Recent Advances in Aqueous Actinide Chemistry and Thermodynamics

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2. Felipe R. Dutra, David A. Dixon. Prediction of Redox Potentials for Different Oxidation States of U, Np, Pu, and Am in Alkaline Aqueous Solution. The Journal of Physical Chemistry A 2025, 129 (10) , 2521-2536. https://doi.org/10.1021/acs.jpca.4c08794
3. Tatiana Poliakova, Iurii Nevolin, Andrey Shiryaev, Alexander Fedoseev, Mikhail Grigoriev, Alexey Averin, Vladislava Zubkova, Daniil Novichkov, Alexander Trigub, Anna Krot, Mikhail Volgin, Petr Matveev. Structural Regularities, Thermal Stability, and Nature of Chemical Bonding in the Series of Actinide Double Sulfates Cs[An(SO4)2(H2O)3]·H2O (An = U, Np, Pu, or Am). Inorganic Chemistry 2025, 64 (8) , 3664-3676. https://doi.org/10.1021/acs.inorgchem.4c04102
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15. Julia Neumann, Sang Soo Lee, Hannes Brinkmann, Peter J. Eng, Joanne E. Stubbs, Thorsten Stumpf, Moritz Schmidt. Impact of Ion–Ion Correlations on the Adsorption of M(III) (M = Am, Eu, Y) onto Muscovite (001) in the Presence of Sulfate. The Journal of Physical Chemistry C 2022, 126 (3) , 1400-1410. https://doi.org/10.1021/acs.jpcc.1c09561
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17. Enrica Balboni, Kurt F. Smith, Liane M. Moreau, Josh Wimpenny, Corwin H. Booth, Annie B. Kersting, Mavrik Zavarin. Plutonium Co-precipitation with Calcite. ACS Earth and Space Chemistry 2021, 5 (12) , 3362-3374. https://doi.org/10.1021/acsearthspacechem.1c00181
18. Manh-Thuong Nguyen Jun Zhang David C. Cantu Roger Rousseau Vassiliki-Alexandra Glezakou . Tailored Computational Approaches to Interrogate Heavy Element Chemistry and Structure in Condensed Phase. , 219-245. https://doi.org/10.1021/bk-2021-1388.ch011
19. Nitesh Kumar Biswajit Sadhu Aurora E. Clark . Essential Aspects of Solvent Effects and Solution Conditions upon the Modeling and Simulation of Lanthanide and Actinide Complexes. , 249-276. https://doi.org/10.1021/bk-2021-1388.ch012
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23. Jagriti Singh, Dolly Yadav, Jai Deo Singh. En Route Activity of Hydration Water Allied with Uranyl (UO22+) Salts Amid Complexation Reactions with an Organothio-Based (O, N, S) Donor Base. Inorganic Chemistry 2019, 58 (8) , 4972-4978. https://doi.org/10.1021/acs.inorgchem.8b03622
24. Harald Zänker, Katja Heine, Stephan Weiss, Vinzenz Brendler, Richard Husar, Gert Bernhard, Karsten Gloe, Thomas Henle, Astrid Barkleit. Strong Uranium(VI) Binding onto Bovine Milk Proteins, Selected Protein Sequences, and Model Peptides. Inorganic Chemistry 2019, 58 (7) , 4173-4189. https://doi.org/10.1021/acs.inorgchem.8b03231
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26. Patric Lindqvist-Reis, Florent Réal, Rafał Janicki, Valérie Vallet. Unraveling the Ground State and Excited State Structures and Dynamics of Hydrated Ce3+ Ions by Experiment and Theory. Inorganic Chemistry 2018, 57 (16) , 10111-10121. https://doi.org/10.1021/acs.inorgchem.8b01224
27. Lei Mei, Kong-qiu Hu, Zhi-hui Zhang, Shu-wen An, Zhi-fang Chai, Wei-qun Shi. Stepwise ortho Chlorination of Carboxyl Groups for Promoting Structure Variance of Heterometallic Uranyl–Silver Coordination Polymers of Isonicotinate. Inorganic Chemistry 2018, 57 (8) , 4673-4685. https://doi.org/10.1021/acs.inorgchem.8b00402
28. Pallavi Singhal, Sanjay K. Jha, Bal Govind Vats, and Hirendra N. Ghosh . Electron-Transfer-Mediated Uranium Detection Using Quasi-Type II Core–Shell Quantum Dots: Insight into Mechanistic Pathways. Langmuir 2017, 33 (33) , 8114-8122. https://doi.org/10.1021/acs.langmuir.7b00926
29. Daniel R. Fröhlich, Alena Kremleva, André Rossberg, Andrej Skerencak-Frech, Carsten Koke, Sven Krüger, Notker Rösch, and Petra J. Panak . Combined EXAFS Spectroscopic and Quantum Chemical Study on the Complex Formation of Am(III) with Formate. Inorganic Chemistry 2017, 56 (12) , 6820-6829. https://doi.org/10.1021/acs.inorgchem.7b00035
30. Takashi Yoshimura, Masayuki Nakaguchi, and Keisuke Morimoto . Synthesis, Structures, and Proton Self-Exchange Reaction of μ3-Oxido/Hydroxido Bridged Trinuclear Uranyl(VI) Complexes with Tridentate Schiff-Base Ligands. Inorganic Chemistry 2017, 56 (7) , 4057-4064. https://doi.org/10.1021/acs.inorgchem.6b03175
31. Wibe A. de Jong, Phuong D. Dau, Richard E. Wilson, Joaquim Marçalo, Michael J. Van Stipdonk, Theodore A. Corcovilos, Giel Berden, Jonathan Martens, Jos Oomens, and John K. Gibson . Revealing Disparate Chemistries of Protactinium and Uranium. Synthesis of the Molecular Uranium Tetroxide Anion, UO4–. Inorganic Chemistry 2017, 56 (6) , 3686-3694. https://doi.org/10.1021/acs.inorgchem.7b00144
32. R.K. Dutta and Ambika Kumar . Highly Sensitive and Selective Method for Detecting Ultratrace Levels of Aqueous Uranyl Ions by Strongly Photoluminescent-Responsive Amine-Modified Cadmium Sulfide Quantum Dots. Analytical Chemistry 2016, 88 (18) , 9071-9078. https://doi.org/10.1021/acs.analchem.6b01943
33. Pieter Bots, Samuel Shaw, Gareth T.W. Law, Timothy A. Marshall, J. Frederick W. Mosselmans, and Katherine Morris . Controls on the Fate and Speciation of Np(V) During Iron (Oxyhydr)oxide Crystallization. Environmental Science & Technology 2016, 50 (7) , 3382-3390. https://doi.org/10.1021/acs.est.5b05571
34. Nidhu lal Banik, Rémi Marsac, Johannes Lützenkirchen, Alexandre Diascorn, Kerstin Bender, Christian Michael Marquardt, and Horst Geckeis . Sorption and Redox Speciation of Plutonium at the Illite Surface. Environmental Science & Technology 2016, 50 (4) , 2092-2098. https://doi.org/10.1021/acs.est.5b05129
35. Brian Haliena, Hangping Zheng, Nathan Melson, Daniel I. Kaplan, and Mark O. Barnett . Decreased Salinity and Actinide Mobility: Colloid-Facilitated Transport or pH Change?. Environmental Science & Technology 2016, 50 (2) , 625-632. https://doi.org/10.1021/acs.est.5b04331
36. Carl-Heinrich Graser, Nidhu lal Banik, Kerstin Anne Bender, Markus Lagos, Christian Michael Marquardt, Rémi Marsac, Vanessa Montoya, and Horst Geckeis . Sensitive Redox Speciation of Iron, Neptunium, and Plutonium by Capillary Electrophoresis Hyphenated to Inductively Coupled Plasma Sector Field Mass Spectrometry. Analytical Chemistry 2015, 87 (19) , 9786-9794. https://doi.org/10.1021/acs.analchem.5b02051
37. Phuong D. Dau, Richard E. Wilson, and John K. Gibson . Elucidating Protactinium Hydrolysis: The Relative Stabilities of PaO2(H2O)+ and PaO(OH)2+. Inorganic Chemistry 2015, 54 (15) , 7474-7480. https://doi.org/10.1021/acs.inorgchem.5b01078
38. Tonya Vitova, Jennifer C. Green, Robert G. Denning, Matthias Löble, Kristina Kvashnina, Joshua J. Kas, Kevin Jorissen, John J. Rehr, Thomas Malcherek, and Melissa A. Denecke . Polarization Dependent High Energy Resolution X-ray Absorption Study of Dicesium Uranyl Tetrachloride. Inorganic Chemistry 2015, 54 (1) , 174-182. https://doi.org/10.1021/ic5020016
39. Atsushi Ikeda-Ohno, Jennifer J. Harrison, Sangeeth Thiruvoth, Kerry Wilsher, Henri K. Y. Wong, Mathew P. Johansen, T. David Waite, and Timothy E. Payne . Solution Speciation of Plutonium and Americium at an Australian Legacy Radioactive Waste Disposal Site. Environmental Science & Technology 2014, 48 (17) , 10045-10053. https://doi.org/10.1021/es500539t
40. Attila Pallagi, Éva G. Bajnóczi, Sophie E. Canton, Trudy Bolin, Gábor Peintler, Bence Kutus, Zoltán Kele, István Pálinkó, and Pál Sipos . Multinuclear Complex Formation between Ca(II) and Gluconate Ions in Hyperalkaline Solutions. Environmental Science & Technology 2014, 48 (12) , 6604-6611. https://doi.org/10.1021/es501067w
41. Qun-Yan Wu, Jian-Hui Lan, Cong-Zhi Wang, Cheng-Liang Xiao, Yu-Liang Zhao, Yue-Zhou Wei, Zhi-Fang Chai, and Wei-Qun Shi . Understanding the Bonding Nature of Uranyl Ion and Functionalized Graphene: A Theoretical Study. The Journal of Physical Chemistry A 2014, 118 (11) , 2149-2158. https://doi.org/10.1021/jp500924a
42. Wei Huang, Wen-Hua Xu, Jing Su, W. H. E. Schwarz, and Jun Li . Oxidation States, Geometries, and Electronic Structures of Plutonium Tetroxide PuO4 Isomers: Is Octavalent Pu Viable?. Inorganic Chemistry 2013, 52 (24) , 14237-14245. https://doi.org/10.1021/ic402170q
43. Karah E. Knope and L. Soderholm . Plutonium(IV) Cluster with a Hexanuclear [Pu6(OH)4O4]12+ Core. Inorganic Chemistry 2013, 52 (12) , 6770-6772. https://doi.org/10.1021/ic4007185
44. Staffan Sjöberg. Solution and Surface Complexation: The European Perspective. Reviews in Mineralogy and Geochemistry 2025, 91A (1) , 1-12. https://doi.org/10.2138/rmg.2025.91A.01
45. Hyeonjin Eun, Peter Gyula Szabo, Darlyn Rehhorn, Seungwoo Lee, Yongheum Jo, Marcus Altmaier, Jinyoung Lee, Xavier Gaona, Jong-Il Yun. Uptake of Eu, Th, U, and Pu by granite and biotite gneiss in Korean fresh groundwater under oxidizing and reducing conditions. Radiochimica Acta 2025, 113 (3) , 181-194. https://doi.org/10.1515/ract-2024-0331
46. Aditya L. Shinde, Priyanka Velmurugan, Akash K. Sahoo, Shanmugam Revathi, Manickaraj Meena, Preethi Raja, Moris S. Eisen, Tapas Ghatak. Chemistry of uranium and thorium complexes towards challenging transformation: A recent trends. Polyhedron 2025, 270 , 117428. https://doi.org/10.1016/j.poly.2025.117428
47. Christian Kiefer, Xavier Gaona, Tomo Suzuki-Muresan, Dieter Schild, Krassimir Garbev, Taishi Kobayashi, Kathy Dardenne, Oliver Dieste Blanco, Marcus Altmaier, Bernd Grambow, Horst Geckeis. Structural characterization of amorphous hydrous Zr(IV) oxide and the transformation occurring under hydrothermal conditions. Applied Geochemistry 2025, 182 , 106302. https://doi.org/10.1016/j.apgeochem.2025.106302
48. Regina R. Kayumova, Sergey L. Khursan. Chiral discrimination during photoinduced electron transfer from L/D-tryptophan to electron-excited uranyl ion as a part of UO22+ ⊂ α–CD inclusion complex. Journal of Photochemistry and Photobiology A: Chemistry 2025, 459 , 116109. https://doi.org/10.1016/j.jphotochem.2024.116109
49. Yi Yu, Bin Xiao, Rüdiger‐A. Eichel, Evgeny V. Alekseev. Insights into Structural Diversity and Morphotropic Evolution in A 4 Th(WO 4 ) 4 (A=Li, Na, K, Rb and Cs) Family. Chemistry – A European Journal 2025, 31 (3) https://doi.org/10.1002/chem.202403343
50. Ion Chiorescu, Sven Krüger. Density functional modeling of ternary Am(III) hydroxo complexes with Ca or Mg counterions. Do Mg stabilized species exist?. Applied Geochemistry 2024, 174 , 106159. https://doi.org/10.1016/j.apgeochem.2024.106159
51. Wansik Cha, Junghwan Park, Euo Chang Jung, Hye Ran Noh, Hee-Kyung Kim, Hye-Ryun Cho. Characterization and solubility measurement of synthetic uranophane and sklodowskite under oxic groundwater conditions. Applied Geochemistry 2024, 175 , 106191. https://doi.org/10.1016/j.apgeochem.2024.106191
52. Wanqiang Zhou, Xiangyun Wang, Chunli Liu. Solubility, speciation and sorption calculation of americium in far-field and near-field Beishan groundwaters. Journal of Radioanalytical and Nuclear Chemistry 2024, 319 https://doi.org/10.1007/s10967-024-09838-3
53. Yang He, Jun-Bo Lu, Yang-Yang Zhang, Han-Shi Hu, Jun Li. Structures of Th 4+ aqueous solutions: insights from AIMD and metadynamics simulations. Physical Chemistry Chemical Physics 2024, 26 (37) , 24447-24454. https://doi.org/10.1039/D4CP02512A
54. Y. Yan, N. Çevirim-Papaioannou, X. Gaona, D. Fellhauer, M. Altmaier. Thermodynamic description of U(IV) solubility and hydrolysis in chloride systems: Pitzer activity model for the system U4+–Na+–Mg2+–Ca2+–H+–Cl––OH––H2O(l). Applied Geochemistry 2024, 171 , 106091. https://doi.org/10.1016/j.apgeochem.2024.106091
55. Rémi Marsac, Charlotte Catrouillet, Mathieu Pédrot, Marc F. Benedetti, Aline Dia, Eric D. van Hullebusch, Mélanie Davranche, Yann Sivry, Anne-Catherine Pierson-Wickmann, Mickael Tharaud, Frank Heberling. Equilibrium surface complexation modeling with metastable natural colloids: The key to predict the oxidation state distribution of trace elements?. Current Opinion in Colloid & Interface Science 2024, 72 , 101820. https://doi.org/10.1016/j.cocis.2024.101820
56. Ashutosh Srivastava, Sk. Musharaf Ali, Rama Mohan Rao Dumpala, Sumit Kumar, Pranaw Kumar, Neetika Rawat, P. K. Mohapatra. Unusual redox stability of pentavalent uranium with hetero-bifunctional phosphonocarboxylate: insight into aqueous speciation. Dalton Transactions 2024, 53 (17) , 7321-7339. https://doi.org/10.1039/D4DT00173G
57. P. F. dos Santos, X. Gaona, A. Lassin, A. Skerencak-Frech, D. Fellhauer, M. Altmaier, B. Madé. Thermodynamics of the Eu( iii )–Mg–SO 4 –H 2 O and Eu( iii )–Na–SO 4 –H 2 O systems. Part II: spectroscopy experiments, complexation and Pitzer/SIT models. Dalton Transactions 2024, 53 (14) , 6323-6332. https://doi.org/10.1039/D3DT04323A
58. Peng Wu, Ju Wang, Hui Ling, Zhichao Zhou, M. Santosh, Zhenping Tang, Haoran Sun, Rengao Gui, Jiaxin Duan, Nan Li, Xianzhe Duan. Safety assessment in the disposal of high-level radioactive wastes (HLWs): a geochemical study of uranium complexes in deep groundwater in granites from Beishan, China. Journal of Radioanalytical and Nuclear Chemistry 2024, 333 (4) , 1779-1791. https://doi.org/10.1007/s10967-024-09413-w
59. Malgorzata Olejniczak, Valérie Vallet, André S.P. Gomes. Modeling Environment Effects on Heavy-Element Compounds. 2024, 129-154. https://doi.org/10.1016/B978-0-12-821978-2.00099-4
60. Bence Kutus, Pál Sipos. Complex Formation in Hyperalkaline Solutions. 2023, 313-330. https://doi.org/10.1039/BK9781839169601-00313
61. Zhipeng Wang, Liqin Huang, Xue Dong, Tong Wu, Qi Qing, Jing Chen, Yuexiang Lu, Chao Xu. Ion sieving in graphene oxide membrane enables efficient actinides/lanthanides separation. Nature Communications 2023, 14 (1) https://doi.org/10.1038/s41467-023-35942-1
62. Tim Graubner, Antti J. Karttunen, Florian Kraus. A Dinuclear Uranium Complex [{UO 2 F 2 (NH 3 )} 2 (μ‐F) 2 ] 2− from Reaction of TlF and UO 2 F 2 in Liquid Anhydrous Ammonia and Fluoride Ion Affinities for Some Uranyl(VI) Species [UO 2 F x ] 2− x and [UO 2 F x (NH 3 ) 5 −x ] 2− x . European Journal of Inorganic Chemistry 2023, 26 (28) https://doi.org/10.1002/ejic.202300387
63. Muqeet Iqbal, Rémi Marsac, Mélanie Davranche, Aline Dia, Khalil Hanna. A mechanistic surface complexation approach for the prediction of rare earth element reactive transport in quartz porous media. Chemical Geology 2023, 634 , 121601. https://doi.org/10.1016/j.chemgeo.2023.121601
64. Cheriyan Ebenezer, Rajadurai Vijay Solomon. Role of sulphur and oxygen in phosphine ligands in the extraction process of Am3+ over Eu3+ ions in water medium – A theoretical study. Journal of Molecular Liquids 2023, 382 , 122035. https://doi.org/10.1016/j.molliq.2023.122035
65. Kazuki Ouchi, Daiju Matsumura, Takuya Tsuji, Tohru Kobayashi, Haruyoshi Otobe, Yoshihiro Kitatsuji. Uranium hydroxide/oxide deposits on uranyl reduction. RSC Advances 2023, 13 (24) , 16321-16326. https://doi.org/10.1039/D3RA02899B
66. Logan J. Augustine, Mikaela Mary F. Pyrch, Dmytro V. Kravchuk, Jay M. Williams, Sara E. Mason, Tori Z. Forbes. Density Functional Theory Guided Investigation of Ligand‐Induced Neptunyl‐Neptunyl Interactions. European Journal of Inorganic Chemistry 2023, 26 (14) https://doi.org/10.1002/ejic.202200693
67. Sen Yang, Zeqin Li, Pujing Pan. Americium solubility and solubility limiting solid phase (SLSP) analysis in groundwater of Beishan, a proposed site for the disposal of high-level radioactive waste in China. Applied Geochemistry 2023, 152 , 105650. https://doi.org/10.1016/j.apgeochem.2023.105650
68. Hye-Ryun Cho, Sangki Cho, Jueun Kim, Sangsoo Han, Hee-Kyung Kim, Wooyong Um. Dissolution behaviors of PuO2(cr) in natural waters. Frontiers in Nuclear Engineering 2023, 2 https://doi.org/10.3389/fnuen.2023.1118594
69. Erik Coppens, Katinka Wouters, Benny de Blochouse, Delphine Durce. Investigating the effect of pore water composition and isosaccharinic acid (ISA) on sorption of Pu to a CEM III/C-based mortar. Frontiers in Nuclear Engineering 2023, 2 https://doi.org/10.3389/fnuen.2023.1151271
70. Shruti Vinod, Cheriyan Ebenezer, Rajadurai Vijay Solomon. Do mono- or diphenol substitutions in phenanthroline-based ligands serve in effective separation of Am 3+ /Eu 3+ ions?- Insights from DFT calculations. Separation Science and Technology 2023, 58 (4) , 627-641. https://doi.org/10.1080/01496395.2022.2160352
71. Xiao-Yi Wu, An-Qi Cui, Jun-Bin Ye, Gang Song, Yan-Ni Wu, Yue-Xi Wu, Jia-Ping Lai, Hui Sun. Novel biocompatible and sensitive visual sensor based on aggregation-induced emission for on-site detection of radioactive uranium in water and live cell imaging. Science of The Total Environment 2023, 858 , 159796. https://doi.org/10.1016/j.scitotenv.2022.159796
72. Cheriyan Ebenezer, Rajadurai Vijay Solomon. Complexation of N‐Heterocyclic Substituted 1,10‐Phenanthroline‐2,9‐diamide with Am 3+ /Eu 3+ Ions for Nuclear Waste Water Treatment. ChemistrySelect 2022, 7 (45) https://doi.org/10.1002/slct.202203535
73. Matthieu Virot, Thomas Dumas, Manon Cot-Auriol, Philippe Moisy, Sergey I. Nikitenko. Synthesis and multi-scale properties of PuO 2 nanoparticles: recent advances and open questions. Nanoscale Advances 2022, 4 (23) , 4938-4971. https://doi.org/10.1039/D2NA00306F
74. Stefan S. Rudel, H. Lars Deubner, Thomas G. Müller, Tim Graubner, Sergei I. Ivlev, Florian Kraus. [U(NH 3 ) 10 ] 4+ Cations in Azide, Bromide, and Iodide Ammoniates and a Hydrolysis Product with an unprecedented [U(H 2 O) 9 ] 4+ Cation. Zeitschrift für anorganische und allgemeine Chemie 2022, 648 (21) https://doi.org/10.1002/zaac.202200211
75. Taylor V. Fetrow, Joshua Zgrabik, Rina Bhowmick, Francesca D. Eckstrom, George Crull, Bess Vlaisavljevich, Scott R. Daly. Quantifying the Influence of Covalent Metal‐Ligand Bonding on Differing Reactivity of Trivalent Uranium and Lanthanide Complexes. Angewandte Chemie 2022, 134 (45) https://doi.org/10.1002/ange.202211145
76. Taylor V. Fetrow, Joshua Zgrabik, Rina Bhowmick, Francesca D. Eckstrom, George Crull, Bess Vlaisavljevich, Scott R. Daly. Quantifying the Influence of Covalent Metal‐Ligand Bonding on Differing Reactivity of Trivalent Uranium and Lanthanide Complexes. Angewandte Chemie International Edition 2022, 61 (45) https://doi.org/10.1002/anie.202211145
77. Tonya Vitova, Radmila Faizova, Jorge I. Amaro-Estrada, Laurent Maron, Tim Pruessmann, Thomas Neill, Aaron Beck, Bianca Schacherl, Farzaneh Fadaei Tirani, Marinella Mazzanti. The mechanism of Fe induced bond stability of uranyl( v ). Chemical Science 2022, 13 (37) , 11038-11047. https://doi.org/10.1039/D2SC03416F
78. Haitao Zhang, Xiaolin Hou, Jixin Qiao, Jianfeng Lin. Determination of 241Am in Environmental Samples: A Review. Molecules 2022, 27 (14) , 4536. https://doi.org/10.3390/molecules27144536
79. P. G. Szabo, A. G. Tasi, X. Gaona, R. Polly, A. C Maier, S. Hedström, M. Altmaier, H. Geckeis. Solubility of Ca( ii ), Ni( ii ), Nd( iii ) and Pu( iv ) in the presence of proxy ligands for the degradation of polyacrylonitrile in cementitious systems. Dalton Transactions 2022, 51 (24) , 9432-9444. https://doi.org/10.1039/D2DT01409B
80. Sumit Kumar, Rama Mohana Rao Dumpala, Annapurna Chandane, Jitendra Bahadur. Elucidation of the sorbent role in sorption thermodynamics of uranium( vi ) on goethite. Environmental Science: Processes & Impacts 2022, 24 (4) , 567-575. https://doi.org/10.1039/D1EM00380A
81. Vanessa Montoya, Ulrich Noseck, Felix Mattick, Susan Britz, Ingo Blechschmidt, Thorsten Schäfer. Radionuclide geochemistry evolution in the Long-term In-situ Test (LIT) at Grimsel Test Site (Switzerland). Journal of Hazardous Materials 2022, 424 , 127733. https://doi.org/10.1016/j.jhazmat.2021.127733
82. Thomas Dumas, Matthieu Virot, Denis Menut, Christelle Tamain, Cyril Micheau, Sandrine Dourdain, Olivier Diat. Size and structure of hexanuclear plutonium oxo-hydroxo clusters in aqueous solution from synchrotron analysis. Journal of Synchrotron Radiation 2022, 29 (1) , 30-36. https://doi.org/10.1107/S1600577521012005
83. Jingzhen Du, Iskander Douair, Erli Lu, John A. Seed, Floriana Tuna, Ashley J. Wooles, Laurent Maron, Stephen T. Liddle. Evidence for ligand- and solvent-induced disproportionation of uranium(IV). Nature Communications 2021, 12 (1) https://doi.org/10.1038/s41467-021-25151-z
84. Jing Su, Thibault Cheisson, Alex McSkimming, Conrad A. P. Goodwin, Ida M. DiMucci, Thomas Albrecht-Schönzart, Brian L. Scott, Enrique R. Batista, Andrew J. Gaunt, Stosh A. Kozimor, Ping Yang, Eric J. Schelter. Complexation and redox chemistry of neptunium, plutonium and americium with a hydroxylaminato ligand. Chemical Science 2021, 12 (40) , 13343-13359. https://doi.org/10.1039/D1SC03905A
85. Wasif Abu Dujana, Arpon Podder, Ovijit Das, Md. Solayman, M. T. Nasir, M. A. Rashid, Md Saiduzzaman, M. A. Hadi. Structural, electronic, mechanical, thermal, and optical properties of UIr3 under pressure: A comprehensive DFT study. AIP Advances 2021, 11 (10) https://doi.org/10.1063/5.0064021
86. Sarah B. Duckworth, Xavier Gaona, Alexander Baumann, Kathy Dardenne, Jörg Rothe, Dieter Schild, Marcus Altmaier, Horst Geckeis. Impact of sulfate on the solubility of Tc(IV) in acidic to hyperalkaline aqueous reducing systems. Radiochimica Acta 2021, 109 (9) , 681-697. https://doi.org/10.1515/ract-2021-1044
87. Jordan F. Corbey, Lucas E. Sweet, Sergey I. Sinkov, Dallas D. Reilly, Cyrena M. Parker, Jason M. Lonergan, Timothy J. Johnson. Quantitative Microstructural Characterization of Plutonium Oxalate Auto‐Degradation and Evidence for PuO 2 Nanocrystal Formation. European Journal of Inorganic Chemistry 2021, 2021 (32) , 3277-3291. https://doi.org/10.1002/ejic.202100511
88. Shanmugam Revathi, Preethi Raja, Sayantani Saha, Moris S. Eisen, Tapas Ghatak. Recent developments in highly basic N-heterocyclic iminato ligands in actinide chemistry. Chemical Communications 2021, 57 (45) , 5483-5502. https://doi.org/10.1039/D1CC00933H
89. Alexander Mansel, Karsten Franke. Production of no-carrier-added 89Zr at an 18 MeV cyclotron, its purification and use in investigations in solvent extraction. Journal of Radioanalytical and Nuclear Chemistry 2021, 328 (1) , 419-423. https://doi.org/10.1007/s10967-021-07634-x
90. Henar Rojo, Xavier Gaona, Thomas Rabung, Robert Polly, Miguel García-Gutiérrez, Tiziana Missana, Marcus Altmaier. Complexation of Nd(III)/Cm(III) with gluconate in alkaline NaCl and CaCl2 solutions: Solubility, TRLFS and DFT studies. Applied Geochemistry 2021, 126 , 104864. https://doi.org/10.1016/j.apgeochem.2020.104864
91. Alexander V. Boyarintsev, Sergey A. Perevalov, Sergey I. Stepanov, Alexander M. Chekmarev. Liquid–liquid extraction of neptunium(VI) and neptunium(V) from carbonate solutions by methyltrioctylammonium carbonate in toluene. Journal of Radioanalytical and Nuclear Chemistry 2021, 327 (1) , 385-393. https://doi.org/10.1007/s10967-020-07487-w
92. Sascha T. Löffler, Karsten Meyer. Actinides. 2021, 471-521. https://doi.org/10.1016/B978-0-12-409547-2.14754-7
93. Yilong Hua, Donghan Li, Tianhang Gu, Wei Wang, Ruofan Li, Jianping Yang, Wei-xian Zhang. Enrichment of Uranium from Aqueous Solutions with Nanoscale Zero-valent Iron: Surface Chemistry and Application Prospect. Acta Chimica Sinica 2021, 79 (8) , 1008. https://doi.org/10.6023/A21040160
94. Xue Dong, Hong Cao, Lei Xu, Zhipeng Wang, Jing Chen, Chao Xu. Advances in Environmental Coordination Chemistry of Np and Pu with Inorganic Anions in Aqueous Solution. Acta Chimica Sinica 2021, 79 (12) , 1415. https://doi.org/10.6023/A21080380
95. Sergio Pérez-Conesa, José M. Martínez, Rafael R. Pappalardo, Enrique Sánchez Marcos. Combining EXAFS and Computer Simulations to Refine the Structural Description of Actinyls in Water. Molecules 2020, 25 (22) , 5250. https://doi.org/10.3390/molecules25225250
96. Éva Böszörményi, Jorge Lado, Csilla Dudás, Bence Kutus, Márton Szabados, Gábor Varga, István Pálinkó, Pál Sipos. The structure and composition of solid complexes comprising of Nd(III), Ca(II) and D-gluconate isolated from solutions relevant to radioactive waste disposal. Pure and Applied Chemistry 2020, 92 (10) , 1709-1715. https://doi.org/10.1515/pac-2019-1010
97. Wansik Cha, Hee-Kyung Kim, Hyejin Cho, Hye-Ryun Cho, Euo Chang Jung, Seung Yeop Lee. Studies of aqueous U( iv ) equilibrium and nanoparticle formation kinetics using spectrophotometric reaction modeling analysis. RSC Advances 2020, 10 (60) , 36723-36733. https://doi.org/10.1039/D0RA05352J
98. Shanli Yang, Yingru Li, Shaofei Wang, Jingsong Xu, Lang Shao, Tao Gai, Hao Tang, Yiming Ren, Mingfu Chu, Bianyuan Xia. A novel synthesis of graphene quantum dots via thermal treatment of crude graphite oxide in a dry and alkaline condition, and their application in uranyl detection. Heliyon 2020, 6 (9) , e04533. https://doi.org/10.1016/j.heliyon.2020.e04533
99. Johannes Lützenkirchen, Gopala Krishna Darbha, Venkata Sai Kiran Chakravadhanula, Engelbert Redel, Atiđa Selmani, Lionel Vayssières. Interaction of Polyoxometalates and Nanoparticles with Collector Surfaces—Focus on the Use of Streaming Current Measurements at Flat Surfaces. Colloids and Interfaces 2020, 4 (3) , 39. https://doi.org/10.3390/colloids4030039
100. Josef T. Boronski, Stephen T. Liddle. The Emergence of Actinide Cyclobutadienyl Chemistry. European Journal of Inorganic Chemistry 2020, 2020 (30) , 2851-2861. https://doi.org/10.1002/ejic.202000383