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μ-O Bridged Mn10 Assemblies with Open O6 Sites for Binding Extra Guests: Structural, Magnetic, and Surface Studies

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    μ-O Bridged Mn10 Assemblies with Open O6 Sites for Binding Extra Guests: Structural, Magnetic, and Surface Studies
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    † Department of Chemistry, Memorial University, St. John’s, NL, A1B 3X7, Canada
    ‡ Department of Physics, Faculty of Science, University of Dhaka, Dhaka-1000, Bangladesh
    *E-mail: [email protected]
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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2012, 51, 21, 11241–11250
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    https://doi.org/10.1021/ic3003355
    Published March 29, 2012
    Copyright © 2012 American Chemical Society
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    Abstract

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    High nuclearity [Mn10M2] clusters have been achieved through a self-assembly approach where multiple coordinating functional groups are incorporated into one ligand. When the hydrazone group appended with an oxime function as a reactive intermediate is used, the attachment of a vanillin subunit creates a ligand (L4) with three coordinating groups, which in their own right lead to cluster assemblies. The trifunctional ligand L4 produces a series of self-assembled, mixed oxidation state (Mn(II)/Mn(III)) Mn10M2 based clusters with an overall linear structure comprising two connected pentanuclear Mn5 halves, which bind alkali metal cations (M = Li, Na, K, Rb, Cs) and H3O+ in the vanillin (O6) end pockets, created by the assembly of three ligands around each Mn5 subunit. Antiferromagnetic exchange dominates the spin coupling in the Mn10 complexes, and surface studies on highly oriented pyrolytic graphite (HOPG) clearly show the arrangement of metal ions (Mn, Cs) in the Mn10Cs2 linear cluster assembly.

    Copyright © 2012 American Chemical Society

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    Further details are given in Figures S1–S2 and Tables S1–S5. This material is available free of charge via the Internet at http://pubs.acs.org.

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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2012, 51, 21, 11241–11250
    Click to copy citationCitation copied!
    https://doi.org/10.1021/ic3003355
    Published March 29, 2012
    Copyright © 2012 American Chemical Society
    Request reuse permissions

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