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YF[MoO4] and YCl[MoO4]: Two Halide Derivatives of Yttrium ortho-Oxomolybdate: Syntheses, Structures, and Luminescence Properties

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    YF[MoO4] and YCl[MoO4]: Two Halide Derivatives of Yttrium ortho-Oxomolybdate: Syntheses, Structures, and Luminescence Properties
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    Institute for Inorganic Chemistry, Universität Stuttgart, Pfaffenwaldring 55, D-70569 Stuttgart Germany, Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523, and Department of Chemistry, Katholieke Universiteit Leuven, B-3000 Leuven, Belgium
    * To whom correspondence should be addressed. Fax: +49(0)711/685-64241. E-mail: [email protected]
    †Universität Stuttgart.
    ‡Colorado State University.
    §Katholieke Universiteit Leuven.
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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2008, 47, 9, 3728–3735
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    https://doi.org/10.1021/ic702350p
    Published April 3, 2008
    Copyright © 2008 American Chemical Society
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    Abstract

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    The halide derivatives of yttrium ortho-oxomolybdate YX[MoO4] (X = F, Cl) both crystallize in the monoclinic system with four formula units per unit cell. YF[MoO4] exhibits a primitive cell setting (space group P21/c; a = 519.62(2) pm, b = 1225.14(7) pm, c = 663.30(3) pm, β = 112.851(4)°), whereas the lattice of YCl[MoO4] shows face-centering (space group C2/m; a = 1019.02(5) pm, b = 720.67(4) pm, c = 681.50(3) pm, β = 107.130(4)°). The two compounds each contain crystallographically unique Y3+ cations, which are found to have a coordination environment of six oxide and two halide anions. In the case of YF[MoO4], the coordination environment is seen as square antiprisms, and for YCl[MoO4], trigon-dodecahedra are found. The discrete tetrahedral [MoO4]2− units of the fluoride derivative are exclusively bound by six terminal Y3+ cations, while those of the chloride compound show a 5-fold coordination around the tetrahedra with one edge-bridging and four terminal Y3+ cations. The halide anions in each compound exhibit a coordination number of two, building up isolated planar rhombus-shaped units according to [Y2F2]4+ in YF[MoO4] and [Y2Cl2]4+ in YCl[MoO4], respectively. Both compounds were synthesized at high temperatures using Y2O3, MoO3, and the corresponding yttrium trihalide in a molar ratio of 1:3:1. Single crystals of both are insensitive to moist air and are found to be coarse shaped and colorless with optical band gaps situated in the near UV around 3.78 eV for the fluoride and 3.82 eV for the chloride derivative. Furthermore, YF[MoO4] seems to be a suitable material for doping to obtain luminescent materials because the Eu3+-doped compound shows an intense red luminescence, which has been spectroscopically investigated.

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    Supporting Information

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    Crystallographic information files (CIFs), IR, and DRS spectra, as well as X-ray powder diffractograms of YF[MoO4] and YCl[MoO4]. This material is available free of charge via the Internet at http://pubs.acs.org.

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    29. Thomas Schleid, Sabine Strobel, Peter K. Dorhout, Peter Nockemann, Koen Binnemans, Ingo Hartenbach. ChemInform Abstract: YF[MoO 4 ] and YCl[MoO 4 ]: Two Halide Derivatives of Yttrium ortho‐Oxomolybdate: Syntheses, Structures, and Luminescence Properties.. ChemInform 2008, 39 (33) https://doi.org/10.1002/chin.200833022
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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2008, 47, 9, 3728–3735
    Click to copy citationCitation copied!
    https://doi.org/10.1021/ic702350p
    Published April 3, 2008
    Copyright © 2008 American Chemical Society
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