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    Proxies and Measurement Techniques for Mineral Dust in Antarctic Ice Cores
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    Alfred-Wegener-Institute for Polar and Marine Research, Bremerhaven, Germany, Department of Environmental Sciences, University of Venice, Venice, Italy, Climate and Environmental Physics, Physics Institute, University of Bern, Bern, Switzerland, Centre for Ice and Climate, Niels Bohr Institute, University of Copenhagen, Denmark, Department of Environmental Sciences, University of Milano Biccoca, Italy, School of Earth Sciences and Byrd Polar Research Center, Ohio State University, Columbus, Ohio, Department of Chemistry, University of Florence, Florence, Italy, Laboratoire de Glaciologie et Géophysique de l’Environnement, CNRS, Grenoble, France, Institut für Umweltphysik, University of Heidelberg, Heidelberg, Germany, and British Antarctic Survey, Cambridge, United Kingdom
    * Corresponding author e-mail: [email protected]. Also at: Climate Analysis and Consulting, Germany.
    †Alfred-Wegener-Institute for Polar and Marine Research.
    ‡University of Venice.
    §University of Bern.
    ∥University of Copenhagen.
    ⊥University of Milano Biccoca.
    #Ohio State University.
    ∇University of Florence.
    ○CNRS.
    ◆University of Heidelberg.
    ¶British Antarctic Survey.
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    Environmental Science & Technology

    Cite this: Environ. Sci. Technol. 2008, 42, 15, 5675–5681
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    https://doi.org/10.1021/es703078z
    Published July 2, 2008
    Copyright © 2008 American Chemical Society
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    Abstract

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    To improve quantitative interpretation of ice core aeolian dust records, a systematic methodological comparison was made. This involved methods for water-insoluble particle counting (Coulter counter and laser-sensing particle detector), soluble ion analysis (ion chromatography and continuous flow analysis), elemental analysis (inductively coupled plasma mass spectroscopy at pH 1 and after full acid digestion), and water-insoluble elemental analysis (proton induced X-ray emission). Antarctic ice core samples covering the last deglaciation from the EPICA Dome C (EDC) and the EPICA Dronning Maud Land (EDML) cores were used. All methods correlate very well among each other, but the ratios of glacial age to Holocene concentrations, which are typically a factor ∼100, differ between the methods by up to a factor of 2 with insoluble particles showing the largest variability. The recovery of ICP-MS measurements depends on the digestion method and is different for different elements and during different climatic periods. EDC and EDML samples have similar dust composition, which suggests a common dust source or a common mixture of sources for the two sites. The analyzed samples further reveal a change of dust composition during the last deglaciation.

    Copyright © 2008 American Chemical Society

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    Cite this: Environ. Sci. Technol. 2008, 42, 15, 5675–5681
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