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Novel Organic/Inorganic Hybrid Materials by Covalent Anchoring of Phenothiazines on MCM-41

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Fachbereich Chemie, Technische Universität Kaiserslautern, Erwin-Schrödinger-Strasse Geb. 54, D-67663 Kaiserslautern, Germany, Institut für Organische Chemie und Makromolekulare Chemie, Heinrich Heine Universität Düsseldorf, Universitätsstrasse 1, D-40225 Düsseldorf, Germany, Institut für Physik, Universität Augsburg, Universitätsstrasse 1, D-86135 Augsburg, Germany, and Institut für Chemie, Technische Universität Chemnitz, Strasse der Nationen 62, D-09107 Chemnitz, Germany
* To whom correspondence should be addressed. E-mail: [email protected]
†Technische Universität Kaiserslautern.
‡Heinrich Heine Universität Düsseldorf.
§Universität Augsburg.
∥Technische Universität Chemnitz.
Cite this: Chem. Mater. 2008, 20, 15, 4986–4992
Publication Date (Web):July 3, 2008
https://doi.org/10.1021/cm800804t
Copyright © 2008 American Chemical Society
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Abstract

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Triethoxysilyl functionalized phenothiazinyl carbamates were synthesized and covalently grafted onto mesoporous MCM-41. XRD and N2 adsorption measurements indicated the presence of a highly ordered two-dimensional hexagonal structure of functional materials, while the incorporation of organic compounds in the solid materials was proven by means of 13C and 29Si solid-state NMR spectroscopy as well as by FT-IR spectroscopy. Upon oxidation with (NO)BF4, stable phenothiazine radical cations were generated in the pores of the materials, which can be detected by means of UV−vis and EPR spectroscopy.

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