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Chiral Single-Chain Magnet: Helically Stacked [MnIII2CuII] Triangles

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    Chiral Single-Chain Magnet: Helically Stacked [MnIII2CuII] Triangles
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    † Graduate School of Pure and Applied Sciences, University of Tsukuba, Tennodai 1-1-1, Tsukuba, Ibaraki 305-8571, Japan
    ‡ EaStCHEM School of Chemistry, University of Edinburgh, West Mains Road, Edinburgh EH9 3JJ, U.K.
    *E-mail: [email protected]
    *E-mail: [email protected]
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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2014, 53, 9, 4272–4274
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    https://doi.org/10.1021/ic5002418
    Published April 17, 2014
    Copyright © 2014 American Chemical Society
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    Abstract

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    The one-dimensional complex [MnIII2CuII(μ3-O)(Cl-sao)3(EtOH)2]·EtOH (Mn2Cu) was obtained by the metal replacement reaction of the trinuclear manganese complex (Et3NH)[MnIII3(μ3-O)Cl2(Cl-sao)3(MeOH)2(H2O)2] with [Cu(acac)2]. The Mn2Cu chain exhibits single-chain-magnet behavior with finite-size effects due to its large magnetic anisotropy.

    Copyright © 2014 American Chemical Society

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    X-ray crystallographic data in CIF format, experimental procedures and supplementary magnetic data plots. This material is available free of charge via the Internet at http://pubs.acs.org.

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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2014, 53, 9, 4272–4274
    Click to copy citationCitation copied!
    https://doi.org/10.1021/ic5002418
    Published April 17, 2014
    Copyright © 2014 American Chemical Society
    Request reuse permissions

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