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Synthesis of Ln(III) Chloride Tetraphenylporphyrin Complexes
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    Synthesis of Ln(III) Chloride Tetraphenylporphyrin Complexes
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    Department of Chemistry and Center for Catalysis, University of Florida, Gainesville, Florida 32611-7200
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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2002, 41, 7, 1704–1706
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    https://doi.org/10.1021/ic015612e
    Published March 12, 2002
    Copyright © 2002 American Chemical Society

    Abstract

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    The isolation and identification of the first examples of anhydrous lanthanide chloride tetraphenylporphyrin complexes have been described. The purple complexes were generated by the reaction of dilithiotetraphenylporphyrin bis(dimethoxyethane) with lanthanide trichloride tris(tetrahydrofuran) salts to yield the products in up to 85% yield. The crystal structures for the holmium and ytterbium complexes are also presented.

    Copyright © 2002 American Chemical Society

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     Author to whom correspondence should be addressed. E-mail:  [email protected].

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    Cited By

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    This article is cited by 24 publications.

    1. Anas Santria, Akira Fuyuhiro, Takamitsu Fukuda, and Naoto Ishikawa . Synthesis of a Series of Heavy Lanthanide(III) Monoporphyrinato Complexes with Tetragonal Symmetry. Inorganic Chemistry 2017, 56 (17) , 10625-10632. https://doi.org/10.1021/acs.inorgchem.7b01546
    2. Meng-Sheng Liao,, John D. Watts, and, Ming-Ju Huang. DFT/TDDFT Study of LanthanideIII Mono- and Bisporphyrin Complexes. The Journal of Physical Chemistry A 2006, 110 (48) , 13089-13098. https://doi.org/10.1021/jp0632236
    3. Steven A. Schuetz,, Carter M. Silvernail,, Christopher D. Incarvito,, Arnold L. Rheingold,, Joanna L. Clark,, Victor W. Day, and, John A. Belot. Mononuclear, Five-Coordinate Lanthanide Amido and Aryloxide Complexes Bearing Tetradentate (N2O2) Schiff Bases. Inorganic Chemistry 2004, 43 (20) , 6203-6214. https://doi.org/10.1021/ic040006f
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    12. Eui-Jong Kim, Pyosang Kim, Chi-Hwa Lee, Jooyoung Sung, Hongsik Yoon, Dongho Kim, Woo-Dong Jang. Synthesis of stable monoporphyrinate lanthanide(iii) complexes without ancillary ligands. Chemical Communications 2012, 48 (45) , 5611. https://doi.org/10.1039/c2cc31015e
    13. Xunjin Zhu, Wai‐Kwok Wong, Wai‐Yeung Wong, Xiaoping Yang. Design and Synthesis of Near‐Infrared Emissive Lanthanide Complexes Based on Macrocyclic Ligands. European Journal of Inorganic Chemistry 2011, 2011 (30) , 4651-4674. https://doi.org/10.1002/ejic.201100481
    14. Xiao Ling Cui, Xin Ming Shi, Shi You Li. Synthesis and Properties of Novel Asymmetrical Porphyrin with [p-(4-Flourobenzoyloxy)-M-Ethyloxy]phenyl and its Lanthanide Complexes. Advanced Materials Research 2011, 308-310 , 643-646. https://doi.org/10.4028/www.scientific.net/AMR.308-310.643
    15. Kohji Suda, Toshikatsu Takanami, Shin-ichiro Nakajima, Shoichi Nakadai, Fumio Hino. Highly Regioselective Rearrangement of 2,3-Diaryloxiranes into 2,2-Diarylacetaldehydes Catalyzed by Ytterbium Porphyrin Complex, Yb(TPP)OTf. HETEROCYCLES 2009, 77 (1) , 365. https://doi.org/10.3987/COM-08-S(F)27
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    18. Xiao Ling Cui, Miao Yu, Guo Fa Liu. Unsymmetrical Porphyrin and Its Two Groups of Lanthanide Complexes: Synthesis, Spectroscopy, and Thermal Analysis. Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry 2005, 35 (10) , 785-793. https://doi.org/10.1080/15533170500360461
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    21. T.‐S. Kang, B.S. Harrison, T.J. Foley, A.S. Knefely, J.M. Boncella, J.R. Reynolds, K.S. Schanze. Near‐Infrared Electroluminescence from Lanthanide Tetraphenylporphyrin:Polystyrene Blends. Advanced Materials 2003, 15 (13) , 1093-1097. https://doi.org/10.1002/adma.200304692
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    24. Haiyan Ma, Thomas P. Spaniol, Jun Okuda. Rare earth metal complexes supported by 1,ω-dithiaalkanediyl-bridged bis(phenolato) ligands: synthesis, characterization and ring-opening polymerization catalysis of l -lactide. Dalton Trans. 2003, 231 (24) , 4770-4780. https://doi.org/10.1039/B311604B

    Inorganic Chemistry

    Cite this: Inorg. Chem. 2002, 41, 7, 1704–1706
    Click to copy citationCitation copied!
    https://doi.org/10.1021/ic015612e
    Published March 12, 2002
    Copyright © 2002 American Chemical Society

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