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Synthesis of Ln(III) Chloride Tetraphenylporphyrin Complexes

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    Synthesis of Ln(III) Chloride Tetraphenylporphyrin Complexes
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    Department of Chemistry and Center for Catalysis, University of Florida, Gainesville, Florida 32611-7200
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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2002, 41, 7, 1704–1706
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    https://doi.org/10.1021/ic015612e
    Published March 12, 2002
    Copyright © 2002 American Chemical Society
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    Abstract

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    The isolation and identification of the first examples of anhydrous lanthanide chloride tetraphenylporphyrin complexes have been described. The purple complexes were generated by the reaction of dilithiotetraphenylporphyrin bis(dimethoxyethane) with lanthanide trichloride tris(tetrahydrofuran) salts to yield the products in up to 85% yield. The crystal structures for the holmium and ytterbium complexes are also presented.

    Copyright © 2002 American Chemical Society

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    Cited By

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    This article is cited by 24 publications.

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    19. Simon A. Cotton. Scandium, Yttrium & the Lanthanides: Inorganic & Coordination Chemistry. 2005https://doi.org/10.1002/9781119951438.eibc0195
    20. Simon A. Cotton. Scandium, Yttrium & the Lanthanides: Inorganic & Coordination Chemistry. 2005https://doi.org/10.1002/0470862106.ia211
    21. T.‐S. Kang, B.S. Harrison, T.J. Foley, A.S. Knefely, J.M. Boncella, J.R. Reynolds, K.S. Schanze. Near‐Infrared Electroluminescence from Lanthanide Tetraphenylporphyrin:Polystyrene Blends. Advanced Materials 2003, 15 (13) , 1093-1097. https://doi.org/10.1002/adma.200304692
    22. S. Cotton. Scandium, Yttrium, and the Lanthanides. 2003, 93-188. https://doi.org/10.1016/B0-08-043748-6/02004-1
    23. S. A. Cotton. 17  Scandium, yttrium, the lanthanides and the actinides. Annu. Rep. Prog. Chem., Sect. A: Inorg. Chem. 2003, 99 , 263-287. https://doi.org/10.1039/B211485M
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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2002, 41, 7, 1704–1706
    Click to copy citationCitation copied!
    https://doi.org/10.1021/ic015612e
    Published March 12, 2002
    Copyright © 2002 American Chemical Society
    Request reuse permissions

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