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Characteristic Phonon Spectrum of Negative Thermal Expansion Materials with Framework Structure through Calorimetric Study of Sc2M3O12 (M = W and Mo)

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Department of Chemistry, Graduate School of Pure and Applied Sciences, University of Tsukuba, Tsukuba, Ibaraki 305-8571, Japan
*Corresponding author. E-mail: [email protected]
Cite this: Chem. Mater. 2009, 21, 13, 3008–3016
Publication Date (Web):June 11, 2009
https://doi.org/10.1021/cm900965p
Copyright © 2009 American Chemical Society
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Abstract

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To study the relation between the structural characteristics and the phonon property in the negative thermal expansion (NTE) compounds, the heat capacities of Sc2W3O12 and Sc2Mo3O12 were measured. Spectrum analysis of heat capacity provided their effective phonon densities of states (DOS). The DOS of Sc2W3O12 shows three features; low-energy phonon modes with negative mode-Grüneisen parameter (γi) around 5 meV, high-energy phonon modes, and separation of phonon DOS into two regions with a wide gap. The relative contribution of γiCi, where Ci is heat capacity of each vibrational mode i, reveals that the low-energy phonon modes with negative γi cause the NTE and that the latter two features are necessary to maintain the NTE in a wide temperature range. Sc2Mo3O12 has the low-energy mode with the negative γi. This fact indicates that Sc2Mo3O12 potentially has the NTE property even in its low-temperature phase showing positive thermal expansion. A comparison of the phonon DOS with other oxides shows that the phonon features are common in the NTE oxides and related to their common chemical and structural characteristics, “strong bond” and “framework structure”. This finding gives us an important guide to search for new actual and/or potential NTE compounds.

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Tables of standard thermodynamic quantities of Sc2W3O12 and Sc2Mo3O12 (PDF). This material is available free of charge via the Internet at http://pubs.acs.org.

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  2. Carl P. Romao, Frédéric A. Perras, Ulrike Werner-Zwanziger, Joey A. Lussier, Kimberly J. Miller, Courtney M. Calahoo, Josef W. Zwanziger, Mario Bieringer, Bojan A. Marinkovic, David L. Bryce, and Mary Anne White . Zero Thermal Expansion in ZrMgMo3O12: NMR Crystallography Reveals Origins of Thermoelastic Properties. Chemistry of Materials 2015, 27 (7) , 2633-2646. https://doi.org/10.1021/acs.chemmater.5b00429
  3. Elaheh Teymouri, Abdolali Alemi, Mohammadali Abdollahpour Aghdam sharabiyani, Leila Sadeghi, Hacali Necefoğlu. Synthesizes and characterization of new double tungstate NaRE(WO4)2 (RE= Pr 3+, Ho 3+, Sm3+). Materials Chemistry and Physics 2020, 240 , 122173. https://doi.org/10.1016/j.matchemphys.2019.122173
  4. Rui-Zi Zhang, Jian Liu, Yu-Yang Zhang, Shixuan Du, Sokrates T. Pantelides. . Applied Physics Letters 2020,,, 083101. https://doi.org/10.1063/1.5142639
  5. Mayanak K. Gupta, Ranjan Mittal, Samrath L. Chaplot. Negative thermal expansion behavior in orthorhombic Sc 2 (MoO 4 ) 3 and Sc 2 (WO 4 ) 3. Journal of Applied Physics 2019, 126 (12) , 125114. https://doi.org/10.1063/1.5115318
  6. Xinwei Li, Hualan Xu, Xianming Xia, Feiyan Xie, Shengliang Zhong, Dekang Xu. One-step synthesis of Sc2W3O12:Eu3+ phosphors with tunable luminescence for WLED. Ceramics International 2019, 45 (8) , 10461-10467. https://doi.org/10.1016/j.ceramint.2019.02.107
  7. Yasuhisa Yamamura, Sakiko Iwagaki, Mafumi Hishida, Shigenori Nagatomo, Kazuhiro Fukada, Kazuya Saito. Heat capacity and standard thermodynamic functions of three ketohexoses in monosaccharides including rare sugars: D-fructose, D-psicose, and D-tagatose. The Journal of Chemical Thermodynamics 2019, 131 , 420-430. https://doi.org/10.1016/j.jct.2018.11.014
  8. Guang Yang, Xiansheng Liu, Xianwen Sun, Erjun Liang, Weifeng Zhang. Synthesis process control of low-thermal-expansion Fe2W3O12 by suppressing the intermediate phase Fe2WO6. Ceramics International 2018, 44 (17) , 22032-22035. https://doi.org/10.1016/j.ceramint.2018.08.274
  9. Ethan T. Ritz, Nicole A. Benedek. Interplay between Phonons and Anisotropic Elasticity Drives Negative Thermal Expansion in PbTiO 3 . Physical Review Letters 2018, 121 (25) https://doi.org/10.1103/PhysRevLett.121.255901
  10. Yixiu Luo, Luchao Sun, Jiemin Wang, Zhilin Tian, Hongqiang Nian, Jingyang Wang. Tunable thermal properties in yttrium silicates switched by anharmonicity of low-frequency phonons. Journal of the European Ceramic Society 2018, 38 (4) , 2043-2052. https://doi.org/10.1016/j.jeurceramsoc.2017.11.010
  11. Xuerui Cheng, Jie Yuan, Xiang Zhu, Kun Yang, Miao Liu, Zeming Qi. Origin of negative thermal expansion in Zn 2 GeO 4 revealed by high pressure study. Journal of Physics D: Applied Physics 2018, 51 (9) , 095303. https://doi.org/10.1088/1361-6463/aaaa3d
  12. R. Mittal, M.K. Gupta, S.L. Chaplot. Phonons and anomalous thermal expansion behaviour in crystalline solids. Progress in Materials Science 2018, 92 , 360-445. https://doi.org/10.1016/j.pmatsci.2017.10.002
  13. Wenpeng Xia, Yufeng Zhang, Shanshan Hu, Jie Xiong, Jianfeng Tang, Jun Yang. Self-assembled hierarchical architecture of tetragonal AgLa(MoO 4 ) 2 crystals: hydrothermal synthesis, morphology evolution and luminescence properties. CrystEngComm 2018, 20 (13) , 1832-1843. https://doi.org/10.1039/C7CE02209C
  14. Mayanak K. Gupta, Baltej Singh, Ranjan Mittal, Mohamed Zbiri, Andrew B. Cairns, Andrew L. Goodwin, Helmut Schober, Samrath L. Chaplot. Anomalous thermal expansion, negative linear compressibility, and high-pressure phase transition in ZnAu 2 ( CN ) 4 : Neutron inelastic scattering and lattice dynamics studies. Physical Review B 2017, 96 (21) https://doi.org/10.1103/PhysRevB.96.214303
  15. Ying-Zhi Cheng, Xiu-Yu Sun, Xiao-Ling Xiao, Xiang-Feng Liu, Li Xue, Zhong-Bo Hu. Effects of doping Fe cations on crystal structure and thermal expansion property of Yb 2 Mo 3 O 12. Chinese Chemical Letters 2017, 28 (7) , 1600-1606. https://doi.org/10.1016/j.cclet.2017.03.002
  16. Kazuya Saito, Mafumi Hishida, Kent Koike, Shigenori Nagatomo, Yasuhisa Yamamura. X-ray study of molecular association in alcohols having bulky substituents. Chemical Physics Letters 2017, 673 , 74-77. https://doi.org/10.1016/j.cplett.2017.02.011
  17. I.A. Stepanov. The isochoric heat capacity of ZrW2O8 and Sc2W3O12 is greater than their isobaric one. Materials Letters 2016, 177 , 112-115. https://doi.org/10.1016/j.matlet.2016.04.153
  18. C. Yang, P. Tong, J. C. Lin, X. G. Guo, K. Zhang, M. Wang, Y. Wu, S. Lin, P. C. Huang, W. Xu, W. H. Song, Y. P. Sun. Size effects on negative thermal expansion in cubic ScF 3. Applied Physics Letters 2016, 109 (2) , 023110. https://doi.org/10.1063/1.4959083
  19. N. Dirany, M. Arab, A. Moreau, J. Ch. Valmalette, J. R. Gavarri. Hierarchical design and control of NaCe(WO 4 ) 2 crystals: structural and optical properties. CrystEngComm 2016, 18 (35) , 6579-6593. https://doi.org/10.1039/C6CE01340F
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  21. Bei Zhao, Li Yuan, Shanshan Hu, Xuemei Zhang, Xianju Zhou, Jianfeng Tang, Jun Yang. Controllable synthesis of Sc 2 Mo 3 O 12 microcrystals with exposed {001} facets and their remarkable tunable luminescence properties by doping lanthanides. CrystEngComm 2016, 18 (41) , 8044-8058. https://doi.org/10.1039/C6CE01640E
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  23. Bei Zhao, Li Yuan, Shanshan Hu, Xuemei Zhang, Xianju Zhou, Jianfeng Tang, Jun Yang. One-step hydrothermal synthesis of Sc 2 Mo 3 O 12 :Ln 3+ (Ln = Eu, Tb, Dy, Tb/Eu, Dy/Eu) nanosheets and their multicolor tunable luminescence. New Journal of Chemistry 2016, 40 (11) , 9211-9222. https://doi.org/10.1039/C6NJ02039A
  24. Radha Velchuri, Suresh Palla, G. Ravi, Naveen Kumar Veldurthi, J.R. Reddy, M. Vithal. Metathesis synthesis, characterization, spectral and photoactivity studies of Ln2/3MoO4 (Ln=La, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Er and Y). Journal of Rare Earths 2015, 33 (8) , 837-845. https://doi.org/10.1016/S1002-0721(14)60493-2
  25. Carl P. Romao, Cody R. Morelock, Michel B. Johnson, J. W. Zwanziger, Angus P. Wilkinson, Mary Anne White. The heat capacities of thermomiotic ScF3 and ScF3–YF3 solid solutions. Journal of Materials Science 2015, 50 (9) , 3409-3415. https://doi.org/10.1007/s10853-015-8899-y
  26. Andrew D Ritchie, Michel B Johnson, John F Niven, Matt Beekman, George S Nolas, Jan Gryko, Mary Anne White. Influence of guest loading on thermal properties of Na x Si 136 clathrates. Journal of Physics: Condensed Matter 2013, 25 (43) , 435401. https://doi.org/10.1088/0953-8984/25/43/435401
  27. C.P. Romao, K.J. Miller, C.A. Whitman, M.A. White, B.A. Marinkovic. Negative Thermal Expansion (Thermomiotic) Materials. 2013,,, 127-151. https://doi.org/10.1016/B978-0-08-097774-4.00425-3
  28. . Comprehensive Inorganic Chemistry II. 2013,,https://doi.org/
  29. You Zhou, Bing Yan. RE2(MO4)3:Ln3+ (RE = Y, La, Gd, Lu; M = W, Mo; Ln = Eu, Sm, Dy) microcrystals: controlled synthesis, microstructure and tunable luminescence. CrystEngComm 2013, 15 (28) , 5694. https://doi.org/10.1039/c3ce40495a
  30. R Mittal, M Zbiri, H Schober, S N Achary, A K Tyagi, S L Chaplot. Phonons and colossal thermal expansion behavior of Ag 3 Co(CN) 6 and Ag 3 Fe(CN) 6. Journal of Physics: Condensed Matter 2012, 24 (50) , 505404. https://doi.org/10.1088/0953-8984/24/50/505404
  31. Cora Lind. Two Decades of Negative Thermal Expansion Research: Where Do We Stand?. Materials 2012, 5 (12) , 1125-1154. https://doi.org/10.3390/ma5061125
  32. Kimberly J. Miller, Michel B. Johnson, Mary Anne White, Bojan A. Marinkovic. Low-temperature investigations of the open-framework material HfMgMo3O12. Solid State Communications 2012, 152 (18) , 1748-1752. https://doi.org/10.1016/j.ssc.2012.06.022
  33. Yasuhisa Yamamura, Aruto Horikoshi, Syuma Yasuzuka, Hideki Saitoh, Kazuya Saito. Negative thermal expansion emerging upon structural phase transition in ZrV2O7 and HfV2O7. Dalton Transactions 2011, 40 (10) , 2242. https://doi.org/10.1039/c0dt01087a

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