ACS Publications. Most Trusted. Most Cited. Most Read
Controlled Synthesis of Isomorphous Coordination Polymers via in Situ Ligand Transformation Reaction: Crystal Structure, Thermal and Magnetic Properties

OR SEARCH CITATIONS

My Activity
Publications

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:Crystal Growth & Design 2010, 10, 9, 4060-4067
    Article

    Controlled Synthesis of Isomorphous Coordination Polymers via in Situ Ligand Transformation Reaction: Crystal Structure, Thermal and Magnetic Properties
    Click to copy article linkArticle link copied!

    View Author Information
    † School of Chemistry, University of New South Wales, Sydney, NSW 2052, Australia
    § Analytical Centre, University of New South Wales, Sydney, NSW 2052, Australia
    ‡ Bragg Institute, Australian Nuclear Science and Technology Organisation, PMB 1, Menai, NSW 2234, Australia
    *To whom correspondence should be addressed. Fax: +61 (02) 9385 6141. Tel: +61 (0)2 9385 4675. E-mail: [email protected]
    Other Access OptionsSupporting Information (1)

    Crystal Growth & Design

    Cite this: Cryst. Growth Des. 2010, 10, 9, 4060–4067
    Click to copy citationCitation copied!
    https://doi.org/10.1021/cg1007389
    Published August 3, 2010
    Copyright © 2010 American Chemical Society
    Request reuse permissions

    Abstract

    Click to copy section linkSection link copied!
    Abstract Image

    A series of isomorphous [M2(ip)2(L)2]n (M = Co, Ni; ip = isophthalate; L = 4,4′-dipyridyl and pyrazine) coordination polymers was synthesized via in situ ligand transformation reactions, in which 1,2,3-benzene tricarboxylic acid (1,2,3-btcH3) undergoes decarboxylation to isophthalate (ip), which was found to be highly dependent on the reaction temperature. The polymers crystallize in the same crystal triclinic system P1̅. The magnetic properties were investigated by a Quantum Design physical property measurement system (PPMS); all four compounds feature almost isostructural M(II) dimers having ferromagnetic (FM) interactions. The interdimer interactions mediated by two different carboxylate groups of ip are weak, while there is no significant magnetic exchange via the 4,4′-dipyridyl ligands along the chain direction. However, substitution with pyrazine leads to antiferromagnetic exchange of nearest neighbor dimers.

    Copyright © 2010 American Chemical Society

    Subjects

    what are subjects

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. Add or change your institution or let them know you’d like them to include access.

    Supporting Information

    Click to copy section linkSection link copied!

    Thermogravimetric curves (S1) and χ vs T plots per dimer of 1−4 (S2). This material is available free of charge via the Internet at http://pubs.acs.org.

    Terms & Conditions

    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    Click to copy section linkSection link copied!

    This article is cited by 32 publications.

    1. Luann R. D’souza, Nikita N. Harmalkar, Sarvesh S. Harmalkar, Sakharam B. Tayade, Sunder N. Dhuri. Construction of Pyrazine-Appended 1D and 3D Cobalt(II) Succinate Coordination Polymers: Influence of Solvent on Architectures and Applications in Gas Adsorption and NAC Detection. ACS Omega 2022, 7 (7) , 5698-5712. https://doi.org/10.1021/acsomega.1c05216
    2. Xiaoqing Wang, Jie Yang, Liangliang Zhang, Fuling Liu, Fangna Dai, and Daofeng Sun . Synthesis of Two Triarylboron-Functionalized Metal–Organic Frameworks: In Situ Decarboxylic Reaction, Structure, Photoluminescence, and Gas Adsorption Properties. Inorganic Chemistry 2014, 53 (20) , 11206-11212. https://doi.org/10.1021/ic501801f
    3. Verónica Paredes-García, Ricardo C. Santana, Rosa Madrid, Andrés Vega, Evgenia Spodine, and Diego Venegas-Yazigi . Unusual Conformation of a Dinuclear Paddle Wheel Copper(II) Complex. Synthesis, Structural Characterization and EPR Studies. Inorganic Chemistry 2013, 52 (15) , 8369-8377. https://doi.org/10.1021/ic3027804
    4. Yuh Hijikata, Satoshi Horike, Masayuki Sugimoto, Munehiro Inukai, Tomohiro Fukushima, and Susumu Kitagawa . Pore Design of Two-Dimensional Coordination Polymers toward Selective Adsorption. Inorganic Chemistry 2013, 52 (7) , 3634-3642. https://doi.org/10.1021/ic302006x
    5. Jiong-Peng Zhao, Song-De Han, Ran Zhao, Qian Yang, Ze Chang, and Xian-He Bu . Tuning the Structure and Magnetism of Heterometallic Sodium(1+)–Cobalt(2+) Formate Coordination Polymers by Varying the Metal Ratio and Solvents. Inorganic Chemistry 2013, 52 (6) , 2862-2869. https://doi.org/10.1021/ic301936k
    6. Benlai Wu, Song Wang, Ruiying Wang, Jinxia Xu, Daqiang Yuan, and Hongwei Hou . Chiral Metallocycles Templated Novel Chiral Water Frameworks. Crystal Growth & Design 2013, 13 (2) , 518-525. https://doi.org/10.1021/cg300971r
    7. Sheng-Yun Liao, Wen Gu, Lin-Yan Yang, Tian-Hao Li, Jin-Lei Tian, Li Wang, Ming Zhang, and Xin Liu . Series of Novel 3D Heterometallic Frameworks Based on the Co(II) Coordination Chains and Ln(III) Coordination Layers. Crystal Growth & Design 2012, 12 (8) , 3927-3936. https://doi.org/10.1021/cg300326e
    8. Karah E. Knope, Hiroshi Kimura, Yoshiro Yasaka, Masaru Nakahara, Michael B. Andrews, and Christopher L. Cahill . Investigation of in Situ Oxalate Formation from 2,3-Pyrazinedicarboxylate under Hydrothermal Conditions Using Nuclear Magnetic Resonance Spectroscopy. Inorganic Chemistry 2012, 51 (6) , 3883-3890. https://doi.org/10.1021/ic3000944
    9. Qian Chu, Zhi Su, Jian Fan, Taka-aki Okamura, Gao-Chao Lv, Guang-Xiang Liu, Wei-Yin Sun, and Norikazu Ueyama . Novel Cobalt(II) Coordination Polymers Constructed from 3,3′,4,4′-Oxydiphthalic Acid and N-Donor Ligands: Syntheses, Crystal Structures, and Magnetic Properties. Crystal Growth & Design 2011, 11 (9) , 3885-3894. https://doi.org/10.1021/cg200416y
    10. Ji-Jiang Wang, Zhuang Cao, Xiao Wang, Long Tang, Xiang-Yang Hou, Ping Ju, Yi-Xia Ren, Xiao-Li Chen, Yu-Qi Zhang. A novel 3D Cd( ii ) coordination polymer generated via in situ ligand synthesis involving C–O ester bond formation. RSC Advances 2019, 9 (1) , 307-312. https://doi.org/10.1039/C8RA06112B
    11. Brianna L. Martinez, Robert L. LaDuca. Diverse layered topology and magnetic subunits in cobalt cyclohexyldicarboxylate coordination polymers with 3-pyridylnicotinamide coligands. Polyhedron 2019, 157 , 276-283. https://doi.org/10.1016/j.poly.2018.09.047
    12. Farnoosh ZareKarizi, Monika Joharian, Ali Morsali. Pillar-layered MOFs: functionality, interpenetration, flexibility and applications. Journal of Materials Chemistry A 2018, 6 (40) , 19288-19329. https://doi.org/10.1039/C8TA03306D
    13. Alysson Duarte Rodrigues, Karim Fahsi, Xavier Dumail, Nathalie Masquelez, Arie van der Lee, Sonia Mallet‐Ladeira, Romain Sibille, Jean‐Sébastien Filhol, Sylvain G. Dutremez. Joint Experimental and Computational Investigation of the Flexibility of a Diacetylene‐Based Mixed‐Linker MOF: Revealing the Existence of Two Low‐Temperature Phase Transitions and the Presence of Colossal Positive and Giant Negative Thermal Expansions. Chemistry – A European Journal 2018, 24 (7) , 1586-1605. https://doi.org/10.1002/chem.201703711
    14. Yong-Feng Qiao, Jie Zhou, Lin Du, Ming-Jin Xie, Qi-Hua Zhao. A new cobalt(II) polycatenation complex based on urazole: In situ ligand synthesis, crystal structure, and properties. Inorganica Chimica Acta 2016, 440 , 48-52. https://doi.org/10.1016/j.ica.2015.10.036
    15. Sabri Cevik, Bariş Telli, Hakan Dal, Musa Sari. A Tridentate In Situ Generated Ligand Leading the Self-Assembly of a Transition Metal Coordination Polymer: Solvothermal Synthesis and Structural Characterization of 1D Cadmium Pyridine-2-Carboxylate. Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry 2015, 45 (1) , 139-144. https://doi.org/10.1080/15533174.2013.819913
    16. Maria D. Torres Salgado, Robert L. LaDuca. Effect of substituent on dimensionality and properties in divalent metal isophthalate coordination polymers with a conformationally flexible dipyridylamide coligand. Journal of Molecular Structure 2015, 1079 , 111-119. https://doi.org/10.1016/j.molstruc.2014.09.001
    17. Sarita Tripathi, Ganapathi Anantharaman. Architectures varying from discrete molecular units to 2-dimensional coordination polymers and photoluminescence behavior of zinc and cadmium comprising an anionic zwitterion of rigid 4,5-dicarboxy-1,3-dimethyl-1 H -imidazolium iodide. CrystEngComm 2015, 17 (13) , 2754-2768. https://doi.org/10.1039/C4CE02215G
    18. Hui-Ru Chen. Synthesis, Structure and Physical Properties of A Novel 2D Cd(II) Coordination Polymer Involving 4-Thiopyridine Based on in situ Formation from 4,4'-Dithiodipyridine. Bulletin of the Korean Chemical Society 2014, 35 (9) , 2839-2842. https://doi.org/10.5012/bkcs.2014.35.9.2839
    19. Xinyu Cao, Liqiong Yu, Rudan Huang. Two Ce-containing 3D metal–organic frameworks: In situ formation of ligand (DDPD). Journal of Solid State Chemistry 2014, 210 (1) , 74-78. https://doi.org/10.1016/j.jssc.2013.10.045
    20. Kang Liu, Xu Han, Yongcun Zou, Yu Peng, Guanghua Li, Zhan Shi, Shouhua Feng. Solvothermal synthesis, structures, and gas adsorption properties of two cadmium-organic frameworks. Inorganic Chemistry Communications 2014, 39 , 131-134. https://doi.org/10.1016/j.inoche.2013.11.011
    21. Sara Tarighi, Alireza Abbasi, Shokoofeh Geranmayeh, Alireza Badiei. Synthesis of a New Interpenetrated Mixed Ligand Ni(II) Metal–Organic Framework: Structural, Thermal and Fluorescence Studies and its Thermal Decomposition to NiO Nanoparticles. Journal of Inorganic and Organometallic Polymers and Materials 2013, 23 (4) , 808-815. https://doi.org/10.1007/s10904-013-9845-6
    22. Jing-Yun Hu, Jiong Wen, Xiao-Gang Yang, Min Chen, Chun-Sen Liu. A 3-D lanthanide–organic framework based on in situ formed benzene-1,2,3,4-tetracarboxylate ligand. Inorganic Chemistry Communications 2013, 33 , 25-28. https://doi.org/10.1016/j.inoche.2013.03.035
    23. Xiaoping Zhang, Jingmin Zhou, Wei Shi, Zhenjie Zhang, Peng Cheng. Two cadmium(ii) coordination polymers constructed by carboxylate and pyridine mixed ligands: synthesis, structure and luminescent properties. CrystEngComm 2013, 15 (45) , 9738. https://doi.org/10.1039/c3ce41073k
    24. Jiong-Peng Zhao, Qian Yang, Song-De Han, Jie Han, Ran Zhao, Bo-Wen Hu, Xian-He Bu. A chiral 2p–3d heterometallic azido complex with 2,6-pyridinedicarboxylate as the co-ligand showing magnetic order. Dalton Transactions 2013, 42 (23) , 8201. https://doi.org/10.1039/c3dt50835h
    25. Xin-Qi Liu, Zhong-Yuan Li, Xiao-Ju Yuan, Ben-Lai Wu. Two new 2-D coordination polymers based on a purine-containing carboxylate. Journal of Coordination Chemistry 2012, 65 (21) , 3721-3730. https://doi.org/10.1080/00958972.2012.724172
    26. Shao-Ming Fang, Min Chen, Xiao-Gang Yang, Jing-Yun Hu, Chun-Sen Liu. Construction of metal–organic replica of sqc1121 network based on a multifunctional ligand via solvothermal in situ disulfide cleavage reaction. Inorganic Chemistry Communications 2012, 22 , 101-103. https://doi.org/10.1016/j.inoche.2012.05.033
    27. Zhao-Peng Deng, Zhu-Yan Zhang, Li-Hua Huo, Seik Weng Ng, Hui Zhao, Shan Gao. Syntheses, crystal structures and properties of transition metal coordination polymers based on isophthalic acid and flexible bis(pyridyl) ligand with unsymmetrical spacer: influence of metal cations, ligand conformations and coordination modes. CrystEngComm 2012, 14 (20) , 6548. https://doi.org/10.1039/c2ce25339a
    28. Ye-Qiang Feng, Jian Long, Juan Li. μ-Decanedioato-bis[aquabis(1,10-phenanthroline-κ 2 N , N ′)manganese(II)] dinitrate–sebacic acid–water (1/1/2). Acta Crystallographica Section E Structure Reports Online 2011, 67 (1) , m80-m81. https://doi.org/10.1107/S1600536810051615
    29. Jia-Lu Liu, Jian-Feng Liu, Guo-Liang Zhao. Bis[μ-2-(4-hydroxyphenyl)acetato]-κ 3 O , O ′: O ;κ 3 O : O , O ′-bis{aqua(4,4′-bipyridine-κ N )bis[2-(4-hydroxyphenyl)acetato-κ 2 O , O ′]dysprosium(III)} monohydrate. Acta Crystallographica Section E Structure Reports Online 2010, 66 (12) , m1505-m1505. https://doi.org/10.1107/S1600536810044107
    30. Jia-Lu Liu, Jian-Feng Liu, Guo-Liang Zhao. Bis[μ-2-(4-hydroxyphenyl)acetato]-κ 3 O , O ′: O ;κ 3 O : O , O ′-bis{aqua(4,4′-bipyridine-κ N )[2-(4-hydroxyphenyl)acetato-κ 2 O , O ′]samarium(III)} monohydrate. Acta Crystallographica Section E Structure Reports Online 2010, 66 (12) , m1511-m1512. https://doi.org/10.1107/S1600536810044454
    31. Hang-Ming Guo. catena -Poly[[[diaqua(nitrato-κ 2 O , O ′)cerium(III)]-bis[μ-2-(4-hydroxyphenyl)acetato]-κ 3 O , O ′: O ;κ 3 O : O , O ′] monohydrate]. Acta Crystallographica Section E Structure Reports Online 2010, 66 (12) , m1602-m1602. https://doi.org/10.1107/S1600536810047239
    32. Jia-Lu Liu, Jian-Feng Liu, Guo-Liang Zhao. catena -Poly[[{diaqua[2-(4-hydroxyphenyl)acetato-κ 2 O , O ′]cerium(III)}-bis[μ-2-(4-hydroxyphenyl)acetato]-κ 3 O , O ′: O ;κ 3 O : O , O ′] 4,4′-bipyridine disolvate monohydrate]. Acta Crystallographica Section E Structure Reports Online 2010, 66 (12) , m1678-m1678. https://doi.org/10.1107/S1600536810048166
    Download PDF
    Go to Crystal Growth & Design
    Get e-Alerts
    Get e-Alerts

    Crystal Growth & Design

    Cite this: Cryst. Growth Des. 2010, 10, 9, 4060–4067
    Click to copy citationCitation copied!
    https://doi.org/10.1021/cg1007389
    Published August 3, 2010
    Copyright © 2010 American Chemical Society
    Request reuse permissions

    Article Views

    916

    Altmetric

    -

    Citations

    32
    Learn about these metrics

    Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.

    Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.

    The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.