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    Confined Growth of Cyanide-Based Magnets in Two Dimensions
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    Universidad de Valencia (ICMol), Polígono de la Coma s/n, 46980 Paterna, Spain
    *To whom correspondence should be addressed. E-mail: [email protected]
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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2010, 49, 4, 1313–1315
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    https://doi.org/10.1021/ic902552t
    Published January 8, 2010
    Copyright © 2010 American Chemical Society
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    Abstract

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    Herein we report the first hybrid magnetic material resulting from the intercalation of a cyanide-based molecular magnet into a solid-state layered host. More specifically, the use of a diamagnetic cationic ZnII−AllII layered double hydroxide host allows for the formation of an anionic two-dimensional ferromagnetic NiII−CrIII Prussian Blue analogue, from the templated assembly of its ionic molecular components in the confined interlamellar space offered by the inorganic host.

    Copyright © 2010 American Chemical Society

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    Details concerning the synthesis, physical characterization, EDAX analysis, SEM images, FT-IR study, thermogravimetric analysis, and additional magnetic characterization of the compounds reported herein. This material is available free of charge via the Internet at http://pubs.acs.org.

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    Inorganic Chemistry

    Cite this: Inorg. Chem. 2010, 49, 4, 1313–1315
    Click to copy citationCitation copied!
    https://doi.org/10.1021/ic902552t
    Published January 8, 2010
    Copyright © 2010 American Chemical Society
    Request reuse permissions

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