ACS Publications. Most Trusted. Most Cited. Most Read

OR SEARCH CITATIONS

My Activity
Publications
CONTENT TYPES

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:Chem. Mater. 2014, 26, 24, 7189-7193
RETURN TO ISSUEPREVArticleNEXT

Preparation of Freestanding Conjugated Microporous Polymer Nanomembranes for Gas Separation

View Author Information
† Institute of Functional Interfaces (IFG), Karlsruhe Institute of Technology (KIT), 76344 Eggenstein-Leopoldshafen, Germany
‡ Institute of Polymer Research, Helmholtz-Zentrum Geesthacht, 21502 Geesthacht, Germany
§ Institute of Physical Chemistry, University of Hamburg, 20146 Hamburg, Germany
∥ Institute for Organic Chemistry (IOC), Karlsruhe Institute of Technology (KIT), 76131 Karlsruhe, Germany
⊥ Faculty of Physics, Bielefeld University, 33615 Bielefeld, Germany
# Institute of Toxicology and Genetics (ITG), Karlsruhe Institute of Technology (KIT), 76344 Eggenstein-Leopoldshafen, Germany
* M. Tsotsalas. E-mail: [email protected]
Cite this: Chem. Mater. 2014, 26, 24, 7189–7193
Publication Date (Web):November 20, 2014
https://doi.org/10.1021/cm503924h
Copyright © 2014 American Chemical Society
Request reuse permissions

    Article Views

    3857

    Altmetric

    -

    Citations

    108
    LEARN ABOUT THESE METRICS
    Read OnlinePDF (2 MB)
    Get e-Alerts
    Supporting Info (1)»
    SUBJECTS:

    Abstract

    Abstract Image

    Conjugated microporous polymers (CMPs) have attracted much interest due to their intrinsic porosity, outstanding stability, and high variability. However, the processing of these materials for membrane application has been limited due to their insoluble nature when synthesized as bulk material. Here we report the synthesis of freestanding CMP-nanomembranes via layer-by-layer growth of a “click” based conjugated microporous polymer on a sacrificial substrate. After dissolution of the substrate the CMP-nanomembrane can be transferred to porous substrates and continuously cover holes of up to 50 μm diameter. The CMP-nanomembranes appear defect-free as inferred from high selectivity values obtained from gas permeation experiments and from electrochemical investigation in the presence of ferrocene. The presented synthesis method represents a versatile strategy to incorporate CMP materials in functional devices for membrane separation, catalysis, or organic electronics.

    Supporting Information

    ARTICLE SECTIONS
    Jump To

    Further information for experimental procedures, IR-spectra, AFM and helium microscopy images, cyclic voltammetry, and permeance measurements. This material is available free of charge via the Internet at http://pubs.acs.org.

    Terms & Conditions

    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    This article is cited by 108 publications.

    1. Kai Li, Junyong Zhu, Decheng Liu, Yatao Zhang, Bart Van der Bruggen. Controllable and Rapid Synthesis of Conjugated Microporous Polymer Membranes via Interfacial Polymerization for Ultrafast Molecular Separation. Chemistry of Materials 2021, 33 (17) , 7047-7056. https://doi.org/10.1021/acs.chemmater.1c02143
    2. Xiaochen Xu, Jie Dong, Xian Xiao, Xin Zhao, Qinghua Zhang. Constructing Thin and Cross-Linked Polyimide Membranes by Interfacial Reaction for Efficient CO2 Separation. ACS Sustainable Chemistry & Engineering 2021, 9 (16) , 5546-5556. https://doi.org/10.1021/acssuschemeng.0c08779
    3. Qiu Zhuang, Ruru Gao, Mingyang Shi, Xiangpeng Lin, Aming Xie, Wei Dong. Confining Palladium Nanoparticles in Microporous Tetrastyrene Polymer Enables Efficient Size-Selective Heterogeneous Catalysis. ACS Applied Nano Materials 2021, 4 (4) , 3869-3876. https://doi.org/10.1021/acsanm.1c00282
    4. Olena Selyanchyn, Roman Selyanchyn, Shigenori Fujikawa. Critical Role of the Molecular Interface in Double-Layered Pebax-1657/PDMS Nanomembranes for Highly Efficient CO2/N2 Gas Separation. ACS Applied Materials & Interfaces 2020, 12 (29) , 33196-33209. https://doi.org/10.1021/acsami.0c07344
    5. Jet-Sing M. Lee, Andrew I. Cooper. Advances in Conjugated Microporous Polymers. Chemical Reviews 2020, 120 (4) , 2171-2214. https://doi.org/10.1021/acs.chemrev.9b00399
    6. Wencai Zhou, Salma Begum, Zhengbang Wang, Peter Krolla, Danny Wagner, Stefan Bräse, Christof Wöll, and Manuel Tsotsalas . High Antimicrobial Activity of Metal–Organic Framework-Templated Porphyrin Polymer Thin Films. ACS Applied Materials & Interfaces 2018, 10 (2) , 1528-1533. https://doi.org/10.1021/acsami.7b14866
    7. Pillaiyar Puthiaraj and Wha-Seung Ahn . CO2 Capture by Porous Hyper-Cross-Linked Aromatic Polymers Synthesized Using Tetrahedral Precursors. Industrial & Engineering Chemistry Research 2016, 55 (29) , 7917-7923. https://doi.org/10.1021/acs.iecr.5b03963
    8. Baltasar Bonillo, Reiner Sebastian Sprick, and Andrew I. Cooper . Tuning Photophysical Properties in Conjugated Microporous Polymers by Comonomer Doping Strategies. Chemistry of Materials 2016, 28 (10) , 3469-3480. https://doi.org/10.1021/acs.chemmater.6b01195
    9. Lingbo Meng, Xiaoqin Zou, Shukun Guo, Heping Ma, Yongnan Zhao, and Guangshan Zhu . Self-Supported Fibrous Porous Aromatic Membranes for Efficient CO2/N2 Separations. ACS Applied Materials & Interfaces 2015, 7 (28) , 15561-15569. https://doi.org/10.1021/acsami.5b04148
    10. Afshin Dianatdar, Ranjita K. Bose. Oxidative chemical vapor deposition for synthesis and processing of conjugated polymers: a critical review. Journal of Materials Chemistry C 2023, 11 (35) , 11776-11802. https://doi.org/10.1039/D3TC01614E
    11. Ziyang Wang, Haicheng Jiang, Yuyang Tian, Xiaoqin Zou, Guangshan Zhu. Porous aromatic frameworks with engineered properties for gas separation membranes. Trends in Chemistry 2023, 5 (6) , 446-459. https://doi.org/10.1016/j.trechm.2023.02.011
    12. Wenliang Song, Yu Zhang, Chinh Hoang Tran, Ha Kyung Choi, Deng-Guang Yu, Il Kim. Porous Organic Polymers with Defined Morphologies: Synthesis, Assembly, and Emerging Applications. Progress in Polymer Science 2023, 8 , 101691. https://doi.org/10.1016/j.progpolymsci.2023.101691
    13. Shenzhen Cong, Ye Yuan, Jixiao Wang, Zhi Wang, Xinlei Liu. Network polyimide membranes prepared by interfacial polymerization for hot H 2 purification. AIChE Journal 2023, 69 (4) https://doi.org/10.1002/aic.17983
    14. Rafał Zbonikowski, Pumza Mente, Bartłomiej Bończak, Jan Paczesny. Adaptive 2D and Pseudo-2D Systems: Molecular, Polymeric, and Colloidal Building Blocks for Tailored Complexity. Nanomaterials 2023, 13 (5) , 855. https://doi.org/10.3390/nano13050855
    15. Qing Hao, You Tao, Xuesong Ding, Yajie Yang, Jie Feng, Rui-Lei Wang, Xue-Ming Chen, Guan-Le Chen, Xiaomeng Li, Huang OuYang, XunLiang Hu, Jia Tian, Bao-Hang Han, Guangshan Zhu, Wei Wang, Fan Zhang, Bien Tan, Zhan-Ting Li, Dong Wang, Li-Jun Wan. Porous organic polymers: a progress report in China. Science China Chemistry 2023, 46 https://doi.org/10.1007/s11426-022-1475-x
    16. Kaijie Yang, Yuxiang Wang, Zhiyi Ling, Xiaogang Pan, Gen Zhang, Jian Su. Alkoxy phosphonic acid-functionalized conjugated microporous polymers for efficient and multi-environmental proton conduction. Materials Advances 2023, 4 (2) , 504-514. https://doi.org/10.1039/D2MA00909A
    17. Xujun Qiu, Julian Brückel, Christoph Zippel, Martin Nieger, Frank Biedermann, Stefan Bräse. Tris(4-azidophenyl)methanol – a novel and multifunctional thiol protecting group. RSC Advances 2023, 13 (4) , 2483-2486. https://doi.org/10.1039/D2RA05997E
    18. Yanqiu Lu, Wei Liu, Kaiyu Wang, Sui Zhang. Electropolymerized thin films with a microporous architecture enabling molecular sieving in harsh organic solvents under high temperature. Journal of Materials Chemistry A 2022, 10 (37) , 20101-20110. https://doi.org/10.1039/D2TA02178A
    19. Agnieszka K. Holda, Semali Perera, Emma A. Emanuelsson Patterson. Photocatalytic membranes containing homocoupled conjugated microporous poly(phenylene butadiynylene) for chemical-free degradation of organic micropollutants. Catalysis Communications 2022, 168 , 106463. https://doi.org/10.1016/j.catcom.2022.106463
    20. Tianyi Zhang, Vasilis G. Gregoriou, Nicola Gasparini, Christos L. Chochos. Porous organic polymers in solar cells. Chemical Society Reviews 2022, 51 (11) , 4465-4483. https://doi.org/10.1039/D2CS00123C
    21. Shankar Kunalan, Kandasamy Palanivelu. Polymeric composite membranes in carbon dioxide capture process: a review. Environmental Science and Pollution Research 2022, 29 (26) , 38735-38767. https://doi.org/10.1007/s11356-022-19519-x
    22. Yanpei Song, Changjia Zhu, Shengqian Ma. Advanced porous organic polymer membranes: design, fabrication, and energy-saving applications. EnergyChem 2022, 532 , 100079. https://doi.org/10.1016/j.enchem.2022.100079
    23. Rina Ningthoujam, Yengkhom Disco Singh, Punuri Jayasekhar Babu, Akriti Tirkey, Srimay Pradhan, Mrinal Sarma. Nanocatalyst in remediating environmental pollutants. Chemical Physics Impact 2022, 4 , 100064. https://doi.org/10.1016/j.chphi.2022.100064
    24. Yunpan Ying, Shing Bo Peh, Hao Yang, Ziqi Yang, Dan Zhao. Ultrathin Covalent Organic Framework Membranes via a Multi‐Interfacial Engineering Strategy for Gas Separation. Advanced Materials 2022, 34 (25) https://doi.org/10.1002/adma.202104946
    25. Zongyao Zhou, Zhen Li, Lubna M. Rehman, Zhiping Lai. Conjugated microporous polymer membranes for chemical separations. Chinese Journal of Chemical Engineering 2022, 45 , 1-14. https://doi.org/10.1016/j.cjche.2022.01.027
    26. Weiyi Zhang, Hongyu Zuo, Zhonghua Cheng, Yu Shi, Zhengjun Guo, Nan Meng, Arne Thomas, Yaozu Liao. Macroscale Conjugated Microporous Polymers: Controlling Versatile Functionalities Over Several Dimensions. Advanced Materials 2022, 34 (18) https://doi.org/10.1002/adma.202104952
    27. Qianwen Su, Ju Wen, Dongyang Wang, Lizhi Zhang, Ming Li. Two-stage polymerization towards C–C bonded Conjugated microporous polymer membranes with excellent nanofiltration performance. Journal of Membrane Science 2022, 647 , 120314. https://doi.org/10.1016/j.memsci.2022.120314
    28. Mengxi Zhang, Xiao Feng. Fabrication Strategies of Conjugated Microporous Polymer Membranes for Molecular Separation. Acta Chimica Sinica 2022, 80 (2) , 168. https://doi.org/10.6023/A21110505
    29. Shaolei Wang, Chengxin Zhang, Qingsong Liu, Bien Tan. Unprecedented Processable Hypercrosslinked Polymers with Controlled Knitting. Macromolecular Rapid Communications 2022, 43 (2) https://doi.org/10.1002/marc.202100449
    30. Nishel Saini, Kamakshi Pandey, Kamlendra Awasthi. Conjugate polymer-based membranes for gas separation applications: current status and future prospects. Materials Today Chemistry 2021, 22 , 100558. https://doi.org/10.1016/j.mtchem.2021.100558
    31. Govindasamy Sathiyan, Dhamodiran Mathivanan, Balasubramaniam Bhuvaneshwari, Ashish Garg, Raju Kumar Gupta, Anand Singh. Olefin-linked conjugated fluorescent oligomer: Design, synthesis, photophysical studies and detection of nitroaromatic compounds (NACs) in aqueous media. Sensors and Actuators A: Physical 2021, 331 , 113026. https://doi.org/10.1016/j.sna.2021.113026
    32. Yanpei Song, Pui Ching Lan, Kyle Martin, Shengqian Ma. Rational design of bifunctional conjugated microporous polymers. Nanoscale Advances 2021, 3 (17) , 4891-4906. https://doi.org/10.1039/D1NA00479D
    33. Isabelle D. Wessely, Yannick Matt, Qi An, Stefan Bräse, Manuel Tsotsalas. Dynamic porous organic polymers with tuneable crosslinking degree and porosity. RSC Advances 2021, 11 (44) , 27714-27719. https://doi.org/10.1039/D1RA05265A
    34. Hongjian Wang, Meidi Wang, Xu Liang, Jinqiu Yuan, Hao Yang, Shaoyu Wang, Yanxiong Ren, Hong Wu, Fusheng Pan, Zhongyi Jiang. Organic molecular sieve membranes for chemical separations. Chemical Society Reviews 2021, 50 (9) , 5468-5516. https://doi.org/10.1039/D0CS01347A
    35. Songhao Luo, Zhuotong Zeng, Han Wang, Weiping Xiong, Biao Song, Chengyun Zhou, Abing Duan, Xiaofei Tan, Qingyun He, Guangming Zeng, Zhifeng Liu, Rong Xiao. Recent progress in conjugated microporous polymers for clean energy: Synthesis, modification, computer simulations, and applications. Progress in Polymer Science 2021, 115 , 101374. https://doi.org/10.1016/j.progpolymsci.2021.101374
    36. Zhengdong Liu, Yuhang Yin, Mustafa Eginligil, Laiyuan Wang, Juqing Liu, Wei Huang. Two-dimensional conjugated microporous polymer films: fabrication strategies and potential applications. Polymer Chemistry 2021, 12 (6) , 807-821. https://doi.org/10.1039/D0PY01368D
    37. Haozhen Dou, Mi Xu, Baoyu Wang, Zhen Zhang, Guobin Wen, Yun Zheng, Dan Luo, Lei Zhao, Aiping Yu, Luhong Zhang, Zhongyi Jiang, Zhongwei Chen. Microporous framework membranes for precise molecule/ion separations. Chemical Society Reviews 2021, 50 (2) , 986-1029. https://doi.org/10.1039/D0CS00552E
    38. Qianwen Su, Ju Wen, Dongyang Wang, Lizhi Zhang, Ming Li. Simple Solution Coating Towards C-C Bonded Conjugated Microporous Polymer Membranes with Excellent Nanofiltration Performance. SSRN Electronic Journal 2021, 120 https://doi.org/10.2139/ssrn.3976711
    39. Yanqiu Lu, Wei Liu, Jiangtao Liu, Xue Li, Sui Zhang. A review on 2D porous organic polymers for membrane-based separations: Processing and engineering of transport channels. Advanced Membranes 2021, 1 , 100014. https://doi.org/10.1016/j.advmem.2021.100014
    40. Junyong Zhu, Shushan Yuan, Jing Wang, Yatao Zhang, Miaomiao Tian, Bart Van der Bruggen. Microporous organic polymer-based membranes for ultrafast molecular separations. Progress in Polymer Science 2020, 110 , 101308. https://doi.org/10.1016/j.progpolymsci.2020.101308
    41. Yuwei Zhang, Qikun Sun, Zhongping Li, Yongfeng Zhi, He Li, Ziping Li, Hong Xia, Xiaoming Liu. Light-emitting conjugated microporous polymers based on an excited-state intramolecular proton transfer strategy and selective switch-off sensing of anions. Materials Chemistry Frontiers 2020, 4 (10) , 3040-3046. https://doi.org/10.1039/D0QM00384K
    42. Saikat Das, Teng Ben, Shilun Qiu. Shaping of porous polymers. Polymer 2020, 207 , 122928. https://doi.org/10.1016/j.polymer.2020.122928
    43. Mohammad Younas, Tariq Tahir, Chunrui Wu, Sarah Farrukh, Qazi Sohaib, Amir Muhammad, Mashallah Rezakazemi, Jianxin Li. Post-combustion CO2 capture with sweep gas in thin film composite (TFC) hollow fiber membrane (HFM) contactor. Journal of CO2 Utilization 2020, 40 , 101266. https://doi.org/10.1016/j.jcou.2020.101266
    44. Dan Ren, Yu-han Li, Shu-ping Ren, Tian-Yin Liu, Xiao-Lin Wang. Microporous polyarylate membrane with nitrogen-containing heterocycles to enhance separation performance for organic solvent nanofiltration. Journal of Membrane Science 2020, 610 , 118295. https://doi.org/10.1016/j.memsci.2020.118295
    45. Wan-Kai An, Shi-Jia Zheng, Ya-Nan Du, San-Yuan Ding, Zhi-Jun Li, Song Jiang, Yuchen Qin, Xiaobiao Liu, Pi-Feng Wei, Zhan-Qi Cao, Meirong Song, Zhenliang Pan. Thiophene-embedded conjugated microporous polymers for photocatalysis. Catalysis Science & Technology 2020, 10 (15) , 5171-5180. https://doi.org/10.1039/D0CY01164A
    46. Kamakshi, Rajesh Kumar, Vibhav K. Saraswat, Manoj Kumar, Kamlendra Awasthi. Active block copolymer layer on carboxyl-functionalized PET film for hydrogen separation. International Journal of Hydrogen Energy 2020, 45 (37) , 18676-18684. https://doi.org/10.1016/j.ijhydene.2019.07.174
    47. Zahid Hassan, Yannick Matt, Salma Begum, Manuel Tsotsalas, Stefan Bräse. Assembly of Molecular Building Blocks into Integrated Complex Functional Molecular Systems: Structuring Matter Made to Order. Advanced Functional Materials 2020, 30 (26) https://doi.org/10.1002/adfm.201907625
    48. Jue Hou, Huacheng Zhang, George P. Simon, Huanting Wang. Polycrystalline Advanced Microporous Framework Membranes for Efficient Separation of Small Molecules and Ions. Advanced Materials 2020, 32 (18) https://doi.org/10.1002/adma.201902009
    49. Tao Hong, Jeffrey T. Culp, Ki-Joong Kim, Jagannath Devkota, Chenhu Sun, Paul R. Ohodnicki. State-of-the-art of methane sensing materials: A review and perspectives. TrAC Trends in Analytical Chemistry 2020, 125 , 115820. https://doi.org/10.1016/j.trac.2020.115820
    50. Jin Huang, Zhi-qiang Tan, Hui-min Su, Yi-wen Guo, Huan Liu, Bo Liao, Qing-quan Liu. Ferrocenyl building block constructing porous organic polymer for gas capture and methyl violet adsorption. Journal of Central South University 2020, 27 (4) , 1247-1261. https://doi.org/10.1007/s11771-020-4364-4
    51. Joe Komeda, Ryo Shiotsuki, Amalia Rapakousiou, Ryota Sakamoto, Ryojun Toyoda, Kazuyuki Iwase, Masaki Tsuji, Kazuhide Kamiya, Hiroshi Nishihara. ‘Click’ conjugated porous polymer nanofilm with a large domain size created by a liquid/liquid interfacial protocol. Chemical Communications 2020, 56 (25) , 3677-3680. https://doi.org/10.1039/D0CC00360C
    52. Samiul Islam Hazarika, Bholanath Dolai, Ananta Kumar Atta. Water compatible triazole linked pyrene-C1-glucosyl fluorescent sensor for Au3+ and living cell imaging studies. Journal of Molecular Structure 2020, 1202 , 127272. https://doi.org/10.1016/j.molstruc.2019.127272
    53. Rajesh Kumar, Kamakshi, Manoj Kumar, Kamlendra Awasthi. Nanoporous Polymeric Membranes for Hydrogen Separation. 2020, 355-376. https://doi.org/10.1007/978-3-030-33774-2_15
    54. Kazuki Sada, Kenta Kokado. Click Chemistry to Metal-Organic Frameworks as a Synthetic Tool for MOF and Applications for Functional Materials. 2020, 523-538. https://doi.org/10.1007/978-981-15-5085-0_25
    55. Julian Hoffmann, Sofia Madrigal Gamboa, Andreas Hofmann, Hartmut Gliemann, Alexander Welle, Irene Wacker, Rasmus R. Schröder, Len Ness, Veit Hagenmeyer, Ulrich Gengenbach. Siloxane-functionalised surface patterns as templates for the ordered deposition of thin lamellar objects. Scientific Reports 2019, 9 (1) https://doi.org/10.1038/s41598-019-54507-1
    56. Bin Liang, Xiao He, Junjun Hou, Lianshan Li, Zhiyong Tang. Membrane Separation in Organic Liquid: Technologies, Achievements, and Opportunities. Advanced Materials 2019, 31 (45) https://doi.org/10.1002/adma.201806090
    57. Yanze Liu, Yiming Zuo, Shuai Li, Jiani Li, Li Li, Caixia Liu, Shumalia Ashraf, Pengfei Li, Bo Wang. Synthesis and fine-tuning the pore properties of a thiophene based porous organic framework by post-oxidation treatment. Journal of Materials Chemistry A 2019, 7 (38) , 21953-21958. https://doi.org/10.1039/C9TA07193H
    58. Sophia Schmitt, Sergey Shishatskiy, Peter Krolla, Qi An, Salma Begum, Alexander Welle, Tawheed Hashem, Sylvain Grosjean, Volker Abetz, Stefan Bräse, Christof Wöll, Manuel Tsotsalas. Synthesis, Transfer, and Gas Separation Characteristics of MOF-Templated Polymer Membranes. Membranes 2019, 9 (10) , 124. https://doi.org/10.3390/membranes9100124
    59. . Microporous Organic Framework Materials for Membrane Separations. 2019, 413-436. https://doi.org/10.1002/9783527343997.ch12
    60. Yu Zang, Toshiki Aoki, Masahiro Teraguchi, Takashi Kaneko, Hongge Jia, Liqun Ma, Fengjuan Miao. New Synthetic Methods of Novel Nanoporous Polycondensates and Excellent Oxygen Permselectivity of Their Composite Membranes. Nanomaterials 2019, 9 (6) , 859. https://doi.org/10.3390/nano9060859
    61. Venkata Suresh Mothika, Papri Sutar, Parul Verma, Shubhajit Das, Swapan K. Pati, Tapas Kumar Maji. Regulating Charge‐Transfer in Conjugated Microporous Polymers for Photocatalytic Hydrogen Evolution. Chemistry – A European Journal 2019, 25 (15) , 3867-3874. https://doi.org/10.1002/chem.201805478
    62. Qi An, Isabelle D. Wessely, Yannick Matt, Zahid Hassan, Stefan Bräse, Manuel Tsotsalas. Recycling and self-healing of dynamic covalent polymer networks with a precisely tuneable crosslinking degree. Polymer Chemistry 2019, 10 (6) , 672-678. https://doi.org/10.1039/C8PY01474D
    63. Rajangam Vinodh, Cadiam Mohan Babu, Aziz Abidov, Muthiahpillai Palanichamy, Wang Seog Cha, Hyun Tae Jang. Preparation and characterization of RGO-incorporated hypercross-linked polymers for CO2 capture. Carbon Letters 2019, 29 (1) , 21-30. https://doi.org/10.1007/s42823-019-00002-6
    64. Pei-Zhou Li, Xiao-Jun Wang, Yanli Zhao. Click chemistry as a versatile reaction for construction and modification of metal-organic frameworks. Coordination Chemistry Reviews 2019, 380 , 484-518. https://doi.org/10.1016/j.ccr.2018.11.006
    65. Ke Xie, Qiang Fu, Greg G. Qiao, Paul A. Webley. Recent progress on fabrication methods of polymeric thin film gas separation membranes for CO2 capture. Journal of Membrane Science 2019, 572 , 38-60. https://doi.org/10.1016/j.memsci.2018.10.049
    66. Huang Ouyang, Li Guo, Cao Li, Xueqin Chen, Bingbing Jiang. Fabrication and adsorption performance for CO2 capture of advanced nanoporous microspheres enriched with amino acids. Journal of Colloid and Interface Science 2018, 532 , 433-440. https://doi.org/10.1016/j.jcis.2018.07.121
    67. Youdong Cheng, Yunpan Ying, Susilo Japip, Shu‐Dong Jiang, Tai‐Shung Chung, Sui Zhang, Dan Zhao. Advanced Porous Materials in Mixed Matrix Membranes. Advanced Materials 2018, 30 (47) https://doi.org/10.1002/adma.201802401
    68. Stefan Wuttke, Dana D. Medina, Julian M. Rotter, Salma Begum, Timothée Stassin, Rob Ameloot, Martin Oschatz, Manuel Tsotsalas. Bringing Porous Organic and Carbon‐Based Materials toward Thin‐Film Applications. Advanced Functional Materials 2018, 28 (44) https://doi.org/10.1002/adfm.201801545
    69. Meixia Shan, Xinlei Liu, Xuerui Wang, Irina Yarulina, Beatriz Seoane, Freek Kapteijn, Jorge Gascon. Facile manufacture of porous organic framework membranes for precombustion CO 2 capture. Science Advances 2018, 4 (9) https://doi.org/10.1126/sciadv.aau1698
    70. Yuanyuan Liu, Alexandre A.S. Gonçalves, Yang Zhou, Mietek Jaroniec. Importance of surface modification of γ-alumina in creating its nanostructured composites with zeolitic imidazolate framework ZIF-67. Journal of Colloid and Interface Science 2018, 526 , 497-504. https://doi.org/10.1016/j.jcis.2018.05.008
    71. Nhamo Chaukura, Welldone Moyo, Bhekie B. Mamba, Thabo I. Nkambule. Abatement of humic acid from aqueous solution using a carbonaceous conjugated microporous polymer derived from waste polystyrene. Environmental Science and Pollution Research 2018, 25 (4) , 3291-3300. https://doi.org/10.1007/s11356-017-0691-x
    72. Changyi Li, Stephen M. Meckler, Zachary P. Smith, Jonathan E. Bachman, Lorenzo Maserati, Jeffrey R. Long, Brett A. Helms. Engineered Transport in Microporous Materials and Membranes for Clean Energy Technologies. Advanced Materials 2018, 30 (8) , 1704953. https://doi.org/10.1002/adma.201704953
    73. Peng Mu, Hanxue Sun, Zhaoqi Zhu, Jingxian He, Weidong Liang, An Li. Monolithic nanofoam based on conjugated microporous polymer nanotubes with ultrahigh mechanical strength and flexibility for energy storage. Journal of Materials Chemistry A 2018, 6 (25) , 11676-11681. https://doi.org/10.1039/C8TA03493A
    74. Xiaoqin Zou, Guangshan Zhu. Microporous Organic Materials for Membrane‐Based Gas Separation. Advanced Materials 2018, 30 (3) , 1700750. https://doi.org/10.1002/adma.201700750
    75. Giovanni Polito, Valentina Robbiano, Chiara Cozzi, Franco Cacialli, Giuseppe Barillaro. Template-Assisted Preparation of Micrometric Suspended Membrane Lattices of Photoluminescent and Non-Photoluminescent Polymers by Capillarity-Driven Solvent Evaporation: Application to Microtagging. Scientific Reports 2017, 7 (1) https://doi.org/10.1038/s41598-017-08278-2
    76. Jieun Lee, Jong Gil Kim, Ji Young Chang. Fabrication of a conjugated microporous polymer membrane and its application for membrane catalysis. Scientific Reports 2017, 7 (1) https://doi.org/10.1038/s41598-017-13827-w
    77. Qingyin Li, Shumaila Razzaque, Shangbin Jin, Bien Tan. Morphology design of microporous organic polymers and their potential applications: an overview. Science China Chemistry 2017, 60 (8) , 1056-1066. https://doi.org/10.1007/s11426-017-9089-3
    78. Kamakshi, Rajesh Kumar, Vibhav K. Saraswat, Manoj Kumar, Kamlendra Awasthi, Manfred Stamm. Hydrogen gas separation with controlled selectivity via efficient and cost effective block copolymer coated PET membranes. International Journal of Hydrogen Energy 2017, 42 (31) , 19977-19983. https://doi.org/10.1016/j.ijhydene.2017.06.113
    79. Amalia Rapakousiou, Ryota Sakamoto, Ryo Shiotsuki, Ryota Matsuoka, Ukyo Nakajima, Tigmansu Pal, Rintaro Shimada, Amran Hossain, Hiroyasu Masunaga, Satoshi Horike, Yasutaka Kitagawa, Sono Sasaki, Kenichi Kato, Takeaki Ozawa, Didier Astruc, Hiroshi Nishihara. Liquid/Liquid Interfacial Synthesis of a Click Nanosheet. Chemistry – A European Journal 2017, 23 (35) , 8443-8449. https://doi.org/10.1002/chem.201700201
    80. Jinshui Zhang, Jennifer Ann Schott, Shannon M. Mahurin, Sheng Dai. Porous Structure Design of Polymeric Membranes for Gas Separation. Small Methods 2017, 1 (5) https://doi.org/10.1002/smtd.201600051
    81. Zhengbang Wang, Alfred Błaszczyk, Olaf Fuhr, Stefan Heissler, Christof Wöll, Marcel Mayor. Molecular weaving via surface-templated epitaxy of crystalline coordination networks.. Nature Communications 2017, 8 (1) https://doi.org/10.1038/ncomms14442
    82. Nhamo Chaukura, Bhekie B. Mamba, Shivani B. Mishra. Porous materials for the sorption of emerging organic pollutants from aqueous systems: The case for conjugated microporous polymers. Journal of Water Process Engineering 2017, 16 , 223-232. https://doi.org/10.1016/j.jwpe.2017.02.001
    83. Tae Jin Choi, Do Yeon Kim, Ji Young Chang. Water wettable, compressible, and hierarchically porous polymer composite. Microporous and Mesoporous Materials 2017, 242 , 82-89. https://doi.org/10.1016/j.micromeso.2017.01.007
    84. Liangxiao Tan, Kewei Wang, Qingyin Li, Yuwan Yang, Yunfei Liu, Bien Tan. Organic Porous Polymer Materials: Design, Preparation, and Applications. 2017, 71-150. https://doi.org/10.1007/978-3-319-57003-7_4
    85. Zhen Chen, Min Chen, Yanlei Yu, Limin Wu. Robust synthesis of free-standing and thickness controllable conjugated microporous polymer nanofilms. Chemical Communications 2017, 53 (12) , 1989-1992. https://doi.org/10.1039/C6CC09763D
    86. Nicolas Chaoui, Matthias Trunk, Robert Dawson, Johannes Schmidt, Arne Thomas. Trends and challenges for microporous polymers. Chemical Society Reviews 2017, 46 (11) , 3302-3321. https://doi.org/10.1039/C7CS00071E
    87. Minghui Wang, Junjie Zhao, Xiaoxue Wang, Andong Liu, Karen K. Gleason. Recent progress on submicron gas-selective polymeric membranes. Journal of Materials Chemistry A 2017, 5 (19) , 8860-8886. https://doi.org/10.1039/C7TA01862B
    88. Zhen Chen, Huiqi Xie, Linfeng Hu, Min Chen, Limin Wu. Fabrication of novel lamellar alternating nitrogen-doped microporous carbon nanofilm/MoS 2 composites with high electrochemical properties. Journal of Materials Chemistry A 2017, 5 (43) , 22726-22734. https://doi.org/10.1039/C7TA07136A
    89. Shiming Zhang, Shenglong Liao, Yuanyuan Cao, Jian Wang, Ruiting Li, Zhen Wang, Yapei Wang. NIR light-triggered expansive starch particles for use as artificial thrombi. Journal of Materials Chemistry B 2017, 5 (25) , 4966-4972. https://doi.org/10.1039/C7TB01094J
    90. Qi An, Youssef Hassan, Xiaotong Yan, Peter Krolla-Sidenstein, Tawheed Mohammed, Mathias Lang, Stefan Bräse, Manuel Tsotsalas. Fast and efficient synthesis of microporous polymer nanomembranes via light-induced click reaction. Beilstein Journal of Organic Chemistry 2017, 13 , 558-563. https://doi.org/10.3762/bjoc.13.54
    91. Sophia Schmitt, Julia Hümmer, Saskia Kraus, Alexander Welle, Sylvain Grosjean, Maximilian Hanke-Roos, Axel Rosenhahn, Stefan Bräse, Christof Wöll, Cornelia Lee-Thedieck, Manuel Tsotsalas. Tuning the Cell Adhesion on Biofunctionalized Nanoporous Organic Frameworks. Advanced Functional Materials 2016, 26 (46) , 8455-8462. https://doi.org/10.1002/adfm.201603054
    92. P.M. Visakh. Processing and Characterizations: State‐of‐the‐Art and New Challenges. 2016, 1-26. https://doi.org/10.1002/9781118831779.ch1
    93. Giuseppe Firpo, Ugo Valbusa. Polymer Nanomembranes. 2016, 293-328. https://doi.org/10.1002/9781118831779.ch8
    94. Joydeb Mandal, S. Ramakrishnan. Azide–Alkyne Click Reaction in Polymer Science. 2016, 203-254. https://doi.org/10.1002/9783527694174.ch7
    95. Binlei Huang, Peng Zhao, Yanan Dai, Sheng Deng, Aiguo Hu. Size-controlled synthesis of soluble-conjugated microporous polymer nanoparticles through sonogashira polycondensation in confined nanoreactors. Journal of Polymer Science Part A: Polymer Chemistry 2016, 54 (15) , 2285-2290. https://doi.org/10.1002/pola.28108
    96. Lingling Hu, Huagang Ni, Xiaolong Chen, Lele Wang, Ying Wei, Tengfei Jiang, Yaohong Lü, Xiaolin Lu, Peng Ye. Hypercrosslinked polymers incorporated with imidazolium salts for enhancing CO 2 capture. Polymer Engineering & Science 2016, 56 (5) , 573-582. https://doi.org/10.1002/pen.24282
    97. P. Lindemann, A. Schade, L. Monnereau, W. Feng, K. Batra, H. Gliemann, P. Levkin, S. Bräse, C. Wöll, M. Tsotsalas. Surface functionalization of conjugated microporous polymer thin films and nanomembranes using orthogonal chemistries. Journal of Materials Chemistry A 2016, 4 (18) , 6815-6818. https://doi.org/10.1039/C5TA09429A
    98. Jeongmin Lee, Ji Young Chang. Preparation of a compressible and hierarchically porous polyimide sponge via the sol–gel process of an aliphatic tetracarboxylic dianhydride and an aromatic triamine. Chemical Communications 2016, 52 (68) , 10419-10422. https://doi.org/10.1039/C6CC04817J
    99. Wei Guo, Zhi Chen, Chengwu Yang, Tobias Neumann, Christian Kübel, Wolfgang Wenzel, Alexander Welle, Wilhelm Pfleging, Osama Shekhah, Christof Wöll, Engelbert Redel. Bi 2 O 3 nanoparticles encapsulated in surface mounted metal–organic framework thin films. Nanoscale 2016, 8 (12) , 6468-6472. https://doi.org/10.1039/C6NR00532B
    100. Eui Soon Kim, Ju Hong Ko, Sang Moon Lee, Hae Jin Kim, Seung Uk Son. Microporous organic network@PET hybrid membranes: removal of minute organic pollutants dissolved in water. RSC Advances 2016, 6 (87) , 83942-83946. https://doi.org/10.1039/C6RA13220K
    Load all citations
    Download PDF

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    Pair your accounts.

    Export articles to Mendeley

    Get article recommendations from ACS based on references in your Mendeley library.

    You’ve supercharged your research process with ACS and Mendeley!

    STEP 1:
    Click to create an ACS ID

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

    MENDELEY PAIRING EXPIRED
    Your Mendeley pairing has expired. Please reconnect