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Saponins: A Renewable and Biodegradable Surfactant From Its Microwave-Assisted Extraction to the Synthesis of Monodisperse Lattices

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† IPREM, UMR 5254, CNRS/UPPA, 2 av.Angot, 64053 Pau cedex 9, France
‡ National Institute of Standards and Technology, Materials Measurement Science Division, 100 Bureau Drive, MS 8520, Gaithersburg, Maryland 20899-8520, United States
*E-mail: [email protected]
Cite this: Biomacromolecules 2014, 15, 3, 856–862
Publication Date (Web):January 21, 2014
https://doi.org/10.1021/bm401708m
Copyright © 2014 American Chemical Society
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    Abstract

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    Synthetic surfactants are widely used in emulsion polymerization, but it is increasingly desirable to replace them with naturally derived molecules with a reduced environmental burden. This study demonstrates the use of saponins as biodegradable and renewable surfactants for emulsion polymerization. This chemical has been extracted from soapnuts by microwave assisted extraction and characterized in terms of surfactant properties prior to emulsion polymerization. The results in terms of particle size distribution and morphology control have been compared to those obtained with classical nonionic (NP40) or anionic (SDS) industrial surfactants. Microwave-extracted saponins were able to lead to latexes as stable as standard PS latex, as shown by the CMC and CCC measurements. The saponin-stabilized PS particles have been characterized in terms of particle size and distribution by Dynamic Light Scattering and Asymmetrical Flow Field Flow Fractionation. Monomodal and monodispersed particles ranging from 250 to 480 nm in terms of diameter with a particle size distribution below 1.03 have been synthesized.

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