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Structural Investigations on Hybrid Polymers Suitable as a Nanoparticle Precipitation Environment

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Download Hi-Res ImageDownload to MS-PowerPointCite This:Chem. Mater. 2009, 21, 4, 695-705
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    Structural Investigations on Hybrid Polymers Suitable as a Nanoparticle Precipitation Environment
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    Institute of Materials Chemistry, Vienna University of Technology, Getreidemarkt 9, 1060 Vienna, Austria, and Faculty of Physics, University of Vienna, Strudlhofgasse 4, 1090 Vienna, Austria
    * Corresponding author. E-mail: [email protected]
    †Vienna University of Technology.
    ‡University of Vienna.
    Other Access OptionsSupporting Information (1)

    Chemistry of Materials

    Cite this: Chem. Mater. 2009, 21, 4, 695–705
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    https://doi.org/10.1021/cm802171s
    Published January 22, 2009
    Copyright © 2009 American Chemical Society
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    Abstract

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    Cross-linked hybrid polymer matrices with tunable hydrophilic/hydrophobic areas were prepared from end-group functionalized poly(ethylene oxides) (PEO) and poly(methylhydrido siloxanes) (PMHS) or trimethylsilyl terminated polydimethyl-co-polymethylhydrido siloxanes (PDMS-PMHS). The combination of the different polymer segments resulted in materials with hydrophilic and metal coordinating sections in a hydrophobic matrix. The polymer morphology was investigated with regard to its chemical composition and structural configuration. Besides spectroscopic methods, DSC and swelling tests were performed to study the chain mobility in the polymer matrix. The cross-linked polymers were swellable in methanol, reaching swelling degrees of up to 550%. On the basis of the excellent swelling behavior and the unique metal ion binding ability of the PEO segments, hybrid nanocomposites were prepared infiltrating the matrix with iron ions and forming nanocrystalline oxide particles in the cross-linked network. The resulting materials were analyzed by electron microscopy techniques, XRD, and small-angle X-ray scattering.

    Copyright © 2009 American Chemical Society

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    Supporting Information

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    Information about FT-IR spectroscopic data, TGA and XRD of the FeO nanoparticle containing samples, and diagrams explaining the swelling behavior (PDF). This material is available free of charge via the Internet at http://pubs.acs.org.

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    Cited By

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    This article is cited by 17 publications.

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    Chemistry of Materials

    Cite this: Chem. Mater. 2009, 21, 4, 695–705
    Click to copy citationCitation copied!
    https://doi.org/10.1021/cm802171s
    Published January 22, 2009
    Copyright © 2009 American Chemical Society
    Request reuse permissions

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