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Isoreticular Expansion of Metal–Organic Frameworks with Triangular and Square Building Units and the Lowest Calculated Density for Porous Crystals

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    Isoreticular Expansion of Metal–Organic Frameworks with Triangular and Square Building Units and the Lowest Calculated Density for Porous Crystals
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    † Center for Reticular Chemistry, Center for Global Mentoring, UCLA-DOE Institute for Genomics and Proteomics, and Department of Chemistry and Biochemistry, University of California−Los Angeles, 607 East Charles E. Young Drive, Los Angeles, California 90095, United States
    ‡ Department of Chemistry, Soongsil University, 511 Sangdo-Dong, Dongjak-Gu, Seoul 156-743, Korea
    § NanoCentury KI and Graduate School of EEWS (WCU), Korea Advanced Institute of Science and Technology (KAIST), Daejeon 305-701, Korea
    E-mail: [email protected]
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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2011, 50, 18, 9147–9152
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    https://doi.org/10.1021/ic201376t
    Published August 15, 2011
    Copyright © 2011 American Chemical Society
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    Abstract

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    The concept and occurrence of isoreticular (same topology) series of metal–organic frameworks (MOFs) is reviewed. We describe the preparation, characterization, and crystal structures of three new MOFs that are isoreticular expansions of known materials with the tbo (Cu3(4,4′,4″-(benzene-1,3,5-triyl-tris(benzene-4,1-diyl))tribenzoate)2, MOF-399) and pto topologies (Cu3(4,4′,4″-(benzene-1,3,5-triyl-tribenzoate)2, MOF-143; Cu3(4,4′,4″-(triazine-2,4,6-triyl-tris(benzene-4,1-diyl))tribenzoate)2, MOF-388). One of these materials (MOF-399) has a unit cell volume 17 times larger than that of the first reported material isoreticular to it, and has the highest porosity (94%) and lowest density (0.126 g cm–3) of any MOFs reported to date.

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    Supporting Information

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    Synthesis of H3TAPB link, single-crystal X-ray, and powder X-ray diffraction details, 1H NMR analyses of digested MOFs, TGA analyses, and crystallographic data in CIF format. This material is available free of charge via the Internet at http://pubs.acs.org.

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    Cite this: Inorg. Chem. 2011, 50, 18, 9147–9152
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    Published August 15, 2011
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