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Carbon in One Dimension:  Structural Analysis of the Higher Conjugated Polyynes

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Department of Chemistry, University of Wroclaw, 14 F. Joliot-Curie, Wroclaw, Poland, and Institut für Organische Chemie, Friedrich-Alexander-Universität Erlangen-Nürnberg, Henkestrasse 42, 91054 Erlangen, Germany
Cite this: Chem. Rev. 2003, 103, 11, 4175–4206
Publication Date (Web):October 29, 2003
Copyright © 2003 American Chemical Society

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    89. Yang Fan, Isiah Po-Chun Liu, Phillip E. Fanwick and Tong Ren. Dimer of Diruthenium Compound Bridged by 1,1′-Diethynylferrocene: Ferrocene as a Weak Mediator for Electronic Coupling. Organometallics 2009, 28 (13) , 3959-3962.
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    93. Bin Xi, Guo-Lin Xu, Phillip E. Fanwick and Tong Ren. Diruthenium Complexes of Axial Ferrocenyl−Polyynyl Ligands: The Cases of C6Fc and C8Fc. Organometallics 2009, 28 (7) , 2338-2341.
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    96. Marek Samoc, Gulliver T. Dalton, John A. Gladysz, Qinglin Zheng, Yasen Velkov, Hans Ågren, Patrick Norman and Mark G. Humphrey . Cubic Nonlinear Optical Properties of Platinum-Terminated Polyynediyl Chains. Inorganic Chemistry 2008, 47 (21) , 9946-9957.
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    100. Constantinos D. Zeinalipour-Yazdi and David P. Pullman . Quantitative Structure−Property Relationships for Longitudinal, Transverse, and Molecular Static Polarizabilities in Polyynes. The Journal of Physical Chemistry B 2008, 112 (25) , 7377-7386.
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