Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

Pair your accounts.

Export articles to Mendeley

Get article recommendations from ACS based on references in your Mendeley library.

You’ve supercharged your research process with ACS and Mendeley!

Click to create an ACS ID

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Please note: If you switch to a different device, you may be asked to login again with only your ACS ID.

Your Mendeley pairing has expired. Please reconnect
ACS Publications. Most Trusted. Most Cited. Most Read
My Activity

Chelation-Controlled Bergman Cyclization:  Synthesis and Reactivity of Enediynyl Ligands

View Author Information
Department of Chemistry, Indian Institute of Technology, Kharagpur 721 302, India
Cite this: Chem. Rev. 2003, 103, 10, 4077–4094
Publication Date (Web):September 13, 2003
Copyright © 2003 American Chemical Society

    Article Views





    Other access options

    Note: In lieu of an abstract, this is the article's first page.

    Free first page

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.


    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. You can change your affiliated institution below.


    In papers with more than one author, the asterisk indicates the name of the author to whom inquiries about the paper should be addressed.

    Cited By

    This article is cited by 176 publications.

    1. Chandrima Maitra, Prakash D. Jadhav, Debashis Barik, Yeu-Shiuan Ho, Chu-Chun Cheng, Mu-Jeng Cheng, Yun-Wei Chiang, Rai-Shung Liu. Nitrosoarenes Implement Cascade Cyclization of 1-Allenyl-2-alkynylbenzenes through Diradical Mechanism. Organic Letters 2023, 25 (1) , 82-86.
    2. Annadka Shrinidhi, Charles L. Perrin. Nucleophilic Addition of Enolates to 1,4-Dehydrobenzene Diradicals Derived from Enediynes: Synthesis of Functionalized Aromatics. ACS Omega 2022, 7 (26) , 22930-22937.
    3. Annadka Shrinidhi, Charles L. Perrin. Cyclohexeno[3,4]cyclodec-1,5-diyne-3-ene: A Convenient Enediyne. Organic Letters 2021, 23 (17) , 6911-6915.
    4. Cong Chi Tran, Shin-ichi Kawaguchi, Fumiya Sato, Akihiro Nomoto, Akiya Ogawa. Photoinduced Cyclizations of o-Diisocyanoarenes with Organic Diselenides and Thiols that Afford Chalcogenated Quinoxalines. The Journal of Organic Chemistry 2020, 85 (11) , 7258-7266.
    5. Eshani Das, Amit Basak. Regioselective Synthesis of Benzo-Fused Tetrahydroisoquinoline-Based Biaryls through a Tandem One-Pot Halogenation of p-Benzynes from Enediynes and Suzuki-Miyaura Coupling. The Journal of Organic Chemistry 2020, 85 (4) , 2697-2703.
    6. Meghan R. Porter, Joan M. Walker, Jeffrey M. Zaleski. The Outliers: Metal-Mediated Radical Reagents for Biological Substrate Degradation. Accounts of Chemical Research 2019, 52 (7) , 1957-1967.
    7. Krystyna M. Kirschner, Stephen C. Ratvasky, Maren Pink, Jeffrey M. Zaleski. Anion Control of Lanthanoenediyne Cyclization. Inorganic Chemistry 2019, 58 (14) , 9225-9235.
    8. Eshani Das, Shyam Basak, Anakuthil Anoop, Santanu Chand, Amit Basak. How To Achieve High Regioselectivity in Barrier-less Nucleophilic Addition to p-Benzynes Generated via Bergman Cyclization of Unsymmetrical Cyclic Azaenediyne?. The Journal of Organic Chemistry 2019, 84 (5) , 2911-2921.
    9. Eshani Das, Shyam Basak, Anakuthil Anoop, Amit Basak. Experiment and Computational Study on the Regioselectivity of Nucleophilic Addition to Unsymmetrical p-Benzynes Derived from Bergman Cyclization of Enediynes. The Journal of Organic Chemistry 2018, 83 (15) , 7730-7740.
    10. Prabuddha Bhattacharya, , Amit Basak, , Adam Campbell, Igor V. Alabugin. Photochemical Activation of Enediyne Warheads: A Potential Tool for Targeted Antitumor Therapy. Molecular Pharmaceutics 2018, 15 (3) , 768-797.
    11. Anna G. Lyapunova, Natalia A. Danilkina, Andrey M. Rumyantsev, A. F. Khlebnikov, Mikhail V. Chislov, Galina L. Starova, Elena V. Sambuk, Anastasia I. Govdi, Stefan Bräse, and Irina A. Balova . Relative Reactivity of Benzothiophene-Fused Enediynes in the Bergman Cyclization. The Journal of Organic Chemistry 2018, 83 (5) , 2788-2801.
    12. Takashi Watanabe, Steven J. Geib, Dennis P. Curran, and Tsuyoshi Taniguchi . N-Heterocyclic Carbene Boranes are Hydrogen Donors in Masamune–Bergman Reactions of Benzo[3,4]cyclodec-3-ene-1,5-diynes. The Journal of Organic Chemistry 2017, 82 (24) , 13034-13042.
    13. Shudan Chen, Qiaoping Li, Shiyuan Sun, Yun Ding, and Aiguo Hu . A Novel Approach toward Polyfulvene: Cationic Polymerization of Enediynes. Macromolecules 2017, 50 (2) , 534-541.
    14. Joyee Das, Subhendu Sekhar Bag, and Amit Basak . Mechanistic Studies on Garratt–Braverman Cyclization: The Diradical–Cycloaddition Puzzle. The Journal of Organic Chemistry 2016, 81 (11) , 4623-4632.
    15. Brett R. Beno, Kap-Sun Yeung, Michael D. Bartberger, Lewis D. Pennington, and Nicholas A. Meanwell . A Survey of the Role of Noncovalent Sulfur Interactions in Drug Design. Journal of Medicinal Chemistry 2015, 58 (11) , 4383-4438.
    16. N. A. Danilkina, A. E. Kulyashova, A. F. Khlebnikov, S. Bräse, and I. A. Balova . Electrophilic Cyclization of Aryldiacetylenes in the Synthesis of Functionalized Enediynes Fused to a Heterocyclic Core. The Journal of Organic Chemistry 2014, 79 (19) , 9018-9045.
    17. Fei Ling, Zexiang Li, Chenguang Zheng, Xiang Liu, and Cheng Ma . Palladium/Copper-Catalyzed Aerobic Intermolecular Cyclization of Enediyne Compounds and Alkynes: Interrupting Cycloaromatization for (4 + 2) Cross-Benzannulation. Journal of the American Chemical Society 2014, 136 (31) , 10914-10917.
    18. Anna V. Gulevskaya, Alexander S. Tyaglivy, Alexander F. Pozharskii, Julia I. Nelina-Nemtseva, and Dmitry V. Steglenko . Heterocyclization of Enediynes Promoted by Sodium Azide: A Case of Ambiguity of X-ray Data and Structure Revision. Organic Letters 2014, 16 (6) , 1582-1585.
    19. Gagik G. Melikyan, Erin Voorhees, and Ruth Sepanian . Radical Reactions of the Cobalt-Complexed Propargyl Acetals: Inter- and Intramolecular Variants. Organometallics 2014, 33 (1) , 69-83.
    20. Rana K. Mohamed, Paul W. Peterson, and Igor V. Alabugin . Concerted Reactions That Produce Diradicals and Zwitterions: Electronic, Steric, Conformational, and Kinetic Control of Cycloaromatization Processes. Chemical Reviews 2013, 113 (9) , 7089-7129.
    21. Debabrata Samanta, Mehmet Emin Cinar, Kalpataru Das, and Michael Schmittel . Nonstatistical Dynamic Effects in the Thermal C2–C6 Diels–Alder Cyclization of Enyne–Allenes. The Journal of Organic Chemistry 2013, 78 (4) , 1451-1462.
    22. Gagik G. Melikyan, Bianca Rivas, Stepan Harutyunyan, Louis Carlson, and Ruth Sepanian . Cobaltocene-Induced Low-Temperature Radical Coupling Reactions in a Cobalt–Alkyne Series. Organometallics 2012, 31 (5) , 1653-1663.
    23. Christophe Laroche, Jing Li, and Sean M. Kerwin . Cytotoxic 1,2-Dialkynylimidazole-Based Aza-Enediynes: Aza-Bergman Rearrangement Rates Do Not Predict Cytotoxicity. Journal of Medicinal Chemistry 2011, 54 (14) , 5059-5069.
    24. Subhendu Sekhar Bag, Rajen Kundu, and Manas Das . Click-Reagent Version of Sonogashira Coupling Protocol to Conjugated Fluorescent Alkynes with No or Reduced Homocoupling. The Journal of Organic Chemistry 2011, 76 (7) , 2332-2337.
    25. Matija Gredičak, Ivana Matanović, Boris Zimmermann, and Ivanka Jerić . Bergman Cyclization of Acyclic Amino Acid Derived Enediynes Leads to the Formation of 2,3-Dihydrobenzo[f]isoindoles. The Journal of Organic Chemistry 2010, 75 (18) , 6219-6228.
    26. Abdulkader Baroudi, Justin Mauldin and Igor V. Alabugin. Conformationally Gated Fragmentations and Rearrangements Promoted by Interception of the Bergman Cyclization through Intramolecular H-Abstraction: A Possible Mechanism of Auto-Resistance to Natural Enediyne Antibiotics?. Journal of the American Chemical Society 2010, 132 (3) , 967-979.
    27. Xin Cheng, Jianguo Ma, Jian Zhi, Xi Yang and Aiguo Hu. Synthesis of Novel “Rod−Coil” Brush Polymers with Conjugated Backbones through Bergman Cyclization. Macromolecules 2010, 43 (2) , 909-913.
    28. Gagik G. Melikyan, Ryan Spencer and Edwin Abedi. Stereoselective Synthesis of meso-1,5-Cyclodecadiynes. The Journal of Organic Chemistry 2009, 74 (22) , 8541-8546.
    29. Amit Basak, Sanket Das, Dibyendu Mallick and Eluvathingal D. Jemmis . Which One Is Preferred: Myers−Saito Cyclization of Ene-Yne-Allene or Garratt−Braverman Cyclization of Conjugated Bisallenic Sulfone? A Theoretical and Experimental Study. Journal of the American Chemical Society 2009, 131 (43) , 15695-15704.
    30. Debojyoti Lahiri, Tuhin Bhowmick, Biswarup Pathak, Oottikkal Shameema, Ashis K. Patra, Suryanarayanarao Ramakumar and Akhil R. Chakravarty. Anaerobic Photocleavage of DNA in Red Light by Dicopper(II) Complexes of 3,3′-Dithiodipropionic Acid. Inorganic Chemistry 2009, 48 (1) , 339-349.
    31. Gagik G. Melikyan, Christopher Wild and Pogban Toure. Intramolecular Cyclizations of Co2(CO)6-Complexed Propargyl Radicals: Synthesis of d,l- and meso-1,5-Cyclodecadiynes. Organometallics 2008, 27 (7) , 1569-1581.
    32. Norbert Hoffmann. Photochemical Reactions as Key Steps in Organic Synthesis. Chemical Reviews 2008, 108 (3) , 1052-1103.
    33. Charles L. Perrin,, Betsy L. Rodgers, and, Joseph M. O'Connor. Nucleophilic Addition to a p-Benzyne Derived from an Enediyne:  A New Mechanism for Halide Incorporation into Biomolecules. Journal of the American Chemical Society 2007, 129 (15) , 4795-4799.
    34. Thomas Mitzel,, Joe Wzorek,, Annie Troutman, and, Kristen Allegue. Control of Skeletal Connectivity in Indium Promoted Reactions:  1,2-Additions and Cope Rearrangements En Route to Lactol Formation. The Journal of Organic Chemistry 2007, 72 (8) , 3042-3052.
    35. Rafael Chinchilla and, Carmen Nájera. The Sonogashira Reaction:  A Booming Methodology in Synthetic Organic Chemistry. Chemical Reviews 2007, 107 (3) , 874-922.
    36. Philip J. Parsons,, Alexander J. Waters,, Daryl S. Walter, and, Johnathan Board. A New Route to Highly Functionalized Heterocyclic Rings. The Journal of Organic Chemistry 2007, 72 (4) , 1395-1398.
    37. Ana García,, Julio Gómez,, Elena Lalinde, and, M. Teresa Moreno. Contrasting Thermal and Photochemical Intramolecular Coupling in Alkynylphosphine Platinum(II) Complexes. Organometallics 2006, 25 (16) , 3926-3934.
    38. Tarek A. Zeidan,, Serguei V. Kovalenko,, Mariappan Manoharan, and, Igor V. Alabugin. Ortho Effect in the Bergman Cyclization:  Comparison of Experimental Approaches and Dissection of Cycloaromatization Kinetics. The Journal of Organic Chemistry 2006, 71 (3) , 962-975.
    39. Mogens Brøndsted Nielsen and, François Diederich. Conjugated Oligoenynes Based on the Diethynylethene Unit. Chemical Reviews 2005, 105 (5) , 1837-1868.
    40. Mahendra Nath,, Maren Pink, and, Jeffrey M. Zaleski. Controlling Both Ground- and Excited-State Thermal Barriers to Bergman Cyclization with Alkyne Termini Substitution. Journal of the American Chemical Society 2005, 127 (2) , 478-479.
    41. T. C. Dinadayalane,, U. Deva Priyakumar, and, G. Narahari Sastry. Exploration of C6H6 Potential Energy Surface:  A Computational Effort to Unravel the Relative Stabilities and Synthetic Feasibility of New Benzene Isomers. The Journal of Physical Chemistry A 2004, 108 (51) , 11433-11448.
    42. Amit Basak,, Subhendu Sekhar Bag,, Pooja Anjali Majumder,, Amit Kumar Das, and, Valerio Bertolasi. Effect of Remote Trigonal Carbons on the Kinetics of Bergman Cyclization:  Synthesis and Chemical Reactivity of Pyridazinedione-Based Enediynes. The Journal of Organic Chemistry 2004, 69 (20) , 6927-6930.
    43. Puneet Singh Gahlaut, Deepak Gautam, Bhawana Shekhawat, Shivani Kushwaha, Barun Jana. Simultaneous N2 and N3 coordination of inverse triazolyl-pyridine ligands in Ag( i ) complexes: synthesis, structure, and application in the A3 coupling reaction to propargylamine under solvent free and low catalyst loading conditions. New Journal of Chemistry 2023, 47 (43) , 19953-19962.
    44. Puneet Singh Gahlaut, Deepak Gautam, Prem Lama, Barun Jana. Unusual coordination of a 1,2,3-triazolyl-pyridine ligand in a Pd( ii ) complex: application in the Suzuki–Miyaura coupling reaction. New Journal of Chemistry 2023, 47 (14) , 6871-6879.
    45. Pablo Wessig, Dominik Badetko, Michael Koebe. Triplet Sensitized Photo‐Dehydro‐Diels‐Alder Reaction. ChemistrySelect 2022, 7 (38)
    46. Anh Le, Saswata Gupta, Man Xu, Yuanzhi Xia, Daesung Lee. Development of an Allenyne‐Alkyne [4+2] Cycloaddition and its Application to Total Synthesis of Selaginpulvilin A. Chemistry – A European Journal 2022, 28 (56)
    47. Natalia A. Danilkina, Ekaterina A. Khmelevskaya, Anna G. Lyapunova, Alexander S. D’yachenko, Alexander S. Bunev, Rovshan E. Gasanov, Maxim A. Gureev, Irina A. Balova. Functionalized 10-Membered Aza- and Oxaenediynes through the Nicholas Reaction. Molecules 2022, 27 (18) , 6071.
    48. Prabuddha Bhattacharya, Soham Chakraborty, Ashwin Balaji, Amit Basak. Angle distortion model for predicting enediyne activation towards Bergman cyclization: an alternate to the distance theory. RSC Advances 2022, 12 (36) , 23552-23565.
    49. Monisha Singha, Prabuddha Bhattacharya, Debashis Ray, Amit Basak. Sterically hindering the trajectory of nucleophilic attack towards p -benzynes by a properly oriented hydrogen atom: an approach to achieve regioselectivity. Organic & Biomolecular Chemistry 2021, 19 (23) , 5148-5154.
    50. Yongjie Xu, Reiner Sebastian Sprick, Nick J. Brownbill, Frédéric Blanc, Qingyin Li, John W. Ward, Shijie Ren, Andrew I. Cooper. Bottom-up wet-chemical synthesis of a two-dimensional porous carbon material with high supercapacitance using a cascade coupling/cyclization route. Journal of Materials Chemistry A 2021, 9 (6) , 3303-3308.
    51. Jie Jack Li. Bergman Cyclization. 2021, 35-37.
    52. Matam Parameshwar, Maneesh Kumar Reddy Singam, Attunuri Nagireddy, Jagadeesh Babu Nanubolu, Maddi Sridhar Reddy. Regioselective benzannulation of allylic sulfur ylides with ynones: a rapid access to substituted thioanisoles. Chemical Communications 2020, 56 (87) , 13457-13460.
    53. Kumaresh Ghosh, Sk. Sarfaraj Ali, Soumen Joardar. Design and synthesis of azaindole heterocycle decorated new scaffold in fluorometric sensing of F − and H 2 PO 4 −. Journal of Heterocyclic Chemistry 2020, 57 (10) , 3558-3565.
    54. Maneesh Kumar Reddy Singam, Attunuri Nagireddy, Sridhar Reddy Maddi. Base-mediated benzannulation of α-cyanocrotonates with ynones: facile synthesis of benzonitriles and fluorenes. Green Chemistry 2020, 22 (8) , 2370-2374.
    55. B. Cornils. Bergman cyclization. 2020
    56. Baojun Li, Mengsi Zhang, Haotian Lu, Hailong Ma, Yue Wang, Huimin Chen, Yun Ding, Aiguo Hu. Coordination‐Accelerated Radical Formation from Acyclic Enediynes for Tumor Cell Suppression. Chemistry – An Asian Journal 2019, 14 (23) , 4352-4357.
    57. Fu Peng, Qian Zhao, Wei Huang, Shuai-Jiang Liu, Ya-Jun Zhong, Qing Mao, Nan Zhang, Gu He, Bo Han. Amine-catalyzed and functional group-controlled chemo- and regioselective synthesis of multi-functionalized CF 3 -benzene via a metal-free process. Green Chemistry 2019, 21 (22) , 6179-6186.
    58. Prabuddha Bhattacharya, Monisha Singha, Eshani Das, Arundhoti Mandal, Manasi Maji, Amit Basak. Recent advances in Garratt-Braverman cyclization: Mechanistic and synthetic explorations. Tetrahedron Letters 2018, 59 (32) , 3033-3051.
    59. Richard C. Larock, Alexandre A. Pletnev. Formation of Arenes by Aromatization. 2018, 1-51.
    60. Gurjaspreet Singh, Pooja Kalra, Aanchal Arora, Akshpreet Singh, Geetika Sharma, Sanchita, Indresh Kumar Maurya, Sanjay Dutta, Parthapratim Munshi, Vikas Verma. Acetylenic Indole-Encapsulated Schiff Bases: Synthesis, In Silico Studies as Potent Antimicrobial Agents, Cytotoxic Evaluation and Synergistic Effects. ChemistrySelect 2018, 3 (8) , 2366-2375.
    61. Chonggang Wang, Shudan Chen, Hao Zhou, Jinlou Gu, Aiguo Hu. Palladium-catalyzed cycloaromatization polymerization of enediynes. Chinese Journal of Polymer Science 2018, 36 (2) , 237-243.
    62. Youfu Wang, Shudan Chen, Aiguo Hu. Construction of Polyarylenes with Various Structural Features via Bergman Cyclization Polymerization. Topics in Current Chemistry 2017, 375 (3)
    63. Tao Wang, Haifeng Lv, Qitang Fan, Lin Feng, Xiaojun Wu, Junfa Zhu. Highly Selective Synthesis of cis ‐Enediynes on a Ag(111) Surface. Angewandte Chemie 2017, 129 (17) , 4840-4844.
    64. Tao Wang, Haifeng Lv, Qitang Fan, Lin Feng, Xiaojun Wu, Junfa Zhu. Highly Selective Synthesis of cis ‐Enediynes on a Ag(111) Surface. Angewandte Chemie International Edition 2017, 56 (17) , 4762-4766.
    65. Youfu Wang, Shudan Chen, Aiguo Hu. Chemical Synthesis of Carbon Nanomaterials Through Bergman Cyclization. 2017, 147-171.
    66. Prabuddha Bhattacharya, Sansa Dutta, Koushik Chandra, Amit Basak. The Never-Ending Story of β-Lactams: Use as Molecular Scaffolds and Building Blocks. 2017, 373-419.
    67. Joyee Das, Sayantani Roy, Swapnil Halnor, Amit Kumar Das, Amit Basak. Enediyne-based protein capture agents: demonstration of an enediyne moiety acting as a photoaffinity label. Organic & Biomolecular Chemistry 2017, 15 (5) , 1122-1129.
    68. Arundhoti Mandal Arundhoti Mandal, Asim Maity, Swarnendu Bag, Prabuddha Bhattacharya, Amit K. Das, Amit Basak. Design and synthesis of dual probes for detection of metal ions by LALDI MS and fluorescence: application in Zn( ii ) imaging in cells. RSC Advances 2017, 7 (12) , 7163-7169.
    69. Shizuka Mei Bautista Maezono, Tej Narayan Poudel, Yong Rok Lee. One-pot construction of sterically challenging and diverse polyarylphenols via transition-metal-free benzannulation and their potent in vitro antioxidant activity. Organic & Biomolecular Chemistry 2017, 15 (9) , 2052-2062.
    70. Pankaj Sharma, Prakash D. Jadhav, Manisha Skaria, Rai-Shung Liu. Stereoselective annulation between an allene, an alkene, and two nitrosoarenes to access bis(isoxazoliodine) derivatives. Organic & Biomolecular Chemistry 2017, 15 (44) , 9389-9397.
    71. , T. V. Osadchuk, O. V. Shybyryn, , V. K. Kibirev, , . Chemical structure and properties of low-molecular furin inhibitors. The Ukrainian Biochemical Journal 2016, 88 (6) , 5-25.
    72. Jin Tu Danence Lee, Yu Zhao. Access to Acyclic Z ‐Enediynes by Alkyne Trimerization: Cooperative Bimetallic Catalysis Using Air as the Oxidant. Angewandte Chemie International Edition 2016, 55 (44) , 13872-13876.
    73. Jin Tu Danence Lee, Yu Zhao. Access to Acyclic Z ‐Enediynes by Alkyne Trimerization: Cooperative Bimetallic Catalysis Using Air as the Oxidant. Angewandte Chemie 2016, 128 (44) , 14076-14080.
    74. Chun‐Lin Zhang, Zhong‐Hua Gao, Zhi‐Qin Liang, Song Ye. N‐Heterocyclic Carbene‐Catalyzed Synthesis of Multi‐Substituted Benzenes from Enals and α‐Cyano‐β‐methylenones. Advanced Synthesis & Catalysis 2016, 358 (18) , 2862-2866.
    75. Takeshi Kawase, Hiroyuki Kurata. Recent Developments in Fulvene and Heterofulvene Chemistry. 2016, 145-248.
    76. Subhendu Sekhar Bag, Isao Saito. Design of Environmentally Sensitive Fluorescent Nucleosides and their Applications. 2016, 137-173.
    77. Dongxu Wang, Fei Ling, Xiang Liu, Zexiang Li, Cheng Ma. Aerobic Dimerization of Enediyne Compounds: Construction of Naphthalene Frameworks. Chemistry – A European Journal 2016, 22 (1) , 124-128.
    78. Youfu Wang, Luhua Dong, Zhiwei Zheng, Xing Li, Rulin Xiong, Jianli Hua, Aiguo Hu. Enediyne as π linker in D–π–A dyes for dye-sensitized solar cells. RSC Advances 2016, 6 (15) , 12124-12130.
    79. Carlotta Raviola, Stefano Protti, Davide Ravelli, Maurizio Fagnoni. (Hetero)aromatics from dienynes, enediynes and enyne–allenes. Chemical Society Reviews 2016, 45 (15) , 4364-4390.
    80. Shudan Chen, Aiguo Hu. Recent advances of the Bergman cyclization in polymer science. Science China Chemistry 2015, 58 (11) , 1710-1723.
    81. Rajdip Karmakar, Sang Young Yun, Jiajia Chen, Yuanzhi Xia, Daesung Lee. Benzannulation of Triynes to Generate Functionalized Arenes by Spontaneous Incorporation of Nucleophiles. Angewandte Chemie International Edition 2015, 54 (22) , 6582-6586.
    82. Rajdip Karmakar, Sang Young Yun, Jiajia Chen, Yuanzhi Xia, Daesung Lee. Benzannulation of Triynes to Generate Functionalized Arenes by Spontaneous Incorporation of Nucleophiles. Angewandte Chemie 2015, 127 (22) , 6682-6686.
    83. Ajoy Basak, Mukunda Goswami, Abishankari Rajkumar, Tapobrata Mitra, Swapan Majumdar, Paul O’Reilly, Hussam M. Bdour, Vance L. Trudeau, Amit Basak. Enediynyl peptides and iso-coumarinyl methyl sulfones as inhibitors of proprotein convertases PCSK8/SKI-1/S1P and PCSK4/PC4: Design, synthesis and biological evaluations. Bioorganic & Medicinal Chemistry Letters 2015, 25 (10) , 2225-2237.
    84. Théo P. Gonçalves, Mubina Mohamed, Richard J. Whitby, Helen F. Sneddon, David C. Harrowven. Exploring Diradical Chemistry: A Carbon‐Centered Radical May Act as either an Anion or Electrophile through an Orbital Isomer. Angewandte Chemie International Edition 2015, 54 (15) , 4531-4534.
    85. Théo P. Gonçalves, Mubina Mohamed, Richard J. Whitby, Helen F. Sneddon, David C. Harrowven. Exploring Diradical Chemistry: A Carbon‐Centered Radical May Act as either an Anion or Electrophile through an Orbital Isomer. Angewandte Chemie 2015, 127 (15) , 4614-4617.
    86. . Catalytic Cycloaddition Aromatization Processes. 2014, 436-490.
    87. Dmitry S. Perekalin, Alexander R. Kudinov. Cyclopentadienyl ruthenium complexes with naphthalene and other polycyclic aromatic ligands. Coordination Chemistry Reviews 2014, 276 , 153-173.
    88. Endrit Shurdha, Hannah A. Miller, Russell E. Johnson, Gary J. Balaich, Scott T. Iacono. Synthesis and thermal properties of a new styryl-functionalized pentafulvene glassy carbon precursor. Tetrahedron 2014, 70 (34) , 5142-5147.
    89. Kyle D. Reichl, Alexander T. Radosevich. A phosphine-mediated stereocontrolled synthesis of Z -enediynes by a vicinal dialkynylation of ethynylphosphonium salts. Chemical Communications 2014, 50 (66) , 9302-9305.
    90. Benjamin Prek, Jure Bezenšek, Marta Kasunič, Uroš Grošelj, Jurij Svete, Branko Stanovnik. Reactions of enaminones and related compounds with N,N-dimethylacetamide dimethyl acetal. A simple one-pot metal-free synthesis of polysubstituted benzene derivatives. Tetrahedron 2014, 70 (14) , 2359-2369.
    91. Max M. Hansmann, Svetlana Tšupova, Matthias Rudolph, Frank Rominger, A. Stephen K. Hashmi. Gold‐Catalyzed Cyclization of Diynes: Controlling the Mode of 5‐ endo versus 6‐ endo Cyclization—An Experimental and Theoretical Study by Utilizing Diethynylthiophenes. Chemistry – A European Journal 2014, 20 (8) , 2215-2223.
    92. Shiyuan Sun, Chuanchuan Zhu, Depeng Song, Fei Li, Aiguo Hu. Preparation of conjugated polyphenylenes from maleimide-based enediynes through thermal-triggered Bergman cyclization polymerization. Polym. Chem. 2014, 5 (4) , 1241-1247.
    93. Ishita Hatial, Saibal Jana, Shrabani Bisai, Manasmita Das, Ananta Kumar Ghosh, Anakuthil Anoop, Amit Basak. Trienediynes on a 1,3,5-trisubstituted benzene template: a new approach for enhancement of reactivity. RSC Advances 2014, 4 (53) , 28041.
    94. Jie Jack Li. Bergman cyclization. 2014, 48-49.
    95. . References. 2013, 255-286.
    96. Gong-Jun Chen, Zhi-Gang Wang, Xin Qiao, Jing-Yuan Xu, Jin-Lei Tian, Shi-Ping Yan. Synthesis, DNA binding, photo-induced DNA cleavage, cytotoxicity studies of a family of heavy rare earth complexes. Journal of Inorganic Biochemistry 2013, 127 , 39-45.
    97. Renzo Rossi, Fabio Bellina, Marco Lessi, Chiara Manzini. Development and applications of highly selective palladium-catalyzed monocoupling reactions of (cyclo)alkenes and 1,3-alkadienes bearing two or three electrophilic sites and bis(enol triflates) with terminal alkynes. Tetrahedron 2013, 69 (37) , 7869-7909.
    98. Paul W. Peterson, Rana K. Mohamed, Igor V. Alabugin. How to Lose a Bond in Two Ways ― The Diradical/Zwitterion Dichotomy in Cycloaromatization Reactions. European Journal of Organic Chemistry 2013, 2013 (13) , 2505-2527.
    99. A. V. Gulevskaya, R. Yu. Lazarevich. Cyclizations of enediynes under the action of electrophiles. Chemistry of Heterocyclic Compounds 2013, 49 (1) , 116-139.
    100. Akhilesh K. Verma, Rajeev R. Jha, Ritu Chaudhary, Rakesh K. Tiwari, Abhinandan K. Danodia. 2‐(1‐Benzotriazolyl)pyridine: A Robust Bidentate Ligand for the Palladium‐Catalyzed CC (Suzuki, Heck, Fujiwara–Moritani, Sonogashira), CN and CS Coupling Reactions. Advanced Synthesis & Catalysis 2013, 355 (2-3) , 421-438.
    Load all citations