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Organotin Chalcogenide Salts: Synthesis, Characterization, and Extended Crystal Structures

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    Organotin Chalcogenide Salts: Synthesis, Characterization, and Extended Crystal Structures
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    Fachbereich Chemie and Wissenschaftliches Zentrum für Materialwissenschaften (WZMW), Philipps-Universität Marburg, Hans-Meerwein-Strasse, 35043 Marburg, Germany
    *To whom correspondence should be addressed. Tel.: 00496421-2825751. Fax: 00496421-2825653. E-mail: [email protected]
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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2010, 49, 12, 5748–5752
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    https://doi.org/10.1021/ic100700f
    Published May 27, 2010
    Copyright © 2010 American Chemical Society
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    Abstract

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    Reactions of Cl3SnR1H with Na2E (E = Se, Te; R1 = C2H4COO) in liquid ammonia afforded the salts of an anionic defect heterocubane, [(RSn)3Se4]− (R = R1 and R1H) or an ∞1[(R1Sn)2Te32−] anionic polymer, respectively. Although a reaction using a 1:1.5 ratio of Cl3SnR1H:Na2S·9H2O in acetone/water produced a compound containing [(R1Sn)3S4]2−, a 1:2 ratio leads to the formation of ∞1[(R1Sn)2S32−], isostructural to the homologous Te species.

    Copyright © 2010 American Chemical Society

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    CIF files for 1−4. Details on crystal structure refinement, atom labeling scheme (PDF). This material is available free of charge via the Internet at http://pubs.acs.org.

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    This article is cited by 24 publications.

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    3. Eliza Leusmann, Felix Schneck, and Stefanie Dehnen . Functionalization of Sn/S Clusters with Hetero- and Polyaromatics. Organometallics 2015, 34 (13) , 3264-3271. https://doi.org/10.1021/acs.organomet.5b00295
    4. Yumei Lin and Stefanie Dehnen . [BMIm]4[Sn9Se20]: Ionothermal Synthesis of a Selenidostannate with a 3D Open-Framework Structure. Inorganic Chemistry 2011, 50 (17) , 7913-7915. https://doi.org/10.1021/ic200697k
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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2010, 49, 12, 5748–5752
    Click to copy citationCitation copied!
    https://doi.org/10.1021/ic100700f
    Published May 27, 2010
    Copyright © 2010 American Chemical Society
    Request reuse permissions

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