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Magnetite Nanocrystals:  Nonaqueous Synthesis, Characterization, and Solubility
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    Magnetite Nanocrystals:  Nonaqueous Synthesis, Characterization, and Solubility
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    Institut für Anorganische Chemie, Martin-Luther-Universität Halle-Wittenberg, Kurt-Mothes-Strasse 2, 06120 Halle (Saale), Germany, Max-Planck-Institute of Colloids and Interfaces, Research Campus Golm, 14424 Potsdam, Germany, Department of Inorganic Chemistry, Fritz-Haber-Institute of the Max-Planck-Society, Faradayweg 4-6, D-14195 Berlin, Germany, and CEA, CE Saclay, DSM/DRECAM/SPEC, 91191 Gif-Sur-Yvette, France
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    Chemistry of Materials

    Cite this: Chem. Mater. 2005, 17, 11, 3044–3049
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    https://doi.org/10.1021/cm050060+
    Published May 7, 2005
    Copyright © 2005 American Chemical Society

    Abstract

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    A novel nonaqueous route has been applied for the preparation of nanocrystalline magnetite. In a simple one-pot reaction process, iron(III) acetylacetonate was dissolved in benzyl alcohol and treated in an autoclave between 175 and 200 °C. This approach leads to monocrystalline magnetite particles with sizes ranging from 12 to 25 nm, as evidenced by X-ray analysis, HRTEM, and Raman and Mössbauer spectroscopy. The isolated particles can be redispersed either in polar or nonpolar solvents by coating them just after synthesis with undecanoic acid or dopamine. Simple sedimentation after redispersion in hexane can be used to lower the polydispersity of the sample.

    Copyright © 2005 American Chemical Society

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     Nicola Pinna would like to dedicate this article to Prof. Dr. J. Urban and Klaus Weiss on the occasion of their retirement for their contributions in the studies of nanoparticles.

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     Corresponding author. E-mail:  [email protected]. Tel: 49 345 55 25870. Fax:  49 345 55 27343.

     Martin-Luther-Universität Halle-Wittenberg.

    §

     Max-Planck-Institute of Colloids and Interfaces.

     Fritz-Haber-Institute of the Max-Planck-Society.

     CEA, CE Saclay, DSM/DRECAM/SPEC.

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    Cite this: Chem. Mater. 2005, 17, 11, 3044–3049
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    Published May 7, 2005
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