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A Tetranuclear CrIIINiII3 Cyano-Bridged Complex Based on M(tacn) Derivative Building Blocks
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    A Tetranuclear CrIIINiII3 Cyano-Bridged Complex Based on M(tacn) Derivative Building Blocks
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    Laboratoire de Chimie Inorganique, ICMMO, CNRS UMR 8613, Université Paris-Sud, 91405 Orsay, France, and Laboratoire Louis Néel, CNRS, 25 Avenue des Martyrs, BP166, 38042 Grenoble, Cedex 9, France
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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2005, 44, 23, 8194–8196
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    https://doi.org/10.1021/ic0514391
    Published October 11, 2005
    Copyright © 2005 American Chemical Society

    Abstract

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    The reaction of Cr(Bztacn)(CN)3 (Bztacn is 1,4,7-trisbenzyl-1,4,7-triazacyclononane) with Ni(iPrtacn)Cl2 (iPrtacn is 1,4,7-trisisopropyl-1,4,7-triazacyclononane) affords a CrNi3 tetranuclear complex. Variable temperature and magnetization versus field measurements show a S = 9/2 ground state and an appreciable magnetic anisotropy with a negative D9/2 value equal to −0.54 cm-1. Magnetization studies on one single crystal using a micro-SQUID show a fast tunneling process at zero field at very low temperature.

    Copyright © 2005 American Chemical Society

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     Laboratoire de Chimie Inorganique, ICMMO, CNRS UMR 8613.

     Laboratoire Louis Néel, CNRS.

    *

     To whom correspondence should be addressed. E-mail:  [email protected].

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    X-ray data for 1 in CIF format and Figures S1−S4. This material is available free of charge via the Internet at http://pubs.acs.org.

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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2005, 44, 23, 8194–8196
    Click to copy citationCitation copied!
    https://doi.org/10.1021/ic0514391
    Published October 11, 2005
    Copyright © 2005 American Chemical Society

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