra, Katrien De Keukeleere, Kristof Van Hecke, Isabel Van Driessche, Alireza Abbasi, Steven P. Nolan, Pascal Van Der Voort. [email protected] – inclusion of POMs in ionic liquid modified MOFs to produce recyclable oxidation catalysts. Catalysis Science & Technology 2017, 7 (7) , 1478-1487. https://doi.org/10.1039/C6CY02662A
  49. Diana Julião, André D. S. Barbosa, Andreia F. Peixoto, Cristina Freire, Baltazar de Castro, Salete S. Balula, Luís Cunha-Silva. Improved catalytic performance of porous metal–organic frameworks for the ring opening of styrene oxide. CrystEngComm 2017, 19 (29) , 4219-4226. https://doi.org/10.1039/C7CE00528H
  50. Cristina Freire, Diana M. Fernandes, Marta Nunes, Mariana Araújo. Polyoxometalate-based Modified Electrodes for Electrocatalysis: From Molecule Sensing to Renewable Energy-related Applications. 2016,,, 147-212. https://doi.org/10.1002/9781119242659.ch5
  51. Marta Nunes, Diana M. Fernandes, Inês M. Rocha, Manuel F. R. Pereira, Israel-Martyr Mbomekalle, Pedro de Oliveira, Cristina Freire. [email protected] Nanocomposites as Electrocatalysts for Oxygen Reduction Reaction. ChemistrySelect 2016, 1 (19) , 6257-6266. https://doi.org/10.1002/slct.201601370
  52. Sheying Dong, Dandan Zhang, Gaochao Suo, Wenbo Wei, Tinglin Huang. Exploiting multi-function Metal-Organic Framework nanocomposite [email protected] as highly efficient immobilization matrixes for sensitive electrochemical biosensing. Analytica Chimica Acta 2016, 934 , 203-211. https://doi.org/10.1016/j.aca.2016.05.040
  53. William Salomon, Yanhua Lan, Eric Rivière, Shu Yang, Catherine Roch-Marchal, Anne Dolbecq, Corine Simonnet-Jégat, Nathalie Steunou, Nathalie Leclerc-Laronze, Laurent Ruhlmann, Talal Mallah, Wolfgang Wernsdorfer, Pierre Mialane. Single-Molecule Magnet Behavior of Individual Polyoxometalate Molecules Incorporated within Biopolymer or Metal-Organic Framework Matrices. Chemistry - A European Journal 2016, 22 (19) , 6564-6574. https://doi.org/10.1002/chem.201600202
  54. Bao-Xia Dong, Yi-Chen Wu, Hui Tian, Chun-Bo Liu, Wen-Long Liu, Yun-Lei Teng. Synthesis, Crystal Structure and Electrochemical Properties of A New 2D Network Containing Linear {ε-H2PMo 8 V Mo 4 VI O40Zn4}∞ Inorganic Chain. Journal of Cluster Science 2016, 27 (1) , 361-371. https://doi.org/10.1007/s10876-015-0935-1
  55. Jin-Liang Zhuang, Andreas Terfort, Christof Wöll. Formation of oriented and patterned films of metal–organic frameworks by liquid phase epitaxy: A review. Coordination Chemistry Reviews 2016, 307 , 391-424. https://doi.org/10.1016/j.ccr.2015.09.013
  56. Zhenyuan Bai, Chunlei Zhou, Ning Gao, Haijun Pang, Huiyuan Ma. A chitosan–Pt nanoparticles/carbon nanotubes-doped phosphomolybdate nanocomposite as a platform for the sensitive detection of nitrite in tap water. RSC Advances 2016, 6 (2) , 937-946. https://doi.org/10.1039/C5RA19383D
  57. Zhewei Peng, Zhongwei Jiang, Xin Huang, Yuanfang Li. A novel electrochemical sensor of tryptophan based on silver nanoparticles/metal–organic framework composite modified glassy carbon electrode. RSC Advances 2016, 6 (17) , 13742-13748. https://doi.org/10.1039/C5RA25251B
  58. Ting-Ting Zhu, Zhi-Ming Zhang, Wei-Lin Chen, Zhu-Jun Liu, En-Bo Wang. Encapsulation of tungstophosphoric acid into harmless MIL-101(Fe) for effectively removing cationic dye from aqueous solution. RSC Advances 2016, 6 (85) , 81622-81630. https://doi.org/10.1039/C6RA16716K
  59. Jingfang Li, Jing Xu, Xiaodong Li, Wenmei Gao, Liyan Wang, Lixin Wu, Myongsoo Lee, Wen Li. Heteropoly acids triggered self-assembly of cationic peptides into photo- and electro-chromic gels. Soft Matter 2016, 12 (25) , 5572-5580. https://doi.org/10.1039/C6SM00752J
  60. Diana Fernandes, Marta Nunes, Ricardo Carvalho, Revathi Bacsa, Israel-Martyr Mbomekalle, Philippe Serp, Pedro de Oliveira, Cristina Freire. Biomolecules Electrochemical Sensing Properties of a [email protected] Few Layer Graphene Nanocomposite. Inorganics 2015, 3 (2) , 178-193. https://doi.org/10.3390/inorganics3020178
  61. Yufan Zhang, Xiangjie Bo, Anaclet Nsabimana, Alexis Munyentwali, Ce Han, Mian Li, Liping Guo. Green and facile synthesis of an Au [email protected]/ordered mesoporous carbon tri-component nanocomposite and its electrochemical applications. Biosensors and Bioelectronics 2015, 66 , 191-197. https://doi.org/10.1016/j.bios.2014.11.022
  62. Diana M. Fernandes, Cristina Freire. Carbon Nanomaterial-Phosphomolybdate Composites for Oxidative Electrocatalysis. ChemElectroChem 2015, 2 (2) , 269-279. https://doi.org/10.1002/celc.201402271
  63. Xiao-Qin Wu, Jian-Gong Ma, Han Li, Di-Ming Chen, Wen Gu, Guang-Ming Yang, Peng Cheng. Metal–organic framework biosensor with high stability and selectivity in a bio-mimic environment. Chemical Communications 2015, 51 (44) , 9161-9164. https://doi.org/10.1039/C5CC02113H
  64. Jagoba Martín-Caballero, Ana San José Wéry, Beñat Artetxe, Santiago Reinoso, Leire San Felices, José Luis Vilas, Juan M. Gutiérrez-Zorrilla. Sequential single-crystal-to-single-crystal transformations promoted by gradual thermal dehydration in a porous metavanadate hybrid. CrystEngComm 2015, 17 (46) , 8915-8925. https://doi.org/10.1039/C5CE01076D
  65. Jian-Sheng Li, Xiao-Jing Sang, Wei-Lin Chen, Lan-Cui Zhang, Zai-Ming Zhu, Yang-Guang Li, Zhong-Min Su, En-Bo Wang. A strategy for breaking the MOF template to obtain small-sized and highly dispersive polyoxometalate clusters loaded on solid films. Journal of Materials Chemistry A 2015, 3 (28) , 14573-14577. https://doi.org/10.1039/C5TA03259H
  66. Diana M. Fernandes, Carlos M. Granadeiro, Patrícia M. Paes de Sousa, Raquel Grazina, José J. G. Moura, Patrícia Silva, Filipe A. Almeida Paz, Luís Cunha-Silva, Salete S. Balula, Cristina Freire. SiW 11 [email protected](Cr) Composite: A Novel and Versatile Electrocatalyst. ChemElectroChem 2014, 1 (8) , 1293-1300. https://doi.org/10.1002/celc.201402094
  67. Samiran Bhattacharjee, Chao Chen, Wha-Seung Ahn. Chromium terephthalate metal–organic framework MIL-101: synthesis, functionalization, and applications for adsorption and catalysis. RSC Adv. 2014, 4 (94) , 52500-52525. https://doi.org/10.1039/C4RA11259H
  68. Miao Shi, Zhimin Chen, Liangxiao Guo, Xiuhua Liang, Jialin Zhang, Chunying He, Bin Wang, Yiqun Wu. A multiwalled carbon nanotube/tetra-β-isoheptyloxyphthalocyanine cobalt( ii ) composite with high dispersibility for electrochemical detection of ascorbic acid. Journal of Materials Chemistry B 2014, 2 (30) , 4876. https://doi.org/10.1039/C4TB00229F

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