ACS Publications. Most Trusted. Most Cited. Most Read

OR SEARCH CITATIONS

My Activity
Publications
CONTENT TYPES

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:ACS Appl. Mater. Interfaces 2014, 6, 15, 12789-12797
RETURN TO ISSUEPREVResearch ArticleNEXT

Conducting Polymer-Skinned Electroactive Materials of Lithium-Ion Batteries: Ready for Monocomponent Electrodes without Additional Binders and Conductive Agents

View Author Information
Department of Energy Engineering, School of Energy, Chemical Engineering, Ulsan National Institute of Science, Technology (UNIST), Ulsan 689-798, Korea
*Phone: +82-52-217-2512. Fax +82-52-217-2019. E-mail: [email protected]
*Phone: +82-52-217-2948. Fax +82-52-217-2019. E-mail: [email protected]
Cite this: ACS Appl. Mater. Interfaces 2014, 6, 15, 12789–12797
Publication Date (Web):July 2, 2014
https://doi.org/10.1021/am502736m
Copyright © 2014 American Chemical Society
Request reuse permissions

    Article Views

    2654

    Altmetric

    -

    Citations

    71
    LEARN ABOUT THESE METRICS
    Read OnlinePDF (7 MB)
    Get e-Alerts
    Supporting Info (1)»
    SUBJECTS:

    Abstract

    Abstract Image

    Rapid growth of mobile and even wearable electronics is in pursuit of high-energy-density lithium-ion batteries. One simple and facile way to achieve this goal is the elimination of nonelectroactive components of electrodes such as binders and conductive agents. Here, we present a new concept of monocomponent electrodes comprising solely electroactive materials that are wrapped with an insignificant amount (less than 0.4 wt %) of conducting polymer (PEDOT:PSS or poly(3,4-ethylenedioxythiophene) doped with poly(styrenesulfonate)). The PEDOT:PSS as an ultraskinny surface layer on electroactive materials (LiCoO2 (LCO) powders are chosen as a model system to explore feasibility of this new concept) successfully acts as a kind of binder as well as mixed (both electrically and ionically) conductive film, playing a key role in enabling the monocomponent electrode. The electric conductivity of the monocomponent LCO cathode is controlled by simply varying the PSS content and also the structural conformation (benzoid-favoring coil structure and quinoid-favoring linear or extended coil structure) of PEDOT in the PEDOT:PSS skin. Notably, a substantial increase in the mass-loading density of the LCO cathode is realized with the PEDOT:PSS skin without sacrificing electronic/ionic transport pathways. We envisage that the PEDOT:PSS-skinned electrode strategy opens a scalable and versatile route for making practically meaningful binder-/conductive agent-free (monocomponent) electrodes.

    KEYWORDS:

    Supporting Information

    ARTICLE SECTIONS
    Jump To

    XRD, TGA of LCO@PEDOT:PSS, and viscosity of the monocomponent and tricomponent slurry, and residual water contents in cathode electrode, surface morphology of the monocomponent cathodes based on two different PEDOT:PSS, C-rate dependency of discharge capacities per active mass. This material is available free of charge via the Internet at http://pubs.acs.org.

    Terms & Conditions

    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    This article is cited by 71 publications.

    1. Gordon Pace, Alexandra Zele, Phong Nguyen, Raphaële J. Clément, Rachel A. Segalman. Mixed Ion–Electron-Conducting Polymer Complexes as High-Rate Battery Binders. Chemistry of Materials 2023, 35 (19) , 8101-8111. https://doi.org/10.1021/acs.chemmater.3c01587
    2. Dong Ok Shin, Hyungjun Kim, Jaecheol Choi, Ju Young Kim, Seok Hun Kang, Young-Sam Park, Maenghyo Cho, Yong Min Lee, Kyeongjae Cho, Young-Gi Lee. Effect of Lithium Substitution Ratio of Polymeric Binders on Interfacial Conduction within All-Solid-State Battery Anodes. ACS Applied Materials & Interfaces 2023, 15 (10) , 13131-13143. https://doi.org/10.1021/acsami.3c00030
    3. Pengfei Sang, Qiliang Chen, Dan-Yang Wang, Wei Guo, Yongzhu Fu. Organosulfur Materials for Rechargeable Batteries: Structure, Mechanism, and Application. Chemical Reviews 2023, 123 (4) , 1262-1326. https://doi.org/10.1021/acs.chemrev.2c00739
    4. Aleksei V. Kubarkov, Artem A. Asharchuk, Oleg A. Drozhzhin, Evgeny A. Karpushkin, Keith J. Stevenson, Evgeny V. Antipov, Vladimir G. Sergeyev. Effect of Polymer Binders with Single-Walled Carbon Nanotubes on the Electrochemical and Physicochemical Properties of the LiFePO4 Cathode. ACS Applied Energy Materials 2021, 4 (11) , 12310-12318. https://doi.org/10.1021/acsaem.1c02135
    5. Billal Zayat, Pratyusha Das, Barry C. Thompson, Sri R. Narayan. In Situ Measurement of Ionic and Electronic Conductivities of Conductive Polymers as a Function of Electrochemical Doping in Battery Electrolytes. The Journal of Physical Chemistry C 2021, 125 (14) , 7533-7541. https://doi.org/10.1021/acs.jpcc.0c08934
    6. Bihag Anothumakkool, Florian Holtstiege, Simon Wiemers-Meyer, Sascha Nowak, Falko Schappacher, Martin Winter. Electropolymerization Triggered in Situ Surface Modification of Electrode Interphases: Alleviating First-Cycle Lithium Loss in Silicon Anode Lithium-Ion Batteries. ACS Sustainable Chemistry & Engineering 2020, 8 (34) , 12788-12798. https://doi.org/10.1021/acssuschemeng.0c02391
    7. Chun-Han Lai, David S. Ashby, Terri C. Lin, Jonathan Lau, Andrew Dawson, Sarah H. Tolbert, Bruce S. Dunn. Application of Poly(3-hexylthiophene-2,5-diyl) as a Protective Coating for High Rate Cathode Materials. Chemistry of Materials 2018, 30 (8) , 2589-2599. https://doi.org/10.1021/acs.chemmater.7b05116
    8. Ye Shi, Xingyi Zhou, Jun Zhang, Andrea M. Bruck, Andrew C. Bond, Amy C. Marschilok, Kenneth J. Takeuchi, Esther S. Takeuchi, and Guihua Yu . Nanostructured Conductive Polymer Gels as a General Framework Material To Improve Electrochemical Performance of Cathode Materials in Li-Ion Batteries. Nano Letters 2017, 17 (3) , 1906-1914. https://doi.org/10.1021/acs.nanolett.6b05227
    9. Hyosung An, Xiaoyi Li, Cody Chalker, Maria Stracke, Rafael Verduzco, and Jodie L. Lutkenhaus . Conducting Block Copolymer Binders for Carbon-Free Hybrid Vanadium Pentoxide Cathodes with Enhanced Performance. ACS Applied Materials & Interfaces 2016, 8 (42) , 28585-28591. https://doi.org/10.1021/acsami.6b08028
    10. Adam R. Meier, Marco Matteucci, Richard F. Vreeland, Rafael Taboryski, and Michael L. Heien . Rapid Voltammetric Measurements at Conducting Polymer Microelectrodes Using Ultralow-Capacitance Poly(3,4-ethylenedioxythiophene):Tosylate. Langmuir 2016, 32 (32) , 8009-8018. https://doi.org/10.1021/acs.langmuir.6b01423
    11. Chuan Ding, Yanwei Zeng, Liangliang Cao, Longfei Zhao, and Qiuyu Meng . Porous Fe3O4–NCs-in-Carbon Nanofoils as High-Rate and High-Capacity Anode Materials for Lithium-Ion Batteries from Na–Citrate-Mediated Growth of Super-Thin Fe–Ethylene Glycolate Nanosheets. ACS Applied Materials & Interfaces 2016, 8 (12) , 7977-7990. https://doi.org/10.1021/acsami.5b12378
    12. Nerea Casado, Guiomar Hernández, Antonio Veloso, Shanmukaraj Devaraj, David Mecerreyes, and Michel Armand . PEDOT Radical Polymer with Synergetic Redox and Electrical Properties. ACS Macro Letters 2016, 5 (1) , 59-64. https://doi.org/10.1021/acsmacrolett.5b00811
    13. Xiaohui Yu, Hongyan Yang, Haowen Meng, Yanli Sun, Jiao Zheng, Daqian Ma, and Xinhua Xu . Three-Dimensional Conductive Gel Network as an Effective Binder for High-Performance Si Electrodes in Lithium-Ion Batteries. ACS Applied Materials & Interfaces 2015, 7 (29) , 15961-15967. https://doi.org/10.1021/acsami.5b04058
    14. Min Ling, Jingxia Qiu, Sheng Li, Cheng Yan, Milton J. Kiefel, Gao Liu, and Shanqing Zhang . Multifunctional SA-PProDOT Binder for Lithium Ion Batteries. Nano Letters 2015, 15 (7) , 4440-4447. https://doi.org/10.1021/acs.nanolett.5b00795
    15. Nyung Joo Kong, Myeong Seon Kim, Jae Hyun Park, Jongbok Kim, Jungho Jin, Hyun-Wook Lee, Seok Ju Kang. Promoting homogeneous lithiation of silicon anodes via the application of bifunctional PEDOT:PSS/PEG composite binders. Energy Storage Materials 2024, 64 , 103074. https://doi.org/10.1016/j.ensm.2023.103074
    16. Wendi Dou, Mengting Zheng, Wu Zhang, Tiefeng Liu, Fating Wang, Guangying Wan, Yujing Liu, Xinyong Tao. Review on the Binders for Sustainable High‐Energy‐Density Lithium Ion Batteries: Status, Solutions, and Prospects. Advanced Functional Materials 2023, 33 (45) https://doi.org/10.1002/adfm.202305161
    17. Anna A. Fedorova, Oleg V. Levin, Svetlana N. Eliseeva, Tomaž Katrašnik, Dmitrii V. Anishchenko. Investigating the Coating Effect on Charge Transfer Mechanisms in Composite Electrodes for Lithium-Ion Batteries. International Journal of Molecular Sciences 2023, 24 (11) , 9406. https://doi.org/10.3390/ijms24119406
    18. Megha Goyal, Satya Narayan Agarwal, Kulwant Singh, Nitu Bhatnagar. Synthesis and characterization of poly [(3,4‐ethylenedioxy) thiophene]:polystyrene sulfonate ( PEDOT : PSS ) for energy storage device application. Journal of Applied Polymer Science 2023, 140 (19) https://doi.org/10.1002/app.53830
    19. Pratyusha Das, Barry C. Thompson. Development of design strategies for conjugated polymer binders in lithium-ion batteries. Polymer Journal 2023, 55 (4) , 317-341. https://doi.org/10.1038/s41428-022-00708-x
    20. Dmitrii Yu. Semerukhin, Aleksei V. Kubarkov, Evgeny V. Antipov, Vladimir G. Sergeyev. Carbon nanotubes and carbon-coated current collector significantly improve the performance of lithium-ion battery with PEDOT:PSS binder. Mendeleev Communications 2023, 33 (2) , 206-208. https://doi.org/10.1016/j.mencom.2023.02.018
    21. Abu Md Numan-Al-Mobin, Alevtina Smirnova. Silicon-based lithium-ion battery anodes and their application in solid-state batteries. 2023, 129-169. https://doi.org/10.1016/B978-0-323-90635-7.00008-7
    22. Veniamin Kondratiev, Rudolf Holze. Intrinsically Conducting Polymer Binders for Battery Electrodes. Encyclopedia 2022, 2 (4) , 1753-1762. https://doi.org/10.3390/encyclopedia2040120
    23. Mozaffar Abdollahifar, Palanivel Molaiyan, Milena Perovic, Arno Kwade. Insights into Enhancing Electrochemical Performance of Li-Ion Battery Anodes via Polymer Coating. Energies 2022, 15 (23) , 8791. https://doi.org/10.3390/en15238791
    24. Tiantian Dong, Huanrui Zhang, Rongxiang Hu, Pengzhou Mu, Zhi Liu, Xiaofan Du, Chenglong Lu, Guoli Lu, Wei Liu, Guanglei Cui. A rigid-flexible coupling poly(vinylene carbonate) based cross-linked network: A versatile polymer platform for solid-state polymer lithium batteries. Energy Storage Materials 2022, 50 , 525-532. https://doi.org/10.1016/j.ensm.2022.05.052
    25. Dong Ok Shin, Hyungjun Kim, Seungwon Jung, Seoungwoo Byun, Jaecheol Choi, Min Pyeong Kim, Ju Young Kim, Seok Hun Kang, Young-Sam Park, Sung You Hong, Maenghyo Cho, Young-Gi Lee, Kyeongjae Cho, Yong Min Lee. Electrolyte-free graphite electrode with enhanced interfacial conduction using Li+-conductive binder for high-performance all-solid-state batteries. Energy Storage Materials 2022, 49 , 481-492. https://doi.org/10.1016/j.ensm.2022.04.029
    26. Tatiana Kulova, Alexander Skundin, Il’ya Gavrilin, Yulia Kudryashova, Irina Martynova, Svetlana Novikova. Binder-Free Ge-Co-P Anode Material for Lithium-Ion and Sodium-Ion Batteries. Batteries 2022, 8 (8) , 98. https://doi.org/10.3390/batteries8080098
    27. Md. Arafat Rahman, Md. Mizanur Rahman, Guangsheng Song. A review on binder‐free NiO‐Ni foam as anode of high performance lithium‐ion batteries. Energy Storage 2022, 4 (3) https://doi.org/10.1002/est2.278
    28. Hari Raj, Anjan Sil. Aqueous processing based novel composite electrode for Li-ion batteries using an environmentally benign binder. Ceramics International 2021, 47 (24) , 34639-34647. https://doi.org/10.1016/j.ceramint.2021.09.002
    29. Chuao Ma, Haixi Luo, Mingzhu Liu, Hua Yang, Hongliang Liu, Xiqi Zhang, Lei Jiang. Preparation of intrinsic flexible conductive PEDOT:PSS@ionogel composite film and its application for touch panel. Chemical Engineering Journal 2021, 425 , 131542. https://doi.org/10.1016/j.cej.2021.131542
    30. Rodrigo Elizalde-Segovia, Pratyusha Das, Billal Zayat, Ahamed Irshad, Barry C. Thompson, S. R. Narayanan. Understanding the Role of π-Conjugated Polymers as Binders in Enabling Designs for High-Energy/High-Rate Lithium Metal Batteries. Journal of The Electrochemical Society 2021, 168 (11) , 110541. https://doi.org/10.1149/1945-7111/ac3850
    31. Veniamin V. Kondratiev, Rudolf Holze. Intrinsically conducting polymers and their combinations with redox-active molecules for rechargeable battery electrodes: an update. Chemical Papers 2021, 75 (10) , 4981-5007. https://doi.org/10.1007/s11696-021-01529-7
    32. Niranjanmurthi Lingappan, Lingxi Kong, Michael Pecht. The significance of aqueous binders in lithium-ion batteries. Renewable and Sustainable Energy Reviews 2021, 147 , 111227. https://doi.org/10.1016/j.rser.2021.111227
    33. Han Yeu Ling, Hao Chen, Zhenzhen Wu, Luke Hencz, Shangshu Qian, Xianhu Liu, Tiefeng Liu, Shanqing Zhang. Sustainable bio-derived materials for addressing critical problems of next-generation high-capacity lithium-ion batteries. Materials Chemistry Frontiers 2021, 5 (16) , 5932-5953. https://doi.org/10.1039/D1QM00255D
    34. Yun Zhao, Zheng Liang, Yuqiong Kang, Yunan Zhou, Yanxi Li, Xiangming He, Li Wang, Weicong Mai, Xianshu Wang, Guangmin Zhou, Junxiong Wang, Jiangang Li, Naser Tavajohi, Baohua Li. Rational design of functional binder systems for high-energy lithium-based rechargeable batteries. Energy Storage Materials 2021, 35 , 353-377. https://doi.org/10.1016/j.ensm.2020.11.021
    35. Hao Li, Fang Lian, Nan Meng, Chenyu Xiong, Nan Wu, Biyi Xu, Yutao Li. Constructing Electronic and Ionic Dual Conductive Polymeric Interface in the Cathode for High‐Energy‐Density Solid‐State Batteries. Advanced Functional Materials 2021, 31 (13) https://doi.org/10.1002/adfm.202008487
    36. Van At Nguyen, Jian Wang, Christian Kuss. Conducting polymer composites as water-dispersible electrode matrices for Li-Ion batteries: Synthesis and characterization. Journal of Power Sources Advances 2020, 6 , 100033. https://doi.org/10.1016/j.powera.2020.100033
    37. Yuqiong Kang, Changjian Deng, Yuqing Chen, Xinyi Liu, Zheng Liang, Tao Li, Quan Hu, Yun Zhao. Binder-Free Electrodes and Their Application for Li-Ion Batteries. Nanoscale Research Letters 2020, 15 (1) https://doi.org/10.1186/s11671-020-03325-w
    38. Hari Raj, Anjan Sil. Energy and power densities of novel composite electrode driven by synergy of poly(3,4-ethylene dioxythiophene):poly(styrene sulfonate) and single walled carbon nanotubes for lithium-ion battery. Journal of Power Sources 2020, 458 , 228052. https://doi.org/10.1016/j.jpowsour.2020.228052
    39. Svetlana N. Eliseeva, Mikhail A. Kamenskii, Elena G. Tolstopyatova, Veniamin V. Kondratiev. Effect of Combined Conductive Polymer Binder on the Electrochemical Performance of Electrode Materials for Lithium-Ion Batteries. Energies 2020, 13 (9) , 2163. https://doi.org/10.3390/en13092163
    40. Van At Nguyen, Christian Kuss. Review—Conducting Polymer-Based Binders for Lithium-Ion Batteries and Beyond. Journal of The Electrochemical Society 2020, 167 (6) , 065501. https://doi.org/10.1149/1945-7111/ab856b
    41. QiLiang Pan, Jianguo Zhao, Wenshan Qu, Rui Liu, Ning Li, Baoyan Xing, Shang Jiang, Mingjun Pang, Lu zhao, Yichan Zhang, Wei Liang. Facile synthesis of the 3D framework Si@N-doped C/Reduced graphene oxide composite by polymer network method for highly stable lithium storage. Journal of Physics and Chemistry of Solids 2019, 133 , 92-99. https://doi.org/10.1016/j.jpcs.2019.05.010
    42. Sai Wang, Jianxiong Liu, Xiaohua Yu, Jiaming Liu, JuRong, Chengyi Zhu, Qiang Wang, Zhentao Yuan, Yannan Zhang. Electrochemical Behavior of 3,4-ethylenedioxythiophene as an Anti-overcharge Additive for Lithium-ion Batteries. International Journal of Electrochemical Science 2019, 14 (10) , 9527-9536. https://doi.org/10.20964/2019.10.36
    43. Qiliang Pan, Jianguo Zhao, Baoyan Xing, Shang Jiang, Mingjun Pang, Wenshan Qu, Shanshan Zhang, Yichan Zhang, Lu Zhao, Wei Liang. A hierarchical porous architecture of silicon@TiO 2 @carbon composite novel anode materials for high performance Li-ion batteries. New Journal of Chemistry 2019, 43 (38) , 15342-15350. https://doi.org/10.1039/C9NJ03708J
    44. Hari Raj, Anjan Sil. PEDOT:PSS coating on pristine and carbon coated LiFePO4 by one-step process: the study of electrochemical performance. Journal of Materials Science: Materials in Electronics 2019, 30 (14) , 13604-13616. https://doi.org/10.1007/s10854-019-01730-1
    45. S.N. Eliseeva, E.V. Shkreba, M.A. Kamenskii, E.G. Tolstopjatova, R. Holze, V.V. Kondratiev. Effects of conductive binder on the electrochemical performance of lithium titanate anodes. Solid State Ionics 2019, 333 , 18-29. https://doi.org/10.1016/j.ssi.2019.01.011
    46. Tiefeng Liu, Chuan‐Jia Tong, Bo Wang, Li‐Min Liu, Shanqing Zhang, Zhan Lin, Dianlong Wang, Jun Lu. Trifunctional Electrode Additive for High Active Material Content and Volumetric Lithium‐Ion Electrode Densities. Advanced Energy Materials 2019, 9 (10) https://doi.org/10.1002/aenm.201803390
    47. Yu Wang, Xuewei Fu, Min Zheng, Wei‐Hong Zhong, Guozhong Cao. Strategies for Building Robust Traffic Networks in Advanced Energy Storage Devices: A Focus on Composite Electrodes. Advanced Materials 2019, 31 (6) https://doi.org/10.1002/adma.201804204
    48. Jinfeng Liu, Jing Xu, Yufang Chen, Weiwei Sun, Xiaoxiong Zhou, Jianhuang Ke. Synthesis and Electrochemical Performance of a PEDOT:PSS@Ge Composite as the Anode Materials for Lithium-Ion Batteries. International Journal of Electrochemical Science 2019, 14 (1) , 359-370. https://doi.org/10.20964/2019.01.08
    49. Naiara Fernández, Paula Sánchez‐Fontecoba, Elizabeth Castillo‐Martínez, Javier Carretero‐González, Teófilo Rojo, Michel Armand. Polymeric Redox‐Active Electrodes for Sodium‐Ion Batteries. ChemSusChem 2018, 11 (1) , 311-319. https://doi.org/10.1002/cssc.201701471
    50. S. Ferrari, J.R. Nair, Y. Zhou, C. Wan. Polymer nanocomposites for lithium battery applications. 2018, 283-313. https://doi.org/10.1016/B978-0-08-102262-7.00010-6
    51. Svetlana N. Eliseeva, Elena V. Alekseeva, Anatoliy A. Vereshchagin, Alexey I. Volkov, Petr S. Vlasov, Alexander S. Konev, Oleg V. Levin. Nickel‐Salen Type Polymers as Cathode Materials for Rechargeable Lithium Batteries. Macromolecular Chemistry and Physics 2017, 218 (24) https://doi.org/10.1002/macp.201700361
    52. Ri-Chao Zhang, Dan Sun, Ruirui Zhang, Wen-Feng Lin, Manuel Macias-Montero, Jenish Patel, Sadegh Askari, Calum McDonald, Davide Mariotti, Paul Maguire. Gold nanoparticle-polymer nanocomposites synthesized by room temperature atmospheric pressure plasma and their potential for fuel cell electrocatalytic application. Scientific Reports 2017, 7 (1) https://doi.org/10.1038/srep46682
    53. Qianhui Wu, Rongfang Zhao, Wenjie Liu, Xiue Zhang, Xiao Shen, Wenlong Li, Guowang Diao, Ming Chen. In-depth nanocrystallization enhanced Li-ions batteries performance with nitrogen-doped carbon coated Fe3O4 yolk−shell nanocapsules. Journal of Power Sources 2017, 344 , 74-84. https://doi.org/10.1016/j.jpowsour.2017.01.101
    54. S.N. Eliseeva, R.V. Apraksin, E.G. Tolstopjatova, V.V. Kondratiev. Electrochemical impedance spectroscopy characterization of LiFePO 4 cathode material with carboxymethylcellulose and poly-3,4-ethylendioxythiophene/polystyrene sulfonate. Electrochimica Acta 2017, 227 , 357-366. https://doi.org/10.1016/j.electacta.2016.12.157
    55. Prakash Sengodu. Conducting Polymers/Inorganic Nanohybrids for Energy Applications. 2017, 365-417. https://doi.org/10.1007/978-3-319-57003-7_9
    56. Amélie Robitaille, Alexis Perea, Daniel Bélanger, Mario Leclerc. Poly(5-alkyl-thieno[3,4-c]pyrrole-4,6-dione): a study of π-conjugated redox polymers as anode materials in lithium-ion batteries. Journal of Materials Chemistry A 2017, 5 (34) , 18088-18094. https://doi.org/10.1039/C7TA03786D
    57. O.Yu. Posudievsky, O.A. Kozarenko, V.G. Koshechko, V.D. Pokhodenko. Conducting Polymer‐based Hybrid Nanocomposites as Promising Electrode Materials for Lithium Batteries. 2016, 355-396. https://doi.org/10.1002/9781119242659.ch9
    58. Gen Chen, Litao Yan, Hongmei Luo, Shaojun Guo. Nanoscale Engineering of Heterostructured Anode Materials for Boosting Lithium‐Ion Storage. Advanced Materials 2016, 28 (35) , 7580-7602. https://doi.org/10.1002/adma.201600164
    59. Ting Ma, Qing Zhao, Jianbin Wang, Zeng Pan, Jun Chen. A Sulfur Heterocyclic Quinone Cathode and a Multifunctional Binder for a High‐Performance Rechargeable Lithium‐Ion Battery. Angewandte Chemie 2016, 128 (22) , 6538-6542. https://doi.org/10.1002/ange.201601119
    60. Ting Ma, Qing Zhao, Jianbin Wang, Zeng Pan, Jun Chen. A Sulfur Heterocyclic Quinone Cathode and a Multifunctional Binder for a High‐Performance Rechargeable Lithium‐Ion Battery. Angewandte Chemie International Edition 2016, 55 (22) , 6428-6432. https://doi.org/10.1002/anie.201601119
    61. Pratik R. Das, Lidiya Komsiyska, Oliver Osters, Gunther Wittstock. Effect of solid loading on the processing and behavior of PEDOT:PSS binder based composite cathodes for lithium ion batteries. Synthetic Metals 2016, 215 , 86-94. https://doi.org/10.1016/j.synthmet.2016.02.011
    62. Aziz Ahmad, Haiping Wu, Yufen Guo, Qinghai Meng, Yuena Meng, Kun Lu, Liwei Liu, Zhixiang Wei. A graphene supported polyimide nanocomposite as a high performance organic cathode material for lithium ion batteries. RSC Advances 2016, 6 (40) , 33287-33294. https://doi.org/10.1039/C5RA27471K
    63. Syed Ali Abbas, Mohammad Aziz Ibrahem, Lung-Hao Hu, Chia-Nan Lin, Jason Fang, Karunakara Moorthy Boopathi, Pen-Cheng Wang, Lain-Jong Li, Chih-Wei Chu. Bifunctional separator as a polysulfide mediator for highly stable Li–S batteries. Journal of Materials Chemistry A 2016, 4 (24) , 9661-9669. https://doi.org/10.1039/C6TA02272C
    64. Chihyun Hwang, Yoon-Gyo Cho, Na-Ri Kang, Younghoon Ko, Ungju Lee, Dongjoon Ahn, Ju-Young Kim, Young-Jin Kim, Hyun-Kon Song. Selectively accelerated lithium ion transport to silicon anodes via an organogel binder. Journal of Power Sources 2015, 298 , 8-13. https://doi.org/10.1016/j.jpowsour.2015.08.017
    65. S.N. Eliseeva, O.V. Levin, E.G. Tolstopjatova, E.V. Alekseeva, R.V. Apraksin, V.V. Kondratiev. New functional conducting poly-3,4-ethylenedioxythiopene:polystyrene sulfonate/carboxymethylcellulose binder for improvement of capacity of LiFePO4-based cathode materials. Materials Letters 2015, 161 , 117-119. https://doi.org/10.1016/j.matlet.2015.08.078
    66. Jiahui Chen, Yuan Gao, Cuihua Li, Hui Zhang, Jianhong Liu, Qianling Zhang. Interface modification in high voltage spinel lithium-ion battery by using N-methylpyrrole as an electrolyte additive. Electrochimica Acta 2015, 178 , 127-133. https://doi.org/10.1016/j.electacta.2015.08.012
    67. O.V. Levin, S.N. Eliseeva, E.V. Alekseeva, E.G. Tolstopjatova, V.V. Kondratiev. Composite LiFePO4/poly-3,4-ethylenedioxythiophene Cathode for Lithium-Ion Batteries with Low Content of Non-Electroactive Components. International Journal of Electrochemical Science 2015, 10 (10) , 8175-8189. https://doi.org/10.1016/S1452-3981(23)11085-6
    68. S. N. Eliseeva, O. V. Levin, E. G. Tolstopyatova, E. V. Alekseeva, V. V. Kondratiev. Effect of addition of a conducting polymer on the properties of the LiFePO4-based cathode material for lithium-ion batteries. Russian Journal of Applied Chemistry 2015, 88 (7) , 1146-1149. https://doi.org/10.1134/S1070427215070071
    69. Bing Li, Xiaoming Ge, F. W. Thomas Goh, T. S. Andy Hor, Dongsheng Geng, Guojun Du, Zhaolin Liu, Jie Zhang, Xiaogang Liu, Yun Zong. Co 3 O 4 nanoparticles decorated carbon nanofiber mat as binder-free air-cathode for high performance rechargeable zinc-air batteries. Nanoscale 2015, 7 (5) , 1830-1838. https://doi.org/10.1039/C4NR05988C
    70. Prakash Sengodu, Abhay D. Deshmukh. Conducting polymers and their inorganic composites for advanced Li-ion batteries: a review. RSC Advances 2015, 5 (52) , 42109-42130. https://doi.org/10.1039/C4RA17254J
    71. Chanhoon Kim, Sinho Choi, Seungmin Yoo, Dohyoung Kwon, Seunghee Ko, Ju-Myung Kim, Sang-Young Lee, Il-Doo Kim, Soojin Park. A facile route for growth of CNTs on Si@hard carbon for conductive agent incorporating anodes for lithium-ion batteries. Nanoscale 2015, 7 (26) , 11286-11290. https://doi.org/10.1039/C5NR02860D
    Download PDF

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    MENDELEY PAIRING EXPIRED
    Your Mendeley pairing has expired. Please reconnect