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Molecular CHEVREL-like Clusters [(RhPPh3)63-Se)8] and [Pd63-Te)8]4–

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Fachbereich Chemie and Wissenschaftliches Zentrum für Materialwissenschaften, Hans-Meerwein-Straße, 35043 Marburg, Germany
Cite this: Inorg. Chem. 2015, 54, 6, 2491–2493
Publication Date (Web):February 26, 2015
https://doi.org/10.1021/ic502409r
Copyright © 2015 American Chemical Society

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    Abstract

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    [(RhPPh3)63-Se)8]·0.5en (1; en = ethane-1,2-diamine), obtained by the reaction of [Pb2Se3]2– anions with [Rh(PPh3)3Cl] in en, represents the first compound comprising a molecular [Rh6] octahedron with all faces capped by Se atoms. Analogous treatment of [Pb2Te3]2– with [Pd(PPh3)2Cl2] yielded [Li4(en)10][Pd63-Te)8] (2), the first compound exhibiting a molecular, chalcogen-capped [Pd6] aggregate. Besides syntheses and structures of the title compounds, we report quantum-chemical calculations to understand the electronic properties of these molecular CHEVREL-like complexes.

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    X-ray crystallographic data in CIF format, crystal structure refinement details, energy-dispersive X-ray analysis results, cyclovoltammetric measurement results, and experimental details. This material is available free of charge via the Internet at http://pubs.acs.org.

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    1. Andrew Pinkard, Anouck M. Champsaur, Xavier Roy. Molecular Clusters: Nanoscale Building Blocks for Solid-State Materials. Accounts of Chemical Research 2018, 51 (4) , 919-929. https://doi.org/10.1021/acs.accounts.8b00016
    2. Anouck M. Champsaur, Alexandra Velian, Daniel W. Paley, Bonnie Choi, Xavier Roy, Michael L. Steigerwald, and Colin Nuckolls . Building Diatomic and Triatomic Superatom Molecules. Nano Letters 2016, 16 (8) , 5273-5277. https://doi.org/10.1021/acs.nanolett.6b02471
    3. Catherine E. Housecroft, Edwin C. Constable. Main group metal coordination chemistry. 2023, 19-117. https://doi.org/10.1016/B978-0-12-823144-9.00155-2
    4. Turbasu Sengupta, Shiv N. Khanna. Superatomic salts with controlled ionicity. Materials Advances 2022, 3 (9) , 4026-4036. https://doi.org/10.1039/D1MA01154E
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    6. Kerstin Mayer, Jana Weßing, Thomas F. Fässler, Roland A. Fischer. Intermetalloid Clusters: Molecules and Solids in a Dialogue. Angewandte Chemie International Edition 2018, 57 (44) , 14372-14393. https://doi.org/10.1002/anie.201805897
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    8. Günther Thiele, Silke Santner, Stefanie Dehnen. Crystalline chalcogenido metalates – synthetic approaches for materials synthesis and transformation. Zeitschrift für Kristallographie - Crystalline Materials 2017, 232 (1-3) , 47-54. https://doi.org/10.1515/zkri-2016-1976
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    11. Vimal K. Jain, Rohit Singh Chauhan. New vistas in the chemistry of platinum group metals with tellurium ligands. Coordination Chemistry Reviews 2016, 306 , 270-301. https://doi.org/10.1016/j.ccr.2015.07.009
    12. Günther Thiele, Yannick Franzke, Florian Weigend, Stefanie Dehnen. {μ‐PbSe}: A Heavy CO Homologue as an Unexpected Ligand. Angewandte Chemie International Edition 2015, 54 (38) , 11283-11288. https://doi.org/10.1002/anie.201504863
    13. Günther Thiele, Yannick Franzke, Florian Weigend, Stefanie Dehnen. μ‐PbSe: ein schweres CO‐Homolog als ungewöhnlicher Ligand. Angewandte Chemie 2015, 127 (38) , 11437-11442. https://doi.org/10.1002/ange.201504863
    14. Guenther Thiele, Zhiliang You, Stefanie Dehnen. ChemInform Abstract: Molecular CHEVREL‐Like Clusters [(RhPPh 3 ) 6 (μ 3 ‐Se) 8 ] and [Pd 6 (μ 3 ‐Te) 8 ] 4‐ .. ChemInform 2015, 46 (22) https://doi.org/10.1002/chin.201522020

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