ACS Publications. Most Trusted. Most Cited. Most Read
Cyclopentadienyl–Silsesquioxane Titanium Complexes: Highly Active Catalysts for Epoxidation of Alkenes with Aqueous Hydrogen Peroxide

OR SEARCH CITATIONS

My Activity
Publications

Figure 1Loading Img
Download Hi-Res ImageDownload to MS-PowerPointCite This:Inorg. Chem. 2012, 51, 11, 6345-6349
    Article

    Cyclopentadienyl–Silsesquioxane Titanium Complexes: Highly Active Catalysts for Epoxidation of Alkenes with Aqueous Hydrogen Peroxide
    Click to copy article linkArticle link copied!

    View Author Information
    † Departamento de Química Inorgánica, Universidad de Alcalá, Campus Universitario, 28871 Alcalá de Henares, Spain
    ‡ Instituto de Tecnologia Química e Biológica, Universidade Nova de Lisboa Av. de República, EAN, 2780-417 Oeiras, Portugal
    §Correspondence concerning the crystallography data should be addressed to this author. E-mail: [email protected]
    *Tel.: 34918854767 (G.J.), 34918854655 (T.C.). Fax: 34 918854683. E-mail: [email protected] (G.J.), [email protected] (T.C.).
    Other Access OptionsSupporting Information (1)

    Inorganic Chemistry

    Cite this: Inorg. Chem. 2012, 51, 11, 6345–6349
    Click to copy citationCitation copied!
    https://doi.org/10.1021/ic300583g
    Published May 17, 2012
    Copyright © 2012 American Chemical Society
    Request reuse permissions

    Abstract

    Click to copy section linkSection link copied!
    Abstract Image

    Titanium complexes bearing an unprecedented tridentate cyclopentadienyl–silsesquioxanate ligand provide a new class of efficient and selective catalysts for epoxidation of olefins with aqueous hydrogen peroxide under homogeneous conditions.

    Copyright © 2012 American Chemical Society

    Subjects

    what are subjects

    Read this article

    To access this article, please review the available access options below.

    Get instant access

    Purchase Access

    Read this article for 48 hours. Check out below using your ACS ID or as a guest.

    Recommended

    Access through Your Institution

    You may have access to this article through your institution.

    Your institution does not have access to this content. Add or change your institution or let them know you’d like them to include access.

    Supporting Information

    Click to copy section linkSection link copied!

    Tables of crystallographic data, including fractional coordinates, bond lengths and angles, anisotropic displacement parameters, and hydrogen atom coordinates in CIF format of complex 3a. 1H and 1H–29Si HMBC spectra for 3a, 3b, and the mixture of 3a and 4a and chromatograms. This material is available free of charge via the Internet at http://pubs.acs.org.

    Terms & Conditions

    Most electronic Supporting Information files are available without a subscription to ACS Web Editions. Such files may be downloaded by article for research use (if there is a public use license linked to the relevant article, that license may permit other uses). Permission may be obtained from ACS for other uses through requests via the RightsLink permission system: http://pubs.acs.org/page/copyright/permissions.html.

    Cited By

    Click to copy section linkSection link copied!
    Citation Statements
    Explore this article's citation statements on scite.ai
    powered by  Scite

    This article is cited by 25 publications.

    1. Irene Reviejo, Joan Vinueza, Javier Ramos, Marta E. G. Mosquera, Vanessa Tabernero, Gerardo Jiménez. Stereospecific Synthesis of Chiral Titanium Complexes Bearing a Bifunctionalized Cyclopentadienyl-Terpenoid Ligand Derived from α-Pinene. Organometallics 2021, 40 (17) , 3076-3086. https://doi.org/10.1021/acs.organomet.1c00421
    2. Kinga Stefanowska, Jakub Szyling, Jędrzej Walkowiak, Adrian Franczyk. Alkenyl-Functionalized Open-Cage Silsesquioxanes (RSiMe2O)3R′7Si7O9: A Novel Class of Building Nanoblocks. Inorganic Chemistry 2021, 60 (15) , 11006-11013. https://doi.org/10.1021/acs.inorgchem.1c00689
    3. Michael R. Gau, Michael J. Zdilla. Multinuclear Clusters of Manganese and Lithium with Silsesquioxane-Derived Ligands: Synthesis and Ligand Rearrangement by Dioxygen- and Base-Mediated Si–O Bond Cleavage. Inorganic Chemistry 2021, 60 (5) , 2866-2871. https://doi.org/10.1021/acs.inorgchem.0c03225
    4. Irene Reviejo, Vanessa Tabernero, Marta E. G. Mosquera, Javier Ramos, Tomás Cuenca, Gerardo Jiménez. Chiral Titanium(IV) Complexes Containing Polydentate Ligands Based on α-Pinene. Catalytic Activity in Sulfoxidation with Hydrogen Peroxide. Organometallics 2018, 37 (20) , 3437-3449. https://doi.org/10.1021/acs.organomet.8b00163
    5. Gulzar A. Bhat, Sonam Verma, Antony Rajendran, Ramaswamy Murugavel. Thermolabile Organotitanium Monoalkyl Phosphates: Synthesis, Structures, and Utility as Epoxidation Catalysts and Single-Source Precursors for TiP2O7. Inorganic Chemistry 2018, 57 (13) , 7644-7654. https://doi.org/10.1021/acs.inorgchem.8b00611
    6. Pascal Guillo, Michael I. Lipschutz, Meg E. Fasulo, and T. Don Tilley . Tantalum–Polyhedral Oligosilsesquioxane Complexes as Structural Models and Functional Catalysts for Epoxidation. ACS Catalysis 2017, 7 (4) , 2303-2312. https://doi.org/10.1021/acscatal.7b00020
    7. Sónia Barroso, Filipe Madeira, Maria José Calhorda, M. João Ferreira, M. Teresa Duarte, and Ana M. Martins . Toward the Understanding of Radical Reactions: Experimental and Computational Studies of Titanium(III) Diamine Bis(phenolate) Complexes. Inorganic Chemistry 2013, 52 (16) , 9427-9439. https://doi.org/10.1021/ic401008y
    8. Thapakorn Jaroentomeechai, Pa-kwan Yingsukkamol, Chuttree Phurat, Ekasith Somsook, Tanakorn Osotchan, and Vuthichai Ervithayasuporn . Synthesis and Reactivity of Nitrogen Nucleophiles-Induced Cage-Rearrangement Silsesquioxanes. Inorganic Chemistry 2012, 51 (22) , 12266-12272. https://doi.org/10.1021/ic3015145
    9. Joan Vinueza-Vaca, Emma Franco-Mateo, Valentina Sessini, Marta E. G. Mosquera, Virginia Souza-Egipsy, Javier Ramos, Juan F. Vega, Gerardo Jiménez, Vanessa Tabernero. Titanium-catalyzed synthesis of polymyrcene and polyanethol and application as sustainable additives for poly(lactic acid). Polymer 2024, 290 , 126494. https://doi.org/10.1016/j.polymer.2023.126494
    10. Vitalii Libanov, Alevtina Kapustina, Nikolay Shapkin, Anna Tarabanova, Anna Rumina. Interaction of Polyphenylsilsesquioxane with Various β-Diketonate Complexes of Titanium by Mechanochemical Activation. Powders 2023, 2 (2) , 445-463. https://doi.org/10.3390/powders2020027
    11. Jiaxin Guo, Liyan Liao, Yibo Li, Jianxing Liang, Yalin Wang, Diwen Ying, Jinping Jia. Enhanced wastewater treatment via direct electrocatalytic activation of hydrogen peroxide in divided cells with flow-through electrode and bipolar membrane. Separation and Purification Technology 2022, 292 , 121030. https://doi.org/10.1016/j.seppur.2022.121030
    12. L.N. Grant, J.R. Aguilar-Calderón, D.J. Mindiola. Titanium. 2021, 97-161. https://doi.org/10.1016/B978-0-12-409547-2.14923-6
    13. María Mateos, Joan Vinueza, Marta E.G. Mosquera, Vanessa Tabernero, Tomás Cuenca, Gerardo Jiménez. Cyclopentadienyl-silsesquioxane titanium compounds as suitable candidates for immobilization on silica-based supports. Inorganica Chimica Acta 2020, 501 , 119275. https://doi.org/10.1016/j.ica.2019.119275
    14. Eike Dornsiepen, Eugenie Geringer, Niklas Rinn, Stefanie Dehnen. Coordination chemistry of organometallic or inorganic binary group 14/16 units towards d-block and f-block metal atoms. Coordination Chemistry Reviews 2019, 380 , 136-169. https://doi.org/10.1016/j.ccr.2018.09.001
    15. M. Carmen Maestre, Patricia B. Gratal, Marta E. G. Mosquera, Tomás Cuenca, Gerardo Jiménez. Suitable Approach to Prepare N‐Substituted Niobium Complexes – Study of the Factors Controlling the Process. European Journal of Inorganic Chemistry 2017, 2017 (7) , 1060-1066. https://doi.org/10.1002/ejic.201601360
    16. María Ventura, Vanessa Tabernero, Tomás Cuenca, Beatriz Royo, Gerardo Jiménez. Cyclopentadienyl–Silsesquioxane Titanium Catalysts: Factors Affecting Their Formation and Activity in Olefin Epoxidation with Aqueous Hydrogen Peroxide. European Journal of Inorganic Chemistry 2016, 2016 (17) , 2843-2849. https://doi.org/10.1002/ejic.201501474
    17. Vuthichai Ervithayasuporn, Kwanchanok Kwanplod, Jaursup Boonmak, Sujittra Youngme, Preeyanuch Sangtrirutnugul. Homogeneous and heterogeneous catalysts of organopalladium functionalized-polyhedral oligomeric silsesquioxanes for Suzuki–Miyaura reaction. Journal of Catalysis 2015, 332 , 62-69. https://doi.org/10.1016/j.jcat.2015.09.014
    18. Anuj K. Rathi, Manoj B. Gawande, Radek Zboril, Rajender S. Varma. Microwave-assisted synthesis – Catalytic applications in aqueous media. Coordination Chemistry Reviews 2015, 291 , 68-94. https://doi.org/10.1016/j.ccr.2015.01.011
    19. Lorena Postigo, Maria Ventura, Tomás Cuenca, Gerardo Jiménez, Beatriz Royo. Selective sulfoxidation with hydrogen peroxide catalysed by a titanium catalyst. Catalysis Science & Technology 2015, 5 (1) , 320-324. https://doi.org/10.1039/C4CY00965G
    20. M. Dutkiewicz, M. Szołyga, H. Maciejewski, B. Marciniec. Thiirane functional spherosilicate as epoxy resin modifier. Journal of Thermal Analysis and Calorimetry 2014, 117 (1) , 259-264. https://doi.org/10.1007/s10973-014-3725-3
    21. Chengguo Sun, Bingcheng Hu, Zuliang Liu. Efficient and ecofriendly options for the chemoselective oxidation of alkenes using manganese porphyrin and dioxygen. Chemical Engineering Journal 2013, 232 , 96-103. https://doi.org/10.1016/j.cej.2013.07.067
    22. Yolanda Pérez, Sandra Bázquez, Mariano Fajardo, Pilar de Frutos, Isabel del Hierro. Synthesis and characterization of homoleptic titanium bulky alkoxo complexes and their application in 1-octene epoxidation. Journal of Organometallic Chemistry 2013, 741-742 , 102-108. https://doi.org/10.1016/j.jorganchem.2013.05.029
    23. Pascal Guillo, Meg E. Fasulo, Michael I. Lipschutz, T. Don Tilley. Synthesis and characterization of tantalum silsesquioxane complexes. Dalton Transactions 2013, 42 (6) , 1991. https://doi.org/10.1039/c2dt32601a
    24. Shengtao Xu, Yu Zhou, Jinyi Xu, Hualiang Jiang, Hong Liu. Gold-catalyzed Michael addition/intramolecular annulation cascade: an effective pathway for the chemoselective- and regioselective synthesis of tetracyclic indole derivatives in water. Green Chemistry 2013, 15 (3) , 718. https://doi.org/10.1039/c2gc36301a
    25. V. Ervithayasuporn, N. Pornsamutsin, P. Prangyoo, K. Sammawutthichai, T. Jaroentomeechai, C. Phurat, T. Teerawatananond. One-pot synthesis of halogen exchanged silsesquioxanes: octakis(3-bromopropyl)octasilsesquioxane and octakis(3-iodopropyl)octasilsesquioxane. Dalton Transactions 2013, 42 (37) , 13747. https://doi.org/10.1039/c3dt51373d
    Download PDF
    Go to Inorganic Chemistry
    Get e-Alerts
    Get e-Alerts

    Inorganic Chemistry

    Cite this: Inorg. Chem. 2012, 51, 11, 6345–6349
    Click to copy citationCitation copied!
    https://doi.org/10.1021/ic300583g
    Published May 17, 2012
    Copyright © 2012 American Chemical Society
    Request reuse permissions

    Article Views

    874

    Altmetric

    -

    Citations

    25
    Learn about these metrics

    Article Views are the COUNTER-compliant sum of full text article downloads since November 2008 (both PDF and HTML) across all institutions and individuals. These metrics are regularly updated to reflect usage leading up to the last few days.

    Citations are the number of other articles citing this article, calculated by Crossref and updated daily. Find more information about Crossref citation counts.

    The Altmetric Attention Score is a quantitative measure of the attention that a research article has received online. Clicking on the donut icon will load a page at altmetric.com with additional details about the score and the social media presence for the given article. Find more information on the Altmetric Attention Score and how the score is calculated.