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Metal-Catalyzed Living Radical Polymerization

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Department of Polymer Chemistry, Graduate School of Engineering, Kyoto University, Kyoto 606-8501, Japan
Cite this: Chem. Rev. 2001, 101, 12, 3689–3746
Publication Date (Web):December 12, 2001
https://doi.org/10.1021/cr9901182
Copyright © 2001 American Chemical Society

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    76. Timothy J. Zerk and Paul V. Bernhardt . Organo-Copper(II) Complexes as Products of Radical Atom Transfer. Inorganic Chemistry 2017, 56 (10) , 5784-5792. https://doi.org/10.1021/acs.inorgchem.7b00402
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    78. Hans Wolfgang Spiess . 50th Anniversary Perspective: The Importance of NMR Spectroscopy to Macromolecular Science. Macromolecules 2017, 50 (5) , 1761-1777. https://doi.org/10.1021/acs.macromol.6b02736
    79. Chern-Hooi Lim, Matthew D. Ryan, Blaine G. McCarthy, Jordan C. Theriot, Steven M. Sartor, Niels H. Damrauer, Charles B. Musgrave, and Garret M. Miyake . Intramolecular Charge Transfer and Ion Pairing in N,N-Diaryl Dihydrophenazine Photoredox Catalysts for Efficient Organocatalyzed Atom Transfer Radical Polymerization. Journal of the American Chemical Society 2017, 139 (1) , 348-355. https://doi.org/10.1021/jacs.6b11022
    80. Atsushi Yasumoto, Hiroaki Gotoh, Yoshie Gotoh, Abu Bin Imran, Mitsuo Hara, Takahiro Seki, Yasuhiro Sakai, Kohzo Ito, and Yukikazu Takeoka . Highly Responsive Hydrogel Prepared Using Poly(N-isopropylacrylamide)-Grafted Polyrotaxane as a Building Block Designed by Reversible Deactivation Radical Polymerization and Click Chemistry. Macromolecules 2017, 50 (1) , 364-374. https://doi.org/10.1021/acs.macromol.6b01955
    81. Sunirmal Pal, William L. A. Brooks, Daniel J. Dobbins, and Brent S. Sumerlin . Employing a Sugar-Derived Dimethacrylate to Evaluate Controlled Branch Growth during Polymerization with Multiolefinic Compounds. Macromolecules 2016, 49 (24) , 9396-9405. https://doi.org/10.1021/acs.macromol.6b02079
    82. Marco Fantin, Sangwoo Park, Yi Wang, and Krzysztof Matyjaszewski . Electrochemical Atom Transfer Radical Polymerization in Miniemulsion with a Dual Catalytic System. Macromolecules 2016, 49 (23) , 8838-8847. https://doi.org/10.1021/acs.macromol.6b02037
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    86. Andrit Allushi, Steffen Jockusch, Gorkem Yilmaz, and Yusuf Yagci . Photoinitiated Metal-Free Controlled/Living Radical Polymerization Using Polynuclear Aromatic Hydrocarbons. Macromolecules 2016, 49 (20) , 7785-7792. https://doi.org/10.1021/acs.macromol.6b01752
    87. Jifu Wang, Liang Yuan, Zhongkai Wang, Md Anisur Rahman, Yucheng Huang, Tianyu Zhu, Ruibo Wang, Jianjun Cheng, Chunpeng Wang, Fuxiang Chu, and Chuanbing Tang . Photoinduced Metal-Free Atom Transfer Radical Polymerization of Biomass-Based Monomers. Macromolecules 2016, 49 (20) , 7709-7717. https://doi.org/10.1021/acs.macromol.6b01997
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    89. Ming Yan, Julian C. Lo, Jacob T. Edwards, and Phil S. Baran . Radicals: Reactive Intermediates with Translational Potential. Journal of the American Chemical Society 2016, 138 (39) , 12692-12714. https://doi.org/10.1021/jacs.6b08856
    90. Timothy J. Zerk, Manuel Martinez, and Paul V. Bernhardt . A Kinetico-Mechanistic Study on CuII Deactivators Employed in Atom Transfer Radical Polymerization. Inorganic Chemistry 2016, 55 (19) , 9848-9857. https://doi.org/10.1021/acs.inorgchem.6b01700
    91. Stéphanie Boissé, Maksym A. Kryuchkov, Nguyen-Dung Tien, C. Géraldine Bazuin, and Robert E. Prud’homme . PLLA Crystallization in Linear AB and BAB Copolymers of l-Lactide and 2-Dimethylaminoethyl Methacrylate. Macromolecules 2016, 49 (18) , 6973-6986. https://doi.org/10.1021/acs.macromol.6b01139
    92. Sajjad Dadashi-Silab, Sean Doran, and Yusuf Yagci . Photoinduced Electron Transfer Reactions for Macromolecular Syntheses. Chemical Reviews 2016, 116 (17) , 10212-10275. https://doi.org/10.1021/acs.chemrev.5b00586
    93. Mao Chen, Mingjiang Zhong, and Jeremiah A. Johnson . Light-Controlled Radical Polymerization: Mechanisms, Methods, and Applications. Chemical Reviews 2016, 116 (17) , 10167-10211. https://doi.org/10.1021/acs.chemrev.5b00671
    94. Xiaofeng Wang, Yi Shi, Robert W. Graff, Xiaosong Cao, and Haifeng Gao . Synthesis of Hyperbranched Polymers with High Molecular Weight in the Homopolymerization of Polymerizable Trithiocarbonate Transfer Agent without Thermal Initiator. Macromolecules 2016, 49 (17) , 6471-6479. https://doi.org/10.1021/acs.macromol.6b00994
    95. Manuela Hollering, Martin Albrecht, and Fritz E. Kühn . Bonding and Catalytic Application of Ruthenium N-Heterocyclic Carbene Complexes Featuring Triazole, Triazolylidene, and Imidazolylidene Ligands. Organometallics 2016, 35 (17) , 2980-2986. https://doi.org/10.1021/acs.organomet.6b00504
    96. Ryan M. Pearson, Chern-Hooi Lim, Blaine G. McCarthy, Charles B. Musgrave, and Garret M. Miyake . Organocatalyzed Atom Transfer Radical Polymerization Using N-Aryl Phenoxazines as Photoredox Catalysts. Journal of the American Chemical Society 2016, 138 (35) , 11399-11407. https://doi.org/10.1021/jacs.6b08068
    97. Jennifer Collins, Kristian Kempe, Paul Wilson, Claudia A. Blindauer, Michelle P. McIntosh, Thomas P. Davis, Michael R. Whittaker, and David M. Haddleton . Stability Enhancing N-Terminal PEGylation of Oxytocin Exploiting Different Polymer Architectures and Conjugation Approaches. Biomacromolecules 2016, 17 (8) , 2755-2766. https://doi.org/10.1021/acs.biomac.6b00919
    98. Makoto Tanabe, Shunsuke Iwase, and Kohtaro Osakada . Nickel(0)-Catalyzed Polycondensation of Silafluorene: Control over Molecular Weight and Polymer Growth Mechanism. Organometallics 2016, 35 (15) , 2557-2562. https://doi.org/10.1021/acs.organomet.6b00459
    99. Arah Cho, Yunju La, Tae Joo Shin, Chiyoung Park, and Kyoung Taek Kim . Structural Requirements of Block Copolymers for Self-Assembly into Inverse Bicontinuous Cubic Mesophases in Solution. Macromolecules 2016, 49 (12) , 4510-4519. https://doi.org/10.1021/acs.macromol.6b00762
    100. Jing M. Ren, Thomas G. McKenzie, Qiang Fu, Edgar H. H. Wong, Jiangtao Xu, Zesheng An, Sivaprakash Shanmugam, Thomas P. Davis, Cyrille Boyer, and Greg G. Qiao . Star Polymers. Chemical Reviews 2016, 116 (12) , 6743-6836. https://doi.org/10.1021/acs.chemrev.6b00008
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